Ge–Sb phases

6 phases (tier A 5, liquid 1); 3 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Ge–Sb system page · Markdown · field reference

Phases of the Ge–Sb system (6)
PhaseStructureBasisStability (calculated)Literature valuesTDB models
DIAMOND_A4
phase:ge-sb:a4-diamond
C (diamond) · A4 · cF8 · Fd-3m (227)tier A: standard phase namestable in 4 of 4 calculated diagram(s): 300–1211.4 K, x(Sb) 0–0.0003174
RHOMBOHEDRAL_A7
phase:ge-sb:a7-rhombohedral
alpha-As · A7 · hR2 · R-3m (166)tier A: standard phase namestable in 4 of 4 calculated diagram(s): 300–1428.78 K, x(Sb) 0.93753–174
BCC_A2
phase:ge-sb:bcc-a2
W · A2 · cI2 · Im-3m (229)tier A: standard phase namenot stable in 4 calculated diagram(s)04
FCC_A1
phase:ge-sb:fcc-a1
Cu · A1 · cF4 · Fm-3m (225)tier A: standard phase namenot stable in 4 calculated diagram(s)04
HCP_A3
phase:ge-sb:hcp-a3
Mg · A3 · hP2 · P6_3/mmc (194)tier A: standard phase namenot stable in 4 calculated diagram(s)04
LIQUID
phase:ge-sb:liquid
liquidliquidstable in 4 of 4 calculated diagram(s): 854.35–2500 K, x(Sb) 0–1124

DIAMOND_A4 (Ge–Sb)

Names (7): corpus: corpus:phase:ge-sb:a4-diamond, corpus:phase:ge-sb:diamond-a4
paper: paper:10.1016/j.tca.2011.03.008:diamond
tdb: tdb:GeSb-09Wan.tdb:DIAMOND_A4, tdb:GeSb-11Liu.tdb:DIAMOND_A4, tdb:GeSb-89Che-LB.tdb:DIAMOND_A4, tdb:GeSb-99Sch.tdb:DIAMOND_A4

TDB models of DIAMOND_A4 (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: DIAMOND_A4, type code %, sha256 dea266b7c521d694…

39: PHASE DIAMOND_A4 % 1 1 !
40: CONST DIAMOND_A4 : GE% SB : !

GeSb-11Liu.tdb: DIAMOND_A4, type code %, sha256 de4f32c2b1c6e2c2…

39: PHASE DIAMOND_A4 % 1 1 !
40: CONST DIAMOND_A4 : GE% SB : !

GeSb-89Che-LB.tdb: DIAMOND_A4, type code %, sha256 6f34fa372184c8f1…

44: PHASE DIAMOND_A4 % 1 1 !
45: CONST DIAMOND_A4 : GE% SB : !

GeSb-99Sch.tdb: DIAMOND_A4, type code %, sha256 dd406e1392cfa749…

39: PHASE DIAMOND_A4 % 1 1 !
40: CONST DIAMOND_A4 : GE% SB : !

Example references (8 of 8; assessments first):

RHOMBOHEDRAL_A7 (Ge–Sb)

Names (7): corpus: corpus:phase:ge-sb:a7-rhombohedral, corpus:phase:ge-sb:rhombohedral-a7
paper: paper:10.1016/j.tca.2011.03.008:rhom
tdb: tdb:GeSb-09Wan.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-11Liu.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-89Che-LB.tdb:RHOMBOHEDRAL_A7, tdb:GeSb-99Sch.tdb:RHOMBOHEDRAL_A7

TDB models of RHOMBOHEDRAL_A7 (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: RHOMBOHEDRAL_A7, type code %, sha256 dea266b7c521d694…

44: PHASE RHOMBOHEDRAL_A7 % 1 1 !
45: CONST RHOMBOHEDRAL_A7 : GE SB% : !

GeSb-11Liu.tdb: RHOMBOHEDRAL_A7, type code %, sha256 de4f32c2b1c6e2c2…

44: PHASE RHOMBOHEDRAL_A7 % 1 1 !
45: CONST RHOMBOHEDRAL_A7 : GE SB% : !

GeSb-89Che-LB.tdb: RHOMBOHEDRAL_A7, type code %, sha256 6f34fa372184c8f1…

49: PHASE RHOMBOHEDRAL_A7 % 1 1 !
50: CONST RHOMBOHEDRAL_A7 : GE SB% : !

GeSb-99Sch.tdb: RHOMBOHEDRAL_A7, type code %, sha256 dd406e1392cfa749…

44: PHASE RHOMBOHEDRAL_A7 % 1 1 !
45: CONST RHOMBOHEDRAL_A7 : SB : !

Example references (8 of 8; assessments first):

BCC_A2 (Ge–Sb)

Names (5): corpus: corpus:phase:ge-sb:bcc-a2
tdb: tdb:GeSb-09Wan.tdb:BCC_A2, tdb:GeSb-11Liu.tdb:BCC_A2, tdb:GeSb-89Che-LB.tdb:BCC_A2, tdb:GeSb-99Sch.tdb:BCC_A2

TDB models of BCC_A2 (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: BCC_A2, type code %, sha256 dea266b7c521d694…

29: PHASE BCC_A2 % 2 1 3 !
30: CONST BCC_A2 : GE SB : VA : !

GeSb-11Liu.tdb: BCC_A2, type code %, sha256 de4f32c2b1c6e2c2…

29: PHASE BCC_A2 % 2 1 3 !
30: CONST BCC_A2 : GE SB : VA : !

GeSb-89Che-LB.tdb: BCC_A2, type code %, sha256 6f34fa372184c8f1…

34: PHASE BCC_A2 % 2 1 3 !
35: CONST BCC_A2 : GE SB : VA : !

GeSb-99Sch.tdb: BCC_A2, type code %, sha256 dd406e1392cfa749…

29: PHASE BCC_A2 % 2 1 3 !
30: CONST BCC_A2 : GE SB : VA : !

Example references (4 of 4; assessments first):

FCC_A1 (Ge–Sb)

Names (5): corpus: corpus:phase:ge-sb:fcc-a1
tdb: tdb:GeSb-09Wan.tdb:FCC_A1, tdb:GeSb-11Liu.tdb:FCC_A1, tdb:GeSb-89Che-LB.tdb:FCC_A1, tdb:GeSb-99Sch.tdb:FCC_A1

TDB models of FCC_A1 (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: FCC_A1, type code %, sha256 dea266b7c521d694…

24: PHASE FCC_A1 % 2 1 1 !
25: CONST FCC_A1 : GE SB : VA : !

GeSb-11Liu.tdb: FCC_A1, type code %, sha256 de4f32c2b1c6e2c2…

24: PHASE FCC_A1 % 2 1 1 !
25: CONST FCC_A1 : GE SB : VA : !

GeSb-89Che-LB.tdb: FCC_A1, type code %, sha256 6f34fa372184c8f1…

29: PHASE FCC_A1 % 2 1 1 !
30: CONST FCC_A1 : GE SB : VA : !

GeSb-99Sch.tdb: FCC_A1, type code %, sha256 dd406e1392cfa749…

24: PHASE FCC_A1 % 2 1 1 !
25: CONST FCC_A1 : GE SB : VA : !

Example references (4 of 4; assessments first):

HCP_A3 (Ge–Sb)

Names (5): corpus: corpus:phase:ge-sb:hcp-a3
tdb: tdb:GeSb-09Wan.tdb:HCP_A3, tdb:GeSb-11Liu.tdb:HCP_A3, tdb:GeSb-89Che-LB.tdb:HCP_A3, tdb:GeSb-99Sch.tdb:HCP_A3

TDB models of HCP_A3 (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: HCP_A3, type code %, sha256 dea266b7c521d694…

34: PHASE HCP_A3 % 2 1 0.5 !
35: CONST HCP_A3 : GE SB : VA: !

GeSb-11Liu.tdb: HCP_A3, type code %, sha256 de4f32c2b1c6e2c2…

34: PHASE HCP_A3 % 2 1 0.5 !
35: CONST HCP_A3 : GE SB : VA: !

GeSb-89Che-LB.tdb: HCP_A3, type code %, sha256 6f34fa372184c8f1…

39: PHASE HCP_A3 % 2 1 0.5 !
40: CONST HCP_A3 : GE SB : VA: !

GeSb-99Sch.tdb: HCP_A3, type code %, sha256 dd406e1392cfa749…

34: PHASE HCP_A3 % 2 1 0.5 !
35: CONST HCP_A3 : GE SB : VA: !

Example references (4 of 4; assessments first):

LIQUID (Ge–Sb)

Names (7): corpus: corpus:phase:ge-sb:liquid
paper: paper:10.1016/j.jallcom.2009.06.030:L, paper:10.1016/j.tca.2011.03.008:Liq.
tdb: tdb:GeSb-09Wan.tdb:LIQUID, tdb:GeSb-11Liu.tdb:LIQUID, tdb:GeSb-89Che-LB.tdb:LIQUID, tdb:GeSb-99Sch.tdb:LIQUID

TDB models of LIQUID (4): PHASE and CONSTITUENT statements as written

GeSb-09Wan.tdb: LIQUID, type code %, sha256 dea266b7c521d694…

19: PHASE LIQUID:L % 1 1 !
20: CONST LIQUID:L : GE SB : !

GeSb-11Liu.tdb: LIQUID, type code %, sha256 de4f32c2b1c6e2c2…

19: PHASE LIQUID:L % 1 1 !
20: CONST LIQUID:L : GE SB : !

GeSb-89Che-LB.tdb: LIQUID, type code %, sha256 6f34fa372184c8f1…

24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : GE SB : !

GeSb-99Sch.tdb: LIQUID, type code %, sha256 dd406e1392cfa749…

19: PHASE LIQUID:L % 1 1 !
20: CONST LIQUID:L : GE SB : !

Example references (8 of 8; assessments first):