{"system":"CA-NA","release":"v2026.10","phases":[{"id":"phase:ca-na:bcc-a2","system":"CA-NA","elements":["CA","NA"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2003.09.001:Bcc(Ca)","namespace":"paper","label":"Bcc(Ca)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2003.09.001:bcc(Ca)","namespace":"paper","label":"bcc(Ca)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2003.09.001:bcc(Na)","namespace":"paper","label":"bcc(Na)","basis":"corpus_mapping:unstated"},{"name":"tdb:CaNa-03Zha.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751"},{"name":"corpus:phase:ca-na:bcc-a2","namespace":"corpus","label":"phase:ca-na:bcc-a2","in_sgte_corpus":true}],"models":[{"tdb":"CaNa-03Zha.tdb","path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["CA","NA"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":33,"line_end":33,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":34,"line_end":34,"text":"CONST BCC_A2 : CA% NA% : VA : !"},"type_definitions":[{"line_start":45,"line_end":45,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":47,"line_end":47,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["CA%","NA%"],["VA"]],"major_constituents":[["CA","NA"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":47},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CaNa-03Zha.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CaNa-03Zha.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CaNa-03Zha.tdb","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","diagram":"phase-diagrams/sgte/CaNa-03Zha.json","status":"ok","x_element":"NA","stable":true,"T_min_K":300.0,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":4,"accepted_values":4,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2003.09.001","citation":"Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BCC_A2","Bcc(Ca)","bcc(Ca)","bcc(Na)"],"values":4,"tdb_files":["CaNa-03Zha.tdb"]}],"total_papers":1},{"id":"phase:ca-na:fcc-a1","system":"CA-NA","elements":["CA","NA"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2003.09.001:fcc(Ca)","namespace":"paper","label":"fcc(Ca)","basis":"corpus_mapping:unstated"},{"name":"tdb:CaNa-03Zha.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751"},{"name":"corpus:phase:ca-na:fcc-a1","namespace":"corpus","label":"phase:ca-na:fcc-a1","in_sgte_corpus":true}],"models":[{"tdb":"CaNa-03Zha.tdb","path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CA","NA"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":28,"line_end":28,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":29,"line_end":29,"text":"CONST FCC_A1 : CA% NA : VA : !"},"type_definitions":[{"line_start":45,"line_end":45,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":46,"line_end":46,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["CA%","NA"],["VA"]],"major_constituents":[["CA"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":46},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CaNa-03Zha.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CaNa-03Zha.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CaNa-03Zha.tdb","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","diagram":"phase-diagrams/sgte/CaNa-03Zha.json","status":"ok","x_element":"NA","stable":true,"T_min_K":300.0,"T_max_K":716.03,"x_min":0.0,"x_max":0.00363,"stable_at_top_of_range":false}],"literature":{"values":1,"accepted_values":1,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2003.09.001","citation":"Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003).","roles":["assessment that models this phase","reports values for this phase"],"labels":["FCC_A1","fcc(Ca)"],"values":1,"tdb_files":["CaNa-03Zha.tdb"]}],"total_papers":1},{"id":"phase:ca-na:hcp-a3","system":"CA-NA","elements":["CA","NA"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:CaNa-03Zha.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751"},{"name":"corpus:phase:ca-na:hcp-a3","namespace":"corpus","label":"phase:ca-na:hcp-a3","in_sgte_corpus":false}],"models":[{"tdb":"CaNa-03Zha.tdb","path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CA","NA"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":38,"line_end":38,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":39,"line_end":39,"text":"CONST HCP_A3 : CA NA : VA : !"},"type_definitions":[{"line_start":45,"line_end":45,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":46,"line_end":46,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["CA","NA"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":46},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CaNa-03Zha.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CaNa-03Zha.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CaNa-03Zha.tdb","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","diagram":"phase-diagrams/sgte/CaNa-03Zha.json","status":"ok","x_element":"NA","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2003.09.001","citation":"Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["CaNa-03Zha.tdb"]}],"total_papers":1},{"id":"phase:ca-na:liquid","system":"CA-NA","elements":["CA","NA"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.calphad.2003.09.001:Liquid2","namespace":"paper","label":"Liquid2","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2003.09.001:liquid2","namespace":"paper","label":"liquid2","basis":"corpus_mapping:unstated"},{"name":"tdb:CaNa-03Zha.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751"},{"name":"corpus:phase:ca-na:liquid","namespace":"corpus","label":"phase:ca-na:liquid","in_sgte_corpus":true}],"models":[{"tdb":"CaNa-03Zha.tdb","path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CA","NA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":23,"line_end":23,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":24,"line_end":24,"text":"CONST LIQUID:L : CA NA : !"},"type_definitions":[{"line_start":45,"line_end":45,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["CA","NA"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CaNa-03Zha.tdb","sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CaNa-03Zha.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CaNa-03Zha.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CaNa-03Zha.tdb","tdb_sha256":"5ea350c8fd6e8ccc531a1731f95e9c4f51654d8da5e0fd593eb3c893e0ef8751","diagram":"phase-diagrams/sgte/CaNa-03Zha.json","status":"ok","x_element":"NA","stable":true,"T_min_K":370.87,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":4,"accepted_values":4,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.calphad.2003.09.001","citation":"Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003).","roles":["assessment that models this phase","reports values for this phase"],"labels":["LIQUID","Liquid2","liquid2"],"values":4,"tdb_files":["CaNa-03Zha.tdb"]}],"total_papers":1}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}