{"system":"CU-HF","release":"v2026.10","phases":[{"id":"phase:cu-hf:bcc-a2","system":"CU-HF","elements":["CU","HF"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:(βHf)","namespace":"paper","label":"(βHf)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.actamat.2012.10.014:bcc","namespace":"paper","label":"bcc","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.jallcom.2006.02.013:bcc","namespace":"paper","label":"bcc","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:bcc-a2","namespace":"corpus","label":"phase:cu-hf:bcc-a2","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":30,"line_end":30,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":31,"line_end":31,"text":"CONST BCC_A2 : CU HF% : VA : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":69,"line_end":69,"text":"TYPE_DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":69},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}}},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":38,"line_end":38,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":39,"line_end":39,"text":"CONST BCC_A2 : CU HF% : VA : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":77,"line_end":77,"text":"TYPE_DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":77},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}}},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":32,"line_end":32,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":33,"line_end":33,"text":"CONST BCC_A2 : CU HF% : VA : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":71,"line_end":71,"text":"TYPE_DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":71},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1813.67,"T_max_K":3999.73,"x_min":0.95737,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1815.4,"T_max_K":2506.99,"x_min":0.9556,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1812.79,"T_max_K":3999.59,"x_min":0.95774,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":6,"accepted_values":6,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["bcc"]},"references":[{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(βHf)","BCC_A2"],"values":2,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BCC_A2","bcc"],"values":2,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["BCC_A2","bcc"],"values":2,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":4},{"id":"phase:cu-hf:cu10hf7","system":"CU-HF","elements":["CU","HF"],"preferred_name":"CU10HF7","status":"assigned","structure":{"structure_type":"st:ni10zr7-oc68","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"Cu10Hf7","model":"Cu10Hf7","pearson":"oC68","phase_name":"CU10HF7","prototype":"Ni10Zr7","space_group":{"number":64,"symbol":"Cmce"},"strukturbericht":null}]},"prototype":"Ni10Zr7","strukturbericht":null,"pearson":"oC68","space_group":{"number":64,"symbol":"Cmce"},"caveats":["not certain from the name or DFT alone (mp_oqmd_space_groups_differ, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:Cu10Hf7","namespace":"paper","label":"Cu10Hf7","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.actamat.2012.10.014:Cu10Hf7","namespace":"paper","label":"Cu10Hf7","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.jallcom.2006.02.013:Cu10Hf7","namespace":"paper","label":"Cu10Hf7","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:CU10HF7","namespace":"tdb","label":"CU10HF7","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:CU10HF7","namespace":"tdb","label":"CU10HF7","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:CU10HF7","namespace":"tdb","label":"CU10HF7","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:cu10hf7","namespace":"corpus","label":"phase:cu-hf:cu10hf7","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"CU10HF7","type_code":"%","sublattices":[{"site_ratio":10.0,"constituents":["CU"]},{"site_ratio":7.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.5882352941176471,"HF":0.4117647058823529},"tdb_definition":{"verbatim":{"phase":{"line_start":55,"line_end":55,"text":"PHASE CU10HF7 % 2 10 7 !"},"constituent":{"line_start":56,"line_end":56,"text":"CONST CU10HF7 : CU : HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU10HF7","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[10,7],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}},"tdb_comment_structure":["Prototype Ni10Zr7 (oC68, Cmca)"]},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"CU10HF7","type_code":"%","sublattices":[{"site_ratio":10.0,"constituents":["CU"]},{"site_ratio":7.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.5882352941176471,"HF":0.4117647058823529},"tdb_definition":{"verbatim":{"phase":{"line_start":63,"line_end":63,"text":"PHASE CU10HF7 % 2 10 7 !"},"constituent":{"line_start":64,"line_end":64,"text":"CONST CU10HF7 : CU : HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU10HF7","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[10,7],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}},"tdb_comment_structure":["Prototype Ni10Zr7 (oC68, Cmca)"]},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"CU10HF7","type_code":"%","sublattices":[{"site_ratio":10.0,"constituents":["CU"]},{"site_ratio":7.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.5882352941176471,"HF":0.4117647058823529},"tdb_definition":{"verbatim":{"phase":{"line_start":57,"line_end":57,"text":"PHASE CU10HF7 % 2 10 7 !"},"constituent":{"line_start":58,"line_end":58,"text":"CONST CU10HF7 : CU : HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU10HF7","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[10,7],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}},"tdb_comment_structure":["Prototype Ni10Zr7 (oC68, Cmca)"]}],"stoichiometry":{"CU":0.5882352941176471,"HF":0.4117647058823529},"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1257.75,"x_min":0.41176,"x_max":0.41176,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1256.22,"x_min":0.41176,"x_max":0.41176,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1279.43,"x_min":0.41176,"x_max":0.41176,"stable_at_top_of_range":false}],"literature":{"values":35,"accepted_values":34,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["Cu10Hf7"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["CU10HF7","Cu10Hf7"],"values":19,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU10HF7","Cu10Hf7"],"values":11,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU10HF7","Cu10Hf7"],"values":7,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1107/s0108270197007142","citation":"J.-M. Joubert, R. Cerný, K. Yvon, M. Latroche, A. Percheron-Guégan, Zirconium–Nickel, Zr<sub>7</sub>Ni<sub>10</sub>: Space Group Revision for the Stoichiometric Phase, Acta Crystallogr C Cryst Struct Commun 53, 1536-1538 (1997).","roles":["cited as the source of values for this phase"],"labels":[],"values":4},{"doi":"10.1007/bf02877460","citation":"P.R. Subramanian, D.E. Laughlin, Bull. Alloy Phase Diagrams 9 (1) (1988) 51–55.","roles":["cited as the source of values for this phase"],"labels":[],"values":3},{"doi":"10.1007/bf02667755","citation":"O. J. Kleppa, Shunroku Watanabe, Thermochemistry of alloys of transition metals: Part III. Copper-Silver, -Titanium, Zirconium, and -Hafnium at 1373 K, Metall Trans B 13, 391-401 (1982).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1007/bf02736446","citation":"R. H. Woodman, B. R. Klotz, L. J. Kecskes, Observation of incongruent melting in Cu10Hf7, JPED 27, 477-481 (2006).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1016/j.actamat.2007.01.037","citation":"G. Ghosh, First-principles calculations of structural energetics of Cu–TM (TM=Ti, Zr, Hf) intermetallics, Acta Materialia 55, 3347-3374 (2007).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":9},{"id":"phase:cu-hf:cu51hf14","system":"CU-HF","elements":["CU","HF"],"preferred_name":"CU51HF14","status":"assigned","structure":{"structure_type":"st:ag51gd14-hp68","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"Cu51Hf14","model":"Cu51Hf14","pearson":"hP68","phase_name":"CU51HF14","prototype":"Ag51Gd14","space_group":{"number":175,"symbol":"P6/m"},"strukturbericht":null}]},"prototype":"Ag51Gd14","strukturbericht":null,"pearson":"hP68","space_group":{"number":175,"symbol":"P6/m"},"caveats":["not certain from the name or DFT alone (no_on_hull_entry_in_oqmd, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:Cu51Hf14","namespace":"paper","label":"Cu51Hf14","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.actamat.2012.10.014:Cu51Hf14","namespace":"paper","label":"Cu51Hf14","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.jallcom.2006.02.013:Cu51Hf14","namespace":"paper","label":"Cu51Hf14","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:CU51HF14","namespace":"tdb","label":"CU51HF14","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:CU51HF14","namespace":"tdb","label":"CU51HF14","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:CU51HF14","namespace":"tdb","label":"CU51HF14","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:cu51hf14","namespace":"corpus","label":"phase:cu-hf:cu51hf14","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"CU51HF14","type_code":"%","sublattices":[{"site_ratio":51.0,"constituents":["CU"]},{"site_ratio":14.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7846153846153846,"HF":0.2153846153846154},"tdb_definition":{"verbatim":{"phase":{"line_start":45,"line_end":45,"text":"PHASE CU51HF14 % 2 51 14 !"},"constituent":{"line_start":46,"line_end":46,"text":"CONST CU51HF14 : CU : HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU51HF14","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[51,14],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}},"tdb_comment_structure":["Prototype Ag51Gd14 (hP68, P6/m)"]},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"CU51HF14","type_code":"%","sublattices":[{"site_ratio":51.0,"constituents":["CU"]},{"site_ratio":14.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7846153846153846,"HF":0.2153846153846154},"tdb_definition":{"verbatim":{"phase":{"line_start":53,"line_end":53,"text":"PHASE CU51HF14 % 2 51 14 !"},"constituent":{"line_start":54,"line_end":54,"text":"CONST CU51HF14 : CU : HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU51HF14","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[51,14],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}},"tdb_comment_structure":["Prototype Ag51Gd14 (hP68, P6/m)"]},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"CU51HF14","type_code":"%","sublattices":[{"site_ratio":51.0,"constituents":["CU"]},{"site_ratio":14.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7846153846153846,"HF":0.2153846153846154},"tdb_definition":{"verbatim":{"phase":{"line_start":47,"line_end":47,"text":"PHASE CU51HF14 % 2 51 14 !"},"constituent":{"line_start":48,"line_end":48,"text":"CONST CU51HF14 : CU : HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU51HF14","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[51,14],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}},"tdb_comment_structure":["Prototype Ag51Gd14 (hP68, P6/m)"]}],"stoichiometry":{"CU":0.7846153846153846,"HF":0.2153846153846154},"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1388.0,"x_min":0.21538,"x_max":0.21538,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1385.04,"x_min":0.21538,"x_max":0.21538,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1384.91,"x_min":0.21538,"x_max":0.21538,"stable_at_top_of_range":false}],"literature":{"values":40,"accepted_values":39,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["Cu51Hf14"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["CU51HF14","Cu51Hf14"],"values":22,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU51HF14","Cu51Hf14"],"values":13,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU51HF14","Cu51Hf14"],"values":7,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1107/s0567740875003378","citation":"J.-P. Gabathuler, P. White, E. Parthé, Zr<sub>14</sub>Cu<sub>51</sub> and Hf<sub>14</sub>Cu<sub>51</sub> with GdAg<sub>3.6</sub> structure type, Acta Crystallogr B Struct Sci 31, 608-610 (1975).","roles":["cited as the source of values for this phase"],"labels":[],"values":7},{"doi":"10.1007/bf02877460","citation":"P.R. Subramanian, D.E. Laughlin, Bull. Alloy Phase Diagrams 9 (1) (1988) 51–55.","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1016/0025-5416(74)90021-4","citation":"A.J Perry, Copper-Cu5Hf alloys: Their constitution and some properties after directional solidification, Materials Science and Engineering 13, 57-62 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1007/bf02667755","citation":"O. J. Kleppa, Shunroku Watanabe, Thermochemistry of alloys of transition metals: Part III. Copper-Silver, -Titanium, Zirconium, and -Hafnium at 1373 K, Metall Trans B 13, 391-401 (1982).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1016/j.actamat.2007.01.037","citation":"G. Ghosh, First-principles calculations of structural energetics of Cu–TM (TM=Ti, Zr, Hf) intermetallics, Acta Materialia 55, 3347-3374 (2007).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":9},{"id":"phase:cu-hf:cu5hf-c15b","system":"CU-HF","elements":["CU","HF"],"preferred_name":"CU5HF_C15B","status":"assigned","structure":{"structure_type":"st:c15-b-aube5-cf24","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"AuBe5","strukturbericht":"C15_b","pearson":"cF24","space_group":{"number":216,"symbol":"F-43m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:Cu5Hf","namespace":"paper","label":"Cu5Hf","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.actamat.2012.10.014:Cu5Hf","namespace":"paper","label":"Cu5Hf","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.jallcom.2006.02.013:Cu5Hf","namespace":"paper","label":"Cu5Hf","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:CU5HF_C15B","namespace":"tdb","label":"CU5HF_C15B","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:CU5HF_C15B","namespace":"tdb","label":"CU5HF_C15B","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:CU5HF_C15B","namespace":"tdb","label":"CU5HF_C15B","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:cu5hf-c15b","namespace":"corpus","label":"phase:cu-hf:cu5hf-c15b","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"CU5HF_C15B","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["CU"]},{"site_ratio":1.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.8333333333333334,"HF":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":40,"line_end":40,"text":"PHASE CU5HF_C15B % 2 5 1 !"},"constituent":{"line_start":41,"line_end":41,"text":"CONST CU5HF_C15B : CU : HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU5HF_C15B","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}},"tdb_comment_structure":["Prototype AuBe5 (cF24, F-43m); assumed to be the same as for Cu5Zr"]},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"CU5HF_C15B","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["CU"]},{"site_ratio":1.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.8333333333333334,"HF":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":48,"line_end":48,"text":"PHASE CU5HF_C15B % 2 5 1 !"},"constituent":{"line_start":49,"line_end":49,"text":"CONST CU5HF_C15B : CU : HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU5HF_C15B","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}},"tdb_comment_structure":["Prototype AuBe5 (cF24, F-43m); assumed to be the same as for Cu5Zr"]},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"CU5HF_C15B","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["CU"]},{"site_ratio":1.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.8333333333333334,"HF":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":42,"line_end":42,"text":"PHASE CU5HF_C15B % 2 5 1 !"},"constituent":{"line_start":43,"line_end":43,"text":"CONST CU5HF_C15B : CU : HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU5HF_C15B","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}},"tdb_comment_structure":["Prototype AuBe5 (cF24, F-43m); assumed to be the same as for Cu5Zr"]}],"stoichiometry":{"CU":0.8333333333333334,"HF":0.16666666666666666},"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1326.8,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1313.2,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1332.63,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false}],"literature":{"values":25,"accepted_values":24,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"formula_identity/confirmed":2},"printed_labels":["Cu5Hf"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["CU5HF_C15B","Cu5Hf"],"values":14,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU5HF_C15B","Cu5Hf"],"values":8,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU5HF_C15B","Cu5Hf"],"values":5,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0025-5416(74)90021-4","citation":"A.J Perry, Copper-Cu5Hf alloys: Their constitution and some properties after directional solidification, Materials Science and Engineering 13, 57-62 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":4},{"doi":"10.1016/j.actamat.2007.01.037","citation":"G. Ghosh, First-principles calculations of structural energetics of Cu–TM (TM=Ti, Zr, Hf) intermetallics, Acta Materialia 55, 3347-3374 (2007).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":5},{"id":"phase:cu-hf:cu8hf3","system":"CU-HF","elements":["CU","HF"],"preferred_name":"CU8HF3","status":"assigned","structure":{"structure_type":"st:cu8hf3-op44","basis":"dft_unique_match","tier":"B","confidence":"high","label":"DFT-supported","dft":{"mp":"mp-aaaaakwv","oqmd":"oqmd-32345","space_group_number":62,"space_group_symbol":"Pnma"},"prototype":"Cu8Hf3","strukturbericht":null,"pearson":"oP44","space_group":{"number":62,"symbol":"Pnma"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:Cu8Hf3","namespace":"paper","label":"Cu8Hf3","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.actamat.2012.10.014:Cu8Hf3","namespace":"paper","label":"Cu8Hf3","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.jallcom.2006.02.013:Cu8Hf3","namespace":"paper","label":"Cu8Hf3","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:CU8HF3","namespace":"tdb","label":"CU8HF3","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:CU8HF3","namespace":"tdb","label":"CU8HF3","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:CU8HF3","namespace":"tdb","label":"CU8HF3","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:cu8hf3","namespace":"corpus","label":"phase:cu-hf:cu8hf3","in_sgte_corpus":true},{"name":"mp:mp-aaaaakwv","namespace":"mp","label":"mp-aaaaakwv","basis":"dft_unique_match"},{"name":"oqmd:oqmd-32345","namespace":"oqmd","label":"oqmd-32345","basis":"dft_unique_match"}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"CU8HF3","type_code":"%","sublattices":[{"site_ratio":8.0,"constituents":["CU"]},{"site_ratio":3.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7272727272727273,"HF":0.2727272727272727},"tdb_definition":{"verbatim":{"phase":{"line_start":50,"line_end":50,"text":"PHASE CU8HF3 % 2 8 3 !"},"constituent":{"line_start":51,"line_end":51,"text":"CONST CU8HF3 : CU : HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU8HF3","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[8,3],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}},"tdb_comment_structure":["Prototype Cu8Hf3 (oP44, Pnma)"]},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"CU8HF3","type_code":"%","sublattices":[{"site_ratio":8.0,"constituents":["CU"]},{"site_ratio":3.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7272727272727273,"HF":0.2727272727272727},"tdb_definition":{"verbatim":{"phase":{"line_start":58,"line_end":58,"text":"PHASE CU8HF3 % 2 8 3 !"},"constituent":{"line_start":59,"line_end":59,"text":"CONST CU8HF3 : CU : HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU8HF3","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[8,3],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}},"tdb_comment_structure":["Prototype Cu8Hf3 (oP44, Pnma)"]},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"CU8HF3","type_code":"%","sublattices":[{"site_ratio":8.0,"constituents":["CU"]},{"site_ratio":3.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.7272727272727273,"HF":0.2727272727272727},"tdb_definition":{"verbatim":{"phase":{"line_start":52,"line_end":52,"text":"PHASE CU8HF3 % 2 8 3 !"},"constituent":{"line_start":53,"line_end":53,"text":"CONST CU8HF3 : CU : HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CU8HF3","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[8,3],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}},"tdb_comment_structure":["Prototype Cu8Hf3 (oP44, Pnma)"]}],"stoichiometry":{"CU":0.7272727272727273,"HF":0.2727272727272727},"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1263.85,"x_min":0.27273,"x_max":0.27273,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":321.43,"T_max_K":1262.38,"x_min":0.27273,"x_max":0.27273,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1274.49,"x_min":0.27273,"x_max":0.27273,"stable_at_top_of_range":false}],"literature":{"values":29,"accepted_values":29,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["Cu8Hf3"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["CU8HF3","Cu8Hf3"],"values":17,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU8HF3","Cu8Hf3"],"values":9,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CU8HF3","Cu8Hf3"],"values":5,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0022-5088(75)90085-5","citation":"Lars Bsenko, Crystallographic data for intermediate phases in the copper-zirconium and copper-hafnium systems, Journal of the Less Common Metals 40, 365-366 (1975).","roles":["cited as the source of values for this phase"],"labels":[],"values":7},{"doi":"10.1007/bf02877460","citation":"P.R. Subramanian, D.E. Laughlin, Bull. Alloy Phase Diagrams 9 (1) (1988) 51–55.","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1016/j.actamat.2007.01.037","citation":"G. Ghosh, First-principles calculations of structural energetics of Cu–TM (TM=Ti, Zr, Hf) intermetallics, Acta Materialia 55, 3347-3374 (2007).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":6},{"id":"phase:cu-hf:cuhf2","system":"CU-HF","elements":["CU","HF"],"preferred_name":"CUHF2","status":"assigned","structure":{"structure_type":"st:cuzr2-ti6","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"CuHf2","model":"CuHf2","pearson":"tI6","phase_name":"CUHF2","prototype":"CuZr2","space_group":{"number":139,"symbol":"I4/mmm"},"strukturbericht":null}]},"prototype":"CuZr2","strukturbericht":null,"pearson":"tI6","space_group":{"number":139,"symbol":"I4/mmm"},"caveats":["not certain from the name or DFT alone (mp_oqmd_space_groups_differ, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:CuHf2","namespace":"paper","label":"CuHf2","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.actamat.2012.10.014:CuHf2","namespace":"paper","label":"CuHf2","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.jallcom.2006.02.013:CuHf2","namespace":"paper","label":"CuHf2","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:CUHF2","namespace":"tdb","label":"CUHF2","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:CUHF2","namespace":"tdb","label":"CUHF2","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:CUHF2","namespace":"tdb","label":"CUHF2","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:cuhf2","namespace":"corpus","label":"phase:cu-hf:cuhf2","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"CUHF2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU"]},{"site_ratio":2.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.3333333333333333,"HF":0.6666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":60,"line_end":60,"text":"PHASE CUHF2 % 2 1 2 !"},"constituent":{"line_start":61,"line_end":61,"text":"CONST CUHF2 : CU : HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CUHF2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}},"tdb_comment_structure":["Prototype CuZr2 (tI6, I4/mmm)"]},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"CUHF2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU"]},{"site_ratio":2.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.3333333333333333,"HF":0.6666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":68,"line_end":68,"text":"PHASE CUHF2 % 2 1 2 !"},"constituent":{"line_start":69,"line_end":69,"text":"CONST CUHF2 : CU : HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CUHF2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}},"tdb_comment_structure":["Prototype CuZr2 (tI6, I4/mmm)"]},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"CUHF2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU"]},{"site_ratio":2.0,"constituents":["HF"]}],"stoichiometric":true,"composition":{"CU":0.3333333333333333,"HF":0.6666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":62,"line_end":62,"text":"PHASE CUHF2 % 2 1 2 !"},"constituent":{"line_start":63,"line_end":63,"text":"CONST CUHF2 : CU : HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"CUHF2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["CU"],["HF"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}},"tdb_comment_structure":["Prototype CuZr2 (tI6, I4/mmm)"]}],"stoichiometry":{"CU":0.3333333333333333,"HF":0.6666666666666666},"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1583.68,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1611.26,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1588.98,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false}],"literature":{"values":42,"accepted_values":41,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["CuHf2"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["CUHF2","CuHf2"],"values":24,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CUHF2","CuHf2"],"values":12,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","cited as the source of values for this phase","reports values for this phase"],"labels":["CUHF2","CuHf2"],"values":8,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":4},{"doi":"10.1007/bf02667755","citation":"O. J. Kleppa, Shunroku Watanabe, Thermochemistry of alloys of transition metals: Part III. Copper-Silver, -Titanium, Zirconium, and -Hafnium at 1373 K, Metall Trans B 13, 391-401 (1982).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1007/bf02736446","citation":"R. H. Woodman, B. R. Klotz, L. J. Kecskes, Observation of incongruent melting in Cu10Hf7, JPED 27, 477-481 (2006).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1007/bf02877460","citation":"P.R. Subramanian, D.E. Laughlin, Bull. Alloy Phase Diagrams 9 (1) (1988) 51–55.","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1016/j.actamat.2007.01.037","citation":"G. Ghosh, First-principles calculations of structural energetics of Cu–TM (TM=Ti, Zr, Hf) intermetallics, Acta Materialia 55, 3347-3374 (2007).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":8},{"id":"phase:cu-hf:fcc-a1","system":"CU-HF","elements":["CU","HF"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:(Cu)","namespace":"paper","label":"(Cu)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.actamat.2012.10.014:fcc","namespace":"paper","label":"fcc","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.jallcom.2006.02.013:fcc","namespace":"paper","label":"fcc","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:fcc-a1","namespace":"corpus","label":"phase:cu-hf:fcc-a1","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":25,"line_end":25,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":26,"line_end":26,"text":"CONST FCC_A1 : CU% HF : VA : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":68,"line_end":68,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["CU%","HF"],["VA"]],"major_constituents":[["CU"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":68},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}}},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":33,"line_end":33,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":34,"line_end":34,"text":"CONST FCC_A1 : CU% HF : VA : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":76,"line_end":76,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["CU%","HF"],["VA"]],"major_constituents":[["CU"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":76},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}}},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":27,"line_end":27,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":28,"line_end":28,"text":"CONST FCC_A1 : CU% HF : VA : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":70,"line_end":70,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["CU%","HF"],["VA"]],"major_constituents":[["CU"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":70},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1360.87,"x_min":0.0,"x_max":0.00276,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1387.77,"x_min":0.0,"x_max":0.00279,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":1360.51,"x_min":0.0,"x_max":0.0042,"stable_at_top_of_range":false}],"literature":{"values":13,"accepted_values":12,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["fcc"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["FCC_A1","fcc"],"values":6,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(Cu)","FCC_A1"],"values":5,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["FCC_A1","fcc"],"values":2,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0025-5416(74)90021-4","citation":"A.J Perry, Copper-Cu5Hf alloys: Their constitution and some properties after directional solidification, Materials Science and Engineering 13, 57-62 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":4},{"id":"phase:cu-hf:hcp-a3","system":"CU-HF","elements":["CU","HF"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:(αHf)","namespace":"paper","label":"(αHf)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.actamat.2012.10.014:hcp","namespace":"paper","label":"hcp","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.jallcom.2006.02.013:hcp","namespace":"paper","label":"hcp","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:hcp-a3","namespace":"corpus","label":"phase:cu-hf:hcp-a3","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":35,"line_end":35,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":36,"line_end":36,"text":"CONST HCP_A3 : CU HF% : VA : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":68,"line_end":68,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":68},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}}},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":43,"line_end":43,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":44,"line_end":44,"text":"CONST HCP_A3 : CU HF% : VA : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":76,"line_end":76,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":76},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}}},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":37,"line_end":37,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":38,"line_end":38,"text":"CONST HCP_A3 : CU HF% : VA : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null},{"line_start":70,"line_end":70,"text":"TYPE_DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["CU","HF%"],["VA"]],"major_constituents":[["HF"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":70},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":2017.02,"x_min":0.99379,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":2016.02,"x_min":0.99695,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":300.0,"T_max_K":2501.02,"x_min":0.99886,"x_max":1.0,"stable_at_top_of_range":false}],"literature":{"values":15,"accepted_values":14,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":2,"mapping_basis":{"curator/confirmed":2},"printed_labels":["hcp"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["HCP_A3","hcp"],"values":6,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(αHf)","HCP_A3"],"values":5,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["HCP_A3","hcp"],"values":4,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":5}],"total_papers":4},{"id":"phase:cu-hf:liquid","system":"CU-HF","elements":["CU","HF"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11106-008-9008-4:L","namespace":"paper","label":"L","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.actamat.2012.10.014:L","namespace":"paper","label":"L","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.actamat.2012.10.014:Liquid","namespace":"paper","label":"Liquid","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.actamat.2012.10.014:liquid","namespace":"paper","label":"liquid","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.jallcom.2006.02.013:Liquid","namespace":"paper","label":"Liquid","basis":"corpus_mapping:confirmed"},{"name":"paper:10.1016/j.jallcom.2006.02.013:liquid","namespace":"paper","label":"liquid","basis":"corpus_mapping:confirmed"},{"name":"tdb:CuHf-06Lia.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442"},{"name":"tdb:CuHf-08Tur.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d"},{"name":"tdb:CuHf-13Zho.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5"},{"name":"corpus:phase:cu-hf:liquid","namespace":"corpus","label":"phase:cu-hf:liquid","in_sgte_corpus":true}],"models":[{"tdb":"CuHf-06Lia.tdb","path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":20,"line_end":20,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":21,"line_end":21,"text":"CONST LIQUID:L : CU HF : !"},"type_definitions":[{"line_start":67,"line_end":67,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["CU","HF"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-06Lia.tdb","sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-06Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-06Lia.tdb"}}},{"tdb":"CuHf-08Tur.tdb","path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU","CUHF","CUHF3","HF"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":28,"line_end":28,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":29,"line_end":29,"text":"CONST LIQUID:L : CU CUHF CUHF3 HF : !"},"type_definitions":[{"line_start":75,"line_end":75,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["CU","CUHF","CUHF3","HF"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":4},"L_by_order":{},"interaction_orders":[],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/CuHf-08Tur.tdb","sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-08Tur.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-08Tur.tdb"}}},{"tdb":"CuHf-13Zho.tdb","path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["CU","HF"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":22,"line_end":22,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":23,"line_end":23,"text":"CONST LIQUID:L : CU HF : !"},"type_definitions":[{"line_start":69,"line_end":69,"text":"TYPE-DEFINITION % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["CU","HF"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":5,"by_kind":{"G":2,"L":3},"L_by_order":{"0":1,"1":1,"2":1},"interaction_orders":[0,1,2],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/CuHf-13Zho.tdb","sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/CuHf-13Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/CuHf-13Zho.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"CuHf-06Lia.tdb","tdb_sha256":"0c635db89455db2193d2338dc7c2c7254656d48062f08f84dc42892948b58442","diagram":"phase-diagrams/sgte/CuHf-06Lia.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1233.92,"T_max_K":4000.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"CuHf-08Tur.tdb","tdb_sha256":"06d472151340d413caab538d0c986d4360544f591246ec54e843796570015f0d","diagram":"phase-diagrams/sgte/CuHf-08Tur.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1254.11,"T_max_K":4000.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"CuHf-13Zho.tdb","tdb_sha256":"e3133d3e66ab9d10462b3945eeb6ffe7f2f660a143f1f84efa8cd389c04aa7b5","diagram":"phase-diagrams/sgte/CuHf-13Zho.json","status":"ok","x_element":"HF","calc_T_range_K":[300,4000],"stable":true,"T_min_K":1255.51,"T_max_K":4000.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":76,"accepted_values":73,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":3,"mapping_basis":{"curator/confirmed":3},"printed_labels":["Liquid","L"]},"references":[{"doi":"10.1016/j.actamat.2012.10.014","citation":"Yu Zhong, Arkapol Saengdeejing, Laszlo Kecskes, Bradley Klotz, Zi-Kui Liu, Experimental and computational studies of the Cu–Hf binary system, Acta Materialia 61, 660-669 (2013).","roles":["assessment that models this phase","reports values for this phase"],"labels":["L","LIQUID","Liquid","liquid"],"values":28,"tdb_files":["CuHf-13Zho.tdb"]},{"doi":"10.1007/s11106-008-9008-4","citation":"M. A. Turchanin, P. G. Agraval, Thermodynamic assessment of the copper-hafnium system, Powder Metall Met Ceram 47, 223-233 (2008).","roles":["assessment that models this phase","reports values for this phase"],"labels":["L","LIQUID"],"values":25,"tdb_files":["CuHf-08Tur.tdb"]},{"doi":"10.1016/j.jallcom.2006.02.013","citation":"Dong Liang, Yajun Liu, Reevaluation of the Cu–Hf binary system, Journal of Alloys and Compounds 426, 101-105 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["LIQUID","Liquid","liquid"],"values":23,"tdb_files":["CuHf-06Lia.tdb"]},{"doi":"10.1016/0022-3115(74)90184-6","citation":"B. Pieraggi, F. Dabosi, M. Armand, Diagramme de phases des alliages hafnium-cuivre riches en hafnium, Journal of Nuclear Materials 52, 336-338 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":8},{"doi":"10.1007/bf02877460","citation":"P.R. Subramanian, D.E. Laughlin, Bull. Alloy Phase Diagrams 9 (1) (1988) 51–55.","roles":["cited as the source of values for this phase"],"labels":[],"values":5},{"doi":"10.1016/0025-5416(74)90021-4","citation":"A.J Perry, Copper-Cu5Hf alloys: Their constitution and some properties after directional solidification, Materials Science and Engineering 13, 57-62 (1974).","roles":["cited as the source of values for this phase"],"labels":[],"values":5},{"doi":"10.1007/bf02736446","citation":"R. H. Woodman, B. R. Klotz, L. J. Kecskes, Observation of incongruent melting in Cu10Hf7, JPED 27, 477-481 (2006).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":7}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:ag51gd14-hp68":{"id":"st:ag51gd14-hp68","prototype":"Ag51Gd14","prototype_spellings":[],"strukturbericht":null,"pearson":"hP68","space_group":{"number":175,"symbol":"P6/m"},"stoichiometry":"Ag51Gd14","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":27}],"verification":"in Hallstedt 2025 mmc2","registry_phases":24},"st:c15-b-aube5-cf24":{"id":"st:c15-b-aube5-cf24","prototype":"AuBe5","prototype_spellings":[],"strukturbericht":"C15_b","pearson":"cF24","space_group":{"number":216,"symbol":"F-43m"},"stoichiometry":"Au1Be5","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15}],"verification":"in Hallstedt 2025 mmc2","registry_phases":11},"st:cu8hf3-op44":{"id":"st:cu8hf3-op44","prototype":"Cu8Hf3","prototype_spellings":[],"strukturbericht":null,"pearson":"oP44","space_group":{"number":62,"symbol":"Pnma"},"stoichiometry":"Cu8Hf3","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":2}],"verification":"in Hallstedt 2025 mmc2","registry_phases":2},"st:cuzr2-ti6":{"id":"st:cuzr2-ti6","prototype":"CuZr2","prototype_spellings":[],"strukturbericht":null,"pearson":"tI6","space_group":{"number":139,"symbol":"I4/mmm"},"stoichiometry":"Cu1Zr2","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15}],"verification":"in Hallstedt 2025 mmc2","registry_phases":13},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304},"st:ni10zr7-oc68":{"id":"st:ni10zr7-oc68","prototype":"Ni10Zr7","prototype_spellings":[],"strukturbericht":null,"pearson":"oC68","space_group":{"number":64,"symbol":"Cmce"},"stoichiometry":"Ni10Zr7","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":6}],"verification":"in Hallstedt 2025 mmc2","registry_phases":5}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}
