Mn–Sb phases

9 phases (tier A 8, liquid 1); 8 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Mn–Sb system page · Markdown · field reference

Phases of the Mn–Sb system (9)
Phase	Structure	Basis	Stability (calculated)	TDB models
RHOMBOHEDRAL_A7 phase:mn-sb:a7-rhombohedral	alpha-As · A7 · hR2 · R-3m (166)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–2498.97 K, x(Sb) 1–1	1
BCC_A2 phase:mn-sb:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 1411.01–1519.99 K, x(Sb) 0–0.01739	1
CBCC_A12 phase:mn-sb:cbcc-a12	alpha-Mn · A12 · cI58 · I-43m (217)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–987 K, x(Sb) 0–0.02023	1
CUB_A13 phase:mn-sb:cub-a13	beta-Mn · A13 · cP20 · P4_132 (213)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 921.25–1359.99 K, x(Sb) 0–0.02693	1
FCC_A1 phase:mn-sb:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 1202.93–1423.52 K, x(Sb) 0–0.04559	1
HCP_A3 phase:mn-sb:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	not stable in 1 calculated diagram(s)	1
LIQUID phase:mn-sb:liquid	liquid	liquid	stable in 1 of 1 calculated diagram(s): 776.47–2500 K, x(Sb) 0–1	1
MN2SB_C38 phase:mn-sb:mn2sb-c38	Cu2Sb · C38 · tP6 · P4/nmm (129)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–1195.11 K, x(Sb) 0.31556–0.33321	1
MNSB_B81 phase:mn-sb:mnsb-b81	NiAs · B8_1 · hP4 · P6_3/mmc (194)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–1117.35 K, x(Sb) 0.48824–0.5	1

RHOMBOHEDRAL_A7 (Mn–Sb)

Id: phase:mn-sb:a7-rhombohedral; status assigned
Structure: alpha-As · A7 · hR2 · R-3m (166); type st:a7-alpha-as-hr2; tier A: standard phase name; confidence high
Stoichiometry: Sb 1.0000
Stability: stable in 1 of 1 calculated diagram(s): 300–2498.97 K, x(Sb) 1–1
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:a7-rhombohedral
tdb: tdb:MnSb-14Uem.tdb:RHOMBOHEDRAL_A7

TDB models of RHOMBOHEDRAL_A7 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: RHOMBOHEDRAL_A7, type code %, sha256 cb6081f7d25deae6…

43: PHASE RHOMBOHEDRAL_A7 % 1 1 !
44: CONST RHOMBOHEDRAL_A7 : SB : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

BCC_A2 (Mn–Sb)

Id: phase:mn-sb:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 1411.01–1519.99 K, x(Sb) 0–0.01739
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:bcc-a2
tdb: tdb:MnSb-14Uem.tdb:BCC_A2

TDB models of BCC_A2 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: BCC_A2, type code %B, sha256 cb6081f7d25deae6…

33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : MN% SB : VA : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

CBCC_A12 (Mn–Sb)

Id: phase:mn-sb:cbcc-a12; status assigned
Structure: alpha-Mn · A12 · cI58 · I-43m (217); type st:a12-alpha-mn-ci58; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 300–987 K, x(Sb) 0–0.02023
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:cbcc-a12
tdb: tdb:MnSb-14Uem.tdb:CBCC_A12

TDB models of CBCC_A12 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: CBCC_A12, type code %A, sha256 cb6081f7d25deae6…

48: PHASE CBCC_A12 %A 2 1 1 !
49: CONST CBCC_A12 : MN% SB : VA : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

CUB_A13 (Mn–Sb)

Id: phase:mn-sb:cub-a13; status assigned
Structure: beta-Mn · A13 · cP20 · P4_132 (213); type st:a13-beta-mn-cp20; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 921.25–1359.99 K, x(Sb) 0–0.02693
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:cub-a13
tdb: tdb:MnSb-14Uem.tdb:CUB_A13

TDB models of CUB_A13 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: CUB_A13, type code %, sha256 cb6081f7d25deae6…

53: PHASE CUB_A13 % 2 1 1 !
54: CONST CUB_A13 : MN% SB : VA : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

FCC_A1 (Mn–Sb)

Id: phase:mn-sb:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 1202.93–1423.52 K, x(Sb) 0–0.04559
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:fcc-a1
tdb: tdb:MnSb-14Uem.tdb:FCC_A1

TDB models of FCC_A1 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: FCC_A1, type code %A, sha256 cb6081f7d25deae6…

28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : MN% SB : VA : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

HCP_A3 (Mn–Sb)

Id: phase:mn-sb:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: not stable in 1 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:hcp-a3
tdb: tdb:MnSb-14Uem.tdb:HCP_A3

TDB models of HCP_A3 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: HCP_A3, type code %A, sha256 cb6081f7d25deae6…

38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : MN SB : VA : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

LIQUID (Mn–Sb)

Id: phase:mn-sb:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 776.47–2500 K, x(Sb) 0–1
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:liquid
tdb: tdb:MnSb-14Uem.tdb:LIQUID

TDB models of LIQUID (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: LIQUID, type code %, sha256 cb6081f7d25deae6…

23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : MN SB : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

MN2SB_C38 (Mn–Sb)

Id: phase:mn-sb:mn2sb-c38; status assigned
Structure: Cu2Sb · C38 · tP6 · P4/nmm (129); type st:c38-cu2sb-tp6; tier A: standard phase name; confidence high
Caveat: partitioned order/disorder model in MnSb-14Uem.tdb also describes the disordered state
Stability: stable in 1 of 1 calculated diagram(s): 300–1195.11 K, x(Sb) 0.31556–0.33321
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:mn2sb-c38
tdb: tdb:MnSb-14Uem.tdb:MN2SB_C38

TDB models of MN2SB_C38 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: MN2SB_C38, type code %A, sha256 cb6081f7d25deae6…

58: PHASE MN2SB_C38 %A 2 2 1 !
59: CONST MN2SB_C38 : MN% SB : MN SB% : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

MNSB_B81 (Mn–Sb)

Id: phase:mn-sb:mnsb-b81; status assigned
Structure: NiAs · B8_1 · hP4 · P6_3/mmc (194); type st:b8-1-nias-hp4; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 300–1117.35 K, x(Sb) 0.48824–0.5
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:mn-sb:mnsb-b81
tdb: tdb:MnSb-14Uem.tdb:MNSB_B81

TDB models of MNSB_B81 (1): PHASE and CONSTITUENT statements as written

MnSb-14Uem.tdb: MNSB_B81, type code %A, sha256 cb6081f7d25deae6…

63: PHASE MNSB_B81 %A 2 1 1 !
64: CONST MNSB_B81 : MN : MN SB% : !

Example references (1 of 1; assessments first):

doi:10.2320/jinstmet.JAW201410 M. Uemitsu, M. Enoki, S. Iikubo, H. Ohtani, J. Japan Inst. Met., 78, 327-36(2014).
assessment that models this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}