{"system":"P-SI","release":"v2026.10","phases":[{"id":"phase:p-si:a4-diamond","system":"P-SI","elements":["P","SI"],"preferred_name":"DIAMOND_A4","status":"assigned","structure":{"structure_type":"st:a4-c-diamond-cf8","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"C (diamond)","strukturbericht":"A4","pearson":"cF8","space_group":{"number":227,"symbol":"Fd-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11669-013-0269-3:(Si)","namespace":"paper","label":"(Si)","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2024.102758:Si","namespace":"paper","label":"Si","basis":"corpus_mapping:unstated"},{"name":"tdb:SiP-04Din-LB.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:a4-diamond","namespace":"corpus","label":"phase:p-si:a4-diamond","in_sgte_corpus":true},{"name":"corpus:phase:p-si:diamond-a4","namespace":"corpus","label":"phase:p-si:diamond-a4","alias_of":"phase:p-si:a4-diamond"}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":52,"line_end":52,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":53,"line_end":53,"text":"CONST DIAMOND_A4 : P SI% : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}},"tdb_comment_structure":["Prototype C (cF8)"]},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":55,"line_end":55,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":56,"line_end":56,"text":"CONST DIAMOND_A4 : P SI% : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}},"tdb_comment_structure":["Prototype C (cF8)"]},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":55,"line_end":55,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":56,"line_end":56,"text":"CONST DIAMOND_A4 : P SI% : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}},"tdb_comment_structure":["Prototype C (cF8)"]},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":58,"line_end":58,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":59,"line_end":59,"text":"CONST DIAMOND_A4 : P SI% : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}},"tdb_comment_structure":["Prototype C (cF8)"]}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1689.01,"x_min":0.0,"x_max":0.02402,"stable_at_top_of_range":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1689.27,"x_min":0.0,"x_max":0.01103,"stable_at_top_of_range":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":2499.24,"x_min":0.0,"x_max":0.0108,"stable_at_top_of_range":true},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1692.29,"x_min":0.0,"x_max":0.0093,"stable_at_top_of_range":false}],"literature":{"values":19,"accepted_values":17,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":1,"mapping_basis":{"curator/confirmed":1},"printed_labels":["Si"]},"references":[{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase","reports values for this phase"],"labels":["DIAMOND_A4","Si"],"values":13,"tdb_files":["SiP-24Fav.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase","reports values for this phase"],"labels":["(Si)","DIAMOND_A4"],"values":6,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["DIAMOND_A4"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11837-012-0387-0","citation":"In-Ho Jung, Yumin Zhang, Thermodynamic Calculations for the Dephosphorization of Silicon Using Molten Slag, JOM 64, 973-981 (2012).","roles":["cited as the source of values for this phase"],"labels":[],"values":1},{"doi":"10.1557/jmr.2011.130","citation":"Jafar Safarian, Merete Tangstad, Phase diagram study of the Si–P system in Si-rich region, J. Mater. Res. 26, 1494-1503 (2011).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":5},{"id":"phase:p-si:bcc-a2","system":"P-SI","elements":["P","SI"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:SiP-04Din-LB.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:bcc-a2","namespace":"corpus","label":"phase:p-si:bcc-a2","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":42,"line_end":42,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":43,"line_end":43,"text":"CONST BCC_A2 : P SI : VA : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":79,"line_end":79,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":79},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":45,"line_end":45,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":46,"line_end":46,"text":"CONST BCC_A2 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":87,"line_end":87,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":87},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":45,"line_end":45,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":46,"line_end":46,"text":"CONST BCC_A2 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":87,"line_end":87,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":87},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":48,"line_end":48,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":49,"line_end":49,"text":"CONST BCC_A2 : P SI : VA : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":90,"line_end":90,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":90},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:fcc-a1","system":"P-SI","elements":["P","SI"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:SiP-04Din-LB.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:fcc-a1","namespace":"corpus","label":"phase:p-si:fcc-a1","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":37,"line_end":37,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":38,"line_end":38,"text":"CONST FCC_A1 : P SI : VA : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":78,"line_end":78,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":78},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":40,"line_end":40,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":41,"line_end":41,"text":"CONST FCC_A1 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":86,"line_end":86,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":86},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":40,"line_end":40,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":41,"line_end":41,"text":"CONST FCC_A1 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":86,"line_end":86,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":86},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":43,"line_end":43,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":44,"line_end":44,"text":"CONST FCC_A1 : P SI : VA : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":89,"line_end":89,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":89},"disordered_part":null,"ordered_partner":null},"parameters":{"total":2,"by_kind":{"G":2},"L_by_order":{},"interaction_orders":[],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:gas","system":"P-SI","elements":["P","SI"],"preferred_name":"GAS","status":"assigned","structure":{"structure_type":"st:gas","basis":"gas","confidence":"high","label":"gas","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:SiP-04Din-LB.tdb:GAS","namespace":"tdb","label":"GAS","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:GAS","namespace":"tdb","label":"GAS","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:GAS","namespace":"tdb","label":"GAS","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:GAS","namespace":"tdb","label":"GAS","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:gas","namespace":"corpus","label":"phase:p-si:gas","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"GAS","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","P2","P3","P4","SI","SI2","SI2P","SI2P2","SI3","SIP","SIP2"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":70,"line_end":70,"text":"PHASE GAS:G % 1 1 !"},"constituent":{"line_start":71,"line_end":71,"text":"CONST GAS:G : SI SI2 SI3 P P2 P3 P4 SIP SIP2 SI2P SI2P2 : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"GAS","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI","SI2","SI3","P","P2","P3","P4","SIP","SIP2","SI2P","SI2P2"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":11,"by_kind":{"G":11},"L_by_order":{},"interaction_orders":[],"endmember_G":11},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"GAS","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","P2","P3","P4","SI","SI2","SI2P","SI2P2","SI3","SIP","SIP2"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":78,"line_end":78,"text":"PHASE GAS:G % 1 1 !"},"constituent":{"line_start":79,"line_end":79,"text":"CONST GAS:G : SI SI2 SI3 P P2 P3 P4 SIP SIP2 SI2P SI2P2 : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"GAS","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI","SI2","SI3","P","P2","P3","P4","SIP","SIP2","SI2P","SI2P2"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":11,"by_kind":{"G":11},"L_by_order":{},"interaction_orders":[],"endmember_G":11},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"GAS","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","P2","P3","P4","SI","SI2","SI2P","SI2P2","SI3","SIP","SIP2"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":78,"line_end":78,"text":"PHASE GAS:G % 1 1 !"},"constituent":{"line_start":79,"line_end":79,"text":"CONST GAS:G : SI SI2 SI3 P P2 P3 P4 SIP SIP2 SI2P SI2P2 : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"GAS","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI","SI2","SI3","P","P2","P3","P4","SIP","SIP2","SI2P","SI2P2"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":11,"by_kind":{"G":11},"L_by_order":{},"interaction_orders":[],"endmember_G":11},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"GAS","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","P2","P3","P4","SI","SI2","SI2P","SI2P2","SI3","SIP","SIP2"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":81,"line_end":81,"text":"PHASE GAS:G % 1 1 !"},"constituent":{"line_start":82,"line_end":82,"text":"CONST GAS:G : SI SI2 SI3 P P2 P3 P4 SIP SIP2 SI2P SI2P2 : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"GAS","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI","SI2","SI3","P","P2","P3","P4","SIP","SIP2","SI2P","SI2P2"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":11,"by_kind":{"G":11},"L_by_order":{},"interaction_orders":[],"endmember_G":11},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":true,"T_min_K":704.7,"T_max_K":2500.0,"x_min":0.97495,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":704.7,"T_max_K":2500.0,"x_min":0.97377,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":704.7,"T_max_K":2500.0,"x_min":0.9725,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":704.7,"T_max_K":2500.0,"x_min":0.97337,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["GAS"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["GAS"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["GAS"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:hcp-a3","system":"P-SI","elements":["P","SI"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:SiP-04Din-LB.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:hcp-a3","namespace":"corpus","label":"phase:p-si:hcp-a3","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":47,"line_end":47,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":48,"line_end":48,"text":"CONST HCP_A3 : P SI : VA : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":78,"line_end":78,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":78},"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":50,"line_end":50,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":51,"line_end":51,"text":"CONST HCP_A3 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":86,"line_end":86,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":86},"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":50,"line_end":50,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":51,"line_end":51,"text":"CONST HCP_A3 : P SI : VA : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":86,"line_end":86,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":86},"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":53,"line_end":53,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":54,"line_end":54,"text":"CONST HCP_A3 : P SI : VA : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":89,"line_end":89,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["P","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":89},"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:liquid","system":"P-SI","elements":["P","SI"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11669-013-0269-3:L","namespace":"paper","label":"L","basis":"corpus_mapping:unstated"},{"name":"paper:10.1007/s11669-013-0269-3:Liquid","namespace":"paper","label":"Liquid","basis":"exact_tdb_name"},{"name":"paper:10.1007/s11669-013-0269-3:liquid","namespace":"paper","label":"liquid","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.calphad.2024.102758:L","namespace":"paper","label":"L","basis":"corpus_mapping:confirmed"},{"name":"tdb:SiP-04Din-LB.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:liquid","namespace":"corpus","label":"phase:p-si:liquid","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":32,"line_end":32,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":33,"line_end":33,"text":"CONST LIQUID:L : P SI : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":35,"line_end":35,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":36,"line_end":36,"text":"CONST LIQUID:L : P SI : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":35,"line_end":35,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":36,"line_end":36,"text":"CONST LIQUID:L : P SI : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":38,"line_end":38,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":39,"line_end":39,"text":"CONST LIQUID:L : P SI : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":5,"by_kind":{"G":2,"L":3},"L_by_order":{"0":1,"1":1,"2":1},"interaction_orders":[0,1,2],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":true,"T_min_K":1404.01,"T_max_K":2500.0,"x_min":0.0,"x_max":0.34575,"stable_at_top_of_range":true},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":1404.27,"T_max_K":2500.0,"x_min":0.0,"x_max":0.34446,"stable_at_top_of_range":true},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":1397.99,"T_max_K":2500.0,"x_min":0.0,"x_max":0.38044,"stable_at_top_of_range":true},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":1407.29,"T_max_K":2500.0,"x_min":0.0,"x_max":0.40583,"stable_at_top_of_range":true}],"literature":{"values":26,"accepted_values":22,"papers":2},"corpus":{"in_sgte_corpus":false,"phase_mappings":1,"mapping_basis":{"curator/confirmed":1},"printed_labels":["L"]},"references":[{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase","reports values for this phase"],"labels":["L","LIQUID","Liquid","liquid"],"values":20,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase","reports values for this phase"],"labels":["L","LIQUID"],"values":6,"tdb_files":["SiP-24Fav.tdb"]},{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["LIQUID"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11837-012-0387-0","citation":"In-Ho Jung, Yumin Zhang, Thermodynamic Calculations for the Dephosphorization of Silicon Using Molten Slag, JOM 64, 973-981 (2012).","roles":["cited as the source of values for this phase"],"labels":[],"values":5},{"doi":"10.1557/jmr.2011.130","citation":"Jafar Safarian, Merete Tangstad, Phase diagram study of the Si–P system in Si-rich region, J. Mater. Res. 26, 1494-1503 (2011).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":5},{"id":"phase:p-si:p-red","system":"P-SI","elements":["P","SI"],"preferred_name":"RED_P","status":"needs_review","structure":null,"candidates":[{"source":"sgte_mmc2","structure_type":"st:red-p","prototype":"(Red P)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for RED_P: Red P"}],"review_reasons":["name_has_descriptive_tokens:RED","no_structure_token"],"names":[{"name":"tdb:SiP-04Din-LB.tdb:RED_P","namespace":"tdb","label":"RED_P","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:RED_P","namespace":"tdb","label":"RED_P","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:RED_P","namespace":"tdb","label":"RED_P","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:RED_P","namespace":"tdb","label":"RED_P","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:p-red","namespace":"corpus","label":"phase:p-si:p-red","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"RED_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":62,"line_end":62,"text":"PHASE RED_P % 1 1 !"},"constituent":{"line_start":63,"line_end":63,"text":"CONST RED_P : P : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RED_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"RED_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":65,"line_end":65,"text":"PHASE RED_P % 1 1 !"},"constituent":{"line_start":66,"line_end":66,"text":"CONST RED_P : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RED_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"RED_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":65,"line_end":65,"text":"PHASE RED_P % 1 1 !"},"constituent":{"line_start":66,"line_end":66,"text":"CONST RED_P : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RED_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"RED_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":68,"line_end":68,"text":"PHASE RED_P % 1 1 !"},"constituent":{"line_start":69,"line_end":69,"text":"CONST RED_P : P : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"RED_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":{"P":1.0},"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":704.7,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":704.7,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":704.7,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":704.7,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["RED_P"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["RED_P"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["RED_P"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:p-white","system":"P-SI","elements":["P","SI"],"preferred_name":"WHITE_P","status":"needs_review","structure":null,"candidates":[{"source":"sgte_mmc2","structure_type":"st:white-p","prototype":"(White P)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for WHITE_P: White P"}],"review_reasons":["name_has_descriptive_tokens:WHITE","no_structure_token"],"names":[{"name":"tdb:SiP-04Din-LB.tdb:WHITE_P","namespace":"tdb","label":"WHITE_P","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:WHITE_P","namespace":"tdb","label":"WHITE_P","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:WHITE_P","namespace":"tdb","label":"WHITE_P","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:WHITE_P","namespace":"tdb","label":"WHITE_P","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:p-white","namespace":"corpus","label":"phase:p-si:p-white","in_sgte_corpus":false}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"WHITE_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":57,"line_end":57,"text":"PHASE WHITE_P % 1 1 !"},"constituent":{"line_start":58,"line_end":58,"text":"CONST WHITE_P : P : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"WHITE_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}}},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"WHITE_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":60,"line_end":60,"text":"PHASE WHITE_P % 1 1 !"},"constituent":{"line_start":61,"line_end":61,"text":"CONST WHITE_P : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"WHITE_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}}},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"WHITE_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":60,"line_end":60,"text":"PHASE WHITE_P % 1 1 !"},"constituent":{"line_start":61,"line_end":61,"text":"CONST WHITE_P : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"WHITE_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}}},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"WHITE_P","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":63,"line_end":63,"text":"PHASE WHITE_P % 1 1 !"},"constituent":{"line_start":64,"line_end":64,"text":"CONST WHITE_P : P : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"WHITE_P","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["P"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}}}],"stoichiometry":{"P":1.0},"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["WHITE_P"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase"],"labels":["WHITE_P"],"values":0,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase"],"labels":["WHITE_P"],"values":0,"tdb_files":["SiP-24Fav.tdb"]}],"total_papers":3},{"id":"phase:p-si:sip","system":"P-SI","elements":["P","SI"],"preferred_name":"SIP","status":"assigned","structure":{"structure_type":"st:sip-oc48","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"SiP","model":"SiP","pearson":"oC48","phase_name":"SIP","prototype":"SiP","space_group":{"number":36,"symbol":"Cmc2_1"},"strukturbericht":null}]},"prototype":"SiP","strukturbericht":null,"pearson":"oC48","space_group":{"number":36,"symbol":"Cmc2_1"},"caveats":["not certain from the name or DFT alone (mp_oqmd_space_groups_differ, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11669-013-0269-3:SiP","namespace":"paper","label":"SiP","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2024.102758:SiP","namespace":"paper","label":"SiP","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.surfcoat.2016.01.016:SiP","namespace":"paper","label":"SiP","basis":"exact_tdb_name"},{"name":"tdb:SiP-04Din-LB.tdb:SIP","namespace":"tdb","label":"SIP","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228"},{"name":"tdb:SiP-14Lia.tdb:SIP","namespace":"tdb","label":"SIP","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:SIP","namespace":"tdb","label":"SIP","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:SIP","namespace":"tdb","label":"SIP","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:sip","namespace":"corpus","label":"phase:p-si:sip","in_sgte_corpus":true}],"models":[{"tdb":"SiP-04Din-LB.tdb","path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","phase_name":"SIP","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":67,"line_end":67,"text":"PHASE SIP % 2 1 1 !"},"constituent":{"line_start":68,"line_end":68,"text":"CONST SIP : SI : P : !"},"type_definitions":[{"line_start":77,"line_end":77,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-04Din-LB.tdb","sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-04Din-LB.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-04Din-LB.tdb"}},"tdb_comment_structure":["Prototype ? (oC48, Cmc2_1)"]},{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"SIP","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":70,"line_end":70,"text":"PHASE SIP % 2 1 1 !"},"constituent":{"line_start":71,"line_end":71,"text":"CONST SIP : SI : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}},"tdb_comment_structure":["Prototype SiP (oC48, Cmc2_1)"]},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"SIP","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":70,"line_end":70,"text":"PHASE SIP % 2 1 1 !"},"constituent":{"line_start":71,"line_end":71,"text":"CONST SIP : SI : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}},"tdb_comment_structure":["Prototype SiP (oC48, Cmc2_1)"]},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"SIP","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":1.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":73,"line_end":73,"text":"PHASE SIP % 2 1 1 !"},"constituent":{"line_start":74,"line_end":74,"text":"CONST SIP : SI : P : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}},"tdb_comment_structure":["Prototype SiP (oC48, Cmc2_1)"]}],"stoichiometry":{"P":0.5,"SI":0.5},"stability":[{"tdb":"SiP-04Din-LB.tdb","tdb_sha256":"09f32a6a90905c36ac5ef60f1b17da959ddac742289f6af3c300808c1a7ff228","diagram":"phase-diagrams/sgte/SiP-04Din-LB.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1412.69,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1405.08,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1400.77,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1409.49,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false}],"literature":{"values":43,"accepted_values":39,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":1,"mapping_basis":{"curator/confirmed":1},"printed_labels":["SiP"]},"references":[{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase","reports values for this phase"],"labels":["SIP","SiP"],"values":30,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase","reports values for this phase"],"labels":["SIP","SiP"],"values":10,"tdb_files":["SiP-24Fav.tdb"]},{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["SIP"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11837-012-0387-0","citation":"In-Ho Jung, Yumin Zhang, Thermodynamic Calculations for the Dephosphorization of Silicon Using Molten Slag, JOM 64, 973-981 (2012).","roles":["cited as the source of values for this phase"],"labels":[],"values":6},{"doi":"10.1016/j.surfcoat.2016.01.016","citation":"Ya Liu, Bin Zhou, Wei Lv, Changjun Wu, Xuping Su, Jianhua Wang, Experimental investigation and thermodynamic assessment of the Zn–Si–P system, Surface and Coatings Technology 306, 370-377 (2016).","roles":["reports values for this phase"],"labels":["SiP"],"values":3},{"doi":"10.1002/9783527618347","citation":"M. Binnewies, E Milke, Thermochemical Data of Elements and Compounds, (2002).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1002/zaac.19764250313","citation":"J. Korb, K. Hein, Dampfdruckuntersuchungen im System ZnSiP, Zeitschrift anorg allge chemie 425, 281-288 (1976).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1007/978-3-662-02293-1","citation":"Ihsan Barin, Ottmar Knacke, Oswald Kubaschewski, Thermochemical properties of inorganic substances, (1977).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1134/s0036024411060057","citation":"N. A. Arutyunyan, A. I. Zaitsev, N. G. Shaposhnikov, Analysis of thermodynamic properties and phase equilibria in the Si-P system, Russ. J. Phys. Chem. 85, 911-915 (2011).","roles":["cited as the source of values for this phase"],"labels":[],"values":2},{"doi":"10.1557/jmr.2011.130","citation":"Jafar Safarian, Merete Tangstad, Phase diagram study of the Si–P system in Si-rich region, J. Mater. Res. 26, 1494-1503 (2011).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":10},{"id":"phase:p-si:sip2","system":"P-SI","elements":["P","SI"],"preferred_name":"SIP2","status":"assigned","structure":{"structure_type":"st:geas2-op24","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"SiP2","model":"SiP2","pearson":"oP24","phase_name":"SIP2","prototype":"GeAs2","space_group":{"number":55,"symbol":"Pbam"},"strukturbericht":null}]},"prototype":"GeAs2","strukturbericht":null,"pearson":"oP24","space_group":{"number":55,"symbol":"Pbam"},"caveats":["not certain from the name or DFT alone (dft_space_group_55_matches_2_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11669-013-0269-3:SiP2","namespace":"paper","label":"SiP2","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.calphad.2024.102758:SiP2","namespace":"paper","label":"SiP2","basis":"exact_tdb_name"},{"name":"paper:10.1016/j.surfcoat.2016.01.016:SiP2","namespace":"paper","label":"SiP2","basis":"exact_tdb_name"},{"name":"tdb:SiP-14Lia.tdb:SIP2","namespace":"tdb","label":"SIP2","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae"},{"name":"tdb:SiP-21Don.tdb:SIP2","namespace":"tdb","label":"SIP2","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43"},{"name":"tdb:SiP-24Fav.tdb:SIP2","namespace":"tdb","label":"SIP2","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551"},{"name":"corpus:phase:p-si:sip2","namespace":"corpus","label":"phase:p-si:sip2","in_sgte_corpus":true}],"models":[{"tdb":"SiP-14Lia.tdb","path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","phase_name":"SIP2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":2.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":75,"line_end":75,"text":"PHASE SIP2 % 2 1 2 !"},"constituent":{"line_start":76,"line_end":76,"text":"CONST SIP2 : SI : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-14Lia.tdb","sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-14Lia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-14Lia.tdb"}},"tdb_comment_structure":["Prototype GeAs2 (oP24, Pbam)"]},{"tdb":"SiP-21Don.tdb","path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","phase_name":"SIP2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":2.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":75,"line_end":75,"text":"PHASE SIP2 % 2 1 2 !"},"constituent":{"line_start":76,"line_end":76,"text":"CONST SIP2 : SI : P : !"},"type_definitions":[{"line_start":85,"line_end":85,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-21Don.tdb","sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-21Don.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-21Don.tdb"}},"tdb_comment_structure":["Prototype GeAs2 (oP24, Pbam)"]},{"tdb":"SiP-24Fav.tdb","path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","phase_name":"SIP2","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]},{"site_ratio":2.0,"constituents":["P"]}],"stoichiometric":true,"composition":{"P":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":78,"line_end":78,"text":"PHASE SIP2 % 2 1 2 !"},"constituent":{"line_start":79,"line_end":79,"text":"CONST SIP2 : SI : P : !"},"type_definitions":[{"line_start":88,"line_end":88,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"SIP2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,2],"constituents":[["SI"],["P"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/SiP-24Fav.tdb","sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/SiP-24Fav.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/SiP-24Fav.tdb"}},"tdb_comment_structure":["Prototype GeAs2 (oP24, Pbam)"]}],"stoichiometry":{"P":0.6666666666666666,"SI":0.3333333333333333},"stability":[{"tdb":"SiP-14Lia.tdb","tdb_sha256":"dbac9d0fa327345990711a4b08ca6a901994e396d5354fb83a4d27e127fb2eae","diagram":"phase-diagrams/sgte/SiP-14Lia.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":956.89,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false},{"tdb":"SiP-21Don.tdb","tdb_sha256":"f90e7e27a7346c0a524c5d034e7b5886e1fe3c29aa716416ce313505e1003b43","diagram":"phase-diagrams/sgte/SiP-21Don.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":956.89,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false},{"tdb":"SiP-24Fav.tdb","tdb_sha256":"b2cf26569758670dfb4949dfa6b4c4c49a95bdcfc5b54e23596bcf3a5eb4c551","diagram":"phase-diagrams/sgte/SiP-24Fav.json","status":"ok","x_element":"P","stable":true,"T_min_K":300.0,"T_max_K":1073.6,"x_min":0.66667,"x_max":0.66667,"stable_at_top_of_range":false}],"literature":{"values":14,"accepted_values":14,"papers":3},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11669-013-0269-3","citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System, J. Phase Equilib. Diffus. 35, 24-35 (2014).","roles":["assessment that models this phase","reports values for this phase"],"labels":["SIP2","SiP2"],"values":10,"tdb_files":["SiP-14Lia.tdb"]},{"doi":"10.1016/j.calphad.2024.102758","citation":"Simon Favre, Ioana Nuta, Guy Chichignoud, Evelyne Fischer, Christian Chatillon, Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation, Calphad 87, 102758 (2024).","roles":["assessment that models this phase","reports values for this phase"],"labels":["SIP2","SiP2"],"values":1,"tdb_files":["SiP-24Fav.tdb"]},{"doi":"10.1007/s11664-021-08861-4","citation":"Hongqun Dong, Xiaoma Tao, Mervi Paulasto-Kröckel, Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon, Journal of Elec Materi 50, 4272-4288 (2021).","roles":["assessment that models this phase"],"labels":["SIP2"],"values":0,"tdb_files":["SiP-21Don.tdb"]},{"doi":"10.1007/s11837-012-0387-0","citation":"In-Ho Jung, Yumin Zhang, Thermodynamic Calculations for the Dephosphorization of Silicon Using Molten Slag, JOM 64, 973-981 (2012).","roles":["cited as the source of values for this phase"],"labels":[],"values":4},{"doi":"10.1016/j.surfcoat.2016.01.016","citation":"Ya Liu, Bin Zhou, Wei Lv, Changjun Wu, Xuping Su, Jianhua Wang, Experimental investigation and thermodynamic assessment of the Zn–Si–P system, Surface and Coatings Technology 306, 370-377 (2016).","roles":["reports values for this phase"],"labels":["SiP2"],"values":3},{"doi":"10.3891/acta.chem.scand.21-0593","citation":"Tommy Wadsten, M. Vikan, C. Krohn, Åke Nilsson, H. Theorell, R. Blinc et al., The Crystal Structures of SiP2, SiAs2, and GeP., Acta Chem. Scand. 21, 593-594 (1967).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":6}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:a4-c-diamond-cf8":{"id":"st:a4-c-diamond-cf8","prototype":"C (diamond)","prototype_spellings":["C(diamond)"],"strukturbericht":"A4","pearson":"cF8","space_group":{"number":227,"symbol":"Fd-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":2},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":187},"st:gas":{"id":"st:gas","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":231},"st:geas2-op24":{"id":"st:geas2-op24","prototype":"GeAs2","prototype_spellings":[],"strukturbericht":null,"pearson":"oP24","space_group":{"number":55,"symbol":"Pbam"},"stoichiometry":"As2Ge1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":3}],"verification":"in Hallstedt 2025 mmc2","registry_phases":3},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304},"st:sip-oc48":{"id":"st:sip-oc48","prototype":"SiP","prototype_spellings":[],"strukturbericht":null,"pearson":"oC48","space_group":{"number":36,"symbol":"Cmc2_1"},"stoichiometry":"P1Si1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":1}],"verification":"in Hallstedt 2025 mmc2","registry_phases":1}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}