# Ag–Mg system

> Ag–Mg system: 110 accepted literature values (mixing / partial 68, heat capacity / entropy / enthalpy 27, crystal structure 9, transformation enthalpy 6) and 4 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/AG-MG.html · Markdown: https://data.orchid-project.org/systems/AG-MG.md

110 accepted literature values from 2 paper(s) (experimental 97, model 4, DFT 9); 4 calculated phase diagram(s). 8 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/AG-MG.json) · [CSV](https://data.orchid-project.org/systems/AG-MG.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AG-MG) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AG-MG/AgMg-15Dai.json) · [phases (14)](https://data.orchid-project.org/phases/pages/AG-MG.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AG-MG.html) · [Markdown](https://data.orchid-project.org/systems/AG-MG.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 97 |
| model | 4 |
| DFT | 9 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| mixing / partial | 68 |
| heat capacity / entropy / enthalpy | 27 |
| crystal structure | 9 |
| transformation enthalpy | 6 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AgMg-15Dai.tdb | C. Dai, D.V. Malakhov, J. Alloys Compd., 619, 20-25(2015). [doi:10.1016/j.jallcom.2014.08.075](https://doi.org/10.1016/j.jallcom.2014.08.075) | `c257bf15ed92de59d3b11381641317310794f0310960302d800c773c63188f24` | [viewer](https://orchid-project.org/phase-diagrams/#AG-MG/AgMg-15Dai.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgMg-15Dai.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgMg-15Dai.json) |
| AgMg-21Deb.tdb | A. Debski, W. Gierlotka, W. Gasior, J. Alloys Compd., 891, 161937(2021). [doi:10.1016/j.jallcom.2021.161937](https://doi.org/10.1016/j.jallcom.2021.161937) | `059efa5f9af5dd0eff2330bde8f5c89e3af5b3ec570dcc057b1dd222a009fcdd` | [viewer](https://orchid-project.org/phase-diagrams/#AG-MG/AgMg-21Deb.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgMg-21Deb.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgMg-21Deb.json) |
| AgMg-97Lim-LB.tdb | M.S. Lim, J.E. Tibballs, P.L. Rossiter, Z. Metallkd., 88, 162-69(1997). [doi:10.3139/ijmr-1997-0029](https://doi.org/10.3139/ijmr-1997-0029) | `1112582e75b20f34ab478c99e95cd993fd63c2ac412a34b3a3cd2f5b1e4c3c9f` | [viewer](https://orchid-project.org/phase-diagrams/#AG-MG/AgMg-97Lim-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgMg-97Lim-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgMg-97Lim-LB.json) |
| AgMg-98Spe.tdb | P.J. Spencer, unpublished, 1998. | `05967f03ceeb90e48c6d1c244113bd4ac44289fc92004fdbc7cb6bbd179572eb` | [viewer](https://orchid-project.org/phase-diagrams/#AG-MG/AgMg-98Spe.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AgMg-98Spe.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AgMg-98Spe.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| AgMg-15Dai.tdb | 1032.27 | FCC_A1 (x(Mg) 0.29851) + LIQUID (x(Mg) 0.33536) + B2_BCC (x(Mg) 0.35473) |
| AgMg-15Dai.tdb | 1032.27 | FCC_4SL (x(Mg) 0.29851) + LIQUID (x(Mg) 0.33536) + B2_BCC (x(Mg) 0.35473) |
| AgMg-15Dai.tdb | 765.28 | B2_BCC (x(Mg) 0.63403) + AGMG3 (x(Mg) 0.77) + LIQUID (x(Mg) 0.7854) |
| AgMg-15Dai.tdb | 743.27 | AGMG3 (x(Mg) 0.77) + LIQUID (x(Mg) 0.86257) + HCP_A3 (x(Mg) 0.9663) |
| AgMg-15Dai.tdb | 743.27 | AGMG3 (x(Mg) 0.77) + LIQUID (x(Mg) 0.86267) + HCP_A3 (x(Mg) 0.96635) |
| AgMg-15Dai.tdb | 738.61 | AGMG3 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96832) |
| AgMg-15Dai.tdb | 738.61 | AGMG3 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96839) |
| AgMg-15Dai.tdb | 738.61 | AGMG3 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96842) |
| AgMg-15Dai.tdb | 669.05 | FCC_A1 (x(Mg) 0.25689) + FCC_4SL (x(Mg) 0.26385) + B2_BCC (x(Mg) 0.38127) |
| AgMg-15Dai.tdb | 669.05 | FCC_A1 (x(Mg) 0.25689) + FCC_4SL (x(Mg) 0.26385) + B2_BCC (x(Mg) 0.38127) |
| AgMg-21Deb.tdb | 1035.04 | L12_FCC (x(Mg) 0.28416) + LIQUID (x(Mg) 0.33588) + B2_BCC (x(Mg) 0.38073) |
| AgMg-21Deb.tdb | 1035.04 | FCC_A1 (x(Mg) 0.28416) + LIQUID (x(Mg) 0.33588) + B2_BCC (x(Mg) 0.38073) |
| AgMg-21Deb.tdb | 1035.04 | FCC_A1 (x(Mg) 0.28416) + LIQUID (x(Mg) 0.33588) + B2_BCC (x(Mg) 0.38073) |
| AgMg-21Deb.tdb | 771.93 | B2_BCC (x(Mg) 0.62561) + AGMG3_PRIME (x(Mg) 0.77) + LIQUID (x(Mg) 0.77336) |
| AgMg-21Deb.tdb | 771.93 | B2_BCC (x(Mg) 0.62561) + AGMG3_PRIME (x(Mg) 0.77) + LIQUID (x(Mg) 0.77336) |
| AgMg-21Deb.tdb | 759.7 | AGMG3_PRIME (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + LIQUID (x(Mg) 0.81728) |
| AgMg-21Deb.tdb | 759.7 | AGMG3_PRIME (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + LIQUID (x(Mg) 0.81785) |
| AgMg-21Deb.tdb | 757.63 | B2_BCC (x(Mg) 0.61959) + AGMG3 (x(Mg) 0.76) + AGMG3_PRIME (x(Mg) 0.77) |
| AgMg-21Deb.tdb | 757.63 | B2_BCC (x(Mg) 0.61953) + AGMG3 (x(Mg) 0.76) + AGMG3_PRIME (x(Mg) 0.77) |
| AgMg-21Deb.tdb | 742.92 | AGMG4 (x(Mg) 0.8) + LIQUID (x(Mg) 0.85907) + HCP_A3 (x(Mg) 0.96833) |
| AgMg-21Deb.tdb | 742.92 | AGMG4 (x(Mg) 0.8) + LIQUID (x(Mg) 0.85915) + HCP_A3 (x(Mg) 0.96834) |
| AgMg-21Deb.tdb | 728.46 | AGMG3 (x(Mg) 0.76) + AGMG3_PRIME (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) |
| AgMg-21Deb.tdb | 705.61 | B2_BCC (x(Mg) 0.59734) + AG2MG5_D811 (x(Mg) 0.71429) + AGMG3 (x(Mg) 0.76) |
| AgMg-21Deb.tdb | 705.61 | B2_BCC (x(Mg) 0.5972) + AG2MG5_D811 (x(Mg) 0.71429) + AGMG3 (x(Mg) 0.76) |
| AgMg-21Deb.tdb | 665.77 | L12_FCC (x(Mg) 0.25797) + FCC_A1 (x(Mg) 0.26028) + B2_BCC (x(Mg) 0.38676) |
| AgMg-21Deb.tdb | 665.77 | L12_FCC (x(Mg) 0.25797) + FCC_A1 (x(Mg) 0.26028) + B2_BCC (x(Mg) 0.38676) |
| AgMg-21Deb.tdb | 545.98 | AGMG3 (x(Mg) 0.76) + AGMG4_PRIME (x(Mg) 0.8) + AGMG4 (x(Mg) 0.8) |
| AgMg-21Deb.tdb | 545.98 | AGMG4_PRIME (x(Mg) 0.8) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.99113) |
| AgMg-21Deb.tdb | 545.98 | AGMG4 (x(Mg) 0.8) + AGMG4_PRIME (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.99118) |
| AgMg-97Lim-LB.tdb | 1028.36 | FCC_A1 (x(Mg) 0.27689) + LIQUID (x(Mg) 0.33515) + B2_BCC (x(Mg) 0.39808) |
| AgMg-97Lim-LB.tdb | 1028.36 | FCC_4SL (x(Mg) 0.27689) + LIQUID (x(Mg) 0.33515) + B2_BCC (x(Mg) 0.39808) |
| AgMg-97Lim-LB.tdb | 764.46 | B2_BCC (x(Mg) 0.62492) + AG23MG77 (x(Mg) 0.77) + LIQUID (x(Mg) 0.80909) |
| AgMg-97Lim-LB.tdb | 746.97 | AG23MG77 (x(Mg) 0.77) + LIQUID (x(Mg) 0.86342) + HCP_A3 (x(Mg) 0.96516) |
| AgMg-97Lim-LB.tdb | 746.97 | AG23MG77 (x(Mg) 0.77) + LIQUID (x(Mg) 0.8636) + HCP_A3 (x(Mg) 0.96525) |
| AgMg-97Lim-LB.tdb | 738.26 | AG23MG77 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96919) |
| AgMg-97Lim-LB.tdb | 738.26 | AG23MG77 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96938) |
| AgMg-97Lim-LB.tdb | 738.25 | AG23MG77 (x(Mg) 0.77) + AGMG4 (x(Mg) 0.8) + HCP_A3 (x(Mg) 0.96929) |
| AgMg-97Lim-LB.tdb | 665.15 | FCC_4SL (x(Mg) 0.23155) + FCC_A1 (x(Mg) 0.23155) + B2_BCC (x(Mg) 0.33727) |
| AgMg-98Spe.tdb | 1029.77 | FCC_A1 (x(Mg) 0.28068) + LIQUID (x(Mg) 0.32942) + BCC_A2 (x(Mg) 0.36645) |
| AgMg-98Spe.tdb | 765.09 | BCC_A2 (x(Mg) 0.7106) + AGMG3 (x(Mg) 0.75) + LIQUID (x(Mg) 0.75292) |
| AgMg-98Spe.tdb | 702.65 | AGMG3 (x(Mg) 0.75) + LIQUID (x(Mg) 0.85617) + HCP_A3 (x(Mg) 0.9396) |
| AgMg-98Spe.tdb | 702.65 | AGMG3 (x(Mg) 0.75) + LIQUID (x(Mg) 0.85624) + HCP_A3 (x(Mg) 0.93964) |
| AgMg-98Spe.tdb | 552.48 | AG3MG_L12 (x(Mg) 0.25) + FCC_A1 (x(Mg) 0.2928) + BCC_A2 (x(Mg) 0.35896) |
| AgMg-98Spe.tdb | 552.48 | AG3MG_L12 (x(Mg) 0.25) + FCC_A1 (x(Mg) 0.29281) + BCC_A2 (x(Mg) 0.35895) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AG/AG-MG.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AG/AG-MG.json) · [CALPHAD hull AgMg-15Dai](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-MG--AgMg-15Dai.json) · [CALPHAD hull AgMg-97Lim-LB](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-MG--AgMg-97Lim-LB.json) · [CALPHAD hull AgMg-98Spe](https://data.orchid-project.org/hulls/calphad-sgte/AG/AG-MG--AgMg-98Spe.json)

## Other properties

### Mixing / partial (68)

Table: Mixing / partial, Ag–Mg system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Enthalpy of mixing; _printed: ΔmixH_ | -8.699 kJ/mol (basis unstated) ± 0.502 | 991 | liquid; _alloy: Ag 0.2057, Mg 0.7943_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 4; `ORC-5FROBP7ARD.953f77` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -5.356 kJ/mol (basis unstated) ± 0.884 | 991 | liquid; _alloy: Ag 0.1134, Mg 0.8866_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 7; `ORC-BAO6SHD72G.5440b2` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -4.419 kJ/mol (basis unstated) ± 1.014 | 991 | liquid; _alloy: Ag 0.0934, Mg 0.9066_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 8; `ORC-CKTKVWFYZH.c24db5` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -3.658 kJ/mol (basis unstated) ± 1.149 | 991 | liquid; _alloy: Ag 0.0762, Mg 0.9238_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 9; `ORC-DC7O5HN2WM.627c1a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -9.415 kJ/mol (basis unstated) ± 0.422 | 991 | liquid; _alloy: Ag 0.2332, Mg 0.7668_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 2; `ORC-DH2IGAU4R4.fbfffc` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -7.27 kJ/mol (basis unstated) ± 0.64 | 991 | liquid; _alloy: Ag 0.1655, Mg 0.8345_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 5; `ORC-KYWYSQIVUH.08e242` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -6.337 kJ/mol (basis unstated) ± 0.757 | 991 | liquid; _alloy: Ag 0.1378, Mg 0.8622_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 6; `ORC-LRHV5MAEZO.4e313a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -9.568 kJ/mol (basis unstated) ± 0.387 | 991 | liquid; _alloy: Ag 0.2484, Mg 0.7516_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 1; `ORC-UPOYVTUV5Y.60edbe` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -9.071 kJ/mol (basis unstated) ± 0.46 | 991 | liquid; _alloy: Ag 0.2197, Mg 0.7803_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 3; `ORC-XZQIWMFZYL.71a627` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.173 kJ/mol (basis unstated) ± 0.516 | 1141 | liquid; _alloy: Ag 0.5345, Mg 0.4655_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 20; `ORC-4DGGWXUTZP.5e6ffb` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -11.153 kJ/mol (basis unstated) ± 0.389 | 1141 | liquid; _alloy: Ag 0.3333, Mg 0.6667_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 11; `ORC-4W6T3ICZIG.9d1ab9` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -11.94 kJ/mol (basis unstated) ± 0.397 | 1141 | liquid; _alloy: Ag 0.366, Mg 0.634_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 12; `ORC-5BZY5GRORQ.219132` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.752 kJ/mol (basis unstated) ± 0.411 | 1141 | liquid; _alloy: Ag 0.4053, Mg 0.5947_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 14; `ORC-6HHKAQX3T5.21bf41` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.219 kJ/mol (basis unstated) ± 0.497 | 1141 | liquid; _alloy: Ag 0.516, Mg 0.484_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 19; `ORC-CEU7U6V4GF.c3820b` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.451 kJ/mol (basis unstated) ± 0.436 | 1141 | liquid; _alloy: Ag 0.4548, Mg 0.5452_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 16; `ORC-GB5GW42HLU.1b3248` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -10.215 kJ/mol (basis unstated) ± 0.381 | 1141 | liquid; _alloy: Ag 0.2968, Mg 0.7032_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 10; `ORC-LYUSMKZDEB.deec2c` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.174 kJ/mol (basis unstated) ± 0.534 | 1141 | liquid; _alloy: Ag 0.5522, Mg 0.4478_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 21; `ORC-OIYJ2ORV6Q.bac776` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.989 kJ/mol (basis unstated) ± 0.551 | 1141 | liquid; _alloy: Ag 0.5645, Mg 0.4355_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 22; `ORC-RNGVKEETAU.1423dd` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.338 kJ/mol (basis unstated) ± 0.477 | 1141 | liquid; _alloy: Ag 0.4981, Mg 0.5019_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 18; `ORC-TN3WLU6ZLT.65a42b` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.194 kJ/mol (basis unstated) ± 0.422 | 1141 | liquid; _alloy: Ag 0.4311, Mg 0.5689_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 15; `ORC-TUCLD4GVW5.40025e` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.42 kJ/mol (basis unstated) ± 0.404 | 1141 | liquid; _alloy: Ag 0.3878, Mg 0.6122_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 13; `ORC-U2PCO2SDRR.31e67a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.901 kJ/mol (basis unstated) ± 0.568 | 1141 | liquid; _alloy: Ag 0.5777, Mg 0.4223_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 23; `ORC-YC6IQIAXZC.6a1582` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.547 kJ/mol (basis unstated) ± 0.454 | 1141 | liquid; _alloy: Ag 0.4782, Mg 0.5218_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 17; `ORC-YDXV67V7T2.2b0fc9` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -4.879 kJ/mol (basis unstated) ± 0.044 | 1272 | liquid; _alloy: Ag 0.9012, Mg 0.0988_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 25; `ORC-2IC6G65Y5M.ee8213` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.177 kJ/mol (basis unstated) ± 0.199 | 1272 | liquid; _alloy: Ag 0.5919, Mg 0.4081_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 34; `ORC-2MH7Y6VAKB.27333d` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -9.821 kJ/mol (basis unstated) ± 0.066 | 1272 | liquid; _alloy: Ag 0.7707, Mg 0.2293_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 28; `ORC-4QWARINJIL.eaa040` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -10.894 kJ/mol (basis unstated) ± 0.081 | 1272 | liquid; _alloy: Ag 0.7309, Mg 0.2691_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 29; `ORC-5BADYO5PR6.29487c` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -11.855 kJ/mol (basis unstated) ± 0.091 | 1272 | liquid; _alloy: Ag 0.6979, Mg 0.3021_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 30; `ORC-CHEJLXLDTE.3bb446` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -13.076 kJ/mol (basis unstated) ± 0.166 | 1272 | liquid; _alloy: Ag 0.6156, Mg 0.3844_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 33; `ORC-D2OAPRRNBX.1e0d8a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.488 kJ/mol (basis unstated) ± 0.108 | 1272 | liquid; _alloy: Ag 0.6696, Mg 0.3304_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 31; `ORC-E2ONQJJDH2.a22a78` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -12.773 kJ/mol (basis unstated) ± 0.138 | 1272 | liquid; _alloy: Ag 0.6418, Mg 0.3582_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 32; `ORC-G3F2LU73LA.24b912` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -6.898 kJ/mol (basis unstated) ± 0.052 | 1272 | liquid; _alloy: Ag 0.8527, Mg 0.1473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 26; `ORC-HYMXJTRFFF.b91ff3` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -2.573 kJ/mol (basis unstated) ± 0.029 | 1272 | liquid; _alloy: Ag 0.9527, Mg 0.0473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 24; `ORC-OQHUT4VFEO.69ba60` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | -8.696 kJ/mol (basis unstated) ± 0.058 | 1272 | liquid; _alloy: Ag 0.8075, Mg 0.1925_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 27; `ORC-TUJST44ZEI.1513aa` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -3.216 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.2057, Mg 0.7943_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 4; `ORC-5FROBP7ARD.c6acfa` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -0.787 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.1134, Mg 0.8866_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 7; `ORC-BAO6SHD72G.b421ca` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -0.049 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.0934, Mg 0.9066_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 8; `ORC-CKTKVWFYZH.015197` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -0.289 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.0762, Mg 0.9238_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 9; `ORC-DC7O5HN2WM.540c4b` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -7.051 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.2332, Mg 0.7668_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 2; `ORC-DH2IGAU4R4.c35531` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -1.382 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.1655, Mg 0.8345_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 5; `ORC-KYWYSQIVUH.30df62` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -1.708 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.1378, Mg 0.8622_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 6; `ORC-LRHV5MAEZO.137a57` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -12.73 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.2484, Mg 0.7516_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 1; `ORC-UPOYVTUV5Y.408e23` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -3.499 kJ/mol (basis unstated) | 991 | liquid; _alloy: Ag 0.2197, Mg 0.7803_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 3; `ORC-XZQIWMFZYL.50983a` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -12.02 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.5345, Mg 0.4655_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 20; `ORC-4DGGWXUTZP.5383fe` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -28.278 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.3333, Mg 0.6667_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 11; `ORC-4W6T3ICZIG.f0cdde` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -27.239 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.366, Mg 0.634_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 12; `ORC-5BZY5GRORQ.04095a` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -24 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.4053, Mg 0.5947_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 14; `ORC-6HHKAQX3T5.404f08` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -9.973 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.516, Mg 0.484_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 19; `ORC-CEU7U6V4GF.494459` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -19.359 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.4548, Mg 0.5452_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 16; `ORC-GB5GW42HLU.ac0164` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -14.526 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.2968, Mg 0.7032_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 10; `ORC-LYUSMKZDEB.c16f84` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -13.209 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.5522, Mg 0.4478_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 21; `ORC-OIYJ2ORV6Q.26cc03` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -6.428 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.5645, Mg 0.4355_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 22; `ORC-RNGVKEETAU.9814f3` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -8.096 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.4981, Mg 0.5019_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 18; `ORC-TN3WLU6ZLT.b44a62` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -22.96 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.4311, Mg 0.5689_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 15; `ORC-TUCLD4GVW5.b73136` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -25.851 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.3878, Mg 0.6122_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 13; `ORC-U2PCO2SDRR.84ee2b` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -10.127 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.5777, Mg 0.4223_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 23; `ORC-YC6IQIAXZC.1c644f` |  |
| Partial enthalpy; _printed: ΔH̄\_Ag_ | -15.688 kJ/mol (basis unstated) | 1141 | liquid; _alloy: Ag 0.4782, Mg 0.5218_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 17; `ORC-YDXV67V7T2.2848eb` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -45.183 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.9012, Mg 0.0988_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 25; `ORC-2IC6G65Y5M.01b774` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -15.722 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.5919, Mg 0.4081_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 34; `ORC-2MH7Y6VAKB.70cc85` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -33.364 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.7707, Mg 0.2293_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 28; `ORC-4QWARINJIL.c701e8` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -30.577 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.7309, Mg 0.2691_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 29; `ORC-5BADYO5PR6.e406ea` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -32.182 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.6979, Mg 0.3021_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 30; `ORC-CHEJLXLDTE.35536e` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -20.159 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.6156, Mg 0.3844_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 33; `ORC-D2OAPRRNBX.365f88` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -27.481 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.6696, Mg 0.3304_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 31; `ORC-E2ONQJJDH2.480a0e` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -19.364 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.6418, Mg 0.3582_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 32; `ORC-G3F2LU73LA.ea12cd` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -42.411 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.8527, Mg 0.1473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 26; `ORC-HYMXJTRFFF.0f2870` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -54.443 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.9527, Mg 0.0473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 24; `ORC-OQHUT4VFEO.16de75` |  |
| Partial enthalpy; _printed: ΔH̄\_Mg_ | -40.854 kJ/mol (basis unstated) | 1272 | liquid; _alloy: Ag 0.8075, Mg 0.1925_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 27; `ORC-TUJST44ZEI.32cd28` |  |

### Heat capacity / entropy / enthalpy (27)

Table: Heat capacity / entropy / enthalpy, Ag–Mg system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Heat content; _printed: H_DISS-Mg_ | -11 J | 991 | liquid; _alloy: Ag 0.2332, Mg 0.7668_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 2; `ORC-DH2IGAU4R4.dc1328` |  |
| Heat content; _printed: H_DISS-Mg_ | -10 J | 991 | liquid; _alloy: Ag 0.1655, Mg 0.8345_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 5; `ORC-KYWYSQIVUH.cfe34b` |  |
| Heat content; _printed: H_DISS-Mg_ | -12 J | 991 | liquid; _alloy: Ag 0.1378, Mg 0.8622_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 6; `ORC-LRHV5MAEZO.a30620` |  |
| Heat content; _printed: H_DISS-Mg_ | -225 J | 991 | liquid; _alloy: Ag 0.2484, Mg 0.7516_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 1; `ORC-UPOYVTUV5Y.8956d7` |  |
| Heat content; _printed: H_DISS-Ag_ | -17 J | 1141 | liquid; _alloy: Ag 0.5345, Mg 0.4655_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 20; `ORC-4DGGWXUTZP.5e6533` |  |
| Heat content; _printed: H_DISS-Ag_ | -37 J | 1141 | liquid; _alloy: Ag 0.3333, Mg 0.6667_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 11; `ORC-4W6T3ICZIG.c89893` |  |
| Heat content; _printed: H_DISS-Ag_ | -36 J | 1141 | liquid; _alloy: Ag 0.366, Mg 0.634_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 12; `ORC-5BZY5GRORQ.a63565` |  |
| Heat content; _printed: H_DISS-Ag_ | -20 J | 1141 | liquid; _alloy: Ag 0.4053, Mg 0.5947_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 14; `ORC-6HHKAQX3T5.945bc9` |  |
| Heat content; _printed: H_DISS-Ag_ | -12 J | 1141 | liquid; _alloy: Ag 0.516, Mg 0.484_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 19; `ORC-CEU7U6V4GF.6d8b6e` |  |
| Heat content; _printed: H_DISS-Ag_ | -25 J | 1141 | liquid; _alloy: Ag 0.4548, Mg 0.5452_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 16; `ORC-GB5GW42HLU.2fb707` |  |
| Heat content; _printed: H_DISS-Ag_ | -19 J | 1141 | liquid; _alloy: Ag 0.5522, Mg 0.4478_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 21; `ORC-OIYJ2ORV6Q.5f109a` |  |
| Heat content; _printed: H_DISS-Ag_ | -10 J | 1141 | liquid; _alloy: Ag 0.4981, Mg 0.5019_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 18; `ORC-TN3WLU6ZLT.7488a2` |  |
| Heat content; _printed: H_DISS-Ag_ | -30 J | 1141 | liquid; _alloy: Ag 0.4311, Mg 0.5689_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 15; `ORC-TUCLD4GVW5.b73fc7` |  |
| Heat content; _printed: H_DISS-Ag_ | -25 J | 1141 | liquid; _alloy: Ag 0.3878, Mg 0.6122_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 13; `ORC-U2PCO2SDRR.0b9a3f` |  |
| Heat content; _printed: H_DISS-Ag_ | -12 J | 1141 | liquid; _alloy: Ag 0.5777, Mg 0.4223_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 23; `ORC-YC6IQIAXZC.b7a64a` |  |
| Heat content; _printed: H_DISS-Ag_ | -22 J | 1141 | liquid; _alloy: Ag 0.4782, Mg 0.5218_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 17; `ORC-YDXV67V7T2.ae2359` |  |
| Heat content; _printed: H_DISS-Mg_ | -73 J | 1272 | liquid; _alloy: Ag 0.9012, Mg 0.0988_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 25; `ORC-2IC6G65Y5M.794833` |  |
| Heat content; _printed: H_DISS-Mg_ | -27 J | 1272 | liquid; _alloy: Ag 0.5919, Mg 0.4081_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 34; `ORC-2MH7Y6VAKB.640de0` |  |
| Heat content; _printed: H_DISS-Mg_ | -53 J | 1272 | liquid; _alloy: Ag 0.7707, Mg 0.2293_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 28; `ORC-4QWARINJIL.f39684` |  |
| Heat content; _printed: H_DISS-Mg_ | -58 J | 1272 | liquid; _alloy: Ag 0.7309, Mg 0.2691_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 29; `ORC-5BADYO5PR6.f9f817` |  |
| Heat content; _printed: H_DISS-Mg_ | -56 J | 1272 | liquid; _alloy: Ag 0.6979, Mg 0.3021_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 30; `ORC-CHEJLXLDTE.8d317c` |  |
| Heat content; _printed: H_DISS-Mg_ | -36 J | 1272 | liquid; _alloy: Ag 0.6156, Mg 0.3844_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 33; `ORC-D2OAPRRNBX.569205` |  |
| Heat content; _printed: H_DISS-Mg_ | -45 J | 1272 | liquid; _alloy: Ag 0.6696, Mg 0.3304_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 31; `ORC-E2ONQJJDH2.bb5337` |  |
| Heat content; _printed: H_DISS-Mg_ | -34 J | 1272 | liquid; _alloy: Ag 0.6418, Mg 0.3582_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 32; `ORC-G3F2LU73LA.d9b650` |  |
| Heat content; _printed: H_DISS-Mg_ | -72 J | 1272 | liquid; _alloy: Ag 0.8527, Mg 0.1473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 26; `ORC-HYMXJTRFFF.cccdd4` |  |
| Heat content; _printed: H_DISS-Mg_ | -72 J | 1272 | liquid; _alloy: Ag 0.9527, Mg 0.0473_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 24; `ORC-OQHUT4VFEO.40cd36` |  |
| Heat content; _printed: H_DISS-Mg_ | -72 J | 1272 | liquid; _alloy: Ag 0.8075, Mg 0.1925_ | experimental | [1] Dębski 2022 | Table 2, p. 5, row 27; `ORC-TUJST44ZEI.3a50b8` |  |

### Crystal structure (9)

Table: Crystal structure, Ag–Mg system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Lattice a | 4.154 Å | 0 | Ag3Mg; _alloy: Mg 0.25_ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 2; `ORC-FJBMG3LA6V` |  |
| Lattice a | 3.331 Å | 0 | AgMg; _alloy: Mg 0.5_ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 3; `ORC-ZENNGJ4JVA` |  |
| Lattice a | 3.209 Å | 0 | HCP_A3(Zn) | DFT | [1] Dębski 2022 | Table 3, p. 6, row 7; `ORC-FAHOX4R65D.8f2881` |  |
| Lattice a | 12.49 Å | 0 | γ’ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 6; `ORC-HK64JX4JTX.361355` |  |
| Lattice a | 12.389 Å | 0 | ε | DFT | [1] Dębski 2022 | Table 3, p. 6, row 5; `ORC-AYATXYL2EG` |  |
| Lattice a | 8.67 Å | 0 | κ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 4; `ORC-XNGUVSQFE6.9054b4` |  |
| Lattice c | 5.154 Å | 0 | HCP_A3(Zn) | DFT | [1] Dębski 2022 | Table 3, p. 6, row 7; `ORC-FAHOX4R65D.e6afb8` |  |
| Lattice c | 14.448 Å | 0 | γ’ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 6; `ORC-HK64JX4JTX.275f15` |  |
| Lattice c | 8.913 Å | 0 | κ | DFT | [1] Dębski 2022 | Table 3, p. 6, row 4; `ORC-XNGUVSQFE6.d864f6` |  |

### Transformation enthalpy (6)

Table: Transformation enthalpy, Ag–Mg system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| transformation enthalpy | 1800 J/mol ± 200 |  | γ -> ε' + (Mg); _γ: Ag 0.2, Mg 0.8; ε': Ag 0.23, Mg 0.77_ | experimental | [2] Dai 2015; _cites Lim 1997_ | Table 1, p. 3, row 1; `ORC-24KCP6PM7L` |  |
| transformation enthalpy | 2021 J/mol |  | γ -> ε' + (Mg); _γ: Ag 0.2, Mg 0.8; ε': Ag 0.23, Mg 0.77_ | model | [2] Dai 2015 | Table 1, p. 3, row 3; `ORC-5ET4BCCUVC` |  |
| transformation enthalpy | 1160 J/mol |  | γ -> ε' + (Mg); _γ: Ag 0.2, Mg 0.8; ε': Ag 0.23, Mg 0.77_ | model | [2] Dai 2015; _cites Lim 1997_ | Table 1, p. 3, row 2; `ORC-SJKPV3YXCX` |  |
| transformation enthalpy | 21651 J/mol |  | ε' -> L + B2; _ε': Ag 0.23, Mg 0.77_ | model | [2] Dai 2015; _cites Lim 1997_ | Table 1, p. 3, row 5; `ORC-IFYJYIE3DU` |  |
| transformation enthalpy | 21218 J/mol |  | ε' -> L + B2; _ε': Ag 0.23, Mg 0.77_ | model | [2] Dai 2015 | Table 1, p. 3, row 6; `ORC-RG3LO5V54C` |  |
| transformation enthalpy | 19000 J/mol ± 900 |  | ε' -> L + B2; _ε': Ag 0.23, Mg 0.77_ | experimental | [2] Dai 2015; _cites Lim 1997_ | Table 1, p. 3, row 4; `ORC-WJEQCUT2ZT` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. A. Dębski, W. Gierlotka, W. Gąsior, Calorimetric studies and thermodynamic calculations of the Ag-Mg system, Journal of Alloys and Compounds 891, 161937 (2022). [doi:10.1016/j.jallcom.2021.161937](https://doi.org/10.1016/j.jallcom.2021.161937)
2. Cong (Leo) Dai, Dmitri V. Malakhov, Reoptimization of the Ag–Mg system, Journal of Alloys and Compounds 619, 20-25 (2015). [doi:10.1016/j.jallcom.2014.08.075](https://doi.org/10.1016/j.jallcom.2014.08.075)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).