Ge–Sb phases
6 phases (tier A 5, liquid 1); 3 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).
Data: interactive registry · full JSON · Ge–Sb system page · Markdown · field reference
| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---|---|
| DIAMOND_A4 phase:ge-sb:a4-diamond | C (diamond) · A4 · cF8 · Fd-3m (227) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–1211.4 K, x(Sb) 0–0.00031 | 7 | 4 |
| RHOMBOHEDRAL_A7 phase:ge-sb:a7-rhombohedral | alpha-As · A7 · hR2 · R-3m (166) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–1428.78 K, x(Sb) 0.93753–1 | 7 | 4 |
| BCC_A2 phase:ge-sb:bcc-a2 | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | not stable in 4 calculated diagram(s) | 0 | 4 |
| FCC_A1 phase:ge-sb:fcc-a1 | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | not stable in 4 calculated diagram(s) | 0 | 4 |
| HCP_A3 phase:ge-sb:hcp-a3 | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | not stable in 4 calculated diagram(s) | 0 | 4 |
| LIQUID phase:ge-sb:liquid | liquid | liquid | stable in 4 of 4 calculated diagram(s): 854.35–2500 K, x(Sb) 0–1 | 12 | 4 |
DIAMOND_A4 (Ge–Sb)
- Id:
phase:ge-sb:a4-diamond; statusassigned - Structure: C (diamond) · A4 · cF8 · Fd-3m (227); type
st:a4-c-diamond-cf8; tier A: standard phase name; confidence high - Stability: stable in 4 of 4 calculated diagram(s): 300–1211.4 K, x(Sb) 0–0.00031
- Literature: 7 values (7 accepted) from 1 papers
- Interactive: phase registry entry
Names (7): corpus: corpus:phase:ge-sb:a4-diamond, corpus:phase:ge-sb:diamond-a4
paper: paper:10.1016/j.tca.2011.03.008:diamond
tdb: tdb:GeSb-09Wan.tdb:DIAMOND_A4, tdb:GeSb-11Liu.tdb:DIAMOND_A4, tdb:GeSb-89Che-LB.tdb:DIAMOND_A4, tdb:GeSb-99Sch.tdb:DIAMOND_A4
TDB models of DIAMOND_A4 (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: DIAMOND_A4, type code %, sha256 dea266b7c521d694…
39: PHASE DIAMOND_A4 % 1 1 ! 40: CONST DIAMOND_A4 : GE% SB : !
GeSb-11Liu.tdb: DIAMOND_A4, type code %, sha256 de4f32c2b1c6e2c2…
39: PHASE DIAMOND_A4 % 1 1 ! 40: CONST DIAMOND_A4 : GE% SB : !
GeSb-89Che-LB.tdb: DIAMOND_A4, type code %, sha256 6f34fa372184c8f1…
44: PHASE DIAMOND_A4 % 1 1 ! 45: CONST DIAMOND_A4 : GE% SB : !
GeSb-99Sch.tdb: DIAMOND_A4, type code %, sha256 dd406e1392cfa749…
39: PHASE DIAMOND_A4 % 1 1 ! 40: CONST DIAMOND_A4 : GE% SB : !
Example references (8 of 8; assessments first):
- doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase; cited as the source of values for this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase; cited as the source of values for this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase - doi:10.1002/zaac.19402440211 Herbert Stöhr, Wilhelm Klemm, Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut, Z. Anorg. Allg. Chem. 244, 205-223 (1940).
cited as the source of values for this phase - doi:10.1007/bf02868990 R.W. Olesinski, G.J. Abbaschian, The Ge–Sb system, Bull. Alloy Phase Diagrams 7 (1986) 219–222.
cited as the source of values for this phase - doi:10.1016/j.jssc.2008.12.009 Navida Nasir, Andriy Grytsiv, Peter Rogl, Adriana Saccone, Gerald Giester, Phase equilibria in systems Ce–M–Sb (M=Si, Ge, Sn) and superstructure Ce12Ge9−xSb23+x (x=3.8±0.1), Journal of Solid State Chemistry 182, 645-656 (2009).
cited as the source of values for this phase - doi:10.1515/ijmr-1940-320302 K. Ruttewit, G. Masing, On the alloys of germanium with bismuth, antimony, iron and nickel, Z. Metallkd. 32 (1940) 52–61.
cited as the source of values for this phase
RHOMBOHEDRAL_A7 (Ge–Sb)
- Id:
phase:ge-sb:a7-rhombohedral; statusassigned - Structure: alpha-As · A7 · hR2 · R-3m (166); type
st:a7-alpha-as-hr2; tier A: standard phase name; confidence high - Stability: stable in 4 of 4 calculated diagram(s): 300–1428.78 K, x(Sb) 0.93753–1
- Literature: 7 values (7 accepted) from 1 papers
- Interactive: phase registry entry
Names (7): corpus: corpus:phase:ge-sb:a7-rhombohedral, corpus:phase:ge-sb:rhombohedral-a7
paper: paper:10.1016/j.tca.2011.03.008:rhom
tdb: tdb:GeSb-09Wan.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-11Liu.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-89Che-LB.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-99Sch.tdb:RHOMBOHEDRAL_A7
TDB models of RHOMBOHEDRAL_A7 (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: RHOMBOHEDRAL_A7, type code %, sha256 dea266b7c521d694…
44: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 45: CONST RHOMBOHEDRAL_A7 : GE SB% : !
GeSb-11Liu.tdb: RHOMBOHEDRAL_A7, type code %, sha256 de4f32c2b1c6e2c2…
44: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 45: CONST RHOMBOHEDRAL_A7 : GE SB% : !
GeSb-89Che-LB.tdb: RHOMBOHEDRAL_A7, type code %, sha256 6f34fa372184c8f1…
49: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 50: CONST RHOMBOHEDRAL_A7 : GE SB% : !
GeSb-99Sch.tdb: RHOMBOHEDRAL_A7, type code %, sha256 dd406e1392cfa749…
44: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 45: CONST RHOMBOHEDRAL_A7 : SB : !
Example references (8 of 8; assessments first):
- doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase; cited as the source of values for this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase; cited as the source of values for this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase - doi:10.1002/zaac.19402440211 Herbert Stöhr, Wilhelm Klemm, Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut, Z. Anorg. Allg. Chem. 244, 205-223 (1940).
cited as the source of values for this phase - doi:10.1007/bf02868990 R.W. Olesinski, G.J. Abbaschian, The Ge–Sb system, Bull. Alloy Phase Diagrams 7 (1986) 219–222.
cited as the source of values for this phase - doi:10.1016/j.jssc.2008.12.009 Navida Nasir, Andriy Grytsiv, Peter Rogl, Adriana Saccone, Gerald Giester, Phase equilibria in systems Ce–M–Sb (M=Si, Ge, Sn) and superstructure Ce12Ge9−xSb23+x (x=3.8±0.1), Journal of Solid State Chemistry 182, 645-656 (2009).
cited as the source of values for this phase - doi:10.1515/ijmr-1940-320302 K. Ruttewit, G. Masing, On the alloys of germanium with bismuth, antimony, iron and nickel, Z. Metallkd. 32 (1940) 52–61.
cited as the source of values for this phase
BCC_A2 (Ge–Sb)
- Id:
phase:ge-sb:bcc-a2; statusassigned - Structure: W · A2 · cI2 · Im-3m (229); type
st:a2-w-ci2; tier A: standard phase name; confidence high - Stability: not stable in 4 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:ge-sb:bcc-a2
tdb: tdb:GeSb-09Wan.tdb:BCC_A2, tdb:GeSb-11Liu.tdb:BCC_A2, tdb:GeSb-89Che-LB.tdb:BCC_A2, tdb:GeSb-99Sch.tdb:BCC_A2
TDB models of BCC_A2 (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: BCC_A2, type code %, sha256 dea266b7c521d694…
29: PHASE BCC_A2 % 2 1 3 ! 30: CONST BCC_A2 : GE SB : VA : !
GeSb-11Liu.tdb: BCC_A2, type code %, sha256 de4f32c2b1c6e2c2…
29: PHASE BCC_A2 % 2 1 3 ! 30: CONST BCC_A2 : GE SB : VA : !
GeSb-89Che-LB.tdb: BCC_A2, type code %, sha256 6f34fa372184c8f1…
34: PHASE BCC_A2 % 2 1 3 ! 35: CONST BCC_A2 : GE SB : VA : !
GeSb-99Sch.tdb: BCC_A2, type code %, sha256 dd406e1392cfa749…
29: PHASE BCC_A2 % 2 1 3 ! 30: CONST BCC_A2 : GE SB : VA : !
Example references (4 of 4; assessments first):
- doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase - doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase
FCC_A1 (Ge–Sb)
- Id:
phase:ge-sb:fcc-a1; statusassigned - Structure: Cu · A1 · cF4 · Fm-3m (225); type
st:a1-cu-cf4; tier A: standard phase name; confidence high - Stability: not stable in 4 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:ge-sb:fcc-a1
tdb: tdb:GeSb-09Wan.tdb:FCC_A1, tdb:GeSb-11Liu.tdb:FCC_A1, tdb:GeSb-89Che-LB.tdb:FCC_A1, tdb:GeSb-99Sch.tdb:FCC_A1
TDB models of FCC_A1 (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: FCC_A1, type code %, sha256 dea266b7c521d694…
24: PHASE FCC_A1 % 2 1 1 ! 25: CONST FCC_A1 : GE SB : VA : !
GeSb-11Liu.tdb: FCC_A1, type code %, sha256 de4f32c2b1c6e2c2…
24: PHASE FCC_A1 % 2 1 1 ! 25: CONST FCC_A1 : GE SB : VA : !
GeSb-89Che-LB.tdb: FCC_A1, type code %, sha256 6f34fa372184c8f1…
29: PHASE FCC_A1 % 2 1 1 ! 30: CONST FCC_A1 : GE SB : VA : !
GeSb-99Sch.tdb: FCC_A1, type code %, sha256 dd406e1392cfa749…
24: PHASE FCC_A1 % 2 1 1 ! 25: CONST FCC_A1 : GE SB : VA : !
Example references (4 of 4; assessments first):
- doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase - doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase
HCP_A3 (Ge–Sb)
- Id:
phase:ge-sb:hcp-a3; statusassigned - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type
st:a3-mg-hp2; tier A: standard phase name; confidence high - Stability: not stable in 4 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:ge-sb:hcp-a3
tdb: tdb:GeSb-09Wan.tdb:HCP_A3, tdb:GeSb-11Liu.tdb:HCP_A3, tdb:GeSb-89Che-LB.tdb:HCP_A3, tdb:GeSb-99Sch.tdb:HCP_A3
TDB models of HCP_A3 (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: HCP_A3, type code %, sha256 dea266b7c521d694…
34: PHASE HCP_A3 % 2 1 0.5 ! 35: CONST HCP_A3 : GE SB : VA: !
GeSb-11Liu.tdb: HCP_A3, type code %, sha256 de4f32c2b1c6e2c2…
34: PHASE HCP_A3 % 2 1 0.5 ! 35: CONST HCP_A3 : GE SB : VA: !
GeSb-89Che-LB.tdb: HCP_A3, type code %, sha256 6f34fa372184c8f1…
39: PHASE HCP_A3 % 2 1 0.5 ! 40: CONST HCP_A3 : GE SB : VA: !
GeSb-99Sch.tdb: HCP_A3, type code %, sha256 dd406e1392cfa749…
34: PHASE HCP_A3 % 2 1 0.5 ! 35: CONST HCP_A3 : GE SB : VA: !
Example references (4 of 4; assessments first):
- doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase - doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase
LIQUID (Ge–Sb)
- Id:
phase:ge-sb:liquid; statusassigned - Structure: liquid; type
st:liquid; liquid; confidence high - Stability: stable in 4 of 4 calculated diagram(s): 854.35–2500 K, x(Sb) 0–1
- Literature: 12 values (12 accepted) from 2 papers
- Interactive: phase registry entry
Names (7): corpus: corpus:phase:ge-sb:liquid
paper: paper:10.1016/j.jallcom.2009.06.030:L, paper:10.1016/j.tca.2011.03.008:Liq.
tdb: tdb:GeSb-09Wan.tdb:LIQUID, tdb:GeSb-11Liu.tdb:LIQUID, tdb:GeSb-89Che-LB.tdb:LIQUID, tdb:GeSb-99Sch.tdb:LIQUID
TDB models of LIQUID (4): PHASE and CONSTITUENT statements as written
GeSb-09Wan.tdb: LIQUID, type code %, sha256 dea266b7c521d694…
19: PHASE LIQUID:L % 1 1 ! 20: CONST LIQUID:L : GE SB : !
GeSb-11Liu.tdb: LIQUID, type code %, sha256 de4f32c2b1c6e2c2…
19: PHASE LIQUID:L % 1 1 ! 20: CONST LIQUID:L : GE SB : !
GeSb-89Che-LB.tdb: LIQUID, type code %, sha256 6f34fa372184c8f1…
24: PHASE LIQUID:L % 1 1 ! 25: CONST LIQUID:L : GE SB : !
GeSb-99Sch.tdb: LIQUID, type code %, sha256 dd406e1392cfa749…
19: PHASE LIQUID:L % 1 1 ! 20: CONST LIQUID:L : GE SB : !
Example references (8 of 8; assessments first):
- doi:10.1016/j.tca.2011.03.008 Jinming Liu, Cuiping Guo, Changrong Li, Zhenmin Du, Thermodynamic optimization of the Ge–Sb and Ge–Sb–Sn systems, Thermochimica Acta 520, 38-47 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2009.06.030 J. Wang, C. Leinenbach, M. Roth, Thermodynamic description of the Au–Ge–Sb ternary system, Journal of Alloys and Compounds 485, 577-582 (2009).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/0040-6031(89)87148-5 Pierre-Yves Chewvalier, A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems, Thermochimica Acta 155, 227-240 (1989).
assessment that models this phase; cited as the source of values for this phase - doi:10.1515/ijmr-1999-900703 A. Schlieper, R. Blachnik, Z. Metallkd., 90, 475-85(1999).
assessment that models this phase - doi:10.1007/bf02868990 R.W. Olesinski, G.J. Abbaschian, The Ge–Sb system, Bull. Alloy Phase Diagrams 7 (1986) 219–222.
cited as the source of values for this phase - doi:10.1002/zaac.19402440211 Herbert Stöhr, Wilhelm Klemm, Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut, Z. Anorg. Allg. Chem. 244, 205-223 (1940).
cited as the source of values for this phase - doi:10.1016/j.jssc.2008.12.009 Navida Nasir, Andriy Grytsiv, Peter Rogl, Adriana Saccone, Gerald Giester, Phase equilibria in systems Ce–M–Sb (M=Si, Ge, Sn) and superstructure Ce12Ge9−xSb23+x (x=3.8±0.1), Journal of Solid State Chemistry 182, 645-656 (2009).
cited as the source of values for this phase - doi:10.1515/ijmr-1940-320302 K. Ruttewit, G. Masing, On the alloys of germanium with bismuth, antimony, iron and nickel, Z. Metallkd. 32 (1940) 52–61.
cited as the source of values for this phase