# Li–Zn phases > Li–Zn system: 12 phases (tier A 4, tier C 2, liquid 1, needs_review 5); 11 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references. HTML: https://data.orchid-project.org/phases/pages/LI-ZN.html · Markdown: https://data.orchid-project.org/phases/pages/LI-ZN.md 12 phases (tier A 4, tier C 2, liquid 1, needs_review 5); 11 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model). Data: [interactive registry](https://orchid-project.org/phases/?q=LI-ZN) · [full JSON](https://data.orchid-project.org/phases/systems/LI-ZN.json) · [Li–Zn system page](https://data.orchid-project.org/systems/LI-ZN.html) · [Markdown](https://data.orchid-project.org/phases/pages/LI-ZN.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md) Table: Phases of the Li–Zn system (12) | Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models | |---|---|---|---|---:|---:| | [BCC_A2](#phase-li-zn-bcc-a2); _phase:li-zn:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–457.6 K, x(Zn) 0–0.00963 | 4 | 6 | | [FCC_A1](#phase-li-zn-fcc-a1); _phase:li-zn:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | not stable in 3 calculated diagram(s) | 0 | 3 | | [HCP_A3](#phase-li-zn-hcp-a3); _phase:li-zn:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–827.68 K, x(Zn) 0.95803–1 | 4 | 5 | | [LI2ZN3_ALPHA](#phase-li-zn-li2zn3-alpha); _phase:li-zn:li2zn3-alpha_ | Li5Sn2 · hR7 · R-3m (166) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 300–447.37 K, x(Zn) 0.56181–0.6 | 8 | 3 | | [LI2ZN3_BETA](#phase-li-zn-li2zn3-beta); _phase:li-zn:li2zn3-beta_ | Ga4Li5 · hP9 · P-3m1 (164) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 3 of 3 calculated diagram(s): 430.14–798.39 K, x(Zn) 0.45464–0.67582 | 18 | 3 | | [LI2ZN5_ALPHA](#phase-li-zn-li2zn5-alpha); _phase:li-zn:li2zn5-alpha_ | | needs_review | stable in 3 of 3 calculated diagram(s): 300–620 K, x(Zn) 0.71429–0.71511 | 8 | 3 | | [LI2ZN5_BETA](#phase-li-zn-li2zn5-beta); _phase:li-zn:li2zn5-beta_ | | needs_review | stable in 3 of 3 calculated diagram(s): 440.07–772.52 K, x(Zn) 0.71432–0.73378 | 10 | 3 | | [LIQUID](#phase-li-zn-liquid); _phase:li-zn:liquid_ | liquid | liquid | stable in 3 of 3 calculated diagram(s): 430–2500 K, x(Zn) 0–1 | 10 | 3 | | [LIZN_B32](#phase-li-zn-lizn-b32); _phase:li-zn:lizn-b32_ | NaTl · B32 · cF16 · Fd-3m (227) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–454.73 K, x(Zn) 0.00023–0.5589 | 6 | 3 | | [LIZN2](#phase-li-zn-lizn2); _phase:li-zn:lizn2_ | | needs_review | stable in 3 of 3 calculated diagram(s): 300–366.27 K, x(Zn) 0.66667–0.66667 | 2 | 3 | | [LIZN4_ALPHA](#phase-li-zn-lizn4-alpha); _phase:li-zn:lizn4-alpha_ | | needs_review | stable in 3 of 3 calculated diagram(s): 300–522.92 K, x(Zn) 0.79981–0.86732 | 6 | 3 | | [LIZN4_BETA](#phase-li-zn-lizn4-beta); _phase:li-zn:lizn4-beta_ | | needs_review | stable in 3 of 3 calculated diagram(s): 300.34–2500 K, x(Zn) 0.2–1 | 8 | 3 | ## BCC_A2 (Li–Zn) - Id: `phase:li-zn:bcc-a2`; status `assigned` - Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high - Stability: stable in 3 of 3 calculated diagram(s): 300–457.6 K, x(Zn) 0–0.00963 - Literature: 4 values (4 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:bcc-a2) Names (8): _corpus: _corpus:phase:li-zn:bcc-a2 _paper: _paper:10.1016/j.jallcom.2007.01.154:bcc (Li) _tdb: _tdb:LiZn-08Lia.tdb:A2_BCC, tdb:LiZn-08Lia.tdb:BCC_A2, tdb:LiZn-11Guo.tdb:A2_BCC, tdb:LiZn-11Guo.tdb:BCC_A2, tdb:LiZn-24Liu.tdb:A2_BCC, tdb:LiZn-24Liu.tdb:BCC_A2 ### TDB models of BCC_A2 (6): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): A2_BCC, type code %B, sha256 `60ba1d9f7a9fd485…` ~~~~text 40: PHASE A2_BCC %B 2 1 3 ! 41: CONST A2_BCC : LI% ZN : VA : ! ~~~~ [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): BCC_A2, type code %B, sha256 `60ba1d9f7a9fd485…` ~~~~text 35: PHASE BCC_A2 %B 2 1 3 ! 36: CONST BCC_A2 : LI% ZN : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): A2_BCC, type code %B, sha256 `663c0cf844cd2698…` ~~~~text 42: PHASE A2_BCC %B 2 1 3 ! 43: CONST A2_BCC : LI% ZN : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): BCC_A2, type code %B, sha256 `663c0cf844cd2698…` ~~~~text 37: PHASE BCC_A2 %B 2 1 3 ! 38: CONST BCC_A2 : LI% ZN : VA : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): A2_BCC, type code %B, sha256 `231043daf7806ab8…` ~~~~text 43: PHASE A2_BCC %B 2 1 3 ! 44: CONST A2_BCC : LI% ZN : VA : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): BCC_A2, type code %B, sha256 `231043daf7806ab8…` ~~~~text 38: PHASE BCC_A2 %B 2 1 3 ! 39: CONST BCC_A2 : LI% ZN : VA : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## FCC_A1 (Li–Zn) - Id: `phase:li-zn:fcc-a1`; status `assigned` - Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high - Stability: not stable in 3 calculated diagram(s) - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:fcc-a1) Names (4): _corpus: _corpus:phase:li-zn:fcc-a1 _tdb: _tdb:LiZn-08Lia.tdb:FCC_A1, tdb:LiZn-11Guo.tdb:FCC_A1, tdb:LiZn-24Liu.tdb:FCC_A1 ### TDB models of FCC_A1 (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): FCC_A1, type code %A, sha256 `60ba1d9f7a9fd485…` ~~~~text 30: PHASE FCC_A1 %A 2 1 1 ! 31: CONST FCC_A1 : LI ZN : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): FCC_A1, type code %A, sha256 `663c0cf844cd2698…` ~~~~text 32: PHASE FCC_A1 %A 2 1 1 ! 33: CONST FCC_A1 : LI ZN : VA : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): FCC_A1, type code %A, sha256 `231043daf7806ab8…` ~~~~text 33: PHASE FCC_A1 %A 2 1 1 ! 34: CONST FCC_A1 : LI ZN : VA : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase_ ## HCP_A3 (Li–Zn) - Id: `phase:li-zn:hcp-a3`; status `assigned` - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high - Stability: stable in 3 of 3 calculated diagram(s): 300–827.68 K, x(Zn) 0.95803–1 - Literature: 4 values (4 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:hcp-a3) Names (7): _corpus: _corpus:phase:li-zn:hcp-a3 _paper: _paper:10.1016/j.jallcom.2007.01.154:hcp (Zn) _tdb: _tdb:LiZn-08Lia.tdb:A3_HCP, tdb:LiZn-08Lia.tdb:HCP_A3, tdb:LiZn-11Guo.tdb:A3_HCP, tdb:LiZn-11Guo.tdb:HCP_A3, tdb:LiZn-24Liu.tdb:HCP_A3 ### TDB models of HCP_A3 (5): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): A3_HCP, type code %A, sha256 `60ba1d9f7a9fd485…` ~~~~text 50: PHASE A3_HCP %A 2 1 0.5 ! 51: CONST A3_HCP : LI ZN% : VA : ! ~~~~ [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): HCP_A3, type code %A, sha256 `60ba1d9f7a9fd485…` ~~~~text 45: PHASE HCP_A3 %A 2 1 0.5 ! 46: CONST HCP_A3 : LI ZN% : VA: ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): A3_HCP, type code %A, sha256 `663c0cf844cd2698…` ~~~~text 52: PHASE A3_HCP %A 2 1 0.5 ! 53: CONST A3_HCP : LI ZN% : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): HCP_A3, type code %A, sha256 `663c0cf844cd2698…` ~~~~text 47: PHASE HCP_A3 %A 2 1 0.5 ! 48: CONST HCP_A3 : LI ZN% : VA: ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): HCP_A3, type code %A, sha256 `231043daf7806ab8…` ~~~~text 48: PHASE HCP_A3 %A 2 1 0.5 ! 49: CONST HCP_A3 : LI ZN% : VA: ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LI2ZN3_ALPHA (Li–Zn) - Id: `phase:li-zn:li2zn3-alpha`; status `assigned` - Structure: Li5Sn2 · hR7 · R-3m (166); type `st:li5sn2-hr7`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system - Stability: stable in 3 of 3 calculated diagram(s): 300–447.37 K, x(Zn) 0.56181–0.6 - Literature: 8 values (8 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:li2zn3-alpha) Names (5): _corpus: _corpus:phase:li-zn:li2zn3-alpha _paper: _paper:10.1016/j.jallcom.2007.01.154:αLi2Zn3 _tdb: _tdb:LiZn-08Lia.tdb:LI2ZN3_ALPHA, tdb:LiZn-11Guo.tdb:LI2ZN3_ALPHA, tdb:LiZn-24Liu.tdb:LI2ZN3_ALPHA ### TDB models of LI2ZN3_ALPHA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LI2ZN3_ALPHA, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 60: PHASE LI2ZN3_ALPHA % 2 2 3 ! 61: CONST LI2ZN3_ALPHA : LI : LI ZN% : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LI2ZN3_ALPHA, type code %, sha256 `663c0cf844cd2698…` ~~~~text 62: PHASE LI2ZN3_ALPHA % 2 2 3 ! 63: CONST LI2ZN3_ALPHA : LI : LI ZN% : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LI2ZN3_ALPHA, type code %, sha256 `231043daf7806ab8…` ~~~~text 58: PHASE LI2ZN3_ALPHA % 2 2 3 ! 59: CONST LI2ZN3_ALPHA : LI : LI ZN% : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LI2ZN3_BETA (Li–Zn) - Id: `phase:li-zn:li2zn3-beta`; status `assigned` - Structure: Ga4Li5 · hP9 · P-3m1 (164); type `st:ga4li5-hp9`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system - Stability: stable in 3 of 3 calculated diagram(s): 430.14–798.39 K, x(Zn) 0.45464–0.67582 - Literature: 18 values (18 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:li2zn3-beta) Names (5): _corpus: _corpus:phase:li-zn:li2zn3-beta _paper: _paper:10.1016/j.jallcom.2007.01.154:βLi2Zn3 _tdb: _tdb:LiZn-08Lia.tdb:LI2ZN3_BETA, tdb:LiZn-11Guo.tdb:LI2ZN3_BETA, tdb:LiZn-24Liu.tdb:LI2ZN3_BETA ### TDB models of LI2ZN3_BETA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LI2ZN3_BETA, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 65: PHASE LI2ZN3_BETA % 2 2 3 ! 66: CONST LI2ZN3_BETA : LI% ZN : LI ZN% : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LI2ZN3_BETA, type code %, sha256 `663c0cf844cd2698…` ~~~~text 67: PHASE LI2ZN3_BETA % 2 2 3 ! 68: CONST LI2ZN3_BETA : LI% ZN : LI ZN% : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LI2ZN3_BETA, type code %, sha256 `231043daf7806ab8…` ~~~~text 63: PHASE LI2ZN3_BETA % 2 2 3 ! 64: CONST LI2ZN3_BETA : LI% ZN : LI ZN% : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LI2ZN5_ALPHA (Li–Zn) - Id: `phase:li-zn:li2zn5-alpha`; status `needs_review` - No structure assigned. Why: no_structure_token; off_stoichiometric_model - Candidate (sgte_mmc2): (Li2Zn5-alpha) — Hallstedt 2025 mmc2 row for LI2ZN5_ALPHA: Li2Zn5-alpha (low T) - Stability: stable in 3 of 3 calculated diagram(s): 300–620 K, x(Zn) 0.71429–0.71511 - Literature: 8 values (8 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:li2zn5-alpha) Names (5): _corpus: _corpus:phase:li-zn:li2zn5-alpha _paper: _paper:10.1016/j.jallcom.2007.01.154:αLi2Zn5 _tdb: _tdb:LiZn-08Lia.tdb:LI2ZN5_ALPHA, tdb:LiZn-11Guo.tdb:LI2ZN5_ALPHA, tdb:LiZn-24Liu.tdb:LI2ZN5_ALPHA ### TDB models of LI2ZN5_ALPHA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LI2ZN5_ALPHA, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 75: PHASE LI2ZN5_ALPHA % 2 2 5 ! 76: CONST LI2ZN5_ALPHA : LI% ZN : ZN : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LI2ZN5_ALPHA, type code %, sha256 `663c0cf844cd2698…` ~~~~text 77: PHASE LI2ZN5_ALPHA % 2 2 5 ! 78: CONST LI2ZN5_ALPHA : LI% ZN : ZN : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LI2ZN5_ALPHA, type code %, sha256 `231043daf7806ab8…` ~~~~text 73: PHASE LI2ZN5_ALPHA % 2 2 5 ! 74: CONST LI2ZN5_ALPHA : LI% ZN : ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LI2ZN5_BETA (Li–Zn) - Id: `phase:li-zn:li2zn5-beta`; status `needs_review` - No structure assigned. Why: no_structure_token; off_stoichiometric_model - Candidate (sgte_mmc2): Li2Zn5-beta · aP86 · P-1 (2) — Hallstedt 2025 mmc2 row for LI2ZN5_BETA: Li2Zn5-beta (high T) - Candidate (tdb_comment): beta-Li2Zn5 · aP86 · P-1 — LiZn-08Lia.tdb: 'Prototype beta-Li2Zn5 (aP86, P-1)' - Candidate (tdb_comment): beta-Li2Zn5 · aP86 · P-1 — LiZn-11Guo.tdb: 'Prototype beta-Li2Zn5 (aP86, P-1)' - Candidate (tdb_comment): beta-Li2Zn5 · aP86 · P-1 — LiZn-24Liu.tdb: 'Prototype beta-Li2Zn5 (aP86, P-1)' - Stability: stable in 3 of 3 calculated diagram(s): 440.07–772.52 K, x(Zn) 0.71432–0.73378 - Literature: 10 values (10 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:li2zn5-beta) Names (5): _corpus: _corpus:phase:li-zn:li2zn5-beta _paper: _paper:10.1016/j.jallcom.2007.01.154:βLi2Zn5 _tdb: _tdb:LiZn-08Lia.tdb:LI2ZN5_BETA, tdb:LiZn-11Guo.tdb:LI2ZN5_BETA, tdb:LiZn-24Liu.tdb:LI2ZN5_BETA ### TDB models of LI2ZN5_BETA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LI2ZN5_BETA, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 80: PHASE LI2ZN5_BETA % 2 2 5 ! 81: CONST LI2ZN5_BETA : LI% ZN : ZN : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LI2ZN5_BETA, type code %, sha256 `663c0cf844cd2698…` ~~~~text 82: PHASE LI2ZN5_BETA % 2 2 5 ! 83: CONST LI2ZN5_BETA : LI% ZN : ZN : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LI2ZN5_BETA, type code %, sha256 `231043daf7806ab8…` ~~~~text 78: PHASE LI2ZN5_BETA % 2 2 5 ! 79: CONST LI2ZN5_BETA : LI% ZN : ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LIQUID (Li–Zn) - Id: `phase:li-zn:liquid`; status `assigned` - Structure: liquid; type `st:liquid`; liquid; confidence high - Stability: stable in 3 of 3 calculated diagram(s): 430–2500 K, x(Zn) 0–1 - Literature: 10 values (10 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:liquid) Names (5): _corpus: _corpus:phase:li-zn:liquid _paper: _paper:10.1016/j.jallcom.2007.01.154:liq. _tdb: _tdb:LiZn-08Lia.tdb:LIQUID, tdb:LiZn-11Guo.tdb:LIQUID, tdb:LiZn-24Liu.tdb:LIQUID ### TDB models of LIQUID (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LIQUID, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 25: PHASE LIQUID:L % 1 1 ! 26: CONST LIQUID:L : LI ZN : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LIQUID, type code %, sha256 `663c0cf844cd2698…` ~~~~text 27: PHASE LIQUID:L % 1 1 ! 28: CONST LIQUID:L : LI ZN : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LIQUID, type code %, sha256 `231043daf7806ab8…` ~~~~text 28: PHASE LIQUID:L % 1 1 ! 29: CONST LIQUID:L : LI ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LIZN_B32 (Li–Zn) - Id: `phase:li-zn:lizn-b32`; status `assigned` - Structure: NaTl · B32 · cF16 · Fd-3m (227); type `st:b32-natl-cf16`; tier A: standard phase name; confidence high - Caveat: LiZn-08Lia.tdb: ordered phase with disordered part A2_BCC (order/disorder model) - Caveat: LiZn-11Guo.tdb: ordered phase with disordered part A2_BCC (order/disorder model) - Caveat: LiZn-24Liu.tdb: ordered phase with disordered part A2_BCC (order/disorder model) - Caveat: partitioned order/disorder model in LiZn-08Lia.tdb also describes the disordered state - Caveat: partitioned order/disorder model in LiZn-11Guo.tdb also describes the disordered state - Caveat: partitioned order/disorder model in LiZn-24Liu.tdb also describes the disordered state - Stability: stable in 3 of 3 calculated diagram(s): 300–454.73 K, x(Zn) 0.00023–0.5589 - Literature: 6 values (6 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:lizn-b32) Names (5): _corpus: _corpus:phase:li-zn:lizn-b32 _paper: _paper:10.1016/j.jallcom.2007.01.154:LiZn _tdb: _tdb:LiZn-08Lia.tdb:LIZN_B32, tdb:LiZn-11Guo.tdb:LIZN_B32, tdb:LiZn-24Liu.tdb:LIZN_B32 ### TDB models of LIZN_B32 (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LIZN_B32, type code %O, sha256 `60ba1d9f7a9fd485…` ~~~~text 55: PHASE LIZN_B32 %O 3 0.5 0.5 3 ! 56: CONST LIZN_B32 : LI% ZN : LI ZN% : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LIZN_B32, type code %O, sha256 `663c0cf844cd2698…` ~~~~text 57: PHASE LIZN_B32 %O 3 0.5 0.5 3 ! 58: CONST LIZN_B32 : LI% ZN : LI ZN% : VA : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LIZN_B32, type code %O, sha256 `231043daf7806ab8…` ~~~~text 53: PHASE LIZN_B32 %O 3 0.5 0.5 3 ! 54: CONST LIZN_B32 : LI% ZN : LI ZN% : VA : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LIZN2 (Li–Zn) - Id: `phase:li-zn:lizn2`; status `needs_review` - No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete - Candidate (literature_printed): (LiZn2) · ? — printed with a label mapped to this phase - Candidate (sgte_mmc2): (LiZn2) — Hallstedt 2025 mmc2 row for LIZN2: LiZn2 - Stoichiometry: Li 0.3333, Zn 0.6667 - Stability: stable in 3 of 3 calculated diagram(s): 300–366.27 K, x(Zn) 0.66667–0.66667 - Literature: 2 values (2 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:lizn2) Names (5): _corpus: _corpus:phase:li-zn:lizn2 _paper: _paper:10.1016/j.jallcom.2007.01.154:LiZn2 _tdb: _tdb:LiZn-08Lia.tdb:LIZN2, tdb:LiZn-11Guo.tdb:LIZN2, tdb:LiZn-24Liu.tdb:LIZN2 ### TDB models of LIZN2 (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LIZN2, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 70: PHASE LIZN2 % 2 1 2 ! 71: CONST LIZN2 : LI : ZN : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LIZN2, type code %, sha256 `663c0cf844cd2698…` ~~~~text 72: PHASE LIZN2 % 2 1 2 ! 73: CONST LIZN2 : LI : ZN : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LIZN2, type code %, sha256 `231043daf7806ab8…` ~~~~text 68: PHASE LIZN2 % 2 1 2 ! 69: CONST LIZN2 : LI : ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LIZN4_ALPHA (Li–Zn) - Id: `phase:li-zn:lizn4-alpha`; status `needs_review` - No structure assigned. Why: no_structure_token; off_stoichiometric_model - Candidate (dft_oqmd): Pm-3 (200) — on-hull OQMD Li2 Zn11 at x(ZN)=0.8462 - Candidate (sgte_mmc2): (LiZn4-alpha) — Hallstedt 2025 mmc2 row for LIZN4_ALPHA: LiZn4-alpha (low T) - Stability: stable in 3 of 3 calculated diagram(s): 300–522.92 K, x(Zn) 0.79981–0.86732 - Literature: 6 values (6 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:lizn4-alpha) Names (5): _corpus: _corpus:phase:li-zn:lizn4-alpha _paper: _paper:10.1016/j.jallcom.2007.01.154:αLiZn4 _tdb: _tdb:LiZn-08Lia.tdb:LIZN4_ALPHA, tdb:LiZn-11Guo.tdb:LIZN4_ALPHA, tdb:LiZn-24Liu.tdb:LIZN4_ALPHA ### TDB models of LIZN4_ALPHA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LIZN4_ALPHA, type code %, sha256 `60ba1d9f7a9fd485…` ~~~~text 85: PHASE LIZN4_ALPHA % 2 1 4 ! 86: CONST LIZN4_ALPHA : LI% ZN : LI ZN% : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LIZN4_ALPHA, type code %, sha256 `663c0cf844cd2698…` ~~~~text 87: PHASE LIZN4_ALPHA % 2 1 4 ! 88: CONST LIZN4_ALPHA : LI% ZN : LI ZN% : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LIZN4_ALPHA, type code %, sha256 `231043daf7806ab8…` ~~~~text 83: PHASE LIZN4_ALPHA % 2 1 4 ! 84: CONST LIZN4_ALPHA : LI% ZN : LI ZN% : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## LIZN4_BETA (Li–Zn) - Id: `phase:li-zn:lizn4-beta`; status `needs_review` - No structure assigned. Why: assessment_declared_order_disorder_ambiguity; no_structure_token; off_stoichiometric_model - Candidate (dft_mp): Fd-3m (227) — on-hull MP LiZn at x(ZN)=0.5000 - Candidate (dft_mp): P6_3/mmc (194) — on-hull MP LiZn3 at x(ZN)=0.7500 - Candidate (dft_oqmd): Fd-3m (227) — on-hull OQMD Li1 Zn1 at x(ZN)=0.5000 - Candidate (dft_oqmd): Pmmn (59) — on-hull OQMD Li1 Zn3 at x(ZN)=0.7500 - Candidate (dft_oqmd): Pm-3 (200) — on-hull OQMD Li2 Zn11 at x(ZN)=0.8462 - Candidate (dft_oqmd): P63 (173) — on-hull OQMD Li3 Zn10 at x(ZN)=0.7692 - Candidate (dft_oqmd): P1 (1) — on-hull OQMD Li3 Zn2 at x(ZN)=0.4000 - Candidate (dft_oqmd): R-3m (166) — on-hull OQMD Li4 Zn9 at x(ZN)=0.6923 - Stability: stable in 3 of 3 calculated diagram(s): 300.34–2500 K, x(Zn) 0.2–1 - Literature: 8 values (8 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:li-zn:lizn4-beta) Names (5): _corpus: _corpus:phase:li-zn:lizn4-beta _paper: _paper:10.1016/j.jallcom.2007.01.154:βLiZn4 _tdb: _tdb:LiZn-08Lia.tdb:LIZN4_BETA, tdb:LiZn-11Guo.tdb:LIZN4_BETA, tdb:LiZn-24Liu.tdb:LIZN4_BETA ### TDB models of LIZN4_BETA (3): PHASE and CONSTITUENT statements as written [LiZn-08Lia.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-08Lia.tdb): LIZN4_BETA, type code %X, sha256 `60ba1d9f7a9fd485…` ~~~~text 90: PHASE LIZN4_BETA %X 3 0.2 0.8 0.5 ! 91: CONST LIZN4_BETA : LI% ZN : LI ZN% : VA : ! ~~~~ [LiZn-11Guo.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-11Guo.tdb): LIZN4_BETA, type code %X, sha256 `663c0cf844cd2698…` ~~~~text 92: PHASE LIZN4_BETA %X 3 0.2 0.8 0.5 ! 93: CONST LIZN4_BETA : LI% ZN : LI ZN% : VA : ! ~~~~ [LiZn-24Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/LiZn-24Liu.tdb): LIZN4_BETA, type code %, sha256 `231043daf7806ab8…` ~~~~text 88: PHASE LIZN4_BETA % 2 1 4 ! 89: CONST LIZN4_BETA : LI% ZN : LI ZN% : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.jallcom.2007.01.154](https://doi.org/10.1016/j.jallcom.2007.01.154) Yu Liang, Zhenmin Du, Cuiping Guo, Changrong Li, Thermodynamic modeling of the Li–Zn system, Journal of Alloys and Compounds 455, 236-242 (2008). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2010.11.006](https://doi.org/10.1016/j.calphad.2010.11.006) Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011). _assessment that models this phase_ - [doi:10.1016/j.calphad.2024.102752](https://doi.org/10.1016/j.calphad.2024.102752) Y. Liu, S. Liu, Y. Du, Calphad, 87, 102752(2024). _assessment that models this phase_ ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_phase_registry_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Registry: phase registry of binary systems}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735970}, url = {https://doi.org/10.5281/zenodo.23735970}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).