Hf–V phases

5 phases (tier A 4, liquid 1); 4 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Hf–V system page · Markdown · field reference

Phases of the Hf–V system (5)
Phase	Structure	Basis	Stability (calculated)	Literature values	TDB models
BCC_A2 phase:hf-v:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–3999.24 K, x(V) 0–1	20	1
C15_LAVES phase:hf-v:c15-laves	Cu2Mg · C15 · cF24 · Fd-3m (227)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–1807.52 K, x(V) 0.64035–0.67472	26	1
FCC_A1 phase:hf-v:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	not stable in 1 calculated diagram(s)	0	1
HCP_A3 phase:hf-v:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–2191.02 K, x(V) 0–0.02651	7	1
LIQUID phase:hf-v:liquid	liquid	liquid	stable in 1 of 1 calculated diagram(s): 1733.12–4000 K, x(V) 0–1	23	1

BCC_A2 (Hf–V)

Id: phase:hf-v:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 300–3999.24 K, x(V) 0–1
Literature: 20 values (12 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:hf-v:bcc-a2
paper: paper:10.1361/15477030522464:bcc_A2
tdb: tdb:HfV-05Ser.tdb:BCC_A2

TDB models of BCC_A2 (1): PHASE and CONSTITUENT statements as written

HfV-05Ser.tdb: BCC_A2, type code %B, sha256 5eb8c7c45b64d39e…

34: PHASE BCC_A2 %B 2 1 3 !
35: CONST BCC_A2 : HF% V% : VA : !

Example references (2 of 2; assessments first):

doi:10.1361/15477030522464 C. Servant, Thermodynamic Assessments of the Phase Diagrams of the Hafnium-Vanadium and Vanadium-Zirconium Systems, Journal of Phase Equilibria & Diffusion 26, 39-49 (2005).
assessment that models this phase; reports values for this phase
doi:10.1016/0022-5088(68)90003-9 E. Rudy, St. Windisch, The phase diagrams hafnium-vanadium and hafnium-chromium, Journal of the Less Common Metals 15, 13-27 (1968).
cited as the source of values for this phase

C15_LAVES (Hf–V)

Id: phase:hf-v:c15-laves; status assigned
Structure: Cu2Mg · C15 · cF24 · Fd-3m (227); type st:c15-cu2mg-cf24; tier A: standard phase name; confidence high
Caveat: partitioned order/disorder model in HfV-05Ser.tdb also describes the disordered state
Stability: stable in 1 of 1 calculated diagram(s): 300–1807.52 K, x(V) 0.64035–0.67472
Literature: 26 values (16 accepted) from 1 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:hf-v:c15-laves
paper: paper:10.1361/15477030522464:C15 Laves, paper:10.1361/15477030522464:C15-Laves
tdb: tdb:HfV-05Ser.tdb:C15_LAVES

TDB models of C15_LAVES (1): PHASE and CONSTITUENT statements as written

HfV-05Ser.tdb: C15_LAVES, type code %, sha256 5eb8c7c45b64d39e…

44: PHASE C15_LAVES % 2 2 1 !
45: CONST C15_LAVES : HF V% : HF% V : !

Example references (2 of 2; assessments first):

doi:10.1361/15477030522464 C. Servant, Thermodynamic Assessments of the Phase Diagrams of the Hafnium-Vanadium and Vanadium-Zirconium Systems, Journal of Phase Equilibria & Diffusion 26, 39-49 (2005).
assessment that models this phase; reports values for this phase
doi:10.1016/0022-5088(68)90003-9 E. Rudy, St. Windisch, The phase diagrams hafnium-vanadium and hafnium-chromium, Journal of the Less Common Metals 15, 13-27 (1968).
cited as the source of values for this phase

FCC_A1 (Hf–V)

Id: phase:hf-v:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: not stable in 1 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:hf-v:fcc-a1
tdb: tdb:HfV-05Ser.tdb:FCC_A1

TDB models of FCC_A1 (1): PHASE and CONSTITUENT statements as written

HfV-05Ser.tdb: FCC_A1, type code %A, sha256 5eb8c7c45b64d39e…

29: PHASE FCC_A1 %A 2 1 1 !
30: CONST FCC_A1 : HF V : VA : !

Example references (1 of 1; assessments first):

doi:10.1361/15477030522464 C. Servant, Thermodynamic Assessments of the Phase Diagrams of the Hafnium-Vanadium and Vanadium-Zirconium Systems, Journal of Phase Equilibria & Diffusion 26, 39-49 (2005).
assessment that models this phase

HCP_A3 (Hf–V)

Id: phase:hf-v:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 300–2191.02 K, x(V) 0–0.02651
Literature: 7 values (4 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:hf-v:hcp-a3
paper: paper:10.1361/15477030522464:cph_A3
tdb: tdb:HfV-05Ser.tdb:HCP_A3

TDB models of HCP_A3 (1): PHASE and CONSTITUENT statements as written

HfV-05Ser.tdb: HCP_A3, type code %A, sha256 5eb8c7c45b64d39e…

39: PHASE HCP_A3 %A 2 1 0.5 !
40: CONST HCP_A3 : HF% V : VA : !

Example references (2 of 2; assessments first):

doi:10.1361/15477030522464 C. Servant, Thermodynamic Assessments of the Phase Diagrams of the Hafnium-Vanadium and Vanadium-Zirconium Systems, Journal of Phase Equilibria & Diffusion 26, 39-49 (2005).
assessment that models this phase; reports values for this phase
doi:10.1016/0022-5088(68)90003-9 E. Rudy, St. Windisch, The phase diagrams hafnium-vanadium and hafnium-chromium, Journal of the Less Common Metals 15, 13-27 (1968).
cited as the source of values for this phase

LIQUID (Hf–V)

Id: phase:hf-v:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 1733.12–4000 K, x(V) 0–1
Literature: 23 values (16 accepted) from 1 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:hf-v:liquid
paper: paper:10.1361/15477030522464:L, paper:10.1361/15477030522464:Liq, paper:10.1361/15477030522464:liquid
tdb: tdb:HfV-05Ser.tdb:LIQUID

TDB models of LIQUID (1): PHASE and CONSTITUENT statements as written

HfV-05Ser.tdb: LIQUID, type code %, sha256 5eb8c7c45b64d39e…

24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : HF V : !

Example references (2 of 2; assessments first):

doi:10.1361/15477030522464 C. Servant, Thermodynamic Assessments of the Phase Diagrams of the Hafnium-Vanadium and Vanadium-Zirconium Systems, Journal of Phase Equilibria & Diffusion 26, 39-49 (2005).
assessment that models this phase; reports values for this phase
doi:10.1016/0022-5088(68)90003-9 E. Rudy, St. Windisch, The phase diagrams hafnium-vanadium and hafnium-chromium, Journal of the Less Common Metals 15, 13-27 (1968).
cited as the source of values for this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}