Ag–Bi system

20 accepted literature values from 1 paper(s) (unspecified 20); 3 calculated phase diagram(s). 7 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (5) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
unspecified	20

Accepted values by property group
Property group	Values
crystal structure	20

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
AgBi-94Kat.tdb	U.R. Kattner, W.J. Boettinger, J. Electron. Mater., 23, 603-10(1994). doi:10.1007/BF02653345	`9b254b03596511d9af343e533921dcfdf394962cdbbdf4a346c5a8c7161a4d12`	viewer · TDB · JSON
AgBi-98Luk-LB.tdb	H.L. Lukas, unpublished, 1998.	`2ed35ed6e53cf51fdd6fb1cda203bba0ad41363dbe7192f525ba68a4402ca1f2`	viewer · TDB · JSON
AgBi-99Ass.tdb	J. Assal, B. Hallstedt, L.J. Gauckler, J. Am. Ceram. Soc., 82, 711-15(1999). doi:10.1111/j.1151-2916.1999.tb01821.x	`7518266c4e2a3c788cdc6d3a482f64303accee4c64b964602eb97bbf96c0e02b`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
AgBi-94Kat.tdb	534.75	FCC_A1 (x(Bi) 0.00651) + LIQUID (x(Bi) 0.94828) + RHOMBOHEDRAL_A7 (x(Bi) 1)
AgBi-94Kat.tdb	534.75	FCC_A1 (x(Bi) 0.00651) + LIQUID (x(Bi) 0.94826) + RHOMBOHEDRAL_A7 (x(Bi) 1)
AgBi-98Luk-LB.tdb	534.96	FCC_A1 (x(Bi) 0.00785) + LIQUID (x(Bi) 0.94968) + RHOMBOHEDRAL_A7 (x(Bi) 1)
AgBi-98Luk-LB.tdb	534.96	FCC_A1 (x(Bi) 0.00787) + LIQUID (x(Bi) 0.94958) + RHOMBOHEDRAL_A7 (x(Bi) 1)
AgBi-99Ass.tdb	535.56	FCC_A1 (x(Bi) 0.00782) + LIQUID (x(Bi) 0.95379) + RHOMBOHEDRAL_A7 (x(Bi) 1)
AgBi-99Ass.tdb	535.56	FCC_A1 (x(Bi) 0.00784) + LIQUID (x(Bi) 0.95369) + RHOMBOHEDRAL_A7 (x(Bi) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull AgBi-94Kat · CALPHAD hull AgBi-98Luk-LB

Other properties

Crystal structure (20)

Crystal structure, Ag–Bi system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Lattice a	4.094 Å	298.15	Ag Ag: Ag 0.992, Bi 0.008	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 12 report
Lattice a	4.0833 Å	298.15	Ag Ag: Ag 0.99479, Bi 0.00521	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 7 report
Lattice a	4.0832 Å	298.15	Ag Ag: Ag 0.99479, Bi 0.00521	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 6 report
Lattice a	4.09 Å	298.15	Ag Ag: Ag 0.996, Bi 0.004	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 9 report
Lattice a	4.093 Å	298.15	Ag Ag: Ag 0.993, Bi 0.007	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 11 report
Lattice a	4.0809 Å	298.15	Ag Ag: Ag 0.99688, Bi 0.00312	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 5 report
Lattice a	4.099 Å	298.15	Ag Ag: Ag 0.987, Bi 0.013	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 15 report
Lattice a	4.103 Å	298.15	Ag Ag: Ag 0.983, Bi 0.017	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 18 report
Lattice a	4.109 Å	298.15	Ag Ag: Ag 0.978, Bi 0.022	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 21 report
Lattice a	4.095 Å	298.15	Ag Ag: Ag 0.991, Bi 0.009	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 13 report
Lattice a	4.101 Å	298.15	Ag Ag: Ag 0.985, Bi 0.015	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 16 report
Lattice a	4.104 Å	298.15	Ag Ag: Ag 0.982, Bi 0.018	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 19 report
Lattice a	4.105 Å	298.15	Ag Ag: Ag 0.981, Bi 0.019	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 20 report
Lattice a	4.0805 Å	298.15	Ag Ag: Ag 0.9974, Bi 0.0026	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 4 report
Lattice a	4.091 Å	298.15	Ag Ag: Ag 0.995, Bi 0.005	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 10 report
Lattice a	4.097 Å	298.15	Ag Ag: Ag 0.989, Bi 0.011	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 14 report
Lattice a	4.089 Å	298.15	Ag Ag: Ag 0.997, Bi 0.003	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 8 report
Lattice a	4.102 Å	298.15	Ag Ag: Ag 0.984, Bi 0.016	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 17 report
Lattice a	2.998 Å	298.15	ξ-phase	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 24 report
Lattice c	4.849 Å	298.15	ξ-phase	unspecified	[1] Karakaya 1993	Table 2, p. 4, row 24 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

I. Karakaya, W. T. Thompson, The Ag-Bi (Silver-Bismuth) System, JPE 14, 525-530 (1993). doi:10.1007/bf02671975

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}