{"system":"PD-SI","release":"v2026.10","phases":[{"id":"phase:pd-si:a4-diamond","system":"PD-SI","elements":["PD","SI"],"preferred_name":"DIAMOND_A4","status":"assigned","structure":{"structure_type":"st:a4-c-diamond-cf8","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"C (diamond)","strukturbericht":"A4","pearson":"cF8","space_group":{"number":227,"symbol":"Fd-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Si-dia","namespace":"paper","label":"Si-dia","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:diamond(Si)","namespace":"paper","label":"diamond(Si)","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:DIAMOND_A4","namespace":"tdb","label":"DIAMOND_A4","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:a4-diamond","namespace":"corpus","label":"phase:pd-si:a4-diamond","in_sgte_corpus":true},{"name":"corpus:phase:pd-si:diamond-a4","namespace":"corpus","label":"phase:pd-si:diamond-a4","alias_of":"phase:pd-si:a4-diamond"}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"SI":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":48,"line_end":48,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":49,"line_end":49,"text":"CONST DIAMOND_A4 : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype C (cF8, Fd-3m)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":49,"line_end":49,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":50,"line_end":50,"text":"CONST DIAMOND_A4 : PD SI% : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype C (cF8, Fd-3m)"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":57,"line_end":57,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":58,"line_end":58,"text":"CONST DIAMOND_A4 : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","SI%"]],"major_constituents":[["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype C (cF8, Fd-3m)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"SI":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":48,"line_end":48,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":49,"line_end":49,"text":"CONST DIAMOND_A4 : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype C (cF8, Fd-3m)"]},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"DIAMOND_A4","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"SI":1.0},"tdb_definition":{"verbatim":{"phase":{"line_start":44,"line_end":44,"text":"PHASE DIAMOND_A4 % 1 1 !"},"constituent":{"line_start":45,"line_end":45,"text":"CONST DIAMOND_A4 : SI : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"DIAMOND_A4","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}},"tdb_comment_structure":["Prototype C (cF8, Fd-3m)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1687.0,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1686.66,"x_min":0.99995,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1687.0,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1687.0,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1687.0,"x_min":1.0,"x_max":1.0,"stable_at_top_of_range":false}],"literature":{"values":5,"accepted_values":5,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["DIAMOND_A4","diamond(Si)"],"values":4,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["DIAMOND_A4","Si-dia"],"values":1,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["DIAMOND_A4"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["DIAMOND_A4"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":1}],"total_papers":5},{"id":"phase:pd-si:bcc-a2","system":"PD-SI","elements":["PD","SI"],"preferred_name":"BCC_A2","status":"assigned","structure":{"structure_type":"st:a2-w-ci2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"W","strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:PdSi-05The.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:BCC_A2","namespace":"tdb","label":"BCC_A2","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:bcc-a2","namespace":"corpus","label":"phase:pd-si:bcc-a2","in_sgte_corpus":false}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":38,"line_end":38,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":39,"line_end":39,"text":"CONST BCC_A2 : PD SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":82,"line_end":82,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":82},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}}},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":39,"line_end":39,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":40,"line_end":40,"text":"CONST BCC_A2 : PD SI : VA : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":113,"line_end":113,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":113},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":47,"line_end":47,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":48,"line_end":48,"text":"CONST BCC_A2 : PD SI : VA : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":91,"line_end":91,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":91},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}}},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":38,"line_end":38,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":39,"line_end":39,"text":"CONST BCC_A2 : PD SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":82,"line_end":82,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":82},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}}},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"BCC_A2","type_code":"%B","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":3.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":34,"line_end":34,"text":"PHASE BCC_A2 %B 2 1 3 !"},"constituent":{"line_start":35,"line_end":35,"text":"CONST BCC_A2 : PD SI : VA : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":68,"line_end":68,"text":"TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 !","type_code":"B","amends":"@"}]},"parsed":{"phase_name":"BCC_A2","type_code":"%B","type_codes":["%","B"],"n_sublattices":2,"site_ratios":[1,3],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"B","afm_factor":-1,"structure_fraction":0.4,"line":68},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase"],"labels":["BCC_A2"],"values":0,"tdb_files":["PdSi-06Du.tdb"]}],"total_papers":4},{"id":"phase:pd-si:fcc-a1","system":"PD-SI","elements":["PD","SI"],"preferred_name":"FCC_A1","status":"assigned","structure":{"structure_type":"st:a1-cu-cf4","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Cu","strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"}},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Pd-fcc","namespace":"paper","label":"Pd-fcc","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:fcc(Pd)","namespace":"paper","label":"fcc(Pd)","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:FCC_A1","namespace":"tdb","label":"FCC_A1","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:fcc-a1","namespace":"corpus","label":"phase:pd-si:fcc-a1","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":33,"line_end":33,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":34,"line_end":34,"text":"CONST FCC_A1 : PD% SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":81,"line_end":81,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["VA"]],"major_constituents":[["PD"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":81},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}}},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":34,"line_end":34,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":35,"line_end":35,"text":"CONST FCC_A1 : PD% SI : VA : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":112,"line_end":112,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["VA"]],"major_constituents":[["PD"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":112},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":42,"line_end":42,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":43,"line_end":43,"text":"CONST FCC_A1 : PD% SI : VA : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":90,"line_end":90,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["VA"]],"major_constituents":[["PD"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":90},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}}},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":33,"line_end":33,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":34,"line_end":34,"text":"CONST FCC_A1 : PD% SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":81,"line_end":81,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["VA"]],"major_constituents":[["PD"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":81},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}}},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"FCC_A1","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":29,"line_end":29,"text":"PHASE FCC_A1 %A 2 1 1 !"},"constituent":{"line_start":30,"line_end":30,"text":"CONST FCC_A1 : PD% SI : VA : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":67,"line_end":67,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"FCC_A1","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["VA"]],"major_constituents":[["PD"],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":67},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1841.0,"x_min":0.0,"x_max":0.0,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1828.84,"x_min":0.0,"x_max":0.00508,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1827.75,"x_min":0.0,"x_max":0.00831,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1827.86,"x_min":0.0,"x_max":0.00155,"stable_at_top_of_range":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1871.34,"x_min":0.0,"x_max":1e-05,"stable_at_top_of_range":false}],"literature":{"values":6,"accepted_values":6,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["FCC_A1","fcc(Pd)"],"values":4,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["FCC_A1","Pd-fcc"],"values":2,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["FCC_A1"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":5},{"id":"phase:pd-si:hcp-a3","system":"PD-SI","elements":["PD","SI"],"preferred_name":"HCP_A3","status":"assigned","structure":{"structure_type":"st:a3-mg-hp2","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Mg","strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"}},"candidates":[],"review_reasons":[],"names":[{"name":"tdb:PdSi-05The.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:HCP_A3","namespace":"tdb","label":"HCP_A3","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:hcp-a3","namespace":"corpus","label":"phase:pd-si:hcp-a3","in_sgte_corpus":false}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":43,"line_end":43,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":44,"line_end":44,"text":"CONST HCP_A3 : PD SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":81,"line_end":81,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":81},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}}},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":44,"line_end":44,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":45,"line_end":45,"text":"CONST HCP_A3 : PD SI : VA : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":112,"line_end":112,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":112},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":52,"line_end":52,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":53,"line_end":53,"text":"CONST HCP_A3 : PD SI : VA : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":90,"line_end":90,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":90},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}}},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":43,"line_end":43,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":44,"line_end":44,"text":"CONST HCP_A3 : PD SI : VA : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":81,"line_end":81,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":81},"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}}},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"HCP_A3","type_code":"%A","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":0.5,"constituents":["VA"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":39,"line_end":39,"text":"PHASE HCP_A3 %A 2 1 0.5 !"},"constituent":{"line_start":40,"line_end":40,"text":"CONST HCP_A3 : PD SI : VA : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null},{"line_start":67,"line_end":67,"text":"TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 !","type_code":"A","amends":"@"}]},"parsed":{"phase_name":"HCP_A3","type_code":"%A","type_codes":["%","A"],"n_sublattices":2,"site_ratios":[1,0.5],"constituents":[["PD","SI"],["VA"]],"major_constituents":[[],[]],"magnetic":{"type_code":"A","afm_factor":-3,"structure_fraction":0.28,"line":67},"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":false}],"literature":{"values":0,"accepted_values":0,"papers":0},"corpus":{"in_sgte_corpus":false,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase"],"labels":["HCP_A3"],"values":0,"tdb_files":["PdSi-06Du.tdb"]}],"total_papers":4},{"id":"phase:pd-si:liquid","system":"PD-SI","elements":["PD","SI"],"preferred_name":"LIQUID","status":"assigned","structure":{"structure_type":"st:liquid","basis":"liquid","confidence":"high","label":"liquid","prototype":null,"strukturbericht":null,"pearson":null,"space_group":null},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:liq.","namespace":"paper","label":"liq.","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:LIQUID","namespace":"tdb","label":"LIQUID","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:liquid","namespace":"corpus","label":"phase:pd-si:liquid","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":28,"line_end":28,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":29,"line_end":29,"text":"CONST LIQUID:L : PD SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}}},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":29,"line_end":29,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":30,"line_end":30,"text":"CONST LIQUID:L : PD SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":7,"by_kind":{"G":2,"L":5},"L_by_order":{"0":1,"1":1,"2":1,"3":1,"4":1},"interaction_orders":[0,1,2,3,4],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","PD2SI","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":37,"line_end":37,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":38,"line_end":38,"text":"CONST LIQUID:L : PD PD2SI SI : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","PD2SI","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":6,"by_kind":{"G":3,"L":3},"L_by_order":{"0":3},"interaction_orders":[0],"endmember_G":3},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}}},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","PD2SI","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":28,"line_end":28,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":29,"line_end":29,"text":"CONST LIQUID:L : PD PD2SI SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","PD2SI","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":6,"by_kind":{"G":3,"L":3},"L_by_order":{"0":3},"interaction_orders":[0],"endmember_G":3},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}}},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"LIQUID","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":24,"line_end":24,"text":"PHASE LIQUID:L % 1 1 !"},"constituent":{"line_start":25,"line_end":25,"text":"CONST LIQUID:L : PD SI : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"LIQUID","type_code":"%","type_codes":["%"],"n_sublattices":1,"site_ratios":[1],"constituents":[["PD","SI"]],"major_constituents":[[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":2,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1061.03,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1088.73,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1076.45,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1089.71,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":940.09,"T_max_K":2500.0,"x_min":0.0,"x_max":1.0,"stable_at_top_of_range":true}],"literature":{"values":22,"accepted_values":22,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["LIQUID","liq."],"values":22,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase"],"labels":["LIQUID"],"values":0,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["LIQUID"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["LIQUID"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":11}],"total_papers":5},{"id":"phase:pd-si:pd14si3","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD14SI3","status":"needs_review","structure":null,"candidates":[{"source":"literature_printed","structure_type":null,"prototype":"(Pd14Si3)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":6},{"source":"sgte_mmc2","structure_type":"st:pd14si3","prototype":"(Pd14Si3)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD14SI3: Pd14Si3"}],"review_reasons":["no_on_hull_entry_in_both","no_structure_token","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:Pd14Si3","namespace":"paper","label":"Pd14Si3","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD14SI3","namespace":"tdb","label":"PD14SI3","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd14si3","namespace":"corpus","label":"phase:pd-si:pd14si3","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD14SI3","type_code":"%","sublattices":[{"site_ratio":14.0,"constituents":["PD"]},{"site_ratio":3.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8235294117647058,"SI":0.17647058823529413},"tdb_definition":{"verbatim":{"phase":{"line_start":64,"line_end":64,"text":"PHASE PD14SI3 % 2 14 3 !"},"constituent":{"line_start":65,"line_end":65,"text":"CONST PD14SI3 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD14SI3","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[14,3],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":{"PD":0.8235294117647058,"SI":0.17647058823529413},"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1068.02,"x_min":0.17647,"x_max":0.17647,"stable_at_top_of_range":false}],"literature":{"values":6,"accepted_values":6,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD14SI3","Pd14Si3"],"values":6,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":2},{"id":"phase:pd-si:pd15si4","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD15SI4","status":"needs_review","structure":null,"candidates":[{"source":"literature_printed","structure_type":null,"prototype":"(Pd15Si4)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":6},{"source":"sgte_mmc2","structure_type":"st:pd15si4","prototype":"(Pd15Si4)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD15SI4: Pd15Si4"}],"review_reasons":["no_on_hull_entry_in_both","no_structure_token","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:Pd15Si4","namespace":"paper","label":"Pd15Si4","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD15SI4","namespace":"tdb","label":"PD15SI4","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd15si4","namespace":"corpus","label":"phase:pd-si:pd15si4","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD15SI4","type_code":"%","sublattices":[{"site_ratio":15.0,"constituents":["PD"]},{"site_ratio":4.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.7894736842105263,"SI":0.21052631578947367},"tdb_definition":{"verbatim":{"phase":{"line_start":74,"line_end":74,"text":"PHASE PD15SI4 % 2 15 4 !"},"constituent":{"line_start":75,"line_end":75,"text":"CONST PD15SI4 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD15SI4","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[15,4],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":{"PD":0.7894736842105263,"SI":0.21052631578947367},"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1025.87,"T_max_K":1064.92,"x_min":0.21053,"x_max":0.21053,"stable_at_top_of_range":false}],"literature":{"values":6,"accepted_values":6,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD15SI4","Pd15Si4"],"values":6,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":2},{"id":"phase:pd-si:pd19si10","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD19SI10","status":"needs_review","structure":null,"candidates":[{"source":"literature_printed","structure_type":null,"prototype":"(Pd19Si10)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":6},{"source":"sgte_mmc2","structure_type":"st:pd19si10","prototype":"(Pd19Si10)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD19SI10: Pd19Si10"}],"review_reasons":["no_on_hull_entry_in_both","no_structure_token","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:Pd19Si10","namespace":"paper","label":"Pd19Si10","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD19SI10","namespace":"tdb","label":"PD19SI10","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd19si10","namespace":"corpus","label":"phase:pd-si:pd19si10","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD19SI10","type_code":"%","sublattices":[{"site_ratio":19.0,"constituents":["PD"]},{"site_ratio":10.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.6551724137931034,"SI":0.3448275862068966},"tdb_definition":{"verbatim":{"phase":{"line_start":99,"line_end":99,"text":"PHASE PD19SI10 % 2 19 10 !"},"constituent":{"line_start":100,"line_end":100,"text":"CONST PD19SI10 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD19SI10","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[19,10],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":{"PD":0.6551724137931034,"SI":0.3448275862068966},"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1344.55,"x_min":0.34483,"x_max":0.34483,"stable_at_top_of_range":false}],"literature":{"values":6,"accepted_values":6,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD19SI10","Pd19Si10"],"values":6,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":2},{"id":"phase:pd-si:pd21si4","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD21SI4","status":"needs_review","structure":null,"candidates":[{"source":"literature_printed","structure_type":null,"prototype":"(Pd21Si4)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":6},{"source":"sgte_mmc2","structure_type":"st:pd21si4","prototype":"(Pd21Si4)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD21SI4: Pd21Si4"}],"review_reasons":["no_structure_token","off_stoichiometric_model","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:Pd21Si4","namespace":"paper","label":"Pd21Si4","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD21SI4","namespace":"tdb","label":"PD21SI4","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd21si4","namespace":"corpus","label":"phase:pd-si:pd21si4","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD21SI4","type_code":"%","sublattices":[{"site_ratio":21.0,"constituents":["PD","SI"]},{"site_ratio":4.0,"constituents":["SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":54,"line_end":54,"text":"PHASE PD21SI4 % 2 21 4 !"},"constituent":{"line_start":55,"line_end":55,"text":"CONST PD21SI4 : PD% SI : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD21SI4","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[21,4],"constituents":[["PD%","SI"],["SI"]],"major_constituents":[["PD"],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1084.16,"x_min":0.16,"x_max":0.16323,"stable_at_top_of_range":false}],"literature":{"values":6,"accepted_values":6,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD21SI4","Pd21Si4"],"values":6,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":2},{"id":"phase:pd-si:pd2si-beta","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD2SI_BETA","status":"needs_review","structure":null,"candidates":[{"source":"dft_mp","structure_type":null,"prototype":null,"strukturbericht":null,"pearson":null,"space_group":{"number":189,"symbol":"P-62m"},"detail":"on-hull MP SiPd2 at x(SI)=0.3333","material_id":"mp-aaabnrei"},{"source":"dft_oqmd","structure_type":null,"prototype":null,"strukturbericht":null,"pearson":null,"space_group":{"number":189,"symbol":"P-62m"},"detail":"on-hull OQMD Pd2 Si1 at x(SI)=0.3333","material_id":"oqmd-669944"},{"source":"literature_printed","structure_type":null,"prototype":"(Pd2Si-beta)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":8},{"source":"sgte_mmc2","structure_type":"st:pd2si-beta","prototype":"(Pd2Si-beta)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD2SI_BETA: Pd2Si (hight T)"}],"review_reasons":["no_structure_token","off_stoichiometric_model","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:βPd2Si","namespace":"paper","label":"βPd2Si","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD2SI_BETA","namespace":"tdb","label":"PD2SI_BETA","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd2si-beta","namespace":"corpus","label":"phase:pd-si:pd2si-beta","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD2SI_BETA","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":89,"line_end":89,"text":"PHASE PD2SI_BETA % 2 2 1 !"},"constituent":{"line_start":90,"line_end":90,"text":"CONST PD2SI_BETA : PD% SI : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_BETA","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD%","SI"],["SI"]],"major_constituents":[["PD"],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":null,"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1325.83,"T_max_K":1676.99,"x_min":0.33333,"x_max":0.33341,"stable_at_top_of_range":false}],"literature":{"values":8,"accepted_values":8,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD2SI_BETA","βPd2Si"],"values":8,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":4}],"total_papers":2},{"id":"phase:pd-si:pd2si-c22","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD2SI_C22","status":"assigned","structure":{"structure_type":"st:c22-fe2p-hp9","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Fe2P","strukturbericht":"C22","pearson":"hP9","space_group":{"number":189,"symbol":"P-62m"},"caveats":["partitioned order/disorder model in PdSi-16Zho.tdb also describes the disordered state"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Pd2Si","namespace":"paper","label":"Pd2Si","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:αPd2Si","namespace":"paper","label":"αPd2Si","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:PD2SI_C22","namespace":"tdb","label":"PD2SI_C22","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:PD2SI_C22","namespace":"tdb","label":"PD2SI_C22","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:PD2SI_C22","namespace":"tdb","label":"PD2SI_C22","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:PD2SI_C22","namespace":"tdb","label":"PD2SI_C22","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:PD2SI_C22","namespace":"tdb","label":"PD2SI_C22","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:pd2si-c22","namespace":"corpus","label":"phase:pd-si:pd2si-c22","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"PD2SI_C22","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":68,"line_end":68,"text":"PHASE PD2SI_C22 % 2 2 1 !"},"constituent":{"line_start":69,"line_end":69,"text":"CONST PD2SI_C22 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_C22","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype Fe2P (hP9, P-62m)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD2SI_C22","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":84,"line_end":84,"text":"PHASE PD2SI_C22 % 2 2 1 !"},"constituent":{"line_start":85,"line_end":85,"text":"CONST PD2SI_C22 : PD% SI : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_C22","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD%","SI"],["SI"]],"major_constituents":[["PD"],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":3,"by_kind":{"G":2,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":2},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype Fe2P (hP9, P-62m), alpha"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"PD2SI_C22","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":77,"line_end":77,"text":"PHASE PD2SI_C22 % 2 2 1 !"},"constituent":{"line_start":78,"line_end":78,"text":"CONST PD2SI_C22 : PD% SI : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_C22","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD%","SI"],["PD","SI%"]],"major_constituents":[["PD"],["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":5,"by_kind":{"G":4,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype Fe2P (hP9, P-62m)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"PD2SI_C22","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":68,"line_end":68,"text":"PHASE PD2SI_C22 % 2 2 1 !"},"constituent":{"line_start":69,"line_end":69,"text":"CONST PD2SI_C22 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_C22","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype Fe2P (hP9, P-62m)"]},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"PD2SI_C22","type_code":"%","sublattices":[{"site_ratio":2.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.6666666666666666,"SI":0.3333333333333333},"tdb_definition":{"verbatim":{"phase":{"line_start":54,"line_end":54,"text":"PHASE PD2SI_C22 % 2 2 1 !"},"constituent":{"line_start":55,"line_end":55,"text":"CONST PD2SI_C22 : PD : SI : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD2SI_C22","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[2,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}},"tdb_comment_structure":["Prototype Fe2P (hP9, P-62m)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1603.63,"x_min":0.33333,"x_max":0.33333,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1362.74,"x_min":0.33333,"x_max":0.33409,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1663.79,"x_min":0.33333,"x_max":0.34965,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1662.93,"x_min":0.33333,"x_max":0.33333,"stable_at_top_of_range":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1630.8,"x_min":0.33333,"x_max":0.33333,"stable_at_top_of_range":false}],"literature":{"values":8,"accepted_values":8,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD2SI_C22","αPd2Si"],"values":6,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD2SI_C22","Pd2Si"],"values":2,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["PD2SI_C22"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["PD2SI_C22"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":5},{"id":"phase:pd-si:pd39si20","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD39SI20","status":"needs_review","structure":null,"candidates":[{"source":"literature_printed","structure_type":null,"prototype":"(Pd39Si20)","strukturbericht":null,"pearson":"?","space_group":null,"detail":"printed with a label mapped to this phase","count":4},{"source":"sgte_mmc2","structure_type":"st:pd39si20","prototype":"(Pd39Si20)","strukturbericht":null,"pearson":null,"space_group":null,"detail":"Hallstedt 2025 mmc2 row for PD39SI20: Pd39Si20"}],"review_reasons":["no_on_hull_entry_in_both","no_structure_token","sgte_mmc2_row_incomplete"],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:Pd39Si20","namespace":"paper","label":"Pd39Si20","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-06Du.tdb:PD39SI20","namespace":"tdb","label":"PD39SI20","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"corpus:phase:pd-si:pd39si20","namespace":"corpus","label":"phase:pd-si:pd39si20","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD39SI20","type_code":"%","sublattices":[{"site_ratio":39.0,"constituents":["PD"]},{"site_ratio":20.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.6610169491525424,"SI":0.3389830508474576},"tdb_definition":{"verbatim":{"phase":{"line_start":94,"line_end":94,"text":"PHASE PD39SI20 % 2 39 20 !"},"constituent":{"line_start":95,"line_end":95,"text":"CONST PD39SI20 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD39SI20","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[39,20],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}}}],"stoichiometry":{"PD":0.6610169491525424,"SI":0.3389830508474576},"stability":[{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1352.67,"x_min":0.33898,"x_max":0.33898,"stable_at_top_of_range":false}],"literature":{"values":4,"accepted_values":4,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD39SI20","Pd39Si20"],"values":4,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":2}],"total_papers":2},{"id":"phase:pd-si:pd3si-d011","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD3SI_D011","status":"assigned","structure":{"structure_type":"st:d0-11-fe3c-op16","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"Fe3C","strukturbericht":"D0_11","pearson":"oP16","space_group":{"number":62,"symbol":"Pnma"},"caveats":["partitioned order/disorder model in PdSi-16Zho.tdb also describes the disordered state"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Pd3Si","namespace":"paper","label":"Pd3Si","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:Pd3Si","namespace":"paper","label":"Pd3Si","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:PD3SI_D011","namespace":"tdb","label":"PD3SI_D011","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:PD3SI_D011","namespace":"tdb","label":"PD3SI_D011","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:PD3SI_D011","namespace":"tdb","label":"PD3SI_D011","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:PD3SI_D011","namespace":"tdb","label":"PD3SI_D011","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:PD3SI_D011","namespace":"tdb","label":"PD3SI_D011","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:pd3si-d011","namespace":"corpus","label":"phase:pd-si:pd3si-d011","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"PD3SI_D011","type_code":"%","sublattices":[{"site_ratio":3.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.75,"SI":0.25},"tdb_definition":{"verbatim":{"phase":{"line_start":63,"line_end":63,"text":"PHASE PD3SI_D011 % 2 3 1 !"},"constituent":{"line_start":64,"line_end":64,"text":"CONST PD3SI_D011 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD3SI_D011","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[3,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype Fe3C (oP16, Pnma)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD3SI_D011","type_code":"%","sublattices":[{"site_ratio":3.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.75,"SI":0.25},"tdb_definition":{"verbatim":{"phase":{"line_start":79,"line_end":79,"text":"PHASE PD3SI_D011 % 2 3 1 !"},"constituent":{"line_start":80,"line_end":80,"text":"CONST PD3SI_D011 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD3SI_D011","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[3,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype Fe3C (oP16, Pnma)"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"PD3SI_D011","type_code":"%","sublattices":[{"site_ratio":3.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":72,"line_end":72,"text":"PHASE PD3SI_D011 % 2 3 1 !"},"constituent":{"line_start":73,"line_end":73,"text":"CONST PD3SI_D011 : PD% SI : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD3SI_D011","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[3,1],"constituents":[["PD%","SI"],["PD","SI%"]],"major_constituents":[["PD"],["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":4},"L_by_order":{},"interaction_orders":[],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype Fe3C (oP16, Pnma)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"PD3SI_D011","type_code":"%","sublattices":[{"site_ratio":3.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.75,"SI":0.25},"tdb_definition":{"verbatim":{"phase":{"line_start":63,"line_end":63,"text":"PHASE PD3SI_D011 % 2 3 1 !"},"constituent":{"line_start":64,"line_end":64,"text":"CONST PD3SI_D011 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD3SI_D011","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[3,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype Fe3C (oP16, Pnma)"]},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"PD3SI_D011","type_code":"%","sublattices":[{"site_ratio":3.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.75,"SI":0.25},"tdb_definition":{"verbatim":{"phase":{"line_start":49,"line_end":49,"text":"PHASE PD3SI_D011 % 2 3 1 !"},"constituent":{"line_start":50,"line_end":50,"text":"CONST PD3SI_D011 : PD : SI : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD3SI_D011","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[3,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}},"tdb_comment_structure":["Prototype Fe3C (oP16, Pnma)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1317.22,"x_min":0.25,"x_max":0.25,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1337.01,"x_min":0.25,"x_max":0.25,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1341.93,"x_min":0.25,"x_max":0.25,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1346.01,"x_min":0.25,"x_max":0.25,"stable_at_top_of_range":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1235.79,"x_min":0.25,"x_max":0.25,"stable_at_top_of_range":false}],"literature":{"values":19,"accepted_values":19,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD3SI_D011","Pd3Si"],"values":12,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD3SI_D011","Pd3Si"],"values":7,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["PD3SI_D011"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["PD3SI_D011"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":6}],"total_papers":5},{"id":"phase:pd-si:pd5si","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD5SI","status":"assigned","structure":{"structure_type":"st:pd5p-mp24","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"Pd5Si","model":"(Pd,Si)0.833(Pd,Si)0.167","pearson":"mP24","phase_name":"PD5SI","prototype":"Pd5P","space_group":{"number":4,"symbol":"P2_1"},"strukturbericht":null},{"actual":"Pd5Si","model":"Pd5Si","pearson":"mP24","phase_name":"PD5SI","prototype":"Pd5P","space_group":{"number":4,"symbol":"P2_1"},"strukturbericht":null}]},"prototype":"Pd5P","strukturbericht":null,"pearson":"mP24","space_group":{"number":4,"symbol":"P2_1"},"caveats":["not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Pd5Si","namespace":"paper","label":"Pd5Si","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:Pd5Si","namespace":"paper","label":"Pd5Si","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:PD5SI","namespace":"tdb","label":"PD5SI","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:PD5SI","namespace":"tdb","label":"PD5SI","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:PD5SI","namespace":"tdb","label":"PD5SI","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:PD5SI","namespace":"tdb","label":"PD5SI","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"corpus:phase:pd-si:pd5si","namespace":"corpus","label":"phase:pd-si:pd5si","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"PD5SI","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8333333333333334,"SI":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":53,"line_end":53,"text":"PHASE PD5SI % 2 5 1 !"},"constituent":{"line_start":54,"line_end":54,"text":"CONST PD5SI : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD5SI","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype Pd5Si (mP24, P2_1)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD5SI","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8333333333333334,"SI":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":59,"line_end":59,"text":"PHASE PD5SI % 2 5 1 !"},"constituent":{"line_start":60,"line_end":60,"text":"CONST PD5SI : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD5SI","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype Pd5P (mP24, P2_1)"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"PD5SI","type_code":"%","sublattices":[{"site_ratio":0.833,"constituents":["PD","SI"]},{"site_ratio":0.167,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":62,"line_end":62,"text":"PHASE PD5SI % 2 0.833 0.167 !"},"constituent":{"line_start":63,"line_end":63,"text":"CONST PD5SI : PD% SI : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD5SI","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[0.833,0.167],"constituents":[["PD%","SI"],["PD","SI%"]],"major_constituents":[["PD"],["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":6,"by_kind":{"G":4,"L":2},"L_by_order":{"0":1,"1":1},"interaction_orders":[0,1],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype Pd5P (mP24, P2_1)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"PD5SI","type_code":"%","sublattices":[{"site_ratio":5.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8333333333333334,"SI":0.16666666666666666},"tdb_definition":{"verbatim":{"phase":{"line_start":53,"line_end":53,"text":"PHASE PD5SI % 2 5 1 !"},"constituent":{"line_start":54,"line_end":54,"text":"CONST PD5SI : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD5SI","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[5,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype Pd5P (mP24, P2_1)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1093.37,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1073.02,"T_max_K":1128.73,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1078.17,"x_min":0.167,"x_max":0.167,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1101.96,"x_min":0.16667,"x_max":0.16667,"stable_at_top_of_range":false}],"literature":{"values":22,"accepted_values":22,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD5SI","Pd5Si"],"values":12,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD5SI","Pd5Si"],"values":10,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["PD5SI"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":6}],"total_papers":4},{"id":"phase:pd-si:pd9si2","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PD9SI2","status":"assigned","structure":{"structure_type":"st:pd9si2-op44","basis":"assessment_declared","tier":"C","confidence":"assessor-stated","label":"assessment-declared (Hallstedt 2025, mmc2)","source":{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","table":"mmc2","rows":[{"actual":"Pd9Si2","model":"(Pd,Si)0.818(Pd,Si)0.182","pearson":"oP44","phase_name":"PD9SI2","prototype":"Pd9Si2","space_group":{"number":62,"symbol":"Pnma"},"strukturbericht":null},{"actual":"Pd9Si2","model":"Pd9Si2","pearson":"oP44","phase_name":"PD9SI2","prototype":"Pd9Si2","space_group":{"number":62,"symbol":"Pnma"},"strukturbericht":null}]},"prototype":"Pd9Si2","strukturbericht":null,"pearson":"oP44","space_group":{"number":62,"symbol":"Pnma"},"caveats":["not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1007/s11661-015-3206-8:Pd9Si2","namespace":"paper","label":"Pd9Si2","basis":"corpus_mapping:unstated"},{"name":"paper:10.1016/j.intermet.2005.09.008:Pd9Si2","namespace":"paper","label":"Pd9Si2","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:PD9SI2","namespace":"tdb","label":"PD9SI2","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:PD9SI2","namespace":"tdb","label":"PD9SI2","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:PD9SI2","namespace":"tdb","label":"PD9SI2","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:PD9SI2","namespace":"tdb","label":"PD9SI2","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"corpus:phase:pd-si:pd9si2","namespace":"corpus","label":"phase:pd-si:pd9si2","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"PD9SI2","type_code":"%","sublattices":[{"site_ratio":9.0,"constituents":["PD"]},{"site_ratio":2.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8181818181818182,"SI":0.18181818181818182},"tdb_definition":{"verbatim":{"phase":{"line_start":58,"line_end":58,"text":"PHASE PD9SI2 % 2 9 2 !"},"constituent":{"line_start":59,"line_end":59,"text":"CONST PD9SI2 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD9SI2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[9,2],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype Pd9Si2 (oP44, Pnma)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PD9SI2","type_code":"%","sublattices":[{"site_ratio":9.0,"constituents":["PD"]},{"site_ratio":2.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8181818181818182,"SI":0.18181818181818182},"tdb_definition":{"verbatim":{"phase":{"line_start":69,"line_end":69,"text":"PHASE PD9SI2 % 2 9 2 !"},"constituent":{"line_start":70,"line_end":70,"text":"CONST PD9SI2 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD9SI2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[9,2],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype Pd9Si2 (oP44, Pnma)"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"PD9SI2","type_code":"%","sublattices":[{"site_ratio":0.818,"constituents":["PD","SI"]},{"site_ratio":0.182,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":67,"line_end":67,"text":"PHASE PD9SI2 % 2 0.818 0.182 !"},"constituent":{"line_start":68,"line_end":68,"text":"CONST PD9SI2 : PD% SI : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD9SI2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[0.818,0.182],"constituents":[["PD%","SI"],["PD","SI%"]],"major_constituents":[["PD"],["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":4,"by_kind":{"G":4},"L_by_order":{},"interaction_orders":[],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype Pd9Si2 (oP44, Pnma)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"PD9SI2","type_code":"%","sublattices":[{"site_ratio":9.0,"constituents":["PD"]},{"site_ratio":2.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.8181818181818182,"SI":0.18181818181818182},"tdb_definition":{"verbatim":{"phase":{"line_start":58,"line_end":58,"text":"PHASE PD9SI2 % 2 9 2 !"},"constituent":{"line_start":59,"line_end":59,"text":"CONST PD9SI2 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PD9SI2","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[9,2],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype Pd9Si2 (oP44, Pnma)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1090.57,"x_min":0.18182,"x_max":0.18182,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1037.31,"T_max_K":1088.68,"x_min":0.18182,"x_max":0.18182,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":538.57,"T_max_K":1084.43,"x_min":0.182,"x_max":0.182,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1096.01,"x_min":0.18182,"x_max":0.18182,"stable_at_top_of_range":false}],"literature":{"values":20,"accepted_values":20,"papers":2},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD9SI2","Pd9Si2"],"values":10,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PD9SI2","Pd9Si2"],"values":10,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["PD9SI2"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":5}],"total_papers":4},{"id":"phase:pd-si:pdsi-b31","system":"PD-SI","elements":["PD","SI"],"preferred_name":"PDSI_B31","status":"assigned","structure":{"structure_type":"st:b31-mnp-op8","basis":"standard_name","tier":"A","confidence":"high","label":"from the standard phase name","prototype":"MnP","strukturbericht":"B31","pearson":"oP8","space_group":{"number":62,"symbol":"Pnma"},"caveats":["partitioned order/disorder model in PdSi-16Zho.tdb also describes the disordered state"]},"candidates":[],"review_reasons":[],"names":[{"name":"paper:10.1016/j.intermet.2005.09.008:PdSi","namespace":"paper","label":"PdSi","basis":"corpus_mapping:unstated"},{"name":"tdb:PdSi-05The.tdb:PDSI_B31","namespace":"tdb","label":"PDSI_B31","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96"},{"name":"tdb:PdSi-06Du.tdb:PDSI_B31","namespace":"tdb","label":"PDSI_B31","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01"},{"name":"tdb:PdSi-16Zho.tdb:PDSI_B31","namespace":"tdb","label":"PDSI_B31","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602"},{"name":"tdb:PdSi-20Jia.tdb:PDSI_B31","namespace":"tdb","label":"PDSI_B31","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501"},{"name":"tdb:PdSi-85Sau.tdb:PDSI_B31","namespace":"tdb","label":"PDSI_B31","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159"},{"name":"corpus:phase:pd-si:pdsi-b31","namespace":"corpus","label":"phase:pd-si:pdsi-b31","in_sgte_corpus":true}],"models":[{"tdb":"PdSi-05The.tdb","path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","phase_name":"PDSI_B31","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":73,"line_end":73,"text":"PHASE PDSI_B31 % 2 1 1 !"},"constituent":{"line_start":74,"line_end":74,"text":"CONST PDSI_B31 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PDSI_B31","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-05The.tdb","sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-05The.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-05The.tdb"}},"tdb_comment_structure":["Prototype MnP (oP8, Pnma)"]},{"tdb":"PdSi-06Du.tdb","path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","phase_name":"PDSI_B31","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":104,"line_end":104,"text":"PHASE PDSI_B31 % 2 1 1 !"},"constituent":{"line_start":105,"line_end":105,"text":"CONST PDSI_B31 : PD : SI : !"},"type_definitions":[{"line_start":111,"line_end":111,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PDSI_B31","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-06Du.tdb","sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-06Du.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-06Du.tdb"}},"tdb_comment_structure":["Prototype MnP (oP8, Pnma)"]},{"tdb":"PdSi-16Zho.tdb","path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","phase_name":"PDSI_B31","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD","SI"]},{"site_ratio":1.0,"constituents":["PD","SI"]}],"stoichiometric":false,"composition":null,"tdb_definition":{"verbatim":{"phase":{"line_start":82,"line_end":82,"text":"PHASE PDSI_B31 % 2 1 1 !"},"constituent":{"line_start":83,"line_end":83,"text":"CONST PDSI_B31 : PD% SI : PD SI% : !"},"type_definitions":[{"line_start":89,"line_end":89,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PDSI_B31","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD%","SI"],["PD","SI%"]],"major_constituents":[["PD"],["SI"]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":5,"by_kind":{"G":4,"L":1},"L_by_order":{"0":1},"interaction_orders":[0],"endmember_G":4},"provenance":{"path":"databases/sgte-binary/PdSi-16Zho.tdb","sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-16Zho.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-16Zho.tdb"}},"tdb_comment_structure":["Prototype MnP (oP8, Pnma)"]},{"tdb":"PdSi-20Jia.tdb","path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","phase_name":"PDSI_B31","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":73,"line_end":73,"text":"PHASE PDSI_B31 % 2 1 1 !"},"constituent":{"line_start":74,"line_end":74,"text":"CONST PDSI_B31 : PD : SI : !"},"type_definitions":[{"line_start":80,"line_end":80,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PDSI_B31","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-20Jia.tdb","sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-20Jia.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-20Jia.tdb"}},"tdb_comment_structure":["Prototype MnP (oP8, Pnma)"]},{"tdb":"PdSi-85Sau.tdb","path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","phase_name":"PDSI_B31","type_code":"%","sublattices":[{"site_ratio":1.0,"constituents":["PD"]},{"site_ratio":1.0,"constituents":["SI"]}],"stoichiometric":true,"composition":{"PD":0.5,"SI":0.5},"tdb_definition":{"verbatim":{"phase":{"line_start":59,"line_end":59,"text":"PHASE PDSI_B31 % 2 1 1 !"},"constituent":{"line_start":60,"line_end":60,"text":"CONST PDSI_B31 : PD : SI : !"},"type_definitions":[{"line_start":66,"line_end":66,"text":"TYPE-DEF % SEQ * !","type_code":"%","amends":null}]},"parsed":{"phase_name":"PDSI_B31","type_code":"%","type_codes":["%"],"n_sublattices":2,"site_ratios":[1,1],"constituents":[["PD"],["SI"]],"major_constituents":[[],[]],"magnetic":null,"disordered_part":null,"ordered_partner":null},"parameters":{"total":1,"by_kind":{"G":1},"L_by_order":{},"interaction_orders":[],"endmember_G":1},"provenance":{"path":"databases/sgte-binary/PdSi-85Sau.tdb","sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","decoded_as":"utf-8","website_url":"https://orchid-project.org/data/databases/sgte-binary/PdSi-85Sau.tdb","github_url":"https://github.com/orchid-calphad/orchid-pipeline/blob/main/databases/sgte-binary/PdSi-85Sau.tdb"}},"tdb_comment_structure":["Prototype MnP (oP8, Pnma)"]}],"stoichiometry":null,"stability":[{"tdb":"PdSi-05The.tdb","tdb_sha256":"4902a5627012ae086508f2f209f47e519884eaff3a2be54e4f086723b67aec96","diagram":"phase-diagrams/sgte/PdSi-05The.json","status":"ok","x_element":"SI","stable":true,"T_min_K":887.16,"T_max_K":1243.78,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"PdSi-06Du.tdb","tdb_sha256":"cd9b240e762b0dd6b1e95317b4a8abfb894e3a49e8bf641d595a2eba32740c01","diagram":"phase-diagrams/sgte/PdSi-06Du.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1096.6,"T_max_K":1170.4,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"PdSi-16Zho.tdb","tdb_sha256":"4aee6a8362e3736660fd7717e9b410f13211d4ddfb5b0b20bf9f9d62a0479602","diagram":"phase-diagrams/sgte/PdSi-16Zho.json","status":"ok","x_element":"SI","stable":true,"T_min_K":1097.12,"T_max_K":1204.74,"x_min":0.50295,"x_max":0.50594,"stable_at_top_of_range":false},{"tdb":"PdSi-20Jia.tdb","tdb_sha256":"6df20c7b29268e2c3997d61d7b781fb8f5cf077b5a4d3119786f45da5fc3f501","diagram":"phase-diagrams/sgte/PdSi-20Jia.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1210.0,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false},{"tdb":"PdSi-85Sau.tdb","tdb_sha256":"bc4cb871532e7a4cd1f841da1927e2530afdec8ab5732af1105c086dd65b7159","diagram":"phase-diagrams/sgte/PdSi-85Sau.json","status":"ok","x_element":"SI","stable":true,"T_min_K":300.0,"T_max_K":1345.0,"x_min":0.5,"x_max":0.5,"stable_at_top_of_range":false}],"literature":{"values":8,"accepted_values":8,"papers":1},"corpus":{"in_sgte_corpus":true,"phase_mappings":0,"mapping_basis":{},"printed_labels":[]},"references":[{"doi":"10.1016/j.intermet.2005.09.008","citation":"Zhenmin Du, Cuiping Guo, Xiaojian Yang, Ting Liu, A thermodynamic description of the Pd–Si–C system, Intermetallics 14, 560-569 (2006).","roles":["assessment that models this phase","reports values for this phase"],"labels":["PDSI_B31","PdSi"],"values":8,"tdb_files":["PdSi-06Du.tdb"]},{"doi":"10.1007/s11661-015-3206-8","citation":"S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016).","roles":["assessment that models this phase"],"labels":["PDSI_B31"],"values":0,"tdb_files":["PdSi-16Zho.tdb"]},{"doi":"10.1016/0364-5916(85)90001-X","citation":"N. Saunders, Calphad, 9, 297-309(1985).","roles":["assessment that models this phase"],"labels":["PDSI_B31"],"values":0,"tdb_files":["PdSi-85Sau.tdb"]},{"doi":"10.1016/j.commatsci.2019.109238","citation":"Chao Jiang, Isabella J. van Rooyen, Subhashish Meher, Ab initio study and thermodynamic modeling of the Pd-Si-C system, Computational Materials Science 171, 109238 (2020).","roles":["assessment that models this phase"],"labels":["PDSI_B31"],"values":0,"tdb_files":["PdSi-20Jia.tdb"]},{"doi":"10.1016/0925-8388(93)90406-d","citation":"R. Massara, P. Feschotte, Le système binaire PdSi, Journal of Alloys and Compounds 190, 249-254 (1993).","roles":["cited as the source of values for this phase"],"labels":[],"values":3}],"total_papers":5}],"structure_types":{"st:a1-cu-cf4":{"id":"st:a1-cu-cf4","prototype":"Cu","prototype_spellings":[],"strukturbericht":"A1","pearson":"cF4","space_group":{"number":225,"symbol":"Fm-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":4},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1177},"st:a2-w-ci2":{"id":"st:a2-w-ci2","prototype":"W","prototype_spellings":[],"strukturbericht":"A2","pearson":"cI2","space_group":{"number":229,"symbol":"Im-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":7},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1216},"st:a3-mg-hp2":{"id":"st:a3-mg-hp2","prototype":"Mg","prototype_spellings":[],"strukturbericht":"A3","pearson":"hP2","space_group":{"number":194,"symbol":"P6_3/mmc"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":15},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":1210},"st:a4-c-diamond-cf8":{"id":"st:a4-c-diamond-cf8","prototype":"C (diamond)","prototype_spellings":["C(diamond)"],"strukturbericht":"A4","pearson":"cF8","space_group":{"number":227,"symbol":"Fd-3m"},"stoichiometry":null,"sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":2},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":187},"st:b31-mnp-op8":{"id":"st:b31-mnp-op8","prototype":"MnP","prototype_spellings":[],"strukturbericht":"B31","pearson":"oP8","space_group":{"number":62,"symbol":"Pnma"},"stoichiometry":"Mn1P1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":12}],"verification":"in Hallstedt 2025 mmc2","registry_phases":10},"st:c22-fe2p-hp9":{"id":"st:c22-fe2p-hp9","prototype":"Fe2P","prototype_spellings":[],"strukturbericht":"C22","pearson":"hP9","space_group":{"number":189,"symbol":"P-62m"},"stoichiometry":"Fe2P1","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":10}],"verification":"in Hallstedt 2025 mmc2","registry_phases":10},"st:d0-11-fe3c-op16":{"id":"st:d0-11-fe3c-op16","prototype":"Fe3C","prototype_spellings":[],"strukturbericht":"D0_11","pearson":"oP16","space_group":{"number":62,"symbol":"Pnma"},"stoichiometry":"C1Fe3","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":36},{"citation":"P. Villars, L. D. Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., ASM International (1991)","doi":null},{"citation":"M. J. Mehl et al., The AFLOW Library of Crystallographic Prototypes: Part 1, Comput. Mater. Sci. 136 (2017) S1-S828","doi":"10.1016/j.commatsci.2017.01.017"}],"verification":"built-in row confirmed by Hallstedt 2025 mmc2 (Strukturbericht, Pearson, space group)","registry_phases":36},"st:liquid":{"id":"st:liquid","prototype":null,"prototype_spellings":[],"strukturbericht":null,"pearson":null,"space_group":null,"stoichiometry":null,"sources":[],"verification":"definition (non-crystalline)","registry_phases":1304},"st:pd5p-mp24":{"id":"st:pd5p-mp24","prototype":"Pd5P","prototype_spellings":[],"strukturbericht":null,"pearson":"mP24","space_group":{"number":4,"symbol":"P2_1"},"stoichiometry":"P1Pd5","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":2}],"verification":"in Hallstedt 2025 mmc2","registry_phases":1},"st:pd9si2-op44":{"id":"st:pd9si2-op44","prototype":"Pd9Si2","prototype_spellings":[],"strukturbericht":null,"pearson":"oP44","space_group":{"number":62,"symbol":"Pnma"},"stoichiometry":"Pd9Si2","sources":[{"citation":"B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2)","doi":"10.1016/j.calphad.2025.102833","license":"CC BY 4.0","rows":2}],"verification":"in Hallstedt 2025 mmc2","registry_phases":1}},"cite_as":{"dataset":"phase-registry","version":"2026.10","release_tag":"v2026.10","license":"CC-BY-4.0","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","title":"ORCHID-Registry: phase registry of binary systems","doi":"10.5281/zenodo.23735970","url":"https://doi.org/10.5281/zenodo.23735970","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970","bibtex":"@misc{orchid_phase_registry_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Registry: phase registry of binary systems}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735970},\n  url       = {https://doi.org/10.5281/zenodo.23735970},\n  note      = {Version 1, machine-extracted}\n}","also_cite":["B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file","A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0)","J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0)","the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"part_of":{"title":"ORCHID data: umbrella record of the ORCHID datasets","doi":"10.5281/zenodo.23736065","url":"https://doi.org/10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}"}}}
