{"system":"BI-LI","release":"v2026.10","phases":[{"id":"phase:bi-li:a7-rhombohedral","system":"BI-LI","elements":["BI","LI"],"preferred_name":"RHOMBOHEDRAL_A7","status":"assigned","structure":{"structure_type":"st:a7-alpha-as-hr2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"alpha-As","strukturbericht":"A7","pearson":"hR2","space_group":{"number":166,"symbol":"R-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:Bi","namespace":"paper","label":"Bi","basis":"corpus_mapping:unstated"},{"name":"tdb:BiLi-13Liu.tdb:RHOMBOHEDRAL_A7","namespace":"tdb","label":"RHOMBOHEDRAL_A7","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:a7-rhombohedral","namespace":"corpus","label":"phase:bi-li:a7-rhombohedral","in_sgte_corpus":true},{"name":"corpus:phase:bi-li:rhombohedral-a7","namespace":"corpus","label":"phase:bi-li:rhombohedral-a7","alias_of":"phase:bi-li:a7-rhombohedral"}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"RHOMBOHEDRAL_A7","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]}],"stoichiometric":true,"composition":{"BI":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":45,"line_end":45,"text":"PHASE RHOMBOHEDRAL_A7 % 1 1 !"},"constituent":{"line_start":46,"line_end":46,"text":"CONST RHOMBOHEDRAL_A7 : BI : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RHOMBOHEDRAL_A7","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["BI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}},"tdb_comment_structure":["Prototype alpha-As (hR2, R-3m)"]}],"stoichiometry":{"BI":1.0},"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":300.0,"T_max_K":544.55,"x_min":0.0,"x_max":0.0,"stable_at_top_of_range":false}],"literature":{"values":2,"accepted_values":2,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["Bi","RHOMBOHEDRAL_A7"],"values":2,"tdb_files":["BiLi-13Liu.tdb"]}],"total_papers":1},{"id":"phase:bi-li:bcc-a2","system":"BI-LI","elements":["BI","LI"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:Li","namespace":"paper","label":"Li","basis":"corpus_mapping:unstated"},{"name":"tdb:BiLi-13Liu.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:bcc-a2","namespace":"corpus","label":"phase:bi-li:bcc-a2","in_sgte_corpus":true}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["BI","LI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":35,"line_end":35,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":36,"line_end":36,"text":"CONST BCC_A2 : BI LI% : VA : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":69,"line_end":69,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["BI","LI%"],["VA"]],"major_constituents":[["LI"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":69},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":300.0,"T_max_K":454.6,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false}],"literature":{"values":2,"accepted_values":2,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BCC_A2","Li"],"values":2,"tdb_files":["BiLi-13Liu.tdb"]}],"total_papers":1},{"id":"phase:bi-li:bili","system":"BI-LI","elements":["BI","LI"],"preferred_name":"BILI_HT","status":"needs_review","structure":null,"candidates":[{"source":"dft_mp","structure_type":null,"prototype":null,"strukturbericht":null,"pearson":null,"space_group":{"number":123,"symbol":"P4/mmm"},"detail":"on-hull MP LiBi at x(LI)=0.5000","material_id":"mp-aaaabhww"},{"source":"dft_oqmd","structure_type":null,"prototype":null,"strukturbericht":null,"pearson":null,"space_group":{"number":123,"symbol":"P4/mmm"},"detail":"on-hull OQMD Bi1 Li1 at x(LI)=0.5000","material_id":"oqmd-28740"},{"source":"literature_printed","structure_type":null,"prototype":"(BiLi)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":3},{"source":"sgte_mmc2","structure_type":"st:bili","prototype":"(BiLi)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for BILI_HT: BiLi (high T)"}],"review_reasons":["no_structure_token","polymorph_family:other phases of this system have the same composition","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:βBiLi","namespace":"paper","label":"βBiLi","basis":"corpus_mapping:unstated"},{"name":"tdb:BiLi-13Liu.tdb:BILI_HT","namespace":"tdb","label":"BILI_HT","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:bili","namespace":"corpus","label":"phase:bi-li:bili","in_sgte_corpus":false},{"name":"corpus:phase:bi-li:bili-ht","namespace":"corpus","label":"phase:bi-li:bili-ht","alias_of":"phase:bi-li:bili"}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"BILI_HT","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]},{"site_ratio":1.0,"constituents":["LI"]}],"stoichiometric":true,"composition":{"BI":0.5,"LI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":55,"line_end":55,"text":"PHASE BILI_HT % 2 1 1 !"},"constituent":{"line_start":56,"line_end":56,"text":"CONST BILI_HT : BI : LI : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BILI_HT","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["BI"],["LI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}}}],"stoichiometry":{"BI":0.5,"LI":0.5},"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":680.0,"T_max_K":680.0,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false}],"literature":{"values":3,"accepted_values":3,"papers":1},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BILI_HT","βBiLi"],"values":3,"tdb_files":["BiLi-13Liu.tdb"]},{"doi":"10.1149/1.2131401","citation":"W. Weppner, R. A. Huggins, Thermodynamic Properties of the Intermetallic Systems Lithium‐Antimony and Lithium‐Bismuth, J. Electrochem. Soc. 125, 7-14 (1978).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":2},{"id":"phase:bi-li:bili-l10","system":"BI-LI","elements":["BI","LI"],"preferred_name":"BILI_L10","status":"assigned","structure":{"structure_type":"st:l1-0-aucu-tp4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"AuCu","strukturbericht":"L1_0","pearson":"tP4","space_group":{"number":123,"symbol":"P4/mmm"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:αBiLi","namespace":"paper","label":"αBiLi","basis":"corpus_mapping:unstated"},{"name":"tdb:BiLi-13Liu.tdb:BILI_L10","namespace":"tdb","label":"BILI_L10","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:bili-l10","namespace":"corpus","label":"phase:bi-li:bili-l10","in_sgte_corpus":true}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"BILI_L10","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]},{"site_ratio":1.0,"constituents":["LI"]}],"stoichiometric":true,"composition":{"BI":0.5,"LI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":50,"line_end":50,"text":"PHASE BILI_L10 % 2 1 1 !"},"constituent":{"line_start":51,"line_end":51,"text":"CONST BILI_L10 : BI : LI : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BILI_L10","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["BI"],["LI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}},"tdb_comment_structure":["Prototype AuCu (tP2, P4/mmm)"]}],"stoichiometry":{"BI":0.5,"LI":0.5},"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":300.0,"T_max_K":670.0,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false}],"literature":{"values":5,"accepted_values":5,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BILI_L10","αBiLi"],"values":5,"tdb_files":["BiLi-13Liu.tdb"]},{"doi":"10.1149/1.2131401","citation":"W. Weppner, R. A. Huggins, Thermodynamic Properties of the Intermetallic Systems Lithium‐Antimony and Lithium‐Bismuth, J. Electrochem. Soc. 125, 7-14 (1978).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":2},{"id":"phase:bi-li:bili3-d03","system":"BI-LI","elements":["BI","LI"],"preferred_name":"BILI3_D03","status":"assigned","structure":{"structure_type":"st:d0-3-bif3-cf16","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"BiF3","strukturbericht":"D0_3","pearson":"cF16","space_group":{"number":225,"symbol":"Fm-3m"},"caveats":["DFT agrees: on-hull mp-aaaabije and oqmd-10938, space group 225"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:BiLi3","namespace":"paper","label":"BiLi3","basis":"corpus_mapping:unstated"},{"name":"tdb:BiLi-13Liu.tdb:BILI3_D03","namespace":"tdb","label":"BILI3_D03","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:bili3-d03","namespace":"corpus","label":"phase:bi-li:bili3-d03","in_sgte_corpus":true},{"name":"mp:mp-aaaabije","namespace":"mp","label":"mp-aaaabije","basis":"standard_name"},{"name":"oqmd:oqmd-10938","namespace":"oqmd","label":"oqmd-10938","basis":"standard_name"}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"BILI3_D03","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI"]},{"site_ratio":3.0,"constituents":["LI"]}],"stoichiometric":true,"composition":{"BI":0.25,"LI":0.75},"tdb_definition":{"verbatim":{"phase":{"line_start":60,"line_end":60,"text":"PHASE BILI3_D03 % 2 1 3 !"},"constituent":{"line_start":61,"line_end":61,"text":"CONST BILI3_D03 : BI : LI : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"BILI3_D03","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["BI"],["LI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}},"tdb_comment_structure":["Prototype BiF3 (cF16, Fm-3m)"]}],"stoichiometry":{"BI":0.25,"LI":0.75},"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":300.0,"T_max_K":1431.82,"x_min":0.75,"x_max":0.75,"stable_at_top_of_range":false}],"literature":{"values":8,"accepted_values":8,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BILI3_D03","BiLi3"],"values":8,"tdb_files":["BiLi-13Liu.tdb"]},{"doi":"10.1149/1.2131401","citation":"W. Weppner, R. A. Huggins, Thermodynamic Properties of the Intermetallic Systems Lithium‐Antimony and Lithium‐Bismuth, J. Electrochem. Soc. 125, 7-14 (1978).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":2},{"id":"phase:bi-li:fcc-a1","system":"BI-LI","elements":["BI","LI"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:BiLi-13Liu.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:fcc-a1","namespace":"corpus","label":"phase:bi-li:fcc-a1","in_sgte_corpus":false}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["BI","LI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":30,"line_end":30,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":31,"line_end":31,"text":"CONST FCC_A1 : BI LI : VA : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":68,"line_end":68,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["BI","LI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":68},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["BiLi-13Liu.tdb"]}],"total_papers":1},{"id":"phase:bi-li:hcp-a3","system":"BI-LI","elements":["BI","LI"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:BiLi-13Liu.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:hcp-a3","namespace":"corpus","label":"phase:bi-li:hcp-a3","in_sgte_corpus":false}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["BI","LI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":40,"line_end":40,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":41,"line_end":41,"text":"CONST HCP_A3 : BI LI : VA: !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":68,"line_end":68,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["BI","LI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":68},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["BiLi-13Liu.tdb"]}],"total_papers":1},{"id":"phase:bi-li:liquid","system":"BI-LI","elements":["BI","LI"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.tca.2013.01.029:liq","namespace":"paper","label":"liq","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.tca.2013.01.029:liquid","namespace":"paper","label":"liquid","basis":"exact_tdb_name"},{"name":"tdb:BiLi-13Liu.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd"},{"name":"corpus:phase:bi-li:liquid","namespace":"corpus","label":"phase:bi-li:liquid","in_sgte_corpus":true}],"models":[{"tdb":"BiLi-13Liu.tdb","path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["BI","BILI3","LI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":25,"line_end":25,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":26,"line_end":26,"text":"CONST LIQUID:L : BI BILI3 LI : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["BI","BILI3","LI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":8,"by_kind":{"G":3,"L":5},"L_by_order":{"0":2,"1":2,"2":1},"interaction_orders":[0,1,2],"endmember_G":3},"provenance":{"path":"databases/sgte-binary/BiLi-13Liu.tdb","sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/BiLi-13Liu.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/BiLi-13Liu.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"BiLi-13Liu.tdb","tdb_sha256":"15b3439c7d98d6a9ed48d06ea0d9e86e501638e2a84d00eb91869b534411c7cd","diagram":"phase-diagrams/sgte/BiLi-13Liu.json","status":"ok","x_element":"LI","stable":true,"T_min_K":453.07,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":14,"accepted_values":14,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.tca.2013.01.029","citation":"Yajun Liu, Zhitao Kang, Jiang Wang, Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems, Thermochimica Acta 558, 53-60 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["LIQUID","liq","liquid"],"values":14,"tdb_files":["BiLi-13Liu.tdb"]},{"doi":"10.1149/1.2131401","citation":"W. Weppner, R. A. Huggins, Thermodynamic Properties of the Intermetallic Systems Lithium‐Antimony and Lithium‐Bismuth, J. Electrochem. Soc. 125, 7-14 (1978).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1007/bf02645966","citation":"J. Sangster, A.D. Pelton, The Bi–Li (bismuth–lithium) system, J. Phase Equilib. 12 (1991) 447–450.","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":3}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:a7-alpha-as-hr2":{"id":"st:a7-alpha-as-hr2","prototype":"alpha-As","prototype_spellings":[],"strukturbericht":"A7","pearson":"hR2","space_group":{"number":166,"symbol":"R-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":1},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":110},"st:d0-3-bif3-cf16":{"id":"st:d0-3-bif3-cf16","prototype":"BiF3","prototype_spellings":["AlFe3"],"strukturbericht":"D0_3","pearson":"cF16","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":"Bi1F3","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":32},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":21},"st:l1-0-aucu-tp4":{"id":"st:l1-0-aucu-tp4","prototype":"AuCu","prototype_spellings":[],"strukturbericht":"L1_0","pearson":"tP4","space_group":{"number":123,"symbol":"P4/mmm"},"stoichiometry":"Au1Cu1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":25},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":17},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}
