# Sb–Zn phases > Sb–Zn system: 24 phases (tier A 5, tier C 5, liquid 1, needs_review 11, unresolved_no_candidates 2); 20 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references. HTML: https://data.orchid-project.org/phases/pages/SB-ZN.html · Markdown: https://data.orchid-project.org/phases/pages/SB-ZN.md 24 phases (tier A 5, tier C 5, liquid 1, needs_review 11, unresolved_no_candidates 2); 20 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model). Data: [interactive registry](https://orchid-project.org/phases/?q=SB-ZN) · [full JSON](https://data.orchid-project.org/phases/systems/SB-ZN.json) · [Sb–Zn system page](https://data.orchid-project.org/systems/SB-ZN.html) · [Markdown](https://data.orchid-project.org/phases/pages/SB-ZN.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md) Table: Phases of the Sb–Zn system (24) | Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models | |---|---|---|---|---:|---:| | [RHOMBOHEDRAL_A7](#phase-sb-zn-a7-rhombohedral); _phase:sb-zn:a7-rhombohedral_ | alpha-As · A7 · hR2 · R-3m (166) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–903.78 K, x(Zn) 0–0.01694 | 10 | 7 | | [BCC_A2](#phase-sb-zn-bcc-a2); _phase:sb-zn:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | not stable in 7 calculated diagram(s) | 0 | 7 | | [FCC_A1](#phase-sb-zn-fcc-a1); _phase:sb-zn:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | not stable in 7 calculated diagram(s) | 0 | 7 | | [HCP_A3](#phase-sb-zn-hcp-a3); _phase:sb-zn:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–2499.55 K, x(Zn) 0.99423–1 | 21 | 7 | | [LIQUID](#phase-sb-zn-liquid); _phase:sb-zn:liquid_ | liquid | liquid | stable in 7 of 7 calculated diagram(s): 682.87–2500 K, x(Zn) 0–1 | 73 | 7 | | [SB17ZN23_H](#phase-sb-zn-sb17zn23-h); _phase:sb-zn:sb17zn23-h_ | | needs_review | stable in 1 of 1 calculated diagram(s): 764.91–833.76 K, x(Zn) 0.575–0.575 | 0 | 1 | | [SB17ZN23_L](#phase-sb-zn-sb17zn23-l); _phase:sb-zn:sb17zn23-l_ | Sb17Zn23 · hR22 · R-3c (167) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 489.61–764.91 K, x(Zn) 0.575–0.575 | 0 | 1 | | [SB19ZN31](#phase-sb-zn-sb19zn31); _phase:sb-zn:sb19zn31_ | Sb2Zn3-ht1 · oP30 · Pmmn (59) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 681.25–727.92 K, x(Zn) 0.62–0.62 | 0 | 1 | | [SB2ZN3](#phase-sb-zn-sb2zn3); _phase:sb-zn:sb2zn3_ | Sb2Zn3-ht2 · oP192 · Pccn (56) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 712.64–836.62 K, x(Zn) 0.6–0.6 | 0 | 1 | | [SB2ZN3_ETA](#phase-sb-zn-sb2zn3-eta); _phase:sb-zn:sb2zn3-eta_ | Sb2Zn3-ht1 · oP30 · Pmmn (59) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 5 of 5 calculated diagram(s): 677.06–757.55 K, x(Zn) 0.6–0.6 | 15 | 5 | | [SB2ZN3_HT](#phase-sb-zn-sb2zn3-ht); _phase:sb-zn:sb2zn3-ht_ | | needs_review | stable in 1 of 1 calculated diagram(s): 719.86–835.51 K, x(Zn) 0.6–0.6 | 0 | 1 | | [SB2ZN3_LT](#phase-sb-zn-sb2zn3-lt); _phase:sb-zn:sb2zn3-lt_ | | needs_review | stable in 1 of 1 calculated diagram(s): 676.1–719.86 K, x(Zn) 0.6–0.6 | 0 | 1 | | [SB2ZN3_ZETA](#phase-sb-zn-sb2zn3-zeta); _phase:sb-zn:sb2zn3-zeta_ | | needs_review | stable in 5 of 5 calculated diagram(s): 703.48–852.57 K, x(Zn) 0.59267–0.595 | 20 | 5 | | [SB3ZN4_ALPHA](#phase-sb-zn-sb3zn4-alpha); _phase:sb-zn:sb3zn4-alpha_ | | needs_review | not stable in 3 calculated diagram(s) | 9 | 3 | | [SB3ZN4_ALPHA_P](#phase-sb-zn-sb3zn4-alpha-p); _phase:sb-zn:sb3zn4-alpha-p_ | | unresolved_no_candidates | not stable in 2 calculated diagram(s) | 1 | 2 | | [SB3ZN4_BETA](#phase-sb-zn-sb3zn4-beta); _phase:sb-zn:sb3zn4-beta_ | | needs_review | stable in 3 of 3 calculated diagram(s): 300–795.32 K, x(Zn) 0.56327–0.57143 | 0 | 3 | | [SB3ZN4_DELTA](#phase-sb-zn-sb3zn4-delta); _phase:sb-zn:sb3zn4-delta_ | | needs_review | stable in 2 of 2 calculated diagram(s): 766.7–802.76 K, x(Zn) 0.559–0.559 | 22 | 2 | | [SB3ZN4_EPS](#phase-sb-zn-sb3zn4-eps); _phase:sb-zn:sb3zn4-eps_ | Sb17Zn23 · hR22 · R-3c (167) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–767.62 K, x(Zn) 0.56556–0.57143 | 26 | 2 | | [SB3ZN4_GAMMA](#phase-sb-zn-sb3zn4-gamma); _phase:sb-zn:sb3zn4-gamma_ | | needs_review | stable in 3 of 3 calculated diagram(s): 765.05–810.41 K, x(Zn) 0.55696–0.559 | 0 | 3 | | [SB3ZN4_HT](#phase-sb-zn-sb3zn4-ht); _phase:sb-zn:sb3zn4-ht_ | | unresolved_no_candidates | stable in 1 of 1 calculated diagram(s): 766–835.75 K, x(Zn) 0.57143–0.57143 | 0 | 1 | | [SB3ZN4_LT](#phase-sb-zn-sb3zn4-lt); _phase:sb-zn:sb3zn4-lt_ | | needs_review | stable in 1 of 1 calculated diagram(s): 338.81–766 K, x(Zn) 0.57143–0.57143 | 0 | 1 | | [SB3ZN4_PRIME](#phase-sb-zn-sb3zn4-prime); _phase:sb-zn:sb3zn4-prime_ | | needs_review | stable in 5 of 5 calculated diagram(s): 797.97–852.27 K, x(Zn) 0.55128–0.558 | 2 | 5 | | [SB9ZN11](#phase-sb-zn-sb9zn11); _phase:sb-zn:sb9zn11_ | | needs_review | stable in 1 of 1 calculated diagram(s): 764.56–801.01 K, x(Zn) 0.55–0.55 | 0 | 1 | | [SBZN_BE](#phase-sb-zn-sbzn-be); _phase:sb-zn:sbzn-be_ | CdSb · B_e · oP16 · Pbca (61) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–838.84 K, x(Zn) 0.4902–0.5 | 62 | 7 | ## RHOMBOHEDRAL_A7 (Sb–Zn) - Id: `phase:sb-zn:a7-rhombohedral`; status `assigned` - Structure: alpha-As · A7 · hR2 · R-3m (166); type `st:a7-alpha-as-hr2`; tier A: standard phase name; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 300–903.78 K, x(Zn) 0–0.01694 - Literature: 10 values (10 accepted) from 2 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:a7-rhombohedral) Names (11): _corpus: _corpus:phase:sb-zn:a7-rhombohedral, corpus:phase:sb-zn:rhombohedral-a7 _paper: _paper:10.1016/j.jallcom.2006.08.035:Sb, paper:10.1016/j.tca.2022.179327:Rho(Sb) _tdb: _tdb:SbZn-00Liu-LB.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-07Li.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-09Liu.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-18Wan.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-22Zha.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-23Zha.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-97Zab.tdb:RHOMBOHEDRAL_A7 ### TDB models of RHOMBOHEDRAL_A7 (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `82e256183b64ede7…` ~~~~text 54: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 55: CONST RHOMBOHEDRAL_A7 : SB ZN : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 40: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 41: CONST RHOMBOHEDRAL_A7 : SB : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `187d17f544e9280e…` ~~~~text 43: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 44: CONST RHOMBOHEDRAL_A7 : SB : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `8427f99df3872e4e…` ~~~~text 46: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 47: CONST RHOMBOHEDRAL_A7 : SB : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 47: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 48: CONST RHOMBOHEDRAL_A7 : SB% ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 46: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 47: CONST RHOMBOHEDRAL_A7 : SB% ZN : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): RHOMBOHEDRAL_A7, type code %, sha256 `dab5acfd3e531488…` ~~~~text 40: PHASE RHOMBOHEDRAL_A7 % 1 1 ! 41: CONST RHOMBOHEDRAL_A7 : SB : ! ~~~~ Example references (10 of 10; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase; cited as the source of values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ - [doi:10.1016/j.jallcom.2006.04.051](https://doi.org/10.1016/j.jallcom.2006.04.051) Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007). _cited as the source of values for this phase_ ## BCC_A2 (Sb–Zn) - Id: `phase:sb-zn:bcc-a2`; status `assigned` - Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high - Stability: not stable in 7 calculated diagram(s) - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:bcc-a2) Names (8): _corpus: _corpus:phase:sb-zn:bcc-a2 _tdb: _tdb:SbZn-00Liu-LB.tdb:BCC_A2, tdb:SbZn-07Li.tdb:BCC_A2, tdb:SbZn-09Liu.tdb:BCC_A2, tdb:SbZn-18Wan.tdb:BCC_A2, tdb:SbZn-22Zha.tdb:BCC_A2, tdb:SbZn-23Zha.tdb:BCC_A2, tdb:SbZn-97Zab.tdb:BCC_A2 ### TDB models of BCC_A2 (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): BCC_A2, type code %B, sha256 `82e256183b64ede7…` ~~~~text 44: PHASE BCC_A2 %B 2 1 3 ! 45: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): BCC_A2, type code %B, sha256 `6e6072cc45a32d33…` ~~~~text 30: PHASE BCC_A2 %B 2 1 3 ! 31: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): BCC_A2, type code %B, sha256 `187d17f544e9280e…` ~~~~text 33: PHASE BCC_A2 %B 2 1 3 ! 34: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): BCC_A2, type code %B, sha256 `8427f99df3872e4e…` ~~~~text 36: PHASE BCC_A2 %B 2 1 3 ! 37: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): BCC_A2, type code %B, sha256 `7c5dd94e653096cd…` ~~~~text 37: PHASE BCC_A2 %B 2 1 3 ! 38: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): BCC_A2, type code %B, sha256 `be7f7a4bc8316cfd…` ~~~~text 36: PHASE BCC_A2 %B 2 1 3 ! 37: CONST BCC_A2 : SB ZN : VA : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): BCC_A2, type code %B, sha256 `dab5acfd3e531488…` ~~~~text 30: PHASE BCC_A2 %B 2 1 3 ! 31: CONST BCC_A2 : SB ZN : VA : ! ~~~~ Example references (7 of 7; assessments first): - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## FCC_A1 (Sb–Zn) - Id: `phase:sb-zn:fcc-a1`; status `assigned` - Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high - Stability: not stable in 7 calculated diagram(s) - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:fcc-a1) Names (8): _corpus: _corpus:phase:sb-zn:fcc-a1 _tdb: _tdb:SbZn-00Liu-LB.tdb:FCC_A1, tdb:SbZn-07Li.tdb:FCC_A1, tdb:SbZn-09Liu.tdb:FCC_A1, tdb:SbZn-18Wan.tdb:FCC_A1, tdb:SbZn-22Zha.tdb:FCC_A1, tdb:SbZn-23Zha.tdb:FCC_A1, tdb:SbZn-97Zab.tdb:FCC_A1 ### TDB models of FCC_A1 (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): FCC_A1, type code %A, sha256 `82e256183b64ede7…` ~~~~text 39: PHASE FCC_A1 %A 2 1 1 ! 40: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): FCC_A1, type code %A, sha256 `6e6072cc45a32d33…` ~~~~text 25: PHASE FCC_A1 %A 2 1 1 ! 26: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): FCC_A1, type code %A, sha256 `187d17f544e9280e…` ~~~~text 28: PHASE FCC_A1 %A 2 1 1 ! 29: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): FCC_A1, type code %A, sha256 `8427f99df3872e4e…` ~~~~text 31: PHASE FCC_A1 %A 2 1 1 ! 32: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): FCC_A1, type code %A, sha256 `7c5dd94e653096cd…` ~~~~text 32: PHASE FCC_A1 %A 2 1 1 ! 33: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): FCC_A1, type code %A, sha256 `be7f7a4bc8316cfd…` ~~~~text 31: PHASE FCC_A1 %A 2 1 1 ! 32: CONST FCC_A1 : SB ZN : VA : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): FCC_A1, type code %A, sha256 `dab5acfd3e531488…` ~~~~text 25: PHASE FCC_A1 %A 2 1 1 ! 26: CONST FCC_A1 : SB ZN : VA : ! ~~~~ Example references (7 of 7; assessments first): - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## HCP_A3 (Sb–Zn) - Id: `phase:sb-zn:hcp-a3`; status `assigned` - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 300–2499.55 K, x(Zn) 0.99423–1 - Literature: 21 values (21 accepted) from 2 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:hcp-a3) Names (10): _corpus: _corpus:phase:sb-zn:hcp-a3 _paper: _paper:10.1016/j.jallcom.2006.08.035:Zn, paper:10.1016/j.tca.2022.179327:Hcp(Zn) _tdb: _tdb:SbZn-00Liu-LB.tdb:HCP_A3, tdb:SbZn-07Li.tdb:HCP_A3, tdb:SbZn-09Liu.tdb:HCP_A3, tdb:SbZn-18Wan.tdb:HCP_A3, tdb:SbZn-22Zha.tdb:HCP_A3, tdb:SbZn-23Zha.tdb:HCP_A3, tdb:SbZn-97Zab.tdb:HCP_A3 ### TDB models of HCP_A3 (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): HCP_A3, type code %A, sha256 `82e256183b64ede7…` ~~~~text 49: PHASE HCP_A3 %A 2 1 0.5 ! 50: CONST HCP_A3 : SB ZN : VA : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): HCP_A3, type code %A, sha256 `6e6072cc45a32d33…` ~~~~text 35: PHASE HCP_A3 %A 2 1 0.5 ! 36: CONST HCP_A3 : ZN : VA : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): HCP_A3, type code %A, sha256 `187d17f544e9280e…` ~~~~text 38: PHASE HCP_A3 %A 2 1 0.5 ! 39: CONST HCP_A3 : SB ZN : VA : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): HCP_A3, type code %A, sha256 `8427f99df3872e4e…` ~~~~text 41: PHASE HCP_A3 %A 2 1 0.5 ! 42: CONST HCP_A3 : SB ZN% : VA : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): HCP_A3, type code %A, sha256 `7c5dd94e653096cd…` ~~~~text 42: PHASE HCP_A3 %A 2 1 0.5 ! 43: CONST HCP_A3 : SB ZN% : VA : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): HCP_A3, type code %A, sha256 `be7f7a4bc8316cfd…` ~~~~text 41: PHASE HCP_A3 %A 2 1 0.5 ! 42: CONST HCP_A3 : SB ZN% : VA : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): HCP_A3, type code %A, sha256 `dab5acfd3e531488…` ~~~~text 35: PHASE HCP_A3 %A 2 1 0.5 ! 36: CONST HCP_A3 : ZN : VA : ! ~~~~ Example references (10 of 11; assessments first): - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase; cited as the source of values for this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase; cited as the source of values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ - [doi:10.1016/j.jallcom.2006.04.051](https://doi.org/10.1016/j.jallcom.2006.04.051) Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007). _cited as the source of values for this phase_ ## LIQUID (Sb–Zn) - Id: `phase:sb-zn:liquid`; status `assigned` - Structure: liquid; type `st:liquid`; liquid; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 682.87–2500 K, x(Zn) 0–1 - Literature: 73 values (72 accepted) from 4 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:liquid) Names (14): _corpus: _corpus:phase:sb-zn:liquid _paper: _paper:10.1016/j.calphad.2009.08.006:L, paper:10.1016/j.jallcom.2006.08.035:L, paper:10.1016/j.jallcom.2006.08.035:L1, paper:10.1016/j.tca.2022.179327:L, paper:10.1016/j.tca.2022.179327:liquid, paper:10.1361/105497100770339608:liquid _tdb: _tdb:SbZn-00Liu-LB.tdb:LIQUID, tdb:SbZn-07Li.tdb:LIQUID, tdb:SbZn-09Liu.tdb:LIQUID, tdb:SbZn-18Wan.tdb:LIQUID, tdb:SbZn-22Zha.tdb:LIQUID, tdb:SbZn-23Zha.tdb:LIQUID, tdb:SbZn-97Zab.tdb:LIQUID ### TDB models of LIQUID (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): LIQUID, type code %, sha256 `82e256183b64ede7…` ~~~~text 34: PHASE LIQUID:L % 1 1 ! 35: CONST LIQUID:L : SB ZN : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): LIQUID, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 20: PHASE LIQUID:L % 1 1 ! 21: CONST LIQUID:L : SB ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): LIQUID, type code %, sha256 `187d17f544e9280e…` ~~~~text 23: PHASE LIQUID:L % 1 1 ! 24: CONST LIQUID:L : SB ZN : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): LIQUID, type code %, sha256 `8427f99df3872e4e…` ~~~~text 26: PHASE LIQUID:L % 1 1 ! 27: CONST LIQUID:L : SB ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): LIQUID, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 27: PHASE LIQUID:L % 1 1 ! 28: CONST LIQUID:L : SB ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): LIQUID, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 26: PHASE LIQUID:L % 1 1 ! 27: CONST LIQUID:L : SB SB3ZN4 ZN : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): LIQUID, type code %, sha256 `dab5acfd3e531488…` ~~~~text 20: PHASE LIQUID:L % 1 1 ! 21: CONST LIQUID:L : SB ZN : ! ~~~~ Example references (10 of 13; assessments first): - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase; cited as the source of values for this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase; cited as the source of values for this phase; reports values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ - [doi:10.1016/j.jallcom.2006.04.051](https://doi.org/10.1016/j.jallcom.2006.04.051) Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007). _cited as the source of values for this phase_ ## SB17ZN23_H (Sb–Zn) - Id: `phase:sb-zn:sb17zn23-h`; status `needs_review` - No structure assigned. Why: name_has_descriptive_tokens:H; no_structure_token; sgte_mmc2_row_incomplete - Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB17ZN23_H: Sb17Zn23 (delta) - Stoichiometry: Sb 0.4250, Zn 0.5750 - Stability: stable in 1 of 1 calculated diagram(s): 764.91–833.76 K, x(Zn) 0.575–0.575 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb17zn23-h) Names (2): _corpus: _corpus:phase:sb-zn:sb17zn23-h _tdb: _tdb:SbZn-00Liu-LB.tdb:SB17ZN23_H ### TDB models of SB17ZN23_H (1): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SB17ZN23_H, type code %, sha256 `82e256183b64ede7…` ~~~~text 74: PHASE SB17ZN23_H % 2 0.425 0.575 ! 75: CONST SB17ZN23_H : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## SB17ZN23_L (Sb–Zn) - Id: `phase:sb-zn:sb17zn23-l`; status `assigned` - Structure: Sb17Zn23 · hR22 · R-3c (167); type `st:sb17zn23-hr22`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (name_has_descriptive_tokens:L, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system - Stoichiometry: Sb 0.4250, Zn 0.5750 - Stability: stable in 1 of 1 calculated diagram(s): 489.61–764.91 K, x(Zn) 0.575–0.575 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb17zn23-l) Names (2): _corpus: _corpus:phase:sb-zn:sb17zn23-l _tdb: _tdb:SbZn-00Liu-LB.tdb:SB17ZN23_L ### TDB models of SB17ZN23_L (1): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SB17ZN23_L, type code %, sha256 `82e256183b64ede7…` ~~~~text 69: PHASE SB17ZN23_L % 2 0.425 0.575 ! 70: CONST SB17ZN23_L : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## SB19ZN31 (Sb–Zn) - Id: `phase:sb-zn:sb19zn31`; status `assigned` - Structure: Sb2Zn3-ht1 · oP30 · Pmmn (59); type `st:sb2zn3-ht1-op30`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system - Stoichiometry: Sb 0.3800, Zn 0.6200 - Stability: stable in 1 of 1 calculated diagram(s): 681.25–727.92 K, x(Zn) 0.62–0.62 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb19zn31) Names (2): _corpus: _corpus:phase:sb-zn:sb19zn31 _tdb: _tdb:SbZn-00Liu-LB.tdb:SB19ZN31 ### TDB models of SB19ZN31 (1): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SB19ZN31, type code %, sha256 `82e256183b64ede7…` ~~~~text 79: PHASE SB19ZN31 % 2 0.38 0.62 ! 80: CONST SB19ZN31 : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## SB2ZN3 (Sb–Zn) - Id: `phase:sb-zn:sb2zn3`; status `assigned` - Structure: Sb2Zn3-ht2 · oP192 · Pccn (56); type `st:sb2zn3-ht2-op192`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system - Stoichiometry: Sb 0.4000, Zn 0.6000 - Stability: stable in 1 of 1 calculated diagram(s): 712.64–836.62 K, x(Zn) 0.6–0.6 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb2zn3) Names (2): _corpus: _corpus:phase:sb-zn:sb2zn3 _tdb: _tdb:SbZn-00Liu-LB.tdb:SB2ZN3 ### TDB models of SB2ZN3 (1): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SB2ZN3, type code %, sha256 `82e256183b64ede7…` ~~~~text 84: PHASE SB2ZN3 % 2 0.4 0.6 ! 85: CONST SB2ZN3 : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## SB2ZN3_ETA (Sb–Zn) - Id: `phase:sb-zn:sb2zn3-eta`; status `assigned` - Structure: Sb2Zn3-ht1 · oP30 · Pmmn (59); type `st:sb2zn3-ht1-op30`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system - Stoichiometry: Sb 0.4000, Zn 0.6000 - Stability: stable in 5 of 5 calculated diagram(s): 677.06–757.55 K, x(Zn) 0.6–0.6 - Literature: 15 values (15 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb2zn3-eta) Names (7): _corpus: _corpus:phase:sb-zn:sb2zn3-eta _paper: _paper:10.1016/j.jallcom.2006.08.035:ηSb2Zn3 _tdb: _tdb:SbZn-07Li.tdb:SB2ZN3_ETA, tdb:SbZn-09Liu.tdb:SB2ZN3_ETA, tdb:SbZn-18Wan.tdb:SB2ZN3_ETA, tdb:SbZn-22Zha.tdb:SB2ZN3_ETA, tdb:SbZn-23Zha.tdb:SB2ZN3_ETA ### TDB models of SB2ZN3_ETA (5): PHASE and CONSTITUENT statements as written [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SB2ZN3_ETA, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 65: PHASE SB2ZN3_ETA % 2 2 3 ! 66: CONST SB2ZN3_ETA : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SB2ZN3_ETA, type code %, sha256 `187d17f544e9280e…` ~~~~text 68: PHASE SB2ZN3_ETA % 2 2 3 ! 69: CONST SB2ZN3_ETA : SB : ZN : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB2ZN3_ETA, type code %, sha256 `8427f99df3872e4e…` ~~~~text 76: PHASE SB2ZN3_ETA % 2 2 3 ! 77: CONST SB2ZN3_ETA : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB2ZN3_ETA, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 82: PHASE SB2ZN3_ETA % 2 2 3 ! 83: CONST SB2ZN3_ETA : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB2ZN3_ETA, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 81: PHASE SB2ZN3_ETA % 2 2 3 ! 82: CONST SB2ZN3_ETA : SB : ZN : ! ~~~~ Example references (8 of 8; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ ## SB2ZN3_HT (Sb–Zn) - Id: `phase:sb-zn:sb2zn3-ht`; status `needs_review` - No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-97Zab.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Stoichiometry: Sb 0.4000, Zn 0.6000 - Stability: stable in 1 of 1 calculated diagram(s): 719.86–835.51 K, x(Zn) 0.6–0.6 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb2zn3-ht) Names (2): _corpus: _corpus:phase:sb-zn:sb2zn3-ht _tdb: _tdb:SbZn-97Zab.tdb:SB2ZN3_HT ### TDB models of SB2ZN3_HT (1): PHASE and CONSTITUENT statements as written [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): SB2ZN3_HT, type code %, sha256 `dab5acfd3e531488…` ~~~~text 65: PHASE SB2ZN3_HT % 2 2 3 ! 66: CONST SB2ZN3_HT : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ ## SB2ZN3_LT (Sb–Zn) - Id: `phase:sb-zn:sb2zn3-lt`; status `needs_review` - No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition - Candidate (tdb_comment): Sb2Zn3-ht1 · oP30 · Pmmn — SbZn-97Zab.tdb: 'Prototype Sb2Zn3-ht1 (oP30, Pmmn), eta, ht1' - Stoichiometry: Sb 0.4000, Zn 0.6000 - Stability: stable in 1 of 1 calculated diagram(s): 676.1–719.86 K, x(Zn) 0.6–0.6 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb2zn3-lt) Names (2): _corpus: _corpus:phase:sb-zn:sb2zn3-lt _tdb: _tdb:SbZn-97Zab.tdb:SB2ZN3_LT ### TDB models of SB2ZN3_LT (1): PHASE and CONSTITUENT statements as written [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): SB2ZN3_LT, type code %, sha256 `dab5acfd3e531488…` ~~~~text 60: PHASE SB2ZN3_LT % 2 2 3 ! 61: CONST SB2ZN3_LT : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ ## SB2ZN3_ZETA (Sb–Zn) - Id: `phase:sb-zn:sb2zn3-zeta`; status `needs_review` - No structure assigned. Why: assessment_declared_blocked_by:models_disagree_on_composition; models_disagree_on_composition; no_structure_token - Candidate (literature_printed): Sb2Zn3-ht2 · oP192 — printed with a label mapped to this phase - Candidate (sgte_mmc2): Sb2Zn3-ht2 · oP192 · Pccn (56) — Hallstedt 2025 mmc2 row for SB2ZN3_ZETA: Sb2Zn3 (zeta, ht2) - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-07Li.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-09Liu.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-18Wan.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-22Zha.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-23Zha.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2' - Stability: stable in 5 of 5 calculated diagram(s): 703.48–852.57 K, x(Zn) 0.59267–0.595 - Literature: 20 values (20 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb2zn3-zeta) Names (7): _corpus: _corpus:phase:sb-zn:sb2zn3-zeta _paper: _paper:10.1016/j.jallcom.2006.08.035:ξSb2Zn3 _tdb: _tdb:SbZn-07Li.tdb:SB2ZN3_ZETA, tdb:SbZn-09Liu.tdb:SB2ZN3_ZETA, tdb:SbZn-18Wan.tdb:SB2ZN3_ZETA, tdb:SbZn-22Zha.tdb:SB2ZN3_ZETA, tdb:SbZn-23Zha.tdb:SB2ZN3_ZETA ### TDB models of SB2ZN3_ZETA (5): PHASE and CONSTITUENT statements as written [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SB2ZN3_ZETA, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 70: PHASE SB2ZN3_ZETA % 2 2.025 2.975 ! 71: CONST SB2ZN3_ZETA : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SB2ZN3_ZETA, type code %, sha256 `187d17f544e9280e…` ~~~~text 73: PHASE SB2ZN3_ZETA % 2 2.025 2.975 ! 74: CONST SB2ZN3_ZETA : SB : ZN : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB2ZN3_ZETA, type code %, sha256 `8427f99df3872e4e…` ~~~~text 81: PHASE SB2ZN3_ZETA % 2 2.025 2.975 ! 82: CONST SB2ZN3_ZETA : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB2ZN3_ZETA, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 87: PHASE SB2ZN3_ZETA % 2 2 2.91 ! 88: CONST SB2ZN3_ZETA : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB2ZN3_ZETA, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 86: PHASE SB2ZN3_ZETA % 2 2 2.91 ! 87: CONST SB2ZN3_ZETA : SB : ZN : ! ~~~~ Example references (8 of 8; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ ## SB3ZN4_ALPHA (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-alpha`; status `needs_review` - No structure assigned. Why: assessment_declared_blocked_by:models_disagree_on_composition; models_disagree_on_composition; no_structure_token - Candidate (literature_printed): Sb10Zn13 · aP92 — printed with a label mapped to this phase - Candidate (sgte_mmc2): Sb10Zn13 · aP92 · P-1 (2) — Hallstedt 2025 mmc2 row for SB3ZN4_ALPHA: Sb3Zn4 (alpha, stable below RT) - Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-18Wan.tdb: 'Prototype Sb10Zn13 (aP92, P-1)' - Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-22Zha.tdb: 'Prototype Sb10Zn13 (aP92, P-1)' - Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-23Zha.tdb: 'Prototype Sb10Zn13 (aP92, P-1)' - Stability: not stable in 3 calculated diagram(s) - Literature: 9 values (9 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-alpha) Names (5): _corpus: _corpus:phase:sb-zn:sb3zn4-alpha _paper: _paper:10.1016/j.tca.2022.179327:α-Zn13Sb10 _tdb: _tdb:SbZn-18Wan.tdb:SB3ZN4_ALPHA, tdb:SbZn-22Zha.tdb:SB3ZN4_ALPHA, tdb:SbZn-23Zha.tdb:SB3ZN4_ALPHA ### TDB models of SB3ZN4_ALPHA (3): PHASE and CONSTITUENT statements as written [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB3ZN4_ALPHA, type code %, sha256 `8427f99df3872e4e…` ~~~~text 56: PHASE SB3ZN4_ALPHA % 2 3 4 ! 57: CONST SB3ZN4_ALPHA : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB3ZN4_ALPHA, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 57: PHASE SB3ZN4_ALPHA % 2 10 13 ! 58: CONST SB3ZN4_ALPHA : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB3ZN4_ALPHA, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 56: PHASE SB3ZN4_ALPHA % 2 10 13 ! 57: CONST SB3ZN4_ALPHA : SB : ZN : ! ~~~~ Example references (4 of 4; assessments first): - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1021/cm035274a](https://doi.org/10.1021/cm035274a) Yurij Mozharivskyj, Alexandra O. Pecharsky, Sergey Bud'ko, Gordon J. Miller, A Promising Thermoelectric Material: Zn\4\Sb\3\ or Zn\6\\-\\δ\Sb\5\. Its Composition, Structure, Stability, and Polymorphs. Structure and Stability of Zn\1\\-\\δ\Sb, Chem. Mater. 16, 1580-1589 (2004). _cited as the source of values for this phase_ ## SB3ZN4_ALPHA_P (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-alpha-p`; status `unresolved_no_candidates` - No structure assigned. Why: name_has_descriptive_tokens:P; no_structure_token - Stoichiometry: Sb 0.4348, Zn 0.5652 - Stability: not stable in 2 calculated diagram(s) - Literature: 1 values (1 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-alpha-p) Names (4): _corpus: _corpus:phase:sb-zn:sb3zn4-alpha-p _paper: _paper:10.1016/j.tca.2022.179327:α'-Zn13Sb10 _tdb: _tdb:SbZn-22Zha.tdb:SB3ZN4_ALPHA_P, tdb:SbZn-23Zha.tdb:SB3ZN4_ALPHA_P ### TDB models of SB3ZN4_ALPHA_P (2): PHASE and CONSTITUENT statements as written [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB3ZN4_ALPHA_P, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 62: PHASE SB3ZN4_ALPHA_P % 2 10 13 ! 63: CONST SB3ZN4_ALPHA_P : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB3ZN4_ALPHA_P, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 61: PHASE SB3ZN4_ALPHA_P % 2 10 13 ! 62: CONST SB3ZN4_ALPHA_P : SB : ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1021/cm035274a](https://doi.org/10.1021/cm035274a) Yurij Mozharivskyj, Alexandra O. Pecharsky, Sergey Bud'ko, Gordon J. Miller, A Promising Thermoelectric Material: Zn\4\Sb\3\ or Zn\6\\-\\δ\Sb\5\. Its Composition, Structure, Stability, and Polymorphs. Structure and Stability of Zn\1\\-\\δ\Sb, Chem. Mater. 16, 1580-1589 (2004). _cited as the source of values for this phase_ ## SB3ZN4_BETA (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-beta`; status `needs_review` - No structure assigned. Why: assessment_declared_compound_differs_from_site_ratios; no_structure_token; off_stoichiometric_model - Candidate (sgte_mmc2): Sb17Zn23 · hR22 · R-3c (167) — Hallstedt 2025 mmc2 row for SB3ZN4_BETA: Sb3Zn4 (beta, same as epsilon) - Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-18Wan.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon' - Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-22Zha.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon' - Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-23Zha.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon' - Stability: stable in 3 of 3 calculated diagram(s): 300–795.32 K, x(Zn) 0.56327–0.57143 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-beta) Names (4): _corpus: _corpus:phase:sb-zn:sb3zn4-beta _tdb: _tdb:SbZn-18Wan.tdb:SB3ZN4_BETA, tdb:SbZn-22Zha.tdb:SB3ZN4_BETA, tdb:SbZn-23Zha.tdb:SB3ZN4_BETA ### TDB models of SB3ZN4_BETA (3): PHASE and CONSTITUENT statements as written [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB3ZN4_BETA, type code %, sha256 `8427f99df3872e4e…` ~~~~text 61: PHASE SB3ZN4_BETA % 2 3 4 ! 62: CONST SB3ZN4_BETA : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB3ZN4_BETA, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 67: PHASE SB3ZN4_BETA % 2 10 13 ! 68: CONST SB3ZN4_BETA : SB : VA ZN% : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB3ZN4_BETA, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 66: PHASE SB3ZN4_BETA % 2 10 13 ! 67: CONST SB3ZN4_BETA : SB : VA ZN% : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ ## SB3ZN4_DELTA (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-delta`; status `needs_review` - No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition; sgte_mmc2_row_incomplete - Candidate (literature_printed): (Sb17Zn23) · ? — printed with a label mapped to this phase - Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_DELTA: Sb3Zn4 (delta) - Stoichiometry: Sb 0.4410, Zn 0.5590 - Stability: stable in 2 of 2 calculated diagram(s): 766.7–802.76 K, x(Zn) 0.559–0.559 - Literature: 22 values (22 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-delta) Names (5): _corpus: _corpus:phase:sb-zn:sb3zn4-delta _paper: _paper:10.1016/j.jallcom.2006.08.035:δ'Sb3Zn4, paper:10.1016/j.jallcom.2006.08.035:δSb3Zn4 _tdb: _tdb:SbZn-07Li.tdb:SB3ZN4_DELTA, tdb:SbZn-09Liu.tdb:SB3ZN4_DELTA ### TDB models of SB3ZN4_DELTA (2): PHASE and CONSTITUENT statements as written [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SB3ZN4_DELTA, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 55: PHASE SB3ZN4_DELTA % 2 3.087 3.913 ! 56: CONST SB3ZN4_DELTA : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SB3ZN4_DELTA, type code %, sha256 `187d17f544e9280e…` ~~~~text 58: PHASE SB3ZN4_DELTA % 2 3.087 3.913 ! 59: CONST SB3ZN4_DELTA : SB : ZN : ! ~~~~ Example references (5 of 5; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _cited as the source of values for this phase_ ## SB3ZN4_EPS (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-eps`; status `assigned` - Structure: Sb17Zn23 · hR22 · R-3c (167); type `st:sb17zn23-hr22`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833) - Caveat: not certain from the name or DFT alone (name_has_descriptive_tokens:EPS, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system - Stability: stable in 2 of 2 calculated diagram(s): 300–767.62 K, x(Zn) 0.56556–0.57143 - Literature: 26 values (26 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-eps) Names (5): _corpus: _corpus:phase:sb-zn:sb3zn4-eps _paper: _paper:10.1016/j.jallcom.2006.08.035:ε-Sb3Zn4, paper:10.1016/j.jallcom.2006.08.035:εSb3Zn4 _tdb: _tdb:SbZn-07Li.tdb:SB3ZN4_EPS, tdb:SbZn-09Liu.tdb:SB3ZN4_EPS ### TDB models of SB3ZN4_EPS (2): PHASE and CONSTITUENT statements as written [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SB3ZN4_EPS, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 50: PHASE SB3ZN4_EPS % 2 3 4 ! 51: CONST SB3ZN4_EPS : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SB3ZN4_EPS, type code %, sha256 `187d17f544e9280e…` ~~~~text 53: PHASE SB3ZN4_EPS % 2 3 4 ! 54: CONST SB3ZN4_EPS : SB : VA ZN% : ! ~~~~ Example references (5 of 5; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _cited as the source of values for this phase_ - [doi:10.1016/0364-5916(93)90005-v](https://doi.org/10.1016/0364-5916%2893%2990005-v) L.A. Zabdyr, CALPHAD 17 (3) (1993) 269. _cited as the source of values for this phase_ ## SB3ZN4_GAMMA (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-gamma`; status `needs_review` - No structure assigned. Why: models_disagree_on_composition; no_structure_token; sgte_mmc2_row_incomplete - Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_GAMMA: Sb3Zn4 (gamma, same as delta) - Stability: stable in 3 of 3 calculated diagram(s): 765.05–810.41 K, x(Zn) 0.55696–0.559 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-gamma) Names (4): _corpus: _corpus:phase:sb-zn:sb3zn4-gamma _tdb: _tdb:SbZn-18Wan.tdb:SB3ZN4_GAMMA, tdb:SbZn-22Zha.tdb:SB3ZN4_GAMMA, tdb:SbZn-23Zha.tdb:SB3ZN4_GAMMA ### TDB models of SB3ZN4_GAMMA (3): PHASE and CONSTITUENT statements as written [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB3ZN4_GAMMA, type code %, sha256 `8427f99df3872e4e…` ~~~~text 66: PHASE SB3ZN4_GAMMA % 2 3.087 3.913 ! 67: CONST SB3ZN4_GAMMA : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB3ZN4_GAMMA, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 72: PHASE SB3ZN4_GAMMA % 2 7 8.8 ! 73: CONST SB3ZN4_GAMMA : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB3ZN4_GAMMA, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 71: PHASE SB3ZN4_GAMMA % 2 7 8.8 ! 72: CONST SB3ZN4_GAMMA : SB : ZN : ! ~~~~ Example references (3 of 3; assessments first): - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ ## SB3ZN4_HT (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-ht`; status `unresolved_no_candidates` - No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition - Stoichiometry: Sb 0.4286, Zn 0.5714 - Stability: stable in 1 of 1 calculated diagram(s): 766–835.75 K, x(Zn) 0.57143–0.57143 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-ht) Names (2): _corpus: _corpus:phase:sb-zn:sb3zn4-ht _tdb: _tdb:SbZn-97Zab.tdb:SB3ZN4_HT ### TDB models of SB3ZN4_HT (1): PHASE and CONSTITUENT statements as written [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): SB3ZN4_HT, type code %, sha256 `dab5acfd3e531488…` ~~~~text 55: PHASE SB3ZN4_HT % 2 3 4 ! 56: CONST SB3ZN4_HT : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ ## SB3ZN4_LT (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-lt`; status `needs_review` - No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition - Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-97Zab.tdb: 'Prototype Sb17Zn23 (hR22, R-3c)' - Stoichiometry: Sb 0.4286, Zn 0.5714 - Stability: stable in 1 of 1 calculated diagram(s): 338.81–766 K, x(Zn) 0.57143–0.57143 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-lt) Names (2): _corpus: _corpus:phase:sb-zn:sb3zn4-lt _tdb: _tdb:SbZn-97Zab.tdb:SB3ZN4_LT ### TDB models of SB3ZN4_LT (1): PHASE and CONSTITUENT statements as written [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): SB3ZN4_LT, type code %, sha256 `dab5acfd3e531488…` ~~~~text 50: PHASE SB3ZN4_LT % 2 3 4 ! 51: CONST SB3ZN4_LT : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ ## SB3ZN4_PRIME (Sb–Zn) - Id: `phase:sb-zn:sb3zn4-prime`; status `needs_review` - No structure assigned. Why: models_disagree_on_composition; name_has_descriptive_tokens:PRIME; no_structure_token; sgte_mmc2_row_incomplete - Candidate (literature_printed): (Sb17Zn23) · ? — printed with a label mapped to this phase - Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_PRIME: Sb3Zn4 (delta-prime/gamma-prime) - Stability: stable in 5 of 5 calculated diagram(s): 797.97–852.27 K, x(Zn) 0.55128–0.558 - Literature: 2 values (2 accepted) from 1 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb3zn4-prime) Names (7): _corpus: _corpus:phase:sb-zn:sb3zn4-prime _paper: _paper:10.1016/j.jallcom.2006.08.035:γSb5Zn6 _tdb: _tdb:SbZn-07Li.tdb:SB3ZN4_PRIME, tdb:SbZn-09Liu.tdb:SB3ZN4_PRIME, tdb:SbZn-18Wan.tdb:SB3ZN4_PRIME, tdb:SbZn-22Zha.tdb:SB3ZN4_PRIME, tdb:SbZn-23Zha.tdb:SB3ZN4_PRIME ### TDB models of SB3ZN4_PRIME (5): PHASE and CONSTITUENT statements as written [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SB3ZN4_PRIME, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 60: PHASE SB3ZN4_PRIME % 2 3.094 3.906 ! 61: CONST SB3ZN4_PRIME : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SB3ZN4_PRIME, type code %, sha256 `187d17f544e9280e…` ~~~~text 63: PHASE SB3ZN4_PRIME % 2 3.094 3.906 ! 64: CONST SB3ZN4_PRIME : SB : ZN : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SB3ZN4_PRIME, type code %, sha256 `8427f99df3872e4e…` ~~~~text 71: PHASE SB3ZN4_PRIME % 2 3.094 3.906 ! 72: CONST SB3ZN4_PRIME : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SB3ZN4_PRIME, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 77: PHASE SB3ZN4_PRIME % 2 7 8.6 ! 78: CONST SB3ZN4_PRIME : SB : ZN : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SB3ZN4_PRIME, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 76: PHASE SB3ZN4_PRIME % 2 7 8.6 ! 77: CONST SB3ZN4_PRIME : SB : ZN : ! ~~~~ Example references (6 of 6; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _cited as the source of values for this phase_ ## SB9ZN11 (Sb–Zn) - Id: `phase:sb-zn:sb9zn11`; status `needs_review` - No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete - Candidate (sgte_mmc2): (Sb9Zn11) — Hallstedt 2025 mmc2 row for SB9ZN11: Sb9Zn11 (gamma) - Stoichiometry: Sb 0.4500, Zn 0.5500 - Stability: stable in 1 of 1 calculated diagram(s): 764.56–801.01 K, x(Zn) 0.55–0.55 - Literature: 0 values (0 accepted) from 0 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sb9zn11) Names (2): _corpus: _corpus:phase:sb-zn:sb9zn11 _tdb: _tdb:SbZn-00Liu-LB.tdb:SB9ZN11 ### TDB models of SB9ZN11 (1): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SB9ZN11, type code %, sha256 `82e256183b64ede7…` ~~~~text 64: PHASE SB9ZN11 % 2 0.45 0.55 ! 65: CONST SB9ZN11 : SB : ZN : ! ~~~~ Example references (1 of 1; assessments first): - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase_ ## SBZN_BE (Sb–Zn) - Id: `phase:sb-zn:sbzn-be`; status `assigned` - Structure: CdSb · B_e · oP16 · Pbca (61); type `st:b-e-cdsb-op16`; tier A: standard phase name; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 300–838.84 K, x(Zn) 0.4902–0.5 - Literature: 62 values (61 accepted) from 2 papers - Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:sb-zn:sbzn-be) Names (11): _corpus: _corpus:phase:sb-zn:sbzn-be _paper: _paper:10.1016/j.jallcom.2006.08.035:SbZn, paper:10.1016/j.jallcom.2006.08.035:βSbZn, paper:10.1016/j.tca.2022.179327:SbZn _tdb: _tdb:SbZn-00Liu-LB.tdb:SBZN_BE, tdb:SbZn-07Li.tdb:SBZN_BE, tdb:SbZn-09Liu.tdb:SBZN_BE, tdb:SbZn-18Wan.tdb:SBZN_BE, tdb:SbZn-22Zha.tdb:SBZN_BE, tdb:SbZn-23Zha.tdb:SBZN_BE, tdb:SbZn-97Zab.tdb:SBZN_BE ### TDB models of SBZN_BE (7): PHASE and CONSTITUENT statements as written [SbZn-00Liu-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb): SBZN_BE, type code %, sha256 `82e256183b64ede7…` ~~~~text 59: PHASE SBZN_BE % 2 1 1 ! 60: CONST SBZN_BE : SB : ZN : ! ~~~~ [SbZn-07Li.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb): SBZN_BE, type code %, sha256 `6e6072cc45a32d33…` ~~~~text 45: PHASE SBZN_BE % 2 1 1 ! 46: CONST SBZN_BE : SB : ZN : ! ~~~~ [SbZn-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb): SBZN_BE, type code %, sha256 `187d17f544e9280e…` ~~~~text 48: PHASE SBZN_BE % 2 1 1 ! 49: CONST SBZN_BE : SB : VA ZN% : ! ~~~~ [SbZn-18Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb): SBZN_BE, type code %, sha256 `8427f99df3872e4e…` ~~~~text 51: PHASE SBZN_BE % 2 1 1 ! 52: CONST SBZN_BE : SB : ZN : ! ~~~~ [SbZn-22Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb): SBZN_BE, type code %, sha256 `7c5dd94e653096cd…` ~~~~text 52: PHASE SBZN_BE % 2 1 1 ! 53: CONST SBZN_BE : SB : VA ZN% : ! ~~~~ [SbZn-23Zha.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb): SBZN_BE, type code %, sha256 `be7f7a4bc8316cfd…` ~~~~text 51: PHASE SBZN_BE % 2 1 1 ! 52: CONST SBZN_BE : SB : VA ZN% : ! ~~~~ [SbZn-97Zab.tdb](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb): SBZN_BE, type code %, sha256 `dab5acfd3e531488…` ~~~~text 45: PHASE SBZN_BE % 2 1 1 ! 46: CONST SBZN_BE : SB : ZN : ! ~~~~ Example references (10 of 13; assessments first): - [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). _assessment that models this phase; reports values for this phase_ - [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). _assessment that models this phase; reports values for this phase_ - [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). _assessment that models this phase; cited as the source of values for this phase_ - [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). _assessment that models this phase_ - [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). _assessment that models this phase_ - [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). _assessment that models this phase_ - [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) L.A. Zabdyr, Calphad, 21, 349-58(1997). _assessment that models this phase_ - [doi:10.1016/s0364-5916(02)00008-1](https://doi.org/10.1016/s0364-5916%2802%2900008-1) V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581. _cited as the source of values for this phase_ - [doi:10.1021/ja01266a055](https://doi.org/10.1021/ja01266a055) Bernard. DeWitt, Harry. Seltz, A Thermodynamic Study of the Zinc-Antimony System. The Thermodynamic Properties of the Intermetallic Compounds: ZnSb, Zn\3\Sb\2\ and Zn\4\Sb\3\, J. Am. Chem. Soc. 61, 3170-3173 (1939). _cited as the source of values for this phase_ - [doi:10.1039/c8dt02521e](https://doi.org/10.1039/c8dt02521e) Chun-Wan Timothy Lo, Volodymyr Svitlyk, Dmitry Chernyshov, Yurij Mozharivskyj, The updated Zn–Sb phase diagram. How to make pure Zn \13\ Sb \10\ (“Zn \4\ Sb \3\ ”)., Dalton Trans. 47, 11512-11520 (2018). _cited as the source of values for this phase_ ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_phase_registry_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Registry: phase registry of binary systems}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735970}, url = {https://doi.org/10.5281/zenodo.23735970}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).