La–Sb phases
10 phases (tier A 6, tier C 2, liquid 1, needs_review 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).
Data: interactive registry · full JSON · La–Sb system page · Markdown · field reference
| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---|---|
| RHOMBOHEDRAL_A7 phase:la-sb:a7-rhombohedral | alpha-As · A7 · hR2 · R-3m (166) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–903.78 K, x(Sb) 1–1 | 4 | 2 |
| BCC_A2 phase:la-sb:bcc-a2 | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 1134–1199 K, x(Sb) 0–0 | 0 | 2 |
| DHCP phase:la-sb:dhcp-a3 | alpha-La · A3' · hP4 · P6_3/mmc (194) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–550 K, x(Sb) 0–0 | 0 | 2 |
| FCC_A1 phase:la-sb:fcc-a1 | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 550–1134 K, x(Sb) 0–0 | 4 | 2 |
| HCP_A3 phase:la-sb:hcp-a3 | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | not stable in 2 calculated diagram(s) | 0 | 2 |
| LA2SB phase:la-sb:la2sb | La2Sb · tI12 · I4/mmm (139) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–1894.39 K, x(Sb) 0.33333–0.33333 | 12 | 2 |
| LA3SB2 phase:la-sb:la3sb2 | needs_review | stable in 2 of 2 calculated diagram(s): 300–2054.39 K, x(Sb) 0.4–0.4 | 10 | 2 | |
| LASB_B1 phase:la-sb:lasb-b1 | NaCl · B1 · cF8 · Fm-3m (225) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1819.26 K, x(Sb) 0.5–0.5 | 8 | 2 |
| LASB2 phase:la-sb:lasb2 | Sb2Sm · oC24 · Cmce (64) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–1382.8 K, x(Sb) 0.66667–0.66667 | 8 | 2 |
| LIQUID phase:la-sb:liquid | liquid | liquid | stable in 2 of 2 calculated diagram(s): 902.41–2500 K, x(Sb) 0–1 | 22 | 2 |
RHOMBOHEDRAL_A7 (La–Sb)
- Id:
phase:la-sb:a7-rhombohedral; statusassigned - Structure: alpha-As · A7 · hR2 · R-3m (166); type
st:a7-alpha-as-hr2; tier A: standard phase name; confidence high - Stoichiometry: Sb 1.0000
- Stability: stable in 2 of 2 calculated diagram(s): 300–903.78 K, x(Sb) 1–1
- Literature: 4 values (4 accepted) from 2 papers
- Interactive: phase registry entry
Names (6): corpus: corpus:phase:la-sb:a7-rhombohedral, corpus:phase:la-sb:rhombohedral-a7
paper: paper:10.1016/j.calphad.2012.01.002:(Sb), paper:10.1016/j.tca.2012.10.026:Rhomb(Sb)
tdb: tdb:LaSb-12Gao.tdb:RHOMBOHEDRAL_A7, tdb:LaSb-13Wan.tdb:RHOMBOHEDRAL_A7
TDB models of RHOMBOHEDRAL_A7 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: RHOMBOHEDRAL_A7, type code %, sha256 5689268b3e6623ac…
45: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 46: CONST RHOMBOHEDRAL_A7 : SB : !
LaSb-13Wan.tdb: RHOMBOHEDRAL_A7, type code %, sha256 301a2f87ebb4bfc1…
58: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 59: CONST RHOMBOHEDRAL_A7 : SB : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase
BCC_A2 (La–Sb)
- Id:
phase:la-sb:bcc-a2; statusassigned - Structure: W · A2 · cI2 · Im-3m (229); type
st:a2-w-ci2; tier A: standard phase name; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 1134–1199 K, x(Sb) 0–0
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:la-sb:bcc-a2
tdb: tdb:LaSb-12Gao.tdb:BCC_A2, tdb:LaSb-13Wan.tdb:BCC_A2
TDB models of BCC_A2 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: BCC_A2, type code %B, sha256 5689268b3e6623ac…
30: PHASE BCC_A2 %B 2 1 3 ! 31: CONST BCC_A2 : LA% SB : VA : !
LaSb-13Wan.tdb: BCC_A2, type code %B, sha256 301a2f87ebb4bfc1…
43: PHASE BCC_A2 %B 2 1 3 ! 44: CONST BCC_A2 : LA% SB : VA : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase
DHCP (La–Sb)
- Id:
phase:la-sb:dhcp-a3; statusassigned - Structure: alpha-La · A3' · hP4 · P6_3/mmc (194); type
st:a3-alpha-la-hp4; tier A: standard phase name; confidence high - Stoichiometry: La 1.0000
- Stability: stable in 2 of 2 calculated diagram(s): 300–550 K, x(Sb) 0–0
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:la-sb:dhcp-a3
tdb: tdb:LaSb-12Gao.tdb:DHCP, tdb:LaSb-13Wan.tdb:DHCP
TDB models of DHCP (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: DHCP, type code %, sha256 5689268b3e6623ac…
40: PHASE DHCP % 1 1 ! 41: CONST DHCP : LA : !
LaSb-13Wan.tdb: DHCP, type code %, sha256 301a2f87ebb4bfc1…
53: PHASE DHCP % 1 1 ! 54: CONST DHCP : LA : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase
FCC_A1 (La–Sb)
- Id:
phase:la-sb:fcc-a1; statusassigned - Structure: Cu · A1 · cF4 · Fm-3m (225); type
st:a1-cu-cf4; tier A: standard phase name; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 550–1134 K, x(Sb) 0–0
- Literature: 4 values (4 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:la-sb:fcc-a1
paper: paper:10.1016/j.calphad.2012.01.002:(β-La), paper:10.1016/j.tca.2012.10.026:Fcc.A1 (La)
tdb: tdb:LaSb-12Gao.tdb:FCC_A1, tdb:LaSb-13Wan.tdb:FCC_A1
TDB models of FCC_A1 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: FCC_A1, type code %A, sha256 5689268b3e6623ac…
25: PHASE FCC_A1 %A 2 1 1 ! 26: CONST FCC_A1 : LA% SB : VA : !
LaSb-13Wan.tdb: FCC_A1, type code %A, sha256 301a2f87ebb4bfc1…
38: PHASE FCC_A1 %A 2 1 1 ! 39: CONST FCC_A1 : LA% SB : VA : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase
HCP_A3 (La–Sb)
- Id:
phase:la-sb:hcp-a3; statusassigned - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type
st:a3-mg-hp2; tier A: standard phase name; confidence high - Stoichiometry: Sb 1.0000
- Stability: not stable in 2 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:la-sb:hcp-a3
tdb: tdb:LaSb-12Gao.tdb:HCP_A3, tdb:LaSb-13Wan.tdb:HCP_A3
TDB models of HCP_A3 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: HCP_A3, type code %A, sha256 5689268b3e6623ac…
35: PHASE HCP_A3 %A 2 1 0.5 ! 36: CONST HCP_A3 : SB : VA : !
LaSb-13Wan.tdb: HCP_A3, type code %A, sha256 301a2f87ebb4bfc1…
48: PHASE HCP_A3 %A 2 1 0.5 ! 49: CONST HCP_A3 : SB : VA : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase
LA2SB (La–Sb)
- Id:
phase:la-sb:la2sb; statusassigned - Structure: La2Sb · tI12 · I4/mmm (139); type
st:la2sb-ti12; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (dft_space_group_139_matches_7_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: La 0.6667, Sb 0.3333
- Stability: stable in 2 of 2 calculated diagram(s): 300–1894.39 K, x(Sb) 0.33333–0.33333
- Literature: 12 values (12 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:la-sb:la2sb
paper: paper:10.1016/j.calphad.2012.01.002:La2Sb, paper:10.1016/j.tca.2012.10.026:La2Sb
tdb: tdb:LaSb-12Gao.tdb:LA2SB, tdb:LaSb-13Wan.tdb:LA2SB
TDB models of LA2SB (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: LA2SB, type code %, sha256 5689268b3e6623ac…
50: PHASE LA2SB % 2 2 1 ! 51: CONST LA2SB : LA : SB : !
LaSb-13Wan.tdb: LA2SB, type code %, sha256 301a2f87ebb4bfc1…
63: PHASE LA2SB % 2 2 1 ! 64: CONST LA2SB : LA : SB : !
Example references (4 of 4; assessments first):
- doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase - doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(79)90115-2 G. Borzone, A. Borsese, A. Saccone, R. Ferro, Heats of formation of lanthanum-antimony alloys, Journal of the Less Common Metals 65, 253-262 (1979).
cited as the source of values for this phase - doi:10.1016/0022-5088(84)90320-5 C. Colinet, A. Pasturel, A. Percheron-Guégan, J.C. Achard, Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, Journal of the Less Common Metals 102, 239-249 (1984).
cited as the source of values for this phase
LA3SB2 (La–Sb)
- Id:
phase:la-sb:la3sb2; statusneeds_review - No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete
- Candidate (literature_printed): (La3Sb2) · ? — printed with a label mapped to this phase
- Candidate (sgte_mmc2): (La3Sb2) — Hallstedt 2025 mmc2 row for LA3SB2: La3Sb2
- Stoichiometry: La 0.6000, Sb 0.4000
- Stability: stable in 2 of 2 calculated diagram(s): 300–2054.39 K, x(Sb) 0.4–0.4
- Literature: 10 values (10 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:la-sb:la3sb2
paper: paper:10.1016/j.calphad.2012.01.002:La3Sb2, paper:10.1016/j.tca.2012.10.026:La3Sb2
tdb: tdb:LaSb-12Gao.tdb:LA3SB2, tdb:LaSb-13Wan.tdb:LA3SB2
TDB models of LA3SB2 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: LA3SB2, type code %, sha256 5689268b3e6623ac…
55: PHASE LA3SB2 % 2 3 2 ! 56: CONST LA3SB2 : LA : SB : !
LaSb-13Wan.tdb: LA3SB2, type code %, sha256 301a2f87ebb4bfc1…
68: PHASE LA3SB2 % 2 3 2 ! 69: CONST LA3SB2 : LA : SB : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase - doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase
LASB_B1 (La–Sb)
- Id:
phase:la-sb:lasb-b1; statusassigned - Structure: NaCl · B1 · cF8 · Fm-3m (225); type
st:b1-nacl-cf8; tier A: standard phase name; confidence high - Caveat: DFT agrees: on-hull mp-aaaaaboz and oqmd-646154, space group 225
- Stoichiometry: La 0.5000, Sb 0.5000
- Stability: stable in 2 of 2 calculated diagram(s): 300–1819.26 K, x(Sb) 0.5–0.5
- Literature: 8 values (8 accepted) from 2 papers
- Interactive: phase registry entry
Names (7): corpus: corpus:phase:la-sb:lasb-b1
mp: mp:mp-aaaaaboz
oqmd: oqmd:oqmd-646154
paper: paper:10.1016/j.calphad.2012.01.002:LaSb, paper:10.1016/j.tca.2012.10.026:LaSb
tdb: tdb:LaSb-12Gao.tdb:LASB_B1, tdb:LaSb-13Wan.tdb:LASB_B1
TDB models of LASB_B1 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: LASB_B1, type code %, sha256 5689268b3e6623ac…
60: PHASE LASB_B1 % 2 1 1 ! 61: CONST LASB_B1 : LA : SB : !
LaSb-13Wan.tdb: LASB_B1, type code %, sha256 301a2f87ebb4bfc1…
73: PHASE LASB_B1 % 2 1 1 ! 74: CONST LASB_B1 : LA : SB : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase
LASB2 (La–Sb)
- Id:
phase:la-sb:lasb2; statusassigned - Structure: Sb2Sm · oC24 · Cmce (64); type
st:sb2sm-oc24; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (dft_space_group_64_matches_2_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: La 0.3333, Sb 0.6667
- Stability: stable in 2 of 2 calculated diagram(s): 300–1382.8 K, x(Sb) 0.66667–0.66667
- Literature: 8 values (8 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:la-sb:lasb2
paper: paper:10.1016/j.calphad.2012.01.002:LaSb2, paper:10.1016/j.tca.2012.10.026:LaSb2
tdb: tdb:LaSb-12Gao.tdb:LASB2, tdb:LaSb-13Wan.tdb:LASB2
TDB models of LASB2 (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: LASB2, type code %, sha256 5689268b3e6623ac…
65: PHASE LASB2 % 2 1 2 ! 66: CONST LASB2 : LA : SB : !
LaSb-13Wan.tdb: LASB2, type code %, sha256 301a2f87ebb4bfc1…
78: PHASE LASB2 % 2 1 2 ! 79: CONST LASB2 : LA : SB : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase - doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase
LIQUID (La–Sb)
- Id:
phase:la-sb:liquid; statusassigned - Structure: liquid; type
st:liquid; liquid; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 902.41–2500 K, x(Sb) 0–1
- Literature: 22 values (22 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:la-sb:liquid
paper: paper:10.1016/j.calphad.2012.01.002:L, paper:10.1016/j.tca.2012.10.026:L
tdb: tdb:LaSb-12Gao.tdb:LIQUID, tdb:LaSb-13Wan.tdb:LIQUID
TDB models of LIQUID (2): PHASE and CONSTITUENT statements as written
LaSb-12Gao.tdb: LIQUID, type code %, sha256 5689268b3e6623ac…
20: PHASE LIQUID:L % 1 1 ! 21: CONST LIQUID:L : LA SB : !
LaSb-13Wan.tdb: LIQUID, type code %, sha256 301a2f87ebb4bfc1…
33: PHASE LIQUID:L % 1 1 ! 34: CONST LIQUID:L : LA LA3SB2 SB : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.tca.2012.10.026 Jinsan Wang, Changrong Li, Cuiping Guo, Zhenmin Du, Xushan Zhao, Jianyun Shen, Thermodynamic assessment of the La–Sb and the Ho–Sb systems using the associate model, Thermochimica Acta 551, 104-109 (2013).
assessment that models this phase; reports values for this phase - doi:10.1016/j.calphad.2012.01.002 F. Gao, S.L. Wang, C.P. Wang, X.J. Liu, Thermodynamic assessments of the Sb–La and Sb–Tb systems, Calphad 37, 158-162 (2012).
assessment that models this phase; reports values for this phase