# Ag–In system

> Ag–In system: 50 accepted literature values (invariant reaction 43, phase transition 7) and 6 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/AG-IN.html · Markdown: https://data.orchid-project.org/systems/AG-IN.md

50 accepted literature values from 2 paper(s) (experimental 35, model 15); 6 calculated phase diagram(s). 12 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/AG-IN.json) · [CSV](https://data.orchid-project.org/systems/AG-IN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AG-IN) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-01Che-LB.json) · [phases (9)](https://data.orchid-project.org/phases/pages/AG-IN.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AG-IN.html) · [Markdown](https://data.orchid-project.org/systems/AG-IN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 35 |
| model | 15 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 43 |
| phase transition | 7 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AgIn-01Che-LB.tdb | P.-Y. Chevalier, E. Fischer, unpublished, Thermodata, 2001. | `4a54fce02faf2be33720e1ad4f7814b3af0abfcb083f44028ac2a25425acd9d8` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-01Che-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-01Che-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-01Che-LB.json) |
| AgIn-01Mos.tdb | Z. Moser, W. Gasior, J. Pstrus, W. Zakulski, I. Ohnuma, X.J. Liu, Y. Inohana, K. Ishida, J. Electron. Mater., 30, 1120-28(2001). [doi:10.1007/s11664-001-0138-4](https://doi.org/10.1007/s11664-001-0138-4) | `8135d127623e0a9013d8029e11addf46d43b24e1ec934005661f5597a0377f6d` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-01Mos.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-01Mos.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-01Mos.json) |
| AgIn-12Gie.tdb | W. Gierlotka, J. Electron. Mater., 41, 86-108(2012). [doi:10.1007/s11664-011-1757-z](https://doi.org/10.1007/s11664-011-1757-z) | `2d44091621ab6487acdd987b8a85c922a12657311bfeb987b529323d1cdd15c5` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-12Gie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-12Gie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-12Gie.json) |
| AgIn-18Muz.tdb | C.P. Muzzillo, T. Anderson, J. Mater. Sci., 53, 6893-6910(2018). [doi:10.1007/s10853-018-1999-8](https://doi.org/10.1007/s10853-018-1999-8) | `c7853514773b1fdba4937525e737d4b9481d4c2e173df43539aa645b7b12db3b` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-18Muz.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-18Muz.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-18Muz.json) |
| AgIn-19Fis.tdb | E. Fischer, K. Gajavalli, G. Mikaelian, P. Benigni, J. Rogez, A. Decreton, M. Barrachin, Calphad, 64, 292-305(2019). [doi:10.1016/j.calphad.2019.01.001](https://doi.org/10.1016/j.calphad.2019.01.001) | `4cca7ad748e801ffd31af18a3ee8dc141526869f2a465276cb689d1d48fee71f` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-19Fis.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-19Fis.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-19Fis.json) |
| AgIn-98Kor.tdb | T.-M. Korhonen, J.K. Kivilahti, J. Electron. Mater., 27, 149-58(1998). [doi:10.1007/s11664-998-0205-1](https://doi.org/10.1007/s11664-998-0205-1) | `4c8fd91ba6cf605ce7d3e75ea4083b0bd14cdd84879b05dc05cb92f028af15c5` | [viewer](https://orchid-project.org/phase-diagrams/#AG-IN/AgIn-98Kor.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgIn-98Kor.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgIn-98Kor.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| AgIn-01Che-LB.tdb | 977.82 | FCC_A1 (x(In) 0.1866) + BCC_A2 (x(In) 0.22525) + LIQUID (x(In) 0.27791) |
| AgIn-01Che-LB.tdb | 946.69 | FCC_A1 (x(In) 0.19227) + HCP_A3 (x(In) 0.22402) + BCC_A2 (x(In) 0.23093) |
| AgIn-01Che-LB.tdb | 933.35 | HCP_A3 (x(In) 0.25156) + BCC_A2 (x(In) 0.25293) + LIQUID (x(In) 0.32913) |
| AgIn-01Che-LB.tdb | 477.7 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41961) + LIQUID (x(In) 0.92573) |
| AgIn-01Che-LB.tdb | 477.7 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41964) + LIQUID (x(In) 0.92594) |
| AgIn-01Che-LB.tdb | 458.25 | AG3IN_L12 (x(In) 0.25) + HCP_A3 (x(In) 0.25596) + AG2IN_D83 (x(In) 0.33333) |
| AgIn-01Che-LB.tdb | 443.76 | FCC_A1 (x(In) 0.19981) + HCP_A3 (x(In) 0.23289) + AG3IN_L12 (x(In) 0.25) |
| AgIn-01Che-LB.tdb | 439.19 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95054) |
| AgIn-01Che-LB.tdb | 439.18 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95042) |
| AgIn-01Che-LB.tdb | 439.18 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95041) |
| AgIn-01Che-LB.tdb | 414.6 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96734) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-01Che-LB.tdb | 414.6 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96734) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-01Mos.tdb | 948.41 | FCC_A1 (x(In) 0.19811) + HCP_A3 (x(In) 0.24204) + LIQUID (x(In) 0.30105) |
| AgIn-01Mos.tdb | 467.94 | AG2IN_D83 (x(In) 0.32) + HCP_A3 (x(In) 0.35928) + LIQUID (x(In) 0.93854) |
| AgIn-01Mos.tdb | 467.94 | AG2IN_D83 (x(In) 0.32) + HCP_A3 (x(In) 0.35928) + LIQUID (x(In) 0.93848) |
| AgIn-01Mos.tdb | 439.02 | AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95452) |
| AgIn-01Mos.tdb | 439.02 | AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95438) |
| AgIn-01Mos.tdb | 439.02 | AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95462) |
| AgIn-01Mos.tdb | 417.64 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97484) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-01Mos.tdb | 417.64 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97498) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-01Mos.tdb | 417.64 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97507) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-12Gie.tdb | 949.14 | FCC_A1 (x(In) 0.21106) + HCP_A3 (x(In) 0.24334) + LIQUID (x(In) 0.31225) |
| AgIn-12Gie.tdb | 472.96 | AG2IN_D83 (x(In) 0.3379) + HCP_A3 (x(In) 0.37285) + LIQUID (x(In) 0.93454) |
| AgIn-12Gie.tdb | 448.95 | AG2IN_D83 (x(In) 0.33808) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94633) |
| AgIn-12Gie.tdb | 415.17 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97216) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-12Gie.tdb | 415.17 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97219) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-18Muz.tdb | 981.81 | FCC_A1 (x(In) 0.19129) + BCC_A2 (x(In) 0.24048) + LIQUID (x(In) 0.28346) |
| AgIn-18Muz.tdb | 939.45 | FCC_A1 (x(In) 0.21057) + HCP_A3 (x(In) 0.24283) + BCC_A2 (x(In) 0.25375) |
| AgIn-18Muz.tdb | 933.98 | HCP_A3 (x(In) 0.25506) + BCC_A2 (x(In) 0.26405) + LIQUID (x(In) 0.33185) |
| AgIn-18Muz.tdb | 477.41 | AG9IN4_D83 (x(In) 0.33621) + HCP_A3 (x(In) 0.37265) + LIQUID (x(In) 0.93226) |
| AgIn-18Muz.tdb | 438.98 | AG9IN4_D83 (x(In) 0.33622) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95121) |
| AgIn-18Muz.tdb | 414.09 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97019) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-18Muz.tdb | 414.09 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97027) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-19Fis.tdb | 965.97 | FCC_A1 (x(In) 0.19271) + BCC_A2 (x(In) 0.23241) + LIQUID (x(In) 0.29591) |
| AgIn-19Fis.tdb | 937.95 | FCC_A1 (x(In) 0.20342) + HCP_A3 (x(In) 0.2353) + BCC_A2 (x(In) 0.24193) |
| AgIn-19Fis.tdb | 932.71 | HCP_A3 (x(In) 0.24927) + BCC_A2 (x(In) 0.25479) + LIQUID (x(In) 0.33246) |
| AgIn-19Fis.tdb | 478.52 | AG3IN_L12 (x(In) 0.25) + HCP_A3 (x(In) 0.26002) + AG2IN_D83 (x(In) 0.33333) |
| AgIn-19Fis.tdb | 477.63 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41382) + LIQUID (x(In) 0.92898) |
| AgIn-19Fis.tdb | 477.63 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41385) + LIQUID (x(In) 0.92918) |
| AgIn-19Fis.tdb | 460.03 | FCC_A1 (x(In) 0.19951) + HCP_A3 (x(In) 0.23094) + AG3IN_L12 (x(In) 0.25) |
| AgIn-19Fis.tdb | 439.22 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95205) |
| AgIn-19Fis.tdb | 439.22 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95184) |
| AgIn-19Fis.tdb | 439.22 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95217) |
| AgIn-19Fis.tdb | 413.62 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96751) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-19Fis.tdb | 413.62 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96767) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-98Kor.tdb | 926.59 | FCC_A1 (x(In) 0.1972) + HCP_A3 (x(In) 0.23529) + LIQUID (x(In) 0.33016) |
| AgIn-98Kor.tdb | 475.58 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41941) + LIQUID (x(In) 0.91711) |
| AgIn-98Kor.tdb | 475.58 | AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41941) + LIQUID (x(In) 0.91702) |
| AgIn-98Kor.tdb | 440.17 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94205) |
| AgIn-98Kor.tdb | 440.17 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94174) |
| AgIn-98Kor.tdb | 440.17 | AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94225) |
| AgIn-98Kor.tdb | 413.27 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96739) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-98Kor.tdb | 413.27 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96759) + TETRAGONAL_A6 (x(In) 1) |
| AgIn-98Kor.tdb | 413.27 | AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96778) + TETRAGONAL_A6 (x(In) 1) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AG/AG-IN.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AG/AG-IN.json) · [CALPHAD hull AgIn-01Che-LB](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-IN--AgIn-01Che-LB.json) · [CALPHAD hull AgIn-01Mos](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-IN--AgIn-01Mos.json) · [CALPHAD hull AgIn-12Gie](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-IN--AgIn-12Gie.json) · [CALPHAD hull AgIn-18Muz](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-IN--AgIn-18Muz.json) · [CALPHAD hull AgIn-98Kor](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-IN--AgIn-98Kor.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Ag–In system (43)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 983 | L + α -> β | L: In 0.194; α: In 0.286; β: In 0.242 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 6; `ORC-M4CFZ45IHR` |  |
| 968 | L + α -> β | L: In 0.208; α: In 0.311; β: In 0.264 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 3; `ORC-QTYCPITMC4` |  |
| 967.1 | L + α -> β | L: In 0.204; α: In 0.3; β: In 0.249 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 7; `ORC-APZQ63ZEKC` |  |
| 967 | L + α -> β | L: In 0.21; α: In 0.3; β: In 0.25 | experimental | [1] Muzzillo 2018; _cites Moser 2001_ [doi](https://doi.org/10.1007/s11664-001-0138-4) | Table 1, p. 3, row 4; `ORC-GYPM2ARS3F` |  |
| 966.1 | L + α -> β | L: In 0.19; α: In 0.282; β: In 0.249 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 5; `ORC-4IUBXY3676` |  |
| 966 | L + α -> β | L: In 0.183; α: In 0.283; β: In 0.239 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 2; `ORC-MRKXIUZNWY` |  |
| 966 | L + α -> β | L: In 0.188; α: In 0.29; β: In 0.239 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 1; `ORC-VX4QH5GEOK` |  |
| 944.5 | α + β -> ζ | α: In 0.192; β: In 0.233; ζ: In 0.228 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 12; `ORC-5PCN6RG23M` |  |
| 944 | α + β -> ζ | α: In 0.209; β: In 0.265; ζ: In 0.25 | experimental | [1] Muzzillo 2018; _cites Moser 2001_ [doi](https://doi.org/10.1007/s11664-001-0138-4) | Table 1, p. 3, row 11; `ORC-3HOJYZSAD2` |  |
| 943 | α + β -> ζ | α: In 0.204; β: In 0.275; ζ: In 0.262 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 10; `ORC-YQI3OS4YPK` |  |
| 940 | α + β -> ζ | α: In 0.186; β: In 0.237; ζ: In 0.231 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 8; `ORC-3UZCZHAE6P` |  |
| 940 | α + β -> ζ | α: In 0.181; β: In 0.237; ζ: In 0.231 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 9; `ORC-ZSPB6ZALBT` |  |
| 935.8 | α + β -> ζ | α: In 0.221; β: In 0.26; ζ: In 0.251 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 14; `ORC-6M2D7TS5BE` |  |
| 935.7 | α + β -> ζ | α: In 0.221; β: In 0.26; ζ: In 0.251 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 13; `ORC-VYR6FN2Q73` |  |
| 934.4 | β -> L + ζ | β: In 0.261; L: In 0.253; ζ: In 0.316 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 19; `ORC-JRSIOS6CR5` |  |
| 934 | β -> L + ζ | β: In 0.264; L: In 0.255; ζ: In 0.332 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 20; `ORC-36NAAYGN2V` |  |
| 934 | β -> L + ζ | β: In 0.264; L: In 0.255; ζ: In 0.332 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 21; `ORC-DAO7CDPVXH` |  |
| 933 | β -> L + ζ | β: In 0.3; L: In 0.28; ζ: In 0.325 | experimental | [1] Muzzillo 2018; _cites Moser 2001_ [doi](https://doi.org/10.1007/s11664-001-0138-4) | Table 1, p. 3, row 18; `ORC-CP73MKTVLF` |  |
| 933 | β -> L + ζ | β: In 0.247; L: In 0.242; ζ: In 0.311 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 16; `ORC-ESMQ7TMI5T` |  |
| 933 | β -> L + ζ | β: In 0.322; L: In 0.298; ζ: In 0.336 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 17; `ORC-USOLJQWAOI` |  |
| 933 | β -> L + ζ | β: In 0.247; L: In 0.242; ζ: In 0.317 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 15; `ORC-XQZWANXRUQ` |  |
| 478.3 | ζ -> L + γ-Ag9In4 | ζ: In 0.387; L: In 0.95; γ-Ag9In4: In 0.332 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 31; `ORC-F2ZBI4VUKJ` |  |
| 478 | ζ -> L + γ-Ag9In4 | ζ: In 0.476; L: In 0.353; γ-Ag9In4: In 0.928 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 30; `ORC-SJ4BC7LNCK` |  |
| 477.4 | ζ -> L + γ-Ag9In4 | ζ: In 0.373; L: In 0.932; γ-Ag9In4: In 0.336 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 33; `ORC-BGI5CBMY4F` |  |
| 477 | ζ -> L + γ-Ag9In4 | L: In 0.925; γ-Ag9In4: In 0.319 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 29; `ORC-7KC3RIW7OS` |  |
| 477 | ζ -> L + γ-Ag9In4 | L: In 0.928; γ-Ag9In4: In 0.322 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 28; `ORC-SEXO6LESS6` |  |
| 474.1 | α + ζ -> α' | α: In 0.204; ζ: In 0.251; α': In 0.243 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 37; `ORC-XHYZEA7F4H` |  |
| 473 | ζ -> L + γ-Ag9In4 | ζ: In 0.373; L: In 0.338; γ-Ag9In4: In 0.935 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 32; `ORC-RTHXZMVOS6` |  |
| 460 | α + ζ -> α' | α: In 0.193; ζ: In 0.254; α': In 0.245 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 36; `ORC-5CBB6XQ743` |  |
| 460 | ζ -> α + α' | ζ: In 0.245; α: In 0.182; α': In 0.254 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 35; `ORC-DVWEL27L6L` |  |
| 460 | ζ -> α + α' | ζ: In 0.248; α: In 0.186; α': In 0.256 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 34; `ORC-PYTRNC5A7Q` |  |
| 451.7 | L + γ-Ag9In4 -> AgIn2 | L: In 0.338; γ-Ag9In4: In 0.945; AgIn2: In 0.67 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 42; `ORC-2LG63VOAQ5` |  |
| 443.3 | L + γ-Ag9In4 -> AgIn2 | L: In 0.968; γ-Ag9In4: In 0.332; AgIn2: In 0.667 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 41; `ORC-A4ZAVHP6JY` |  |
| 439 | L + γ-Ag9In4 -> AgIn2 | L: In 0.951; γ-Ag9In4: In 0.336; AgIn2: In 0.667 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 43; `ORC-5RH6LOA3P6` |  |
| 439 | L + γ-Ag9In4 -> AgIn2 | L: In 0.355; γ-Ag9In4: In 0.955; AgIn2: In 0.667 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 40; `ORC-7M6UQXWDLJ` |  |
| 439 | L + γ-Ag9In4 -> AgIn2 | L: In 0.951; γ-Ag9In4: In 0.319; AgIn2: In 0.731 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 39; `ORC-LRLRSBEPDL` |  |
| 439 | L + γ-Ag9In4 -> AgIn2 | L: In 0.953; γ-Ag9In4: In 0.321; AgIn2: In 0.737 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 38; `ORC-WQADKSEYYU` |  |
| 418.7 | eutectic: L -> AgIn2 + In | L: In 0.99; AgIn2: In 0.667; In: In 1 | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 47; `ORC-5IVIVDWFNS` |  |
| 417 | eutectic: L -> AgIn2 + In | L: In 0.977; AgIn2: In 0.667; In: In 1 | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 46; `ORC-XMJAV7X7VM` |  |
| 415.6 | eutectic: L -> AgIn2 + In | L: In 0.973; AgIn2: In 0.67; In: In 1 | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 48; `ORC-3LXLKPHPIP` |  |
| 414.1 | eutectic: L -> AgIn2 + In | L: In 0.97; AgIn2: In 0.667; In: In 1 | model | [1] Muzzillo 2018 | Table 1, p. 3, row 49; `ORC-YHWSLTPKGI` |  |
| 414 | eutectic: L -> AgIn2 + In | L: In 0.97; AgIn2: In 0.742; In: In 1 | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 44; `ORC-3AIMQHPNVE` |  |
| 414 | eutectic: L -> AgIn2 + In | L: In 0.962; AgIn2: In 0.738; In: In 1 | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 45; `ORC-CNIXJO25ND` |  |

## Other properties

### Phase transition (7)

Table: Phase transition, Ag–In system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 477 K | 477 | other | model | [2] Fischer 2019 | p. 15; `ORC-GCULBZQAAW` | “The optimization based on the experimental points from Weibke and Eggers \[59\] for the (Ag2In + hcp) silver rich domain leads to a symmetric shape, the hcp composition reaches 42 at.% In at the metatectic temperature of 477 K.” |
| Phase transition | 557.4 K | 557.4 | ζ -> γ-Ag9In4; _ζ: In 0.327; γ-Ag9In4: In 0.327_ | experimental | [1] Muzzillo 2018; _cites Bahari 2009_ [doi](https://doi.org/10.1016/j.jallcom.2008.10.030) | Table 1, p. 3, row 25; `ORC-IB6I5BULNQ` |  |
| Phase transition | 570 K | 570 | ζ -> γ-Ag9In4; _ζ: In 0.342; γ-Ag9In4: In 0.342_ | experimental | [1] Muzzillo 2018; _cites Campbell 1970_ [doi](https://doi.org/10.1139/v70-281) | Table 1, p. 3, row 24; `ORC-QR4UVEPKLS` |  |
| Phase transition | 570.9 K | 570.9 | ζ -> γ-Ag9In4; _ζ: In 0.318; γ-Ag9In4: In 0.318_ | model | [1] Muzzillo 2018 | Table 1, p. 3, row 27; `ORC-LWBGVDWKKM` |  |
| Phase transition | 572 K | 572 | ζ -> γ-Ag9In4; _ζ: In 0.314; γ-Ag9In4: In 0.314_ | experimental | [1] Muzzillo 2018; _cites Hellner 1951_ | Table 1, p. 3, row 23; `ORC-DYHL4WYVPN` |  |
| Phase transition | 574 K | 574 | ζ -> γ-Ag9In4; _ζ: In 0.317; γ-Ag9In4: In 0.317_ | experimental | [1] Muzzillo 2018; _cites Weibke 1935_ [doi](https://doi.org/10.1002/zaac.19352220205) | Table 1, p. 3, row 22; `ORC-IFDLSOLEXC` |  |
| Phase transition | 577.1 K | 577.1 | ζ -> γ-Ag9In4; _ζ: In 0.33; γ-Ag9In4: In 0.33_ | model | [1] Muzzillo 2018; _cites Gierlotka 2012_ [doi](https://doi.org/10.1007/s11664-011-1757-z) | Table 1, p. 3, row 26; `ORC-PKQX5CVC5Q` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Christopher P. Muzzillo, Tim Anderson, Thermodynamic assessment of Ag–Cu–In, J Mater Sci 53, 6893-6910 (2018). [doi:10.1007/s10853-018-1999-8](https://doi.org/10.1007/s10853-018-1999-8)
2. E. Fischer, K. Gajavalli, G. Mikaelian, P. Benigni, J. Rogez, A. Decreton et al., Experimental study and thermodynamic modelling of the Ag-Cd-In system, Calphad 64, 292-305 (2019). [doi:10.1016/j.calphad.2019.01.001](https://doi.org/10.1016/j.calphad.2019.01.001)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).