# Ge–Mg phases

> Ge–Mg system: 6 phases (tier A 5, liquid 1); 4 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references.

HTML: https://data.orchid-project.org/phases/pages/GE-MG.html · Markdown: https://data.orchid-project.org/phases/pages/GE-MG.md

6 phases (tier A 5, liquid 1); 4 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: [interactive registry](https://orchid-project.org/phases/?q=GE-MG) · [full JSON](https://data.orchid-project.org/phases/systems/GE-MG.json) · [Ge–Mg system page](https://data.orchid-project.org/systems/GE-MG.html) · [Markdown](https://data.orchid-project.org/phases/pages/GE-MG.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md)

Table: Phases of the Ge–Mg system (6)

| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---:|---:|
| [DIAMOND_A4](#phase-ge-mg-a4-diamond); _phase:ge-mg:a4-diamond_ | C (diamond) · A4 · cF8 · Fd-3m (227) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–1211.4 K, x(Mg) 0–0 | 0 | 3 |
| [BCC_A2](#phase-ge-mg-bcc-a2); _phase:ge-mg:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | not stable in 3 calculated diagram(s) | 0 | 3 |
| [FCC_A1](#phase-ge-mg-fcc-a1); _phase:ge-mg:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | not stable in 3 calculated diagram(s) | 0 | 3 |
| [GEMG2_C1](#phase-ge-mg-gemg2-c1); _phase:ge-mg:gemg2-c1_ | CaF2 · C1 · cF12 · Fm-3m (225) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–1390.96 K, x(Mg) 0.66667–0.66667 | 0 | 3 |
| [HCP_A3](#phase-ge-mg-hcp-a3); _phase:ge-mg:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–2499.89 K, x(Mg) 1–1 | 0 | 3 |
| [LIQUID](#phase-ge-mg-liquid); _phase:ge-mg:liquid_ | liquid | liquid | stable in 3 of 3 calculated diagram(s): 903.71–2500 K, x(Mg) 0–1 | 0 | 3 |

## DIAMOND_A4 (Ge–Mg)

- Id: `phase:ge-mg:a4-diamond`; status `assigned`
- Structure: C (diamond) · A4 · cF8 · Fd-3m (227); type `st:a4-c-diamond-cf8`; tier A: standard phase name; confidence high
- Stoichiometry: Ge 1.0000
- Stability: stable in 3 of 3 calculated diagram(s): 300–1211.4 K, x(Mg) 0–0
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:a4-diamond)

Names (4): _corpus: _corpus:phase:ge-mg:a4-diamond  
_tdb: _tdb:GeMg-06Isl.tdb:DIAMOND_A4, tdb:GeMg-10Yan-1.tdb:DIAMOND_A4, tdb:GeMg-10Yan-2.tdb:DIAMOND_A4  


### TDB models of DIAMOND_A4 (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): DIAMOND_A4, type code %, sha256 `8081df690d59d028…`

~~~~text
42: PHASE DIAMOND_A4 % 1 1 !
43: CONST DIAMOND_A4 : GE : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): DIAMOND_A4, type code %, sha256 `22c07581734a5757…`

~~~~text
47: PHASE DIAMOND_A4 % 1 1 !
48: CONST DIAMOND_A4 : GE : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): DIAMOND_A4, type code %, sha256 `12570a7d080460a4…`

~~~~text
49: PHASE DIAMOND_A4 % 1 1 !
50: CONST DIAMOND_A4 : GE : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## BCC_A2 (Ge–Mg)

- Id: `phase:ge-mg:bcc-a2`; status `assigned`
- Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high
- Stability: not stable in 3 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:bcc-a2)

Names (4): _corpus: _corpus:phase:ge-mg:bcc-a2  
_tdb: _tdb:GeMg-06Isl.tdb:BCC_A2, tdb:GeMg-10Yan-1.tdb:BCC_A2, tdb:GeMg-10Yan-2.tdb:BCC_A2  


### TDB models of BCC_A2 (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): BCC_A2, type code %B, sha256 `8081df690d59d028…`

~~~~text
32: PHASE BCC_A2 %B 2 1 3 !
33: CONST BCC_A2 : GE MG : VA : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): BCC_A2, type code %B, sha256 `22c07581734a5757…`

~~~~text
37: PHASE BCC_A2 %B 2 1 3 !
38: CONST BCC_A2 : GE MG : VA : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): BCC_A2, type code %B, sha256 `12570a7d080460a4…`

~~~~text
39: PHASE BCC_A2 %B 2 1 3 !
40: CONST BCC_A2 : GE MG : VA : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## FCC_A1 (Ge–Mg)

- Id: `phase:ge-mg:fcc-a1`; status `assigned`
- Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high
- Stability: not stable in 3 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:fcc-a1)

Names (4): _corpus: _corpus:phase:ge-mg:fcc-a1  
_tdb: _tdb:GeMg-06Isl.tdb:FCC_A1, tdb:GeMg-10Yan-1.tdb:FCC_A1, tdb:GeMg-10Yan-2.tdb:FCC_A1  


### TDB models of FCC_A1 (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): FCC_A1, type code %A, sha256 `8081df690d59d028…`

~~~~text
27: PHASE FCC_A1 %A 2 1 1 !
28: CONST FCC_A1 : GE MG : VA : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): FCC_A1, type code %A, sha256 `22c07581734a5757…`

~~~~text
32: PHASE FCC_A1 %A 2 1 1 !
33: CONST FCC_A1 : GE MG : VA : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): FCC_A1, type code %A, sha256 `12570a7d080460a4…`

~~~~text
34: PHASE FCC_A1 %A 2 1 1 !
35: CONST FCC_A1 : GE MG : VA : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## GEMG2_C1 (Ge–Mg)

- Id: `phase:ge-mg:gemg2-c1`; status `assigned`
- Structure: CaF2 · C1 · cF12 · Fm-3m (225); type `st:c1-caf2-cf12`; tier A: standard phase name; confidence high
- Caveat: DFT agrees: on-hull mp-aaaaaaps and oqmd-646873, space group 225
- Stoichiometry: Ge 0.3333, Mg 0.6667
- Stability: stable in 3 of 3 calculated diagram(s): 300–1390.96 K, x(Mg) 0.66667–0.66667
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:gemg2-c1)

Names (6): _corpus: _corpus:phase:ge-mg:gemg2-c1  
_mp: _mp:mp-aaaaaaps  
_oqmd: _oqmd:oqmd-646873  
_tdb: _tdb:GeMg-06Isl.tdb:GEMG2_C1, tdb:GeMg-10Yan-1.tdb:GEMG2_C1, tdb:GeMg-10Yan-2.tdb:GEMG2_C1  


### TDB models of GEMG2_C1 (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): GEMG2_C1, type code %, sha256 `8081df690d59d028…`

~~~~text
47: PHASE GEMG2_C1 % 2 1 2 !
48: CONST GEMG2_C1 : GE : MG : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): GEMG2_C1, type code %, sha256 `22c07581734a5757…`

~~~~text
52: PHASE GEMG2_C1 % 2 1 2 !
53: CONST GEMG2_C1 : GE : MG : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): GEMG2_C1, type code %, sha256 `12570a7d080460a4…`

~~~~text
54: PHASE GEMG2_C1 % 2 1 2 !
55: CONST GEMG2_C1 : GE : MG : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## HCP_A3 (Ge–Mg)

- Id: `phase:ge-mg:hcp-a3`; status `assigned`
- Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high
- Stability: stable in 3 of 3 calculated diagram(s): 300–2499.89 K, x(Mg) 1–1
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:hcp-a3)

Names (4): _corpus: _corpus:phase:ge-mg:hcp-a3  
_tdb: _tdb:GeMg-06Isl.tdb:HCP_A3, tdb:GeMg-10Yan-1.tdb:HCP_A3, tdb:GeMg-10Yan-2.tdb:HCP_A3  


### TDB models of HCP_A3 (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): HCP_A3, type code %, sha256 `8081df690d59d028…`

~~~~text
37: PHASE HCP_A3 % 2 1 0.5 !
38: CONST HCP_A3 : GE MG% : VA : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): HCP_A3, type code %A, sha256 `22c07581734a5757…`

~~~~text
42: PHASE HCP_A3 %A 2 1 0.5 !
43: CONST HCP_A3 : GE MG% : VA : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): HCP_A3, type code %A, sha256 `12570a7d080460a4…`

~~~~text
44: PHASE HCP_A3 %A 2 1 0.5 !
45: CONST HCP_A3 : GE MG% : VA : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## LIQUID (Ge–Mg)

- Id: `phase:ge-mg:liquid`; status `assigned`
- Structure: liquid; type `st:liquid`; liquid; confidence high
- Stability: stable in 3 of 3 calculated diagram(s): 903.71–2500 K, x(Mg) 0–1
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:ge-mg:liquid)

Names (4): _corpus: _corpus:phase:ge-mg:liquid  
_tdb: _tdb:GeMg-06Isl.tdb:LIQUID, tdb:GeMg-10Yan-1.tdb:LIQUID, tdb:GeMg-10Yan-2.tdb:LIQUID  


### TDB models of LIQUID (3): PHASE and CONSTITUENT statements as written

[GeMg-06Isl.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-06Isl.tdb): LIQUID, type code %, sha256 `8081df690d59d028…`

~~~~text
22: PHASE LIQUID:L % 1 1 !
23: CONST LIQUID:L : GE MG : !
~~~~

[GeMg-10Yan-1.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-1.tdb): LIQUID, type code %, sha256 `22c07581734a5757…`

~~~~text
27: PHASE LIQUID:L % 1 1 !
28: CONST LIQUID:L : GE MG : !
~~~~

[GeMg-10Yan-2.tdb](https://orchid-project.org/data/databases/sgte-binary/GeMg-10Yan-2.tdb): LIQUID, type code %, sha256 `12570a7d080460a4…`

~~~~text
29: PHASE LIQUID:L % 1 1 !
30: CONST LIQUID:L : GE GEMG2 MG : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1016/j.jallcom.2006.01.050](https://doi.org/10.1016/j.jallcom.2006.01.050) F. Islam, A.K. Thykadavil, M. Medraj, A computational thermodynamic model of the Mg–Al–Ge system, Journal of Alloys and Compounds 425, 129-139 (2006).  
_assessment that models this phase_
- [doi:10.3139/146.110436](https://doi.org/10.3139/146.110436) H. Yan, Y. Du, L. Zhou, H. Xu, L. Zhang, S. Liu, Int. J. Mater. Res., 101, 1489-96(2010).  
_assessment that models this phase_

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).
