{"system":"BI-CS","release":"v2026.10","phases":[{"id":"phase:bi-cs:a7-rhombohedral","system":"BI-CS","elements":["BI","CS"],"preferred_name":"RHOMBOHEDRAL_A7","status":"assigned","structure":{"structure_type":"st:a7-alpha-as-hr2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"alpha-As","strukturbericht":"A7","pearson":"hR2","space_group":{"number":166,"symbol":"R-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:(Bi)","namespace":"paper","label":"(Bi)","basis":"corpus_mapping:unstated"},{"name":"tdb:BiCs-15Dja.tdb:RHOMBOHEDRAL_A7","namespace":"tdb","label":"RHOMBOHEDRAL_A7","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:a7-rhombohedral","namespace":"corpus","label":"phase:bi-cs:a7-rhombohedral","in_sgte_corpus":true},{"name":"corpus:phase:bi-cs:rhombohedral-a7","namespace":"corpus","label":"phase:bi-cs:rhombohedral-a7","alias_of":"phase:bi-cs:a7-rhombohedral"}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"RHOMBOHEDRAL_A7","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]}],"stoichiometric":true,"composition":{"BI":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":47,"line_end":47,"text":"PHASE RHOMBOHEDRAL_A7 % 1 1 !"},"constituent":{"line_start":48,"line_end":48,"text":"CONST RHOMBOHEDRAL_A7 : BI : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RHOMBOHEDRAL_A7","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["BI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}},"tdb_comment_structure":["Prototype alpha-As (hR2, R-3m)"]}],"stoichiometry":{"BI":1.0},"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":544.55,"x_min":0.0,"x_max":0.0,"stable_at_top_of_range":false}],"literature":{"values":4,"accepted_values":4,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(Bi)","RHOMBOHEDRAL_A7"],"values":4,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":3},{"id":"phase:bi-cs:bcc-a2","system":"BI-CS","elements":["BI","CS"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:(Cs)","namespace":"paper","label":"(Cs)","basis":"corpus_mapping:unstated"},{"name":"tdb:BiCs-15Dja.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:bcc-a2","namespace":"corpus","label":"phase:bi-cs:bcc-a2","in_sgte_corpus":true}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["BI","CS"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":37,"line_end":37,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":38,"line_end":38,"text":"CONST BCC_A2 : BI CS% : VA : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"},{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["BI","CS%"],["VA"]],"major_constituents":[["CS"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":75},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":301.5,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false}],"literature":{"values":2,"accepted_values":2,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(Cs)","BCC_A2"],"values":2,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":2},{"id":"phase:bi-cs:bi2cs-c15","system":"BI-CS","elements":["BI","CS"],"preferred_name":"BI2CS_C15","status":"assigned","structure":{"structure_type":"st:c15-cu2mg-cf24","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu2Mg","strukturbericht":"C15","pearson":"cF24","space_group":{"number":227,"symbol":"Fd-3m"},"caveats":["DFT agrees: on-hull mp-aaaabigx and oqmd-647553, space group 227"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:Bi2Cs","namespace":"paper","label":"Bi2Cs","basis":"corpus_mapping:unstated"},{"name":"tdb:BiCs-15Dja.tdb:BI2CS_C15","namespace":"tdb","label":"BI2CS_C15","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:bi2cs-c15","namespace":"corpus","label":"phase:bi-cs:bi2cs-c15","in_sgte_corpus":true},{"name":"mp:mp-aaaabigx","namespace":"mp","label":"mp-aaaabigx","basis":"standard_name"},{"name":"oqmd:oqmd-647553","namespace":"oqmd","label":"oqmd-647553","basis":"standard_name"}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"BI2CS_C15","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["BI"]},{"site_ratio":1.0,"constituents":["CS"]}],"stoichiometric":true,"composition":{"BI":0.6666666666666666,"CS":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":52,"line_end":52,"text":"PHASE BI2CS_C15 % 2 2 1 !"},"constituent":{"line_start":53,"line_end":53,"text":"CONST BI2CS_C15 : BI : CS : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BI2CS_C15","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["BI"],["CS"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}},"tdb_comment_structure":["Prototype Cu2Mg (cF24, Fd-3m)"]}],"stoichiometry":{"BI":0.6666666666666666,"CS":0.3333333333333333},"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":854.13,"x_min":0.33333,"x_max":0.33333,"stable_at_top_of_range":false}],"literature":{"values":11,"accepted_values":11,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BI2CS_C15","Bi2Cs"],"values":11,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":3},{"id":"phase:bi-cs:bi2cs3","system":"BI-CS","elements":["BI","CS"],"preferred_name":"BI2CS3","status":"assigned","structure":{"structure_type":"st:eu3ga2-mc20","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"Bi2Cs3","model":"Bi2Cs3","pearson":"mC20","phase_name":"BI2CS3","prototype":"Eu3Ga2","space_group":{"number":15,"symbol":"C2/c"},"strukturbericht":null}]},"prototype":"Eu3Ga2","strukturbericht":null,"pearson":"mC20","space_group":{"number":15,"symbol":"C2/c"},"caveats":["not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:Bi2Cs3","namespace":"paper","label":"Bi2Cs3","basis":"exact_tdb_name"},{"name":"tdb:BiCs-15Dja.tdb:BI2CS3","namespace":"tdb","label":"BI2CS3","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:bi2cs3","namespace":"corpus","label":"phase:bi-cs:bi2cs3","in_sgte_corpus":true}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"BI2CS3","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["BI"]},{"site_ratio":3.0,"constituents":["CS"]}],"stoichiometric":true,"composition":{"BI":0.4,"CS":0.6},"tdb_definition":{"verbatim":{"phase":{"line_start":62,"line_end":62,"text":"PHASE BI2CS3 % 2 2 3 !"},"constituent":{"line_start":63,"line_end":63,"text":"CONST BI2CS3 : BI : CS : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BI2CS3","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,3],"constituents":[["BI"],["CS"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}},"tdb_comment_structure":["Prototype Eu3Ga2 (mC20, C2/c)"]}],"stoichiometry":{"BI":0.4,"CS":0.6},"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":760.0,"x_min":0.6,"x_max":0.6,"stable_at_top_of_range":false}],"literature":{"values":21,"accepted_values":21,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BI2CS3","Bi2Cs3"],"values":21,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1021/ja002606t","citation":"Franck Gascoin, Slavi C. Sevov, Synthesis and Characterization of A<sub>3</sub>Bi<sub>2</sub> (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi<sub>2</sub>]<sup>2</sup><sup>-</sup>, and an Extra Delocalized Electron, J. Am. Chem. Soc. 122, 10251-10252 (2000).","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":4},{"id":"phase:bi-cs:bi4cs5","system":"BI-CS","elements":["BI","CS"],"preferred_name":"BI4CS5","status":"needs_review","structure":null,"candidates":[{"source":"dft_oqmd","structure_type":null,"prototype":null,"strukturbericht":null,"pearson":null,"space_group":{"number":12,"symbol":"C2/m"},"detail":"on-hull OQMD Bi4 Cs5 at x(CS)=0.5556","material_id":"oqmd-1372721"},{"source":"literature_printed","structure_type":null,"prototype":"Rb5As4","strukturbericht":null,"pearson":"mC20","space_group":null,"detail":"printed with a label mapped to this phase","count":5},{"source":"sgte_mmc2","structure_type":"st:rb5as4-mc20","prototype":"Rb5As4","strukturbericht":null,"pearson":"mC20","space_group":{"number":12,"symbol":"C2/m"},"detail":"Hallstedt 2025 mmc2 row for BI4CS5: Bi24Cs5"},{"source":"tdb_comment","structure_type":null,"prototype":"Rb5As4","strukturbericht":null,"pearson":"mC20","space_group":{"number":null,"symbol":"C2/m"},"detail":"BiCs-15Dja.tdb: 'Prototype Rb5As4 (mC20, C2/m)'"}],"review_reasons":["assessment_declared_compound_differs_from_model_composition","no_on_hull_entry_in_mp","no_structure_token"],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:Bi4Cs5","namespace":"paper","label":"Bi4Cs5","basis":"exact_tdb_name"},{"name":"tdb:BiCs-15Dja.tdb:BI4CS5","namespace":"tdb","label":"BI4CS5","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:bi4cs5","namespace":"corpus","label":"phase:bi-cs:bi4cs5","in_sgte_corpus":true}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"BI4CS5","type_code":"%","sublattices":[{"site_ratio":4.0,"constituents":["BI"]},{"site_ratio":5.0,"constituents":["CS"]}],"stoichiometric":true,"composition":{"BI":0.4444444444444444,"CS":0.5555555555555556},"tdb_definition":{"verbatim":{"phase":{"line_start":57,"line_end":57,"text":"PHASE BI4CS5 % 2 4 5 !"},"constituent":{"line_start":58,"line_end":58,"text":"CONST BI4CS5 : BI : CS : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BI4CS5","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[4,5],"constituents":[["BI"],["CS"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}},"tdb_comment_structure":["Prototype Rb5As4 (mC20, C2/m)"]}],"stoichiometry":{"BI":0.4444444444444444,"CS":0.5555555555555556},"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":679.55,"x_min":0.55556,"x_max":0.55556,"stable_at_top_of_range":false}],"literature":{"values":14,"accepted_values":14,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BI4CS5","Bi4Cs5"],"values":14,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1021/ic0104499","citation":"Franck Gascoin, Slavi C. Sevov, Synthesis and Characterization of the “Metallic Salts” A<sub>5</sub>Pn<sub>4</sub> (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn<sub>4</sub><sup>4-</sup> and an Extra Delocalized Electron, Inorg. Chem. 40, 5177-5181 (2001).","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":4},{"id":"phase:bi-cs:bics3-d03","system":"BI-CS","elements":["BI","CS"],"preferred_name":"BICS3_D03","status":"assigned","structure":{"structure_type":"st:d0-3-bif3-cf16","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"BiF3","strukturbericht":"D0_3","pearson":"cF16","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:BiCs3","namespace":"paper","label":"BiCs3","basis":"corpus_mapping:unstated"},{"name":"tdb:BiCs-15Dja.tdb:BICS3_D03","namespace":"tdb","label":"BICS3_D03","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:bics3-d03","namespace":"corpus","label":"phase:bi-cs:bics3-d03","in_sgte_corpus":true}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"BICS3_D03","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]},{"site_ratio":3.0,"constituents":["CS"]}],"stoichiometric":true,"composition":{"BI":0.25,"CS":0.75},"tdb_definition":{"verbatim":{"phase":{"line_start":67,"line_end":67,"text":"PHASE BICS3_D03 % 2 1 3 !"},"constituent":{"line_start":68,"line_end":68,"text":"CONST BICS3_D03 : BI : CS : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BICS3_D03","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["BI"],["CS"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}},"tdb_comment_structure":["Prototype BiF3 (cF16, Fm-3m)"]}],"stoichiometry":{"BI":0.25,"CS":0.75},"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":300.0,"T_max_K":934.18,"x_min":0.75,"x_max":0.75,"stable_at_top_of_range":false}],"literature":{"values":10,"accepted_values":10,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BICS3_D03","BiCs3"],"values":10,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":3},{"id":"phase:bi-cs:fcc-a1","system":"BI-CS","elements":["BI","CS"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:BiCs-15Dja.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:fcc-a1","namespace":"corpus","label":"phase:bi-cs:fcc-a1","in_sgte_corpus":false}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["BI","CS"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":32,"line_end":32,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":33,"line_end":33,"text":"CONST FCC_A1 : BI CS : VA : !"},"type_definitions":[{"line_start":74,"line_end":74,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"},{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["BI","CS"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":74},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["BiCs-15Dja.tdb"]}],"total_papers":1},{"id":"phase:bi-cs:hcp-a3","system":"BI-CS","elements":["BI","CS"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:BiCs-15Dja.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:hcp-a3","namespace":"corpus","label":"phase:bi-cs:hcp-a3","in_sgte_corpus":false}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["BI","CS"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":42,"line_end":42,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":43,"line_end":43,"text":"CONST HCP_A3 : BI CS : VA: !"},"type_definitions":[{"line_start":74,"line_end":74,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"},{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["BI","CS"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":74},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["BiCs-15Dja.tdb"]}],"total_papers":1},{"id":"phase:bi-cs:liquid","system":"BI-CS","elements":["BI","CS"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2014.11.002:L","namespace":"paper","label":"L","basis":"corpus_mapping:unstated"},{"name":"tdb:BiCs-15Dja.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3"},{"name":"corpus:phase:bi-cs:liquid","namespace":"corpus","label":"phase:bi-cs:liquid","in_sgte_corpus":true}],"models":[{"tdb":"BiCs-15Dja.tdb","path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI","BICS","BICS3","CS"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":27,"line_end":27,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":28,"line_end":28,"text":"CONST LIQUID:L : BI BICS BICS3 CS : !"},"type_definitions":[{"line_start":76,"line_end":76,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["BI","BICS","BICS3","CS"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":13,"by_kind":{"G":4,"L":9},"L_by_order":{"0":6,"1":3},"interaction_orders":[0,1],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/BiCs-15Dja.tdb","sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiCs-15Dja.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiCs-15Dja.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiCs-15Dja.tdb","tdb_sha256":"f0497ab1e5628a6068329844ee642503b92cdb730ce9bcf24818f1f5875cb8b3","diagram":"phase-diagrams/sgte/BiCs-15Dja.json","status":"ok","x_element":"CS","stable":true,"T_min_K":301.5,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":24,"accepted_values":24,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2014.11.002","citation":"Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida, Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations, Calphad 48, 72-78 (2015).","roles":["assessment that models this phase","reports values for this phase"],"labels":["L","LIQUID"],"values":24,"tdb_files":["BiCs-15Dja.tdb"]},{"doi":"10.1007/bf02645965","citation":"J. Sangster, A. Pelton, The Bi–Cs (bismuth–cesium) system, J. Phase Equilib. 12 (1991) 443–446.","roles":["cited as the source of values for this phase"],"labels":[],"values":7},{"doi":"10.1002/zaac.19613090305","citation":"Geert Gnutzmann, Wilhelm Klemm, Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut, Zeitschrift anorg allge chemie 309, 181-188 (1961).","roles":["cited as the source of values for this phase"],"labels":[],"values":6}],"total_papers":3}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:a7-alpha-as-hr2":{"id":"st:a7-alpha-as-hr2","prototype":"alpha-As","prototype_spellings":[],"strukturbericht":"A7","pearson":"hR2","space_group":{"number":166,"symbol":"R-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":1},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":110},"st:c15-cu2mg-cf24":{"id":"st:c15-cu2mg-cf24","prototype":"Cu2Mg","prototype_spellings":[],"strukturbericht":"C15","pearson":"cF24","space_group":{"number":227,"symbol":"Fd-3m"},"stoichiometry":"Cu2Mg1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":94},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":115},"st:d0-3-bif3-cf16":{"id":"st:d0-3-bif3-cf16","prototype":"BiF3","prototype_spellings":["AlFe3"],"strukturbericht":"D0_3","pearson":"cF16","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":"Bi1F3","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":32},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":21},"st:eu3ga2-mc20":{"id":"st:eu3ga2-mc20","prototype":"Eu3Ga2","prototype_spellings":[],"strukturbericht":null,"pearson":"mC20","space_group":{"number":15,"symbol":"C2/c"},"stoichiometry":"Eu3Ga2","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":3}],"verification":"in Hallstedt 2025 mmc2","registry_phases":3},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}
