Ag–Fe system

8 accepted literature values from 1 paper(s) (experimental 4, model 4); 2 calculated phase diagram(s). 7 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (4) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	4
model	4

Accepted values by property group
Property group	Values
invariant reaction	8

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
AgFe-04Kor-LB.tdb	J. Korb, unpublished, GTT, 2004.	`6c8fc844a70bdb21050a5bd442aa08c77acfe9352473aaab2463d0a25f189433`	viewer · TDB · JSON
AgFe-20Zho.tdb	J. Zhou, B. Hu, Y. Jiang, C. Qiu, Y. Du, H. Yin, J. Phase Equilib. Diffus., 41, 257-68(2020). doi:10.1007/s11669-020-00813-5	`677fab8182cdea2bcd028904930616e8b92ff52292546db2251f8eecb44222a6`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
AgFe-04Kor-LB.tdb	1807.15	LIQUID (x(Fe) 0.00823) + LIQUID#2 (x(Fe) 0.99759) + BCC_A2 (x(Fe) 0.99956)
AgFe-04Kor-LB.tdb	1668.91	LIQUID (x(Fe) 0.005) + FCC_A1 (x(Fe) 0.9997) + BCC_A2 (x(Fe) 0.99975)
AgFe-04Kor-LB.tdb	1234.4	FCC_A1#2 (x(Fe) 6.000e-5) + LIQUID (x(Fe) 5.400e-4) + FCC_A1 (x(Fe) 0.99997)
AgFe-04Kor-LB.tdb	1234.4	FCC_A1#2 (x(Fe) 6.000e-5) + LIQUID (x(Fe) 5.400e-4) + FCC_A1 (x(Fe) 0.99997)
AgFe-04Kor-LB.tdb	1184.74	FCC_A1#2 (x(Fe) 4.000e-5) + FCC_A1 (x(Fe) 0.99998) + BCC_A2 (x(Fe) 0.99999)
AgFe-20Zho.tdb	1806.24	LIQUID (x(Fe) 0.00862) + LIQUID#2 (x(Fe) 0.99741) + BCC_A2 (x(Fe) 0.99985)
AgFe-20Zho.tdb	1671.2	LIQUID (x(Fe) 0.00532) + FCC_A1 (x(Fe) 0.99979) + BCC_A2 (x(Fe) 0.99992)
AgFe-20Zho.tdb	1671.2	LIQUID (x(Fe) 0.00532) + FCC_A1 (x(Fe) 0.99978) + BCC_A2 (x(Fe) 0.99992)
AgFe-20Zho.tdb	1234.3	FCC_A1#2 (x(Fe) 2.000e-5) + LIQUID (x(Fe) 5.800e-4) + FCC_A1 (x(Fe) 0.99998)
AgFe-20Zho.tdb	1234.3	FCC_A1#2 (x(Fe) 2.000e-5) + LIQUID (x(Fe) 5.800e-4) + FCC_A1 (x(Fe) 0.99998)
AgFe-20Zho.tdb	1184.72	FCC_A1#2 (x(Fe) 1.000e-5) + FCC_A1 (x(Fe) 0.99999) + BCC_A2 (x(Fe) 1)
AgFe-20Zho.tdb	1184.72	FCC_A1 (x(Fe) 1.000e-5) + FCC_A1#2 (x(Fe) 0.99999) + BCC_A2 (x(Fe) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull AgFe-04Kor-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ag–Fe system (8)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1806.15	monotectic: Liquid#1 -> Liquid#2 + (δFe)	Liquid#1: Fe 0.9974; Liquid#2: Fe 0.009; (δFe): Fe 0.99983	model	[1] Zhou 2020	Table 5, p. 8, row 1 report
1806.15	monotectic: Liquid#1 -> Liquid#2 + (δFe)	Liquid#1: Fe 0.997412; Liquid#2: Fe 0.008625; (δFe): Fe 0.999847	experimental	[1] Zhou 2020 cites Swartzendruber 1984 doi	Table 5, p. 8, row 2 report
1671.15	peritectic: Liquid#2 + (δFe) -> (γFe)	Liquid#2: Fe 0.005323; (δFe): Fe 0.999919; (γFe): Fe 0.999785	experimental	[1] Zhou 2020 cites Swartzendruber 1984 doi	Table 5, p. 8, row 4 report
1671.15	peritectic: Liquid#2 + (δFe) -> (γFe)	Liquid#2: Fe 0.005; (δFe): Fe 0.99991; (γFe): Fe 0.99978	model	[1] Zhou 2020	Table 5, p. 8, row 3 report
1234.15	eutectic: Liquid#2 -> (γFe) + (Ag)	Liquid#2: Fe 1.600e-5; (γFe): Fe 0.999984; (Ag): Fe 5.780e-4	model	[1] Zhou 2020	Table 5, p. 8, row 5 report
1234.15	eutectic: Liquid#2 -> (γFe) + (Ag)	Liquid#2: Fe 7.000e-5; (γFe): Fe 0.999984; (Ag): Fe 6.000e-4	experimental	[1] Zhou 2020 cites Swartzendruber 1984 doi	Table 5, p. 8, row 6 report
1185.15	eutectoid: (γFe) -> (αFe) + (Ag)	(γFe): Fe 0.999998; (αFe): Fe 0.999999; (Ag): Fe 1.000e-5	model	[1] Zhou 2020	Table 5, p. 8, row 7 report
1185.15	eutectoid: (γFe) -> (αFe) + (Ag)	(γFe): Fe 0.99999; (αFe): Fe 0.999998; (Ag): Fe 4.000e-5	experimental	[1] Zhou 2020 cites Swartzendruber 1984 doi	Table 5, p. 8, row 8 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Jiaqiang Zhou, Biao Hu, Yu Jiang, Chengliang Qiu, Yong Du, Huiqin Yin, Thermodynamic Modeling of the Ag-X (X = B, Fe, Sm, Pu) Binary Systems, J. Phase Equilib. Diffus. 41, 257-268 (2020). doi:10.1007/s11669-020-00813-5

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}