# Li–Sn phases

> Li–Sn system: 15 phases (tier A 5, tier C 7, liquid 1, needs_review 2); 13 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references.

HTML: https://data.orchid-project.org/phases/pages/LI-SN.html · Markdown: https://data.orchid-project.org/phases/pages/LI-SN.md

15 phases (tier A 5, tier C 7, liquid 1, needs_review 2); 13 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: [interactive registry](https://orchid-project.org/phases/?q=LI-SN) · [full JSON](https://data.orchid-project.org/phases/systems/LI-SN.json) · [Li–Sn system page](https://data.orchid-project.org/systems/LI-SN.html) · [Markdown](https://data.orchid-project.org/phases/pages/LI-SN.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md)

Table: Phases of the Li–Sn system (15)

| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---:|---:|
| [DIAMOND_A4](#phase-li-sn-a4-diamond); _phase:li-sn:a4-diamond_ | C (diamond) · A4 · cF8 · Fd-3m (227) | tier A: standard phase name | not stable in 3 calculated diagram(s) | 0 | 3 |
| [BCT_A5](#phase-li-sn-a5-bct); _phase:li-sn:a5-bct_ | beta-Sn · A5 · tI4 · I4_1/amd (141) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–505.08 K, x(Sn) 1–1 | 7 | 3 |
| [BCC_A2](#phase-li-sn-bcc-a2); _phase:li-sn:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–2500 K, x(Sn) 0–0.4496 | 11 | 3 |
| [FCC_A1](#phase-li-sn-fcc-a1); _phase:li-sn:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 1 of 3 calculated diagram(s): 1091.34–2500 K, x(Sn) 0.39257–0.58597 | 0 | 3 |
| [HCP_A3](#phase-li-sn-hcp-a3); _phase:li-sn:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | not stable in 3 calculated diagram(s) | 0 | 3 |
| [LI13SN5](#phase-li-sn-li13sn5); _phase:li-sn:li13sn5_ | Li13Sn5 · hP18 · P-3m1 (164) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–994.84 K, x(Sn) 0.27778–0.27778 | 27 | 3 |
| [LI17SN4](#phase-li-sn-li17sn4); _phase:li-sn:li17sn4_ |  | needs_review | stable in 1 of 1 calculated diagram(s): 300–1030.98 K, x(Sn) 0.19048–0.19048 | 26 | 1 |
| [LI22SN5](#phase-li-sn-li22sn5); _phase:li-sn:li22sn5_ | Li17Pb4 · cF420 · F-43m (216) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–1035.76 K, x(Sn) 0.18519–0.18519 | 14 | 2 |
| [LI2SN5](#phase-li-sn-li2sn5); _phase:li-sn:li2sn5_ | Hg5Mn2 · tP14 · P4/mbm (127) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–593.45 K, x(Sn) 0.71429–0.71429 | 21 | 3 |
| [LI5SN2](#phase-li-sn-li5sn2); _phase:li-sn:li5sn2_ | Li5Sn2 · hR7 · R-3m (166) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–971.51 K, x(Sn) 0.28571–0.28571 | 26 | 3 |
| [LI7SN2](#phase-li-sn-li7sn2); _phase:li-sn:li7sn2_ | Ge2Li7 · oC36 · Cmmm (65) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–1056.06 K, x(Sn) 0.22222–0.25242 | 34 | 3 |
| [LI7SN3](#phase-li-sn-li7sn3); _phase:li-sn:li7sn3_ | Li7Sn3 · mP20 · P2_1/m (11) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–787.31 K, x(Sn) 0.3–0.3 | 29 | 3 |
| [LI8SN3](#phase-li-sn-li8sn3); _phase:li-sn:li8sn3_ |  | needs_review | stable in 1 of 1 calculated diagram(s): 300–989.19 K, x(Sn) 0.27273–0.27273 | 0 | 1 |
| [LIQUID](#phase-li-sn-liquid); _phase:li-sn:liquid_ | liquid | liquid | stable in 3 of 3 calculated diagram(s): 451.52–2500 K, x(Sn) 0–1 | 109 | 3 |
| [LISN](#phase-li-sn-lisn); _phase:li-sn:lisn_ | LiSn · mP6 · P2/m (10) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–761.43 K, x(Sn) 0.48539–0.5 | 43 | 3 |

## DIAMOND_A4 (Li–Sn)

- Id: `phase:li-sn:a4-diamond`; status `assigned`
- Structure: C (diamond) · A4 · cF8 · Fd-3m (227); type `st:a4-c-diamond-cf8`; tier A: standard phase name; confidence high
- Stoichiometry: Sn 1.0000
- Stability: not stable in 3 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:a4-diamond)

Names (4): _corpus: _corpus:phase:li-sn:a4-diamond  
_tdb: _tdb:LiSn-05Yin-LB.tdb:DIAMOND_A4, tdb:LiSn-06Du.tdb:DIAMOND_A4, tdb:LiSn-14Li.tdb:DIAMOND_A4  


### TDB models of DIAMOND_A4 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): DIAMOND_A4, type code %, sha256 `71144325a80cb495…`

~~~~text
40: PHASE DIAMOND_A4 % 1 1 !
41: CONST DIAMOND_A4 : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): DIAMOND_A4, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
42: PHASE DIAMOND_A4 % 1 1 !
43: CONST DIAMOND_A4 : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): DIAMOND_A4, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
47: PHASE DIAMOND_A4 % 1 1 !
48: CONST DIAMOND_A4 : SN : !
~~~~

Example references (3 of 3; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_

## BCT_A5 (Li–Sn)

- Id: `phase:li-sn:a5-bct`; status `assigned`
- Structure: beta-Sn · A5 · tI4 · I4_1/amd (141); type `st:a5-beta-sn-ti4`; tier A: standard phase name; confidence high
- Stoichiometry: Sn 1.0000
- Stability: stable in 3 of 3 calculated diagram(s): 300–505.08 K, x(Sn) 1–1
- Literature: 7 values (7 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:a5-bct)

Names (7): _corpus: _corpus:phase:li-sn:a5-bct, corpus:phase:li-sn:bct-a5  
_paper: _paper:10.1016/j.calphad.2014.09.002:(βSn), paper:10.1016/j.jallcom.2004.09.047:(βSn)  
_tdb: _tdb:LiSn-05Yin-LB.tdb:BCT_A5, tdb:LiSn-06Du.tdb:BCT_A5, tdb:LiSn-14Li.tdb:BCT_A5  


### TDB models of BCT_A5 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): BCT_A5, type code %, sha256 `71144325a80cb495…`

~~~~text
45: PHASE BCT_A5 % 1 1 !
46: CONST BCT_A5 : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): BCT_A5, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
47: PHASE BCT_A5 % 1 1 !
48: CONST BCT_A5 : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): BCT_A5, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
52: PHASE BCT_A5 % 1 1 !
53: CONST BCT_A5 : SN : !
~~~~

Example references (5 of 5; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_

## BCC_A2 (Li–Sn)

- Id: `phase:li-sn:bcc-a2`; status `assigned`
- Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high
- Stability: stable in 3 of 3 calculated diagram(s): 300–2500 K, x(Sn) 0–0.4496
- Literature: 11 values (11 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:bcc-a2)

Names (6): _corpus: _corpus:phase:li-sn:bcc-a2  
_paper: _paper:10.1016/j.calphad.2014.09.002:(βLi), paper:10.1016/j.jallcom.2004.09.047:(βLi)  
_tdb: _tdb:LiSn-05Yin-LB.tdb:BCC_A2, tdb:LiSn-06Du.tdb:BCC_A2, tdb:LiSn-14Li.tdb:BCC_A2  


### TDB models of BCC_A2 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): BCC_A2, type code %B, sha256 `71144325a80cb495…`

~~~~text
30: PHASE BCC_A2 %B 2 1 3 !
31: CONST BCC_A2 : LI% SN : VA : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): BCC_A2, type code %B, sha256 `917e7098d5e1cf01…`

~~~~text
32: PHASE BCC_A2 %B 2 1 3 !
33: CONST BCC_A2 : LI% SN : VA : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): BCC_A2, type code %B, sha256 `d9e6b25b55ac0666…`

~~~~text
37: PHASE BCC_A2 %B 2 1 3 !
38: CONST BCC_A2 : LI% SN : VA : !
~~~~

Example references (5 of 5; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_

## FCC_A1 (Li–Sn)

- Id: `phase:li-sn:fcc-a1`; status `assigned`
- Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high
- Stability: stable in 1 of 3 calculated diagram(s): 1091.34–2500 K, x(Sn) 0.39257–0.58597
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:fcc-a1)

Names (4): _corpus: _corpus:phase:li-sn:fcc-a1  
_tdb: _tdb:LiSn-05Yin-LB.tdb:FCC_A1, tdb:LiSn-06Du.tdb:FCC_A1, tdb:LiSn-14Li.tdb:FCC_A1  


### TDB models of FCC_A1 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): FCC_A1, type code %, sha256 `71144325a80cb495…`

~~~~text
25: PHASE FCC_A1 % 2 1 1 !
26: CONST FCC_A1 : LI SN : VA : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): FCC_A1, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
27: PHASE FCC_A1 % 2 1 1 !
28: CONST FCC_A1 : LI SN : VA : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): FCC_A1, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
32: PHASE FCC_A1 % 2 1 1 !
33: CONST FCC_A1 : LI SN : VA : !
~~~~

Example references (3 of 3; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_

## HCP_A3 (Li–Sn)

- Id: `phase:li-sn:hcp-a3`; status `assigned`
- Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high
- Stability: not stable in 3 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:hcp-a3)

Names (4): _corpus: _corpus:phase:li-sn:hcp-a3  
_tdb: _tdb:LiSn-05Yin-LB.tdb:HCP_A3, tdb:LiSn-06Du.tdb:HCP_A3, tdb:LiSn-14Li.tdb:HCP_A3  


### TDB models of HCP_A3 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): HCP_A3, type code %, sha256 `71144325a80cb495…`

~~~~text
35: PHASE HCP_A3 % 2 1 0.5 !
36: CONST HCP_A3 : LI SN : VA: !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): HCP_A3, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
37: PHASE HCP_A3 % 2 1 0.5 !
38: CONST HCP_A3 : LI SN : VA: !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): HCP_A3, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
42: PHASE HCP_A3 % 2 1 0.5 !
43: CONST HCP_A3 : LI SN : VA: !
~~~~

Example references (3 of 3; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_

## LI13SN5 (Li–Sn)

- Id: `phase:li-sn:li13sn5`; status `assigned`
- Structure: Li13Sn5 · hP18 · P-3m1 (164); type `st:li13sn5-hp18`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_mp, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Li 0.7222, Sn 0.2778
- Stability: stable in 3 of 3 calculated diagram(s): 300–994.84 K, x(Sn) 0.27778–0.27778
- Literature: 27 values (27 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li13sn5)

Names (6): _corpus: _corpus:phase:li-sn:li13sn5  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li13Sn5, paper:10.1016/j.jallcom.2004.09.047:Li13Sn5  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI13SN5, tdb:LiSn-06Du.tdb:LI13SN5, tdb:LiSn-14Li.tdb:LI13SN5  


### TDB models of LI13SN5 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI13SN5, type code %, sha256 `71144325a80cb495…`

~~~~text
60: PHASE LI13SN5 % 2 13 5 !
61: CONST LI13SN5 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI13SN5, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
67: PHASE LI13SN5 % 2 13 5 !
68: CONST LI13SN5 : LI : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI13SN5, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
67: PHASE LI13SN5 % 2 13 5 !
68: CONST LI13SN5 : LI : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1515/znb-1975-1-203](https://doi.org/10.1515/znb-1975-1-203) Ursula Frank, Wiking Müller, Herbert Schäfer, Die Kristallstruktur der Phase Li\<sub>7\</sub>Sn\<sub>2\</sub> / The Crystal Structure of Li\<sub>7\</sub>Sn\<sub>2\</sub>, Zeitschrift für Naturforschung B 30, 6-9 (1975).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_
- [doi:10.1016/0022-5088(79)90174-7](https://doi.org/10.1016/0022-5088%2879%2990174-7) D.M. Bailey, W.H. Skelton, J.F. Smith, Lithium-tin phase relationships between Li7Sn2 and LiSn, Journal of the Less Common Metals 64, 233-239 (1979).  
_cited as the source of values for this phase_

## LI17SN4 (Li–Sn)

- Id: `phase:li-sn:li17sn4`; status `needs_review`
- No structure assigned. Why: dft_space_group_216_matches_2_structure_types; no_structure_token
- Candidate (dft_mp): F-43m (216) — on-hull MP Li17Sn4 at x(SN)=0.1905
- Candidate (dft_oqmd): F-43m (216) — on-hull OQMD Li17 Sn4 at x(SN)=0.1905
- Candidate (dft_space_group_and_stoichiometry): Li17Pb4 · cF420 · F-43m (216) — space group 216 and stoichiometry match
- Candidate (dft_space_group_and_stoichiometry): Li17Si4 · cF420 · F-43m (216) — space group 216 and stoichiometry match
- Candidate (tdb_comment): Li17Pb4 · cF420 · F-43m — LiSn-14Li.tdb: 'Prototype Li17Pb4 (cF420, F-43m)'
- Stoichiometry: Li 0.8095, Sn 0.1905
- Stability: stable in 1 of 1 calculated diagram(s): 300–1030.98 K, x(Sn) 0.19048–0.19048
- Literature: 26 values (26 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li17sn4)

Names (3): _corpus: _corpus:phase:li-sn:li17sn4  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li17Sn4  
_tdb: _tdb:LiSn-14Li.tdb:LI17SN4  


### TDB models of LI17SN4 (1): PHASE and CONSTITUENT statements as written

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI17SN4, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
57: PHASE LI17SN4 % 2 17 4 !
58: CONST LI17SN4 : LI : SN : !
~~~~

Example references (3 of 3; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1021/ic026235o](https://doi.org/10.1021/ic026235o) Corina Lupu, Jiang-Gao Mao, J. Wayne Rabalais, Arnold M. Guloy, James W. Richardson, X-ray and Neutron Diffraction Studies on “Li\<sub>4.4\</sub>Sn”, Inorg. Chem. 42, 3765-3771 (2003).  
_cited as the source of values for this phase_

## LI22SN5 (Li–Sn)

- Id: `phase:li-sn:li22sn5`; status `assigned`
- Structure: Li17Pb4 · cF420 · F-43m (216); type `st:li17pb4-cf420`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Li 0.8148, Sn 0.1852
- Stability: stable in 2 of 2 calculated diagram(s): 300–1035.76 K, x(Sn) 0.18519–0.18519
- Literature: 14 values (14 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li22sn5)

Names (4): _corpus: _corpus:phase:li-sn:li22sn5  
_paper: _paper:10.1016/j.jallcom.2004.09.047:Li22Sn5  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI22SN5, tdb:LiSn-06Du.tdb:LI22SN5  


### TDB models of LI22SN5 (2): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI22SN5, type code %, sha256 `71144325a80cb495…`

~~~~text
50: PHASE LI22SN5 % 2 22 5 !
51: CONST LI22SN5 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI22SN5, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
52: PHASE LI22SN5 % 2 22 5 !
53: CONST LI22SN5 : LI : SN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_

## LI2SN5 (Li–Sn)

- Id: `phase:li-sn:li2sn5`; status `assigned`
- Structure: Hg5Mn2 · tP14 · P4/mbm (127); type `st:hg5mn2-tp14`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_mp, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Li 0.2857, Sn 0.7143
- Stability: stable in 3 of 3 calculated diagram(s): 300–593.45 K, x(Sn) 0.71429–0.71429
- Literature: 21 values (21 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li2sn5)

Names (6): _corpus: _corpus:phase:li-sn:li2sn5  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li2Sn5, paper:10.1016/j.jallcom.2004.09.047:Li2Sn5  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI2SN5, tdb:LiSn-06Du.tdb:LI2SN5, tdb:LiSn-14Li.tdb:LI2SN5  


### TDB models of LI2SN5 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI2SN5, type code %, sha256 `71144325a80cb495…`

~~~~text
81: PHASE LI2SN5 % 2 2 5 !
82: CONST LI2SN5 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI2SN5, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
88: PHASE LI2SN5 % 2 2 5 !
89: CONST LI2SN5 : LI : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI2SN5, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
88: PHASE LI2SN5 % 2 2 5 !
89: CONST LI2SN5 : LI : SN : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1107/s0567740869005760](https://doi.org/10.1107/s0567740869005760) D. A. Hansen, L. J. Chang, Crystal structure of Li\<sub>2\</sub>Sn\<sub>5\</sub>, Acta Crystallogr B Struct Sci 25, 2392-2395 (1969).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_

## LI5SN2 (Li–Sn)

- Id: `phase:li-sn:li5sn2`; status `assigned`
- Structure: Li5Sn2 · hR7 · R-3m (166); type `st:li5sn2-hr7`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_oqmd, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Li 0.7143, Sn 0.2857
- Stability: stable in 3 of 3 calculated diagram(s): 300–971.51 K, x(Sn) 0.28571–0.28571
- Literature: 26 values (26 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li5sn2)

Names (6): _corpus: _corpus:phase:li-sn:li5sn2  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li5Sn2, paper:10.1016/j.jallcom.2004.09.047:Li5Sn2  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI5SN2, tdb:LiSn-06Du.tdb:LI5SN2, tdb:LiSn-14Li.tdb:LI5SN2  


### TDB models of LI5SN2 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI5SN2, type code %, sha256 `71144325a80cb495…`

~~~~text
66: PHASE LI5SN2 % 2 5 2 !
67: CONST LI5SN2 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI5SN2, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
73: PHASE LI5SN2 % 2 5 2 !
74: CONST LI5SN2 : LI : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI5SN2, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
73: PHASE LI5SN2 % 2 5 2 !
74: CONST LI5SN2 : LI : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1515/znb-1975-1-203](https://doi.org/10.1515/znb-1975-1-203) Ursula Frank, Wiking Müller, Herbert Schäfer, Die Kristallstruktur der Phase Li\<sub>7\</sub>Sn\<sub>2\</sub> / The Crystal Structure of Li\<sub>7\</sub>Sn\<sub>2\</sub>, Zeitschrift für Naturforschung B 30, 6-9 (1975).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1016/0022-5088(79)90174-7](https://doi.org/10.1016/0022-5088%2879%2990174-7) D.M. Bailey, W.H. Skelton, J.F. Smith, Lithium-tin phase relationships between Li7Sn2 and LiSn, Journal of the Less Common Metals 64, 233-239 (1979).  
_cited as the source of values for this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_

## LI7SN2 (Li–Sn)

- Id: `phase:li-sn:li7sn2`; status `assigned`
- Structure: Ge2Li7 · oC36 · Cmmm (65); type `st:ge2li7-oc36`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system
- Stability: stable in 3 of 3 calculated diagram(s): 300–1056.06 K, x(Sn) 0.22222–0.25242
- Literature: 34 values (34 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li7sn2)

Names (6): _corpus: _corpus:phase:li-sn:li7sn2  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li7Sn2, paper:10.1016/j.jallcom.2004.09.047:Li7Sn2  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI7SN2, tdb:LiSn-06Du.tdb:LI7SN2, tdb:LiSn-14Li.tdb:LI7SN2  


### TDB models of LI7SN2 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI7SN2, type code %, sha256 `71144325a80cb495…`

~~~~text
55: PHASE LI7SN2 % 2 7 2 !
56: CONST LI7SN2 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI7SN2, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
57: PHASE LI7SN2 % 2 7 2 !
58: CONST LI7SN2 : LI% SN : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI7SN2, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
62: PHASE LI7SN2 % 2 7 2 !
63: CONST LI7SN2 : LI% SN : SN : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1515/znb-1975-1-203](https://doi.org/10.1515/znb-1975-1-203) Ursula Frank, Wiking Müller, Herbert Schäfer, Die Kristallstruktur der Phase Li\<sub>7\</sub>Sn\<sub>2\</sub> / The Crystal Structure of Li\<sub>7\</sub>Sn\<sub>2\</sub>, Zeitschrift für Naturforschung B 30, 6-9 (1975).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_

## LI7SN3 (Li–Sn)

- Id: `phase:li-sn:li7sn3`; status `assigned`
- Structure: Li7Sn3 · mP20 · P2_1/m (11); type `st:li7sn3-mp20`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Li 0.7000, Sn 0.3000
- Stability: stable in 3 of 3 calculated diagram(s): 300–787.31 K, x(Sn) 0.3–0.3
- Literature: 29 values (29 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li7sn3)

Names (6): _corpus: _corpus:phase:li-sn:li7sn3  
_paper: _paper:10.1016/j.calphad.2014.09.002:Li7Sn3, paper:10.1016/j.jallcom.2004.09.047:Li7Sn3  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LI7SN3, tdb:LiSn-06Du.tdb:LI7SN3, tdb:LiSn-14Li.tdb:LI7SN3  


### TDB models of LI7SN3 (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LI7SN3, type code %, sha256 `71144325a80cb495…`

~~~~text
71: PHASE LI7SN3 % 2 7 3 !
72: CONST LI7SN3 : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI7SN3, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
78: PHASE LI7SN3 % 2 7 3 !
79: CONST LI7SN3 : LI : SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LI7SN3, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
78: PHASE LI7SN3 % 2 7 3 !
79: CONST LI7SN3 : LI : SN : !
~~~~

Example references (8 of 8; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1515/znb-1974-5-602](https://doi.org/10.1515/znb-1974-5-602) Wiking Müller, Darstellung und Struktur der Phase Li\<sub>7\</sub>Sn\<sub>3\</sub> / Preparation und Crystal Structure of Li\<sub>7\</sub>Sn\<sub>3\</sub>, Zeitschrift für Naturforschung B 29, 304-311 (1974).  
_cited as the source of values for this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1016/0022-5088(79)90174-7](https://doi.org/10.1016/0022-5088%2879%2990174-7) D.M. Bailey, W.H. Skelton, J.F. Smith, Lithium-tin phase relationships between Li7Sn2 and LiSn, Journal of the Less Common Metals 64, 233-239 (1979).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_

## LI8SN3 (Li–Sn)

- Id: `phase:li-sn:li8sn3`; status `needs_review`
- No structure assigned. Why: no_on_hull_entry_in_mp; no_structure_token; sgte_mmc2_row_incomplete
- Candidate (dft_oqmd): C2/m (12) — on-hull OQMD Li8 Sn3 at x(SN)=0.2727
- Candidate (sgte_mmc2): (Li8Sn3) — Hallstedt 2025 mmc2 row for LI8SN3: Li8Sn3
- Stoichiometry: Li 0.7273, Sn 0.2727
- Stability: stable in 1 of 1 calculated diagram(s): 300–989.19 K, x(Sn) 0.27273–0.27273
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:li8sn3)

Names (2): _corpus: _corpus:phase:li-sn:li8sn3  
_tdb: _tdb:LiSn-06Du.tdb:LI8SN3  


### TDB models of LI8SN3 (1): PHASE and CONSTITUENT statements as written

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LI8SN3, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
62: PHASE LI8SN3 % 2 8 3 !
63: CONST LI8SN3 : LI : SN : !
~~~~

Example references (1 of 1; assessments first): 

- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_

## LIQUID (Li–Sn)

- Id: `phase:li-sn:liquid`; status `assigned`
- Structure: liquid; type `st:liquid`; liquid; confidence high
- Stability: stable in 3 of 3 calculated diagram(s): 451.52–2500 K, x(Sn) 0–1
- Literature: 109 values (109 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:liquid)

Names (7): _corpus: _corpus:phase:li-sn:liquid  
_paper: _paper:10.1016/j.calphad.2014.09.002:L, paper:10.1016/j.calphad.2014.09.002:liquid, paper:10.1016/j.jallcom.2004.09.047:L  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LIQUID, tdb:LiSn-06Du.tdb:LIQUID, tdb:LiSn-14Li.tdb:LIQUID  


### TDB models of LIQUID (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LIQUID, type code %, sha256 `71144325a80cb495…`

~~~~text
20: PHASE LIQUID:L % 1 1 !
21: CONST LIQUID:L : LI SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LIQUID, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
22: PHASE LIQUID:L % 1 1 !
23: CONST LIQUID:L : LI SN : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LIQUID, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
27: PHASE LIQUID:L % 1 1 !
28: CONST LIQUID:L : LI LI4SN SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_
- [doi:10.1016/0022-5088(79)90174-7](https://doi.org/10.1016/0022-5088%2879%2990174-7) D.M. Bailey, W.H. Skelton, J.F. Smith, Lithium-tin phase relationships between Li7Sn2 and LiSn, Journal of the Less Common Metals 64, 233-239 (1979).  
_cited as the source of values for this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_

## LISN (Li–Sn)

- Id: `phase:li-sn:lisn`; status `assigned`
- Structure: LiSn · mP6 · P2/m (10); type `st:lisn-mp6`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system
- Stability: stable in 3 of 3 calculated diagram(s): 300–761.43 K, x(Sn) 0.48539–0.5
- Literature: 43 values (43 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-sn:lisn)

Names (6): _corpus: _corpus:phase:li-sn:lisn  
_paper: _paper:10.1016/j.calphad.2014.09.002:LiSn, paper:10.1016/j.jallcom.2004.09.047:LiSn  
_tdb: _tdb:LiSn-05Yin-LB.tdb:LISN, tdb:LiSn-06Du.tdb:LISN, tdb:LiSn-14Li.tdb:LISN  


### TDB models of LISN (3): PHASE and CONSTITUENT statements as written

[LiSn-05Yin-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-05Yin-LB.tdb): LISN, type code %, sha256 `71144325a80cb495…`

~~~~text
76: PHASE LISN % 2 1 1 !
77: CONST LISN : LI : SN : !
~~~~

[LiSn-06Du.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-06Du.tdb): LISN, type code %, sha256 `917e7098d5e1cf01…`

~~~~text
83: PHASE LISN % 2 1 1 !
84: CONST LISN : LI : LI SN% : !
~~~~

[LiSn-14Li.tdb](https://orchid-project.org/data/databases/sgte-binary/LiSn-14Li.tdb): LISN, type code %, sha256 `d9e6b25b55ac0666…`

~~~~text
83: PHASE LISN % 2 1 1 !
84: CONST LISN : LI : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2014.09.002](https://doi.org/10.1016/j.calphad.2014.09.002) D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid, Thermodynamic assessment and experimental investigation of the Li–Sn system, Calphad 47, 181-195 (2014).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2004.09.047](https://doi.org/10.1016/j.jallcom.2004.09.047) Fucheng Yin, Xuping Su, Zhi Li, Jianhua Wang, Thermodynamic assessment of the Li–Sn (Lithium–Tin) system, Journal of Alloys and Compounds 393, 105-108 (2005).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1515/ijmr-2006-0002](https://doi.org/10.1515/ijmr-2006-0002) Z. Du, Z. Jiang, C. Guo, Z. Metallkd., 97, 10-16(2006).  
_assessment that models this phase_
- [doi:10.1149/1.2127590](https://doi.org/10.1149/1.2127590) C. John Wen, R. A. Huggins, Thermodynamic Study of the Lithium‐Tin System, J. Electrochem. Soc. 128, 1181-1187 (1981).  
_cited as the source of values for this phase_
- [doi:10.1007/s12385-006-5008-6](https://doi.org/10.1007/s12385-006-5008-6) J. Sangster, C.W. Bale, The Li–Sn (lithium–tin) system, J. Phase Equilib. 19 (1998) 70–75.  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19100670114](https://doi.org/10.1002/zaac.19100670114) G. Masing, G. Tammann, Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium, Z. Anorg. Chem. 67, 183-199 (1910).  
_cited as the source of values for this phase_
- [doi:10.1016/0022-5088(79)90174-7](https://doi.org/10.1016/0022-5088%2879%2990174-7) D.M. Bailey, W.H. Skelton, J.F. Smith, Lithium-tin phase relationships between Li7Sn2 and LiSn, Journal of the Less Common Metals 64, 233-239 (1979).  
_cited as the source of values for this phase_

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).