Al–H system
14 accepted literature values from 1 paper(s) (experimental 13, model 1); 1 calculated phase diagram(s).
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| Evidence class | Values |
|---|---|
| experimental | 13 |
| model | 1 |
| Property group | Values |
|---|---|
| mixing / partial | 14 |
Calculated phase diagrams
Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.
| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AlH-04Qiu.tdb | C. Qiu, G.B. Olson, S.M. Opalka, D.L. Anton, J. Phase Equilib. Diffus., 25, 520-27(2004). doi:10.1361/15477020421043 | cafc133e72167e9d6e3798d9b03129c2d3ec789f69ce3d6948649bf9e85ad256 | viewer · TDB · JSON |
| TDB file | T (K) | Phases at the invariant |
|---|---|---|
| AlH-04Qiu.tdb | 933.47 | FCC_A1 (x(H) 0) + LIQUID (x(H) 0) + GAS (x(H) 1) |
| AlH-04Qiu.tdb | 933.46 | FCC_A1 (x(H) 0) + LIQUID (x(H) 2.000e-5) + GAS (x(H) 1) |
| AlH-04Qiu.tdb | 933.46 | FCC_A1 (x(H) 0) + LIQUID (x(H) 2.000e-5) + GAS (x(H) 1) |
| AlH-04Qiu.tdb | 933.46 | FCC_A1 (x(H) 0) + LIQUID (x(H) 2.000e-5) + GAS (x(H) 1) |
Convex hulls: Materials Project DFT hull · OQMD DFT hull
Other properties
Mixing / partial (14)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Partial enthalpy printed: ΔH | 63.18 kJ/mol (basis unstated) | fcc Al alloy: H 0 | experimental | [1] Qiu 2004 cites Eichenauer 1968 | Table 1, p. 2, row 5 report | ||
| Partial enthalpy printed: ΔH | 96.49 kJ/mol (basis unstated) | fcc Al alloy: H 0 | experimental | [1] Qiu 2004 cites Hashimoto 1983 | Table 1, p. 2, row 7 report | ||
| Partial enthalpy printed: ΔH | 58.24 kJ/mol (basis unstated) | fcc Al alloy: H 0 | experimental | [1] Qiu 2004 cites Eichenauer 1961 | Table 1, p. 2, row 3 report | ||
| Partial enthalpy printed: ΔH | 39.82 kJ/mol (basis unstated) | fcc Al alloy: H 0 | experimental | [1] Qiu 2004 cites Ransley 1948 | Table 1, p. 2, row 1 report | ||
| Partial enthalpy printed: ΔH | 63.94 kJ/mol (basis unstated) | fcc Al alloy: H 0 | experimental | [1] Qiu 2004 cites Ichimura 1979 | Table 1, p. 2, row 6 report | ||
| Partial enthalpy printed: ΔH | 51.94 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Grigorenko 1967 | Table 1, p. 2, row 4 report | ||
| Partial enthalpy printed: ΔH | 51.69 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Talbot 1988 | Table 1, p. 2, row 9 report | ||
| Partial enthalpy printed: ΔH | 59.08 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Eichenauer 1961 | Table 1, p. 2, row 3 report | ||
| Partial enthalpy printed: ΔH | 52.84 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Ransley 1948 | Table 1, p. 2, row 1 report | ||
| Partial enthalpy printed: ΔH | 45.8 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Imabayashi 1995 | Table 1, p. 2, row 11 report | ||
| Partial enthalpy printed: ΔH | 48.82 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Opie 1950 | Table 1, p. 2, row 2 report | ||
| Partial enthalpy printed: ΔH | 57.05 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Liu 1995 | Table 1, p. 2, row 10 report | ||
| Partial enthalpy printed: ΔH | 56.86 kJ/mol (basis unstated) | liquid | experimental | [1] Qiu 2004 cites Feichtinger 1987 | Table 1, p. 2, row 8 report | ||
| Partial enthalpy printed: ⌬H | 57.505 kJ/mol-atom | 933.15 | model | [1] Qiu 2004 | p. 6 report | It is seen that the calculated ⌬H for liquid has a value of 57.505 kJ/mol atom at 660 °C and decreases slightly with increasing temperature. |
Sources
Reporting papers the values were read from (a value cited from another work names that work in its row).
- Caian Qiu, Gregory B. Olson, Susanne M. Opalka, Donald L. Anton, Thermodynamic Evaluation of the Al-H System, Journal of Phase Equilibria & Diffusion 25, 520-527 (2004). doi:10.1361/15477020421043