# Al–Bi system

> Al–Bi system: 145 accepted literature values (phase equilibrium 113, model expression 15, mixing / partial 14, invariant reaction 2) and 3 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/AL-BI.html · Markdown: https://data.orchid-project.org/systems/AL-BI.md

145 accepted literature values from 1 paper(s) (experimental 143, unspecified 2); 3 calculated phase diagram(s). 2 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/AL-BI.json) · [CSV](https://data.orchid-project.org/systems/AL-BI.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AL-BI) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AL-BI/AlBi-06Kim.json) · [phases (5)](https://data.orchid-project.org/phases/pages/AL-BI.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AL-BI.html) · [Markdown](https://data.orchid-project.org/systems/AL-BI.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 143 |
| unspecified | 2 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 2 |
| phase equilibrium | 113 |
| mixing / partial | 14 |
| activity / EMF / Gibbs energy | 1 |
| model expression | 15 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AlBi-06Kim.tdb | S.S. Kim, T.H. Sanders, Jr., Modelling Simul. Mater. Sci. Eng., 14, 1181-88(2006). [doi:10.1088/0965-0393/14/7/006](https://doi.org/10.1088/0965-0393/14/7/006) | `4fadaae9c10c6b6b7b996a3cba09236329bdfb861b771857d15207ad4a5a45ff` | [viewer](https://orchid-project.org/phase-diagrams/#AL-BI/AlBi-06Kim.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AlBi-06Kim.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AlBi-06Kim.json) |
| AlBi-09Mir.tdb | D. Mirkovic, J. Groebner, I. Kaban, W. Hoyer, R. Schmid-Fetzer, Int. J. Mater. Res., 100, 176-88(2009). [doi:10.3139/146.110009](https://doi.org/10.3139/146.110009) | `eddf53291d6feb3202a53a9bbb9fdf08bd19df2dd4ca35fcf53a2540eadfc75e` | [viewer](https://orchid-project.org/phase-diagrams/#AL-BI/AlBi-09Mir.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AlBi-09Mir.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AlBi-09Mir.json) |
| AlBi-84McA-LB.tdb | A.J. McAlister, Bull. Alloy Phase Diag., 5, 247-50(1984). [doi:10.1007/BF02868547](https://doi.org/10.1007/BF02868547) | `da883e23d8b9f383aa26bd94d6a0154dddf695c4b2b05368c54b88292d48e43e` | [viewer](https://orchid-project.org/phase-diagrams/#AL-BI/AlBi-84McA-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AlBi-84McA-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AlBi-84McA-LB.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| AlBi-06Kim.tdb | 931.71 | FCC_A1 (x(Bi) 5.600e-4) + LIQUID#2 (x(Bi) 0.00327) + LIQUID (x(Bi) 0.83957) |
| AlBi-06Kim.tdb | 544.39 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99928) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-06Kim.tdb | 544.39 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99929) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-09Mir.tdb | 930.82 | FCC_A1 (x(Bi) 6.000e-4) + LIQUID#2 (x(Bi) 0.00487) + LIQUID (x(Bi) 0.83424) |
| AlBi-09Mir.tdb | 543.33 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99432) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-09Mir.tdb | 543.33 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99432) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-09Mir.tdb | 543.33 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99434) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-84McA-LB.tdb | 931.19 | FCC_A1 (x(Bi) 6.100e-4) + LIQUID#2 (x(Bi) 0.00426) + LIQUID (x(Bi) 0.84121) |
| AlBi-84McA-LB.tdb | 543.56 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99539) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-84McA-LB.tdb | 543.56 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.99539) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AlBi-84McA-LB.tdb | 543.56 | FCC_A1 (x(Bi) 1.000e-5) + LIQUID (x(Bi) 0.9954) + RHOMBOHEDRAL_A7 (x(Bi) 1) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AL/AL-BI.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AL/AL-BI.json) · [CALPHAD hull AlBi-06Kim](https://data.orchid-project.org/hulls/calphad-sgte/AL/AL-BI--AlBi-06Kim.json) · [CALPHAD hull AlBi-84McA-LB](https://data.orchid-project.org/hulls/calphad-sgte/AL/AL-BI--AlBi-84McA-LB.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Al–Bi system (2)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 930.15 | monotectic: L -> (Al) + L | L: Bi 0.84; (Al): Bi 2.000e-4 | unspecified | [1] McAlister 1984 | Table 1, p. 2, row 1; `ORC-AX467XS44I` |  |
| 543.15 | eutectic: L -> (Al) + Bi | L: Bi 0.995; (Al): Bi 0; Bi: Bi 1 | unspecified | [1] McAlister 1984 | Table 1, p. 2, row 2; `ORC-MC2NZYUCMB` |  |

## Other properties

### Phase equilibrium (113)

Table: Phase equilibrium, Al–Bi system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase composition |  | 591.15 | L; _L: Al 0.01, Bi 0.99_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 10; `ORC-MJIHVLYZZH` |  |
| Phase composition |  | 623.15 | L; _L: Al 0.017, Bi 0.983_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 20; `ORC-7M5GEAZGNJ` |  |
| Phase composition |  | 625.15 | L; _L: Al 0.013, Bi 0.987_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 39; `ORC-MQS3274G2X` |  |
| Phase composition |  | 645.15 | L; _L: Al 0.015, Bi 0.985_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 9; `ORC-34K6WDDORD` |  |
| Phase composition |  | 649.15 | L; _L: Al 0.014, Bi 0.986_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 38; `ORC-MIVUK56UWL` |  |
| Phase composition |  | 661.15 | L; _L: Al 0.021, Bi 0.979_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 19; `ORC-RT3TT7PMHT` |  |
| Phase composition |  | 665.15 | L; _L: Al 0.02, Bi 0.98_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 8; `ORC-XJHNDMXGV7` |  |
| Phase composition |  | 666.15 | L; _L: Al 0.023, Bi 0.977_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 18; `ORC-B5YW7FMXCM` |  |
| Phase composition |  | 677.15 | L; _L: Al 0.024, Bi 0.976_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 37; `ORC-SGM62SCW4R` |  |
| Phase composition |  | 691.15 | L; _L: Al 0.032, Bi 0.968_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 17; `ORC-7XY5TAG32I` |  |
| Phase composition |  | 699.15 | L; _L: Al 0.025, Bi 0.975_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 36; `ORC-UCSNOF65C3` |  |
| Phase composition |  | 713.15 | L; _L: Al 0.03, Bi 0.97_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 7; `ORC-7SD7OATPMW` |  |
| Phase composition |  | 714.15 | L; _L: Al 0.032, Bi 0.968_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 28; `ORC-FQXMBXHDJU` |  |
| Phase composition |  | 719.15 | L; _L: Al 0.038, Bi 0.962_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 16; `ORC-T4KVSOLQLO` |  |
| Phase composition |  | 723.15 | L; _L: Al 0.031, Bi 0.969_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 29; `ORC-CDBSZJ4AHW` |  |
| Phase composition |  | 723.15 | L; _L: Al 0.033, Bi 0.967_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 35; `ORC-HGMO37DWHR` |  |
| Phase composition |  | 747.15 | L; _L: Al 0.041, Bi 0.959_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 34; `ORC-DFQHCT3Q2T` |  |
| Phase composition |  | 762.15 | L; _L: Al 0.06, Bi 0.94_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 15; `ORC-ZUKB5EA2IP` |  |
| Phase composition |  | 764.15 | L; _L: Al 0.046, Bi 0.954_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 27; `ORC-UXZ3TPOTYQ` |  |
| Phase composition |  | 769.15 | L; _L: Al 0.05, Bi 0.95_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 6; `ORC-IBRO3DOV3M` |  |
| Phase composition |  | 774.15 | L; _L: Al 0.065, Bi 0.935_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 14; `ORC-7A2WGUROWO` |  |
| Phase composition |  | 774.15 | L; _L: Al 0.047, Bi 0.953_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 26; `ORC-TRQ2DNY3PJ` |  |
| Phase composition |  | 776.15 | L; _L: Al 0.053, Bi 0.947_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 33; `ORC-II6UFTUIUE` |  |
| Phase composition |  | 781.15 | L; _L: Al 0.051, Bi 0.949_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 25; `ORC-D4A6FNZAKU` |  |
| Phase composition |  | 783.15 | L; _L: Al 0.056, Bi 0.944_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 24; `ORC-W5V2JCJ6JK` |  |
| Phase composition |  | 800.15 | L; _L: Al 0.062, Bi 0.938_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 32; `ORC-4RDRFKKQV7` |  |
| Phase composition |  | 813.15 | L; _L: Al 0.065, Bi 0.935_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 5; `ORC-GNQYOSTA5E` |  |
| Phase composition |  | 822.15 | L; _L: Al 0.068, Bi 0.932_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 23; `ORC-ABXFYD7PT2` |  |
| Phase composition |  | 825.15 | L; _L: Al 0.066, Bi 0.934_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 31; `ORC-XAD7HXTZF3` |  |
| Phase composition |  | 829.15 | L; _L: Al 0.073, Bi 0.927_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 22; `ORC-W4QKV4WO2B` |  |
| Phase composition |  | 839.15 | L; _L: Al 0.08, Bi 0.92_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 4; `ORC-YJ7FEQOQXU` |  |
| Phase composition |  | 862.15 | L; _L: Al 0.097, Bi 0.903_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 13; `ORC-EKUHHAH6TJ` |  |
| Phase composition |  | 863.15 | L; _L: Al 0.1, Bi 0.9_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 3; `ORC-5MVGWVL2MW` |  |
| Phase composition |  | 879.15 | L; _L: Al 0.106, Bi 0.894_ | experimental | [1] McAlister 1984; _cites ref. 65Obe_ | Table 3, p. 3, row 21; `ORC-FMLO434X7I` |  |
| Phase composition |  | 880.15 | L; _L: Al 0.1, Bi 0.9_ | experimental | [1] McAlister 1984; _cites ref. 65Wee_ | Table 3, p. 3, row 30; `ORC-7HIX4AIQUD` |  |
| Phase composition |  | 897.15 | L; _L: Al 0.125, Bi 0.875_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 2; `ORC-KFVVZ2QQKQ` |  |
| Phase composition |  | 908.15 | L; _L: Al 0.135, Bi 0.865_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 12; `ORC-4PY55X3CIQ` |  |
| Phase composition |  | 918.15 | L; _L: Al 0.147, Bi 0.853_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 3, p. 3, row 11; `ORC-5K4J3K73HN` |  |
| Phase composition |  | 921.15 | L; _L: Al 0.15, Bi 0.85_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 3, p. 3, row 1; `ORC-UVLD2F3LWZ` |  |
| Phase composition |  | 930.15 | L + L (Bi-rich); _L: Al 0.155, Bi 0.845; L (Bi-rich): Al 0.155, Bi 0.845_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 36; `ORC-6KTVQ7UOG3` |  |
| Phase composition |  | 933.15 | L + L (Bi-rich); _L: Al 0.1674, Bi 0.8326; L (Bi-rich): Al 0.1674, Bi 0.8326_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 48; `ORC-BQBQCT2ZZG` |  |
| Phase composition |  | 940.15 | L + L (Bi-rich); _L: Al 0.174, Bi 0.826; L (Bi-rich): Al 0.174, Bi 0.826_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 1; `ORC-TMQJKLRN55` |  |
| Phase composition |  | 952.15 | L + L (Al-rich); _L: Al 0.9947, Bi 0.0053; L (Al-rich): Al 0.9947, Bi 0.0053_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 15; `ORC-7OOLWXVJZL` |  |
| Phase composition |  | 953.15 | L + L (Bi-rich); _L: Al 0.165, Bi 0.835; L (Bi-rich): Al 0.165, Bi 0.835_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 37; `ORC-FPUDDMYIMF` |  |
| Phase composition |  | 958.15 | L + L (Al-rich); _L: Al 0.9941, Bi 0.0059; L (Al-rich): Al 0.9941, Bi 0.0059_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 5; `ORC-DHUZ5MWZKV` |  |
| Phase composition |  | 963.15 | L + L (Al-rich); _L: Al 0.9941, Bi 0.0059; L (Al-rich): Al 0.9941, Bi 0.0059_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 16; `ORC-KCIHQMAAWO` |  |
| Phase composition |  | 963.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.1662, Bi 0.8338; L (Al-rich): Al 0.9954, Bi 0.0046; L (Bi-rich): Al 0.1662, Bi 0.8338_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 25; `ORC-OIW6LUTG6H` |  |
| Phase composition |  | 967.15 | L + L (Bi-rich); _L: Al 0.199, Bi 0.801; L (Bi-rich): Al 0.199, Bi 0.801_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 2; `ORC-YWAAXEHYI4` |  |
| Phase composition |  | 968.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.189, Bi 0.811; L (Al-rich): Al 0.9931, Bi 0.0069; L (Bi-rich): Al 0.189, Bi 0.811_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 26; `ORC-XFMXU6MXW6` |  |
| Phase composition |  | 973.15 | L + L (Bi-rich); _L: Al 0.193, Bi 0.807; L (Bi-rich): Al 0.193, Bi 0.807_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 3; `ORC-IS3UPQMQGW` |  |
| Phase composition |  | 975.15 | L + L (Al-rich); _L: Al 0.993, Bi 0.007; L (Al-rich): Al 0.993, Bi 0.007_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 6; `ORC-FT5WRQIG3Z` |  |
| Phase composition |  | 983.15 | L + L (Al-rich); _L: Al 0.9928, Bi 0.0072; L (Al-rich): Al 0.9928, Bi 0.0072_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 17; `ORC-L5KXZSE73C` |  |
| Phase composition |  | 987.15 | L + L (Al-rich); _L: Al 0.9926, Bi 0.0074; L (Al-rich): Al 0.9926, Bi 0.0074_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 18; `ORC-VSREAPIJIY` |  |
| Phase composition |  | 993.15 | L + L (Bi-rich); _L: Al 0.2, Bi 0.8; L (Bi-rich): Al 0.2, Bi 0.8_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 38; `ORC-SHKMGBG3R5` |  |
| Phase composition |  | 998.15 | L + L (Al-rich); _L: Al 0.9915, Bi 0.0085; L (Al-rich): Al 0.9915, Bi 0.0085_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 7; `ORC-KUDQGA3OHU` |  |
| Phase composition |  | 1001.15 | L + L (Bi-rich); _L: Al 0.2047, Bi 0.7953; L (Bi-rich): Al 0.2047, Bi 0.7953_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 49; `ORC-GL7LXK5JQB` |  |
| Phase composition |  | 1007.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.2293, Bi 0.7707; L (Al-rich): Al 0.9921, Bi 0.0079; L (Bi-rich): Al 0.2293, Bi 0.7707_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 27; `ORC-OTB4OP5CRT` |  |
| Phase composition |  | 1008.15 | L + L (Al-rich); _L: Al 0.9909, Bi 0.0091; L (Al-rich): Al 0.9909, Bi 0.0091_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 8; `ORC-7TYQSRFJS3` |  |
| Phase composition |  | 1010.15 | L + L (Al-rich); _L: Al 0.9912, Bi 0.0088; L (Al-rich): Al 0.9912, Bi 0.0088_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 19; `ORC-IGGRZPDVOY` |  |
| Phase composition |  | 1011.15 | L + L (Al-rich); _L: Al 0.9906, Bi 0.0094; L (Al-rich): Al 0.9906, Bi 0.0094_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 9; `ORC-CI3KTL23JN` |  |
| Phase composition |  | 1033.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.2028, Bi 0.7972; L (Al-rich): Al 0.9887, Bi 0.0113; L (Bi-rich): Al 0.2028, Bi 0.7972_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 28; `ORC-LLD3P3AGFJ` |  |
| Phase composition |  | 1035.15 | L + L (Al-rich); _L: Al 0.9899, Bi 0.0101; L (Al-rich): Al 0.9899, Bi 0.0101_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 10; `ORC-SJ6TXC3SW2` |  |
| Phase composition |  | 1037.15 | L + L (Al-rich); _L: Al 0.9886, Bi 0.0114; L (Al-rich): Al 0.9886, Bi 0.0114_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 20; `ORC-VXVXUKW4LR` |  |
| Phase composition |  | 1047.15 | L + L (Bi-rich); _L: Al 0.25, Bi 0.75; L (Bi-rich): Al 0.25, Bi 0.75_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 39; `ORC-BBKUMBKKTS` |  |
| Phase composition |  | 1055.15 | L + L (Al-rich); _L: Al 0.9877, Bi 0.0123; L (Al-rich): Al 0.9877, Bi 0.0123_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 11; `ORC-MEUEKTUPK4` |  |
| Phase composition |  | 1059.15 | L + L (Bi-rich); _L: Al 0.2472, Bi 0.7528; L (Bi-rich): Al 0.2472, Bi 0.7528_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 50; `ORC-ASXKNA5LE7` |  |
| Phase composition |  | 1062.15 | L + L (Al-rich); _L: Al 0.9868, Bi 0.0132; L (Al-rich): Al 0.9868, Bi 0.0132_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 12; `ORC-ZOMZ2WDNSE` |  |
| Phase composition |  | 1068.15 | L + L (Al-rich); _L: Al 0.9862, Bi 0.0138; L (Al-rich): Al 0.9862, Bi 0.0138_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 13; `ORC-W4YTDV5672` |  |
| Phase composition |  | 1075.15 | L + L (Bi-rich); _L: Al 0.275, Bi 0.725; L (Bi-rich): Al 0.275, Bi 0.725_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 40; `ORC-YZ634RDGSI` |  |
| Phase composition |  | 1077.15 | L + L (Bi-rich); _L: Al 0.281, Bi 0.719; L (Bi-rich): Al 0.281, Bi 0.719_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 4; `ORC-EJ66TQJZGY` |  |
| Phase composition |  | 1083.15 | L + L (Al-rich); _L: Al 0.9847, Bi 0.0153; L (Al-rich): Al 0.9847, Bi 0.0153_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 14; `ORC-W2S4IIJFGU` |  |
| Phase composition |  | 1090.15 | L + L (Bi-rich); _L: Al 0.2874, Bi 0.7126; L (Bi-rich): Al 0.2874, Bi 0.7126_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 51; `ORC-F73F4DV6WN` |  |
| Phase composition |  | 1091.15 | L + L (Al-rich); _L: Al 0.9822, Bi 0.0178; L (Al-rich): Al 0.9822, Bi 0.0178_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 21; `ORC-K2B7F7PBDL` |  |
| Phase composition |  | 1093.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.2931, Bi 0.7069; L (Al-rich): Al 0.9831, Bi 0.0169; L (Bi-rich): Al 0.2931, Bi 0.7069_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 29; `ORC-UQKEUETCUS` |  |
| Phase composition |  | 1100.15 | L + L (Bi-rich); _L: Al 0.2999, Bi 0.7001; L (Bi-rich): Al 0.2999, Bi 0.7001_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 52; `ORC-VIW5COO5EM` |  |
| Phase composition |  | 1110.15 | L + L (Bi-rich); _L: Al 0.3125, Bi 0.6875; L (Bi-rich): Al 0.3125, Bi 0.6875_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 53; `ORC-M3CUNTLWXI` |  |
| Phase composition |  | 1119.15 | L + L (Al-rich); _L: Al 0.9858, Bi 0.0142; L (Al-rich): Al 0.9858, Bi 0.0142_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 74; `ORC-H5XRWNHT6T` |  |
| Phase composition |  | 1123.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.3066, Bi 0.6934; L (Al-rich): Al 0.9811, Bi 0.0189; L (Bi-rich): Al 0.3066, Bi 0.6934_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 30; `ORC-YY6BWGNIKR` |  |
| Phase composition |  | 1125.15 | L + L (Bi-rich); _L: Al 0.3224, Bi 0.6776; L (Bi-rich): Al 0.3224, Bi 0.6776_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 54; `ORC-YYXA5IEYPV` |  |
| Phase composition |  | 1131.15 | L + L (Al-rich); _L: Al 0.971, Bi 0.029; L (Al-rich): Al 0.971, Bi 0.029_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 42; `ORC-B2Z6KVNSU2` |  |
| Phase composition |  | 1131.15 | L + L (Bi-rich); _L: Al 0.325, Bi 0.675; L (Bi-rich): Al 0.325, Bi 0.675_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 2, p. 2, row 41; `ORC-RE5JQTK4Q6` |  |
| Phase composition |  | 1138.15 | L + L (Bi-rich); _L: Al 0.3502, Bi 0.6498; L (Bi-rich): Al 0.3502, Bi 0.6498_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 55; `ORC-JQNYBGI7XZ` |  |
| Phase composition |  | 1148.15 | L + L (Bi-rich); _L: Al 0.3779, Bi 0.6221; L (Bi-rich): Al 0.3779, Bi 0.6221_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 56; `ORC-ABOBURWBVU` |  |
| Phase composition |  | 1150.15 | L + L (Al-rich); _L: Al 0.9774, Bi 0.0226; L (Al-rich): Al 0.9774, Bi 0.0226_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 22; `ORC-6VWQWU5YIG` |  |
| Phase composition |  | 1150.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.3658, Bi 0.6342; L (Al-rich): Al 0.9773, Bi 0.0227; L (Bi-rich): Al 0.3658, Bi 0.6342_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 31; `ORC-E6JJV6AQC2` |  |
| Phase composition |  | 1161.15 | L + L (Bi-rich); _L: Al 0.3927, Bi 0.6073; L (Bi-rich): Al 0.3927, Bi 0.6073_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 57; `ORC-ULY5ZKEMUW` |  |
| Phase composition |  | 1163.15 | L + L (Al-rich); _L: Al 0.962, Bi 0.038; L (Al-rich): Al 0.962, Bi 0.038_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 43; `ORC-JIRRVTRK4K` |  |
| Phase composition |  | 1171.15 | L + L (Bi-rich); _L: Al 0.3929, Bi 0.6071; L (Bi-rich): Al 0.3929, Bi 0.6071_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 58; `ORC-YNRAIPZSW4` |  |
| Phase composition |  | 1173.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.97, Bi 0.03; L (Al-rich): Al 0.9692, Bi 0.0308; L (Bi-rich): Al 0.97, Bi 0.03_ | experimental | [1] McAlister 1984; _cites ref. 64Wil_ | Table 2, p. 2, row 24; `ORC-VSSIL475WA` |  |
| Phase composition |  | 1179.15 | L + L (Bi-rich); _L: Al 0.413, Bi 0.587; L (Bi-rich): Al 0.413, Bi 0.587_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 59; `ORC-TXMF376TKO` |  |
| Phase composition |  | 1193.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.4026, Bi 0.5974; L (Al-rich): Al 0.9635, Bi 0.0365; L (Bi-rich): Al 0.4026, Bi 0.5974_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 32; `ORC-ZNURTFHUDF` |  |
| Phase composition |  | 1195.15 | L + L (Al-rich); _L: Al 0.9684, Bi 0.0316; L (Al-rich): Al 0.9684, Bi 0.0316_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 73; `ORC-MRQBSNSCTZ` |  |
| Phase composition |  | 1204.15 | L + L (Al-rich); _L: Al 0.9729, Bi 0.0271; L (Al-rich): Al 0.9729, Bi 0.0271_ | experimental | [1] McAlister 1984; _cites ref. 39Kem_ | Table 2, p. 2, row 23; `ORC-3SRWI757X3` |  |
| Phase composition |  | 1212.15 | L + L (Bi-rich); _L: Al 0.4912, Bi 0.5088; L (Bi-rich): Al 0.4912, Bi 0.5088_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 60; `ORC-BO47RQS66C` |  |
| Phase composition |  | 1215.15 | L + L (Al-rich); _L: Al 0.942, Bi 0.058; L (Al-rich): Al 0.942, Bi 0.058_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 44; `ORC-2NIYBOIVLV` |  |
| Phase composition |  | 1241.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.4683, Bi 0.5317; L (Al-rich): Al 0.9552, Bi 0.0448; L (Bi-rich): Al 0.4683, Bi 0.5317_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 33; `ORC-TSDC4JSZLS` |  |
| Phase composition |  | 1248.15 | L + L (Bi-rich); _L: Al 0.5389, Bi 0.4611; L (Bi-rich): Al 0.5389, Bi 0.4611_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 61; `ORC-MTEIN44GNA` |  |
| Phase composition |  | 1255.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.5276, Bi 0.4724; L (Al-rich): Al 0.9547, Bi 0.0453; L (Bi-rich): Al 0.5276, Bi 0.4724_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 34; `ORC-QUKFPHXCMW` |  |
| Phase composition |  | 1255.15 | L + L (Bi-rich); _L: Al 0.5768, Bi 0.4232; L (Bi-rich): Al 0.5768, Bi 0.4232_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 62; `ORC-BFNZ3NKULN` |  |
| Phase composition |  | 1261.15 | L + L (Al-rich); _L: Al 0.917, Bi 0.083; L (Al-rich): Al 0.917, Bi 0.083_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 45; `ORC-AG6CMAX6CM` |  |
| Phase composition |  | 1264.15 | L + L (Al-rich); _L: Al 0.9337, Bi 0.0663; L (Al-rich): Al 0.9337, Bi 0.0663_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 72; `ORC-SUNQCCZY4C` |  |
| Phase composition |  | 1271.15 | L + L (Bi-rich); _L: Al 0.5868, Bi 0.4132; L (Bi-rich): Al 0.5868, Bi 0.4132_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 63; `ORC-RICWZI5D4K` |  |
| Phase composition |  | 1281.15 | L + L (Al-rich) + L (Bi-rich); _L: Al 0.5698, Bi 0.4302; L (Al-rich): Al 0.9567, Bi 0.0433; L (Bi-rich): Al 0.5698, Bi 0.4302_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 2, p. 2, row 35; `ORC-5KE6BZC6OI` |  |
| Phase composition |  | 1281.15 | L + L (Bi-rich); _L: Al 0.6348, Bi 0.3652; L (Bi-rich): Al 0.6348, Bi 0.3652_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 64; `ORC-N5UCAFRPJE` |  |
| Phase composition |  | 1282.15 | L + L (Al-rich); _L: Al 0.9132, Bi 0.0868; L (Al-rich): Al 0.9132, Bi 0.0868_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 71; `ORC-6IFSNUOJM6` |  |
| Phase composition |  | 1295.15 | L + L (Bi-rich); _L: Al 0.6853, Bi 0.3147; L (Bi-rich): Al 0.6853, Bi 0.3147_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 65; `ORC-LKSF5XNAG7` |  |
| Phase composition |  | 1298.15 | L + L (Al-rich); _L: Al 0.883, Bi 0.117; L (Al-rich): Al 0.883, Bi 0.117_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 46; `ORC-VWEURKTBQ6` |  |
| Phase composition |  | 1303.15 | L + L (Bi-rich); _L: Al 0.7358, Bi 0.2642; L (Bi-rich): Al 0.7358, Bi 0.2642_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 66; `ORC-V7D5M3GN42` |  |
| Phase composition |  | 1306.15 | L + L (Al-rich); _L: Al 0.8016, Bi 0.1984; L (Al-rich): Al 0.8016, Bi 0.1984_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 68; `ORC-A64ZDEIPT7` |  |
| Phase composition |  | 1308.15 | L + L (Al-rich); _L: Al 0.7763, Bi 0.2237; L (Al-rich): Al 0.7763, Bi 0.2237_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 67; `ORC-TWLRUIMUDX` |  |
| Phase composition |  | 1311.15 | L + L (Al-rich); _L: Al 0.88, Bi 0.12; L (Al-rich): Al 0.88, Bi 0.12_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 70; `ORC-6IUWJ4GL3Q` |  |
| Phase composition |  | 1313.15 | L + L (Al-rich); _L: Al 0.8193, Bi 0.1807; L (Al-rich): Al 0.8193, Bi 0.1807_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 2, p. 2, row 69; `ORC-ZCBHK2372U` |  |
| Phase composition |  | 1314.15 | L + L (Al-rich); _L: Al 0.841, Bi 0.159; L (Al-rich): Al 0.841, Bi 0.159_ | experimental | [1] McAlister 1984; _cites ref. 83Cha_ | Table 2, p. 2, row 47; `ORC-C2FAW353LP` |  |

### Mixing / partial (14)

Table: Mixing / partial, Al–Bi system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Enthalpy of mixing; _printed: ΔmixH_ | 6.278 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.7, Bi 0.3_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 2; `ORC-AUYCQF5V3P.758178` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 7.323 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.51, Bi 0.49_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 5; `ORC-BVBVFODNJX.0276dc` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 7.952 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.6, Bi 0.4_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 4; `ORC-KPVWDH2QSE.b1bd9d` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 5.859 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.4, Bi 0.6_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 7; `ORC-MHA2OFIL35.4314c1` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 4.101 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.2, Bi 0.8_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 9; `ORC-PN5VANG4CB.fc6f1a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 6.8 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.7, Bi 0.3_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 3; `ORC-RA7QBHUYER.d1cd2f` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 3.766 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.9, Bi 0.1_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 1; `ORC-SKEDOZDKMD.881d16` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 4.52 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.3, Bi 0.7_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 8; `ORC-U3TYEPGY5T.95def1` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 6.319 kJ/mol (basis unstated) |  | liquid; _alloy: Al 0.4, Bi 0.6_ | experimental | [1] McAlister 1984; _cites ref. 69Pre_ | Table 4, p. 3, row 6; `ORC-YIQ5JPJ4UG.50a930` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 1.75 kJ/mol (basis unstated) | 975.15 | liquid; _alloy: Al 0.09, Bi 0.91_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 4, p. 3, row 13; `ORC-APQT7ZKMRO.e7799d` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 1.962 kJ/mol (basis unstated) | 975.15 | liquid; _alloy: Al 0.1, Bi 0.9_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 4, p. 3, row 12; `ORC-IBRQIR6GFI.6b950a` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 2.561 kJ/mol (basis unstated) | 975.15 | liquid; _alloy: Al 0.15, Bi 0.85_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 4, p. 3, row 11; `ORC-IGR7SO3LTS.fbd99d` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 0.832 kJ/mol (basis unstated) | 975.15 | liquid; _alloy: Al 0.04, Bi 0.96_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 4, p. 3, row 14; `ORC-TEUZLVFVW4.23d0fa` |  |
| Enthalpy of mixing; _printed: ΔmixH_ | 0.433 kJ/mol (basis unstated) | 1077.15 | liquid; _alloy: Al 0.98, Bi 0.02_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 4, p. 3, row 10; `ORC-MRXG4QVO4K.a93890` |  |

### Activity / EMF / Gibbs energy (1)

Table: Activity / EMF / Gibbs energy, Al–Bi system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Chemical potential; _printed: ... C_ | 25397 J/mol | 1173.15 | liquid; _alloy: Al 0.35, Bi 0.65_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 5, p. 3, row 1; `ORC-NDU6ONDCNG.fcbfa4` |  |

### Model expression (15)

Table: Model expression, Al–Bi system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 18125 J/mol |  | liquid; _alloy: Al 0.125, Bi 0.875_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 9; `ORC-3PICIOMUQE` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 23662 J/mol |  | liquid; _alloy: Al 0.015, Bi 0.985_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 16; `ORC-4ZQSBDF5OG` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 21963 J/mol |  | liquid; _alloy: Al 0.02, Bi 0.98_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 15; `ORC-7KRKHFOW3H` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 19339 J/mol |  | liquid; _alloy: Al 0.08, Bi 0.92_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 11; `ORC-E6YADDIUKC` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 15204 J/mol |  | liquid; _alloy: Al 0.2, Bi 0.8_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 5; `ORC-FBRIRDIVOW` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 18134 J/mol |  | liquid; _alloy: Al 0.155, Bi 0.845_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 7; `ORC-IAF6NFNYPG` |  |
| chemical potential expression term; _printed: ΔmixGAl = x²(A + Bx) + 8.314T ln(1-x): A_ | 32384 J/mol |  | liquid; _alloy: Al 0.2, Bi 0.8_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 5, p. 3, row 2; `ORC-MRNSOOASCT` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 23051 J/mol |  | liquid; _alloy: Al 0.01, Bi 0.99_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 17; `ORC-MWMGCYNELN` |  |
| chemical potential expression term; _printed: ΔmixGAl = x²(A + Bx + Cx²) + 8.314T ln(1-x): A_ | 52178 J/mol |  | liquid; _alloy: Al 0.35, Bi 0.65_ | experimental | [1] McAlister 1984; _cites ref. 63Wit_ | Table 5, p. 3, row 1; `ORC-NDU6ONDCNG.72f6f3` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 18606 J/mol |  | liquid; _alloy: Al 0.1, Bi 0.9_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 10; `ORC-PMZ6OULXDD` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 21030 J/mol |  | liquid; _alloy: Al 0.065, Bi 0.935_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 12; `ORC-R26DAAEDM6` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 17451 J/mol |  | liquid; _alloy: Al 0.15, Bi 0.85_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 8; `ORC-TRZYUSLBNI` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 12702 J/mol |  | liquid; _alloy: Al 0.275, Bi 0.725_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 3; `ORC-UEOLGMREPJ` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 22666 J/mol |  | liquid; _alloy: Al 0.05, Bi 0.95_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 13; `ORC-VOBPCQWKI7` |  |
| chemical potential expression term; _printed: ΔmixGAl (constant)_ | 21109 J/mol |  | liquid; _alloy: Al 0.03, Bi 0.97_ | experimental | [1] McAlister 1984; _cites ref. 66Mar_ | Table 5, p. 3, row 14; `ORC-YD6QOCE76D` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. A. J. McAlister, The Al−Bi (Aluminum−Bismuth) system, Bulletin of Alloy Phase Diagrams 5, 247-250 (1984). [doi:10.1007/bf02868547](https://doi.org/10.1007/bf02868547)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).