Al–Mo–Ti system
29 accepted literature values from 1 paper(s) (experimental 11, model 18); 0 calculated phase diagram(s).
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| Evidence class | Values |
|---|---|
| experimental | 11 |
| model | 18 |
| Property group | Values |
|---|---|
| invariant reaction | 16 |
| phase equilibrium | 13 |
Invariant reactions (literature)
| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|
| 1800 | Liquid + Al63Mo37 -> β + Al8Mo3 | Liquid: Al 0.649, Mo 0.337, Ti 0.014; Al63Mo37: Al 0.63, Mo 0.37, Ti 0; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 1 report | |
| 1773 | Liquid + Al63Mo37 -> β + Al8Mo3 | Al63Mo37: Al 0.63, Mo 0.37, Ti 0; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0 | experimental | [1] Cupid 2010 cites Tretyachenko 2005 | Table 3, p. 9, row 2 report | |
| 1743 | Liquid + Al8Mo3 -> β + η | Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0 | experimental | [1] Cupid 2010 cites Tretyachenko 2005 | Table 3, p. 9, row 6 report | |
| 1713 | Liquid + α -> β + γ | experimental | [1] Cupid 2010 cites Tretyachenko 2005 | Table 3, p. 9, row 4 report | ||
| 1701 | Liquid + α -> β + γ | Liquid: Al 0.551, Mo 0.015, Ti 0.435 | model | [1] Cupid 2010 | Table 3, p. 9, row 3 report | |
| 1676 | Liquid + Al8Mo3 -> β + η | Liquid: Al 0.634, Mo 0.251, Ti 0.115; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 5 report | |
| 1673 | Liquid + ζ -> η + γ | experimental | [1] Cupid 2010 cites Tretyachenko 2005 | Table 3, p. 9, row 8 report | ||
| 1643 | Liquid -> γ + η + β | experimental | [1] Cupid 2010 cites Tretyachenko 2005 | Table 3, p. 9, row 10 report | ||
| 1627 | Liquid + ζ -> η + γ | Liquid: Al 0.674, Mo 0.024, Ti 0.302 | model | [1] Cupid 2010 | Table 3, p. 9, row 7 report | |
| 1569 | Liquid -> γ + η + β | Liquid: Al 0.554, Mo 0.082, Ti 0.334 | model | [1] Cupid 2010 | Table 3, p. 9, row 9 report | |
| 1494 | Liquid + Al8Mo3 -> η + Al3Mo | Liquid: Al 0.952, Mo 0.047, Ti 0.001; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 11 report | |
| 1425 | Liquid + Al3Mo -> η + Al4Mo | Liquid: Al 0.967, Mo 0.033, Ti 0; Al4Mo: Al 0.8, Mo 0.2, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 12 report | |
| 1270 | Liquid + Al4Mo -> η + Al17Mo4 | Liquid: Al 0.994, Mo 0.006, Ti 0; Al4Mo: Al 0.8, Mo 0.2, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 13 report | |
| 1213 | Liquid + Al17Mo4 -> η + Al22Mo5 | Liquid: Al 0.998, Mo 0.002, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 14 report | |
| 1119 | Liquid + Al22Mo5 -> η + Al5Mo | Liquid: Al 0.998, Mo 0.002, Ti 0; Al5Mo: Al 0.833333, Mo 0.166667, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 15 report | |
| 985 | Liquid + η + Al5Mo -> Al12Mo | Liquid: Al 0.9997, Mo 3.000e-4, Ti 0; Al5Mo: Al 0.833333, Mo 0.166667, Ti 0; Al12Mo: Al 0.923077, Mo 0.076923, Ti 0 | model | [1] Cupid 2010 | Table 3, p. 9, row 16 report |
Other properties
Phase equilibrium (13)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Phase assemblage | 1073 | a alloy: Al 0.025, Mo 0.025, Ti 0.95 | experimental | [1] Cupid 2010 cites Eremenko 1990 | p. 3 report | The Ti-rich a single phase was also observed in an alloy 95 at.%Tie2.5 at. %Ale2.5 at.%Mo which was heat treated at 1073 K for 222 h and quenched [53]. | |
| Phase assemblage | 1198 | d-AlMo3 alloy: Al 0.24, Mo 0.58, Ti 0.18 | model | [1] Cupid 2010 cites Hansen 1970 | p. 3 report | Additionally, an alloy of composition 18 at.%Tie24 at.%Ale58 at.% Mo, which was heat treated at 1198 K and quenched, contained only the d-AlMo3 phase [48], which indicates that the d-AlMo3 phase extends to at least 18 at.%Ti at 1198 K in the TieAleMo system. | |
| Phase assemblage | 1198 | h-(Ti,Mo)Al3 alloy: Al 0.75, Mo 0.125, Ti 0.125 | model | [1] Cupid 2010 cites Hansen 1970 | p. 3 report | Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48]. | |
| Phase assemblage | 1198 | h-(Ti,Mo)Al3 alloy: Al 0.68, Mo 0.16, Ti 0.16 | model | [1] Cupid 2010 cites Hansen 1970 | p. 3 report | Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48]. | |
| Phase assemblage | 1198 | h-(Ti,Mo)Al3 alloy: Al 0.64, Mo 0.1, Ti 0.26 | model | [1] Cupid 2010 cites Hansen 1970 | p. 3 report | Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48]. | |
| Phase assemblage | 1198 | s alloy: Al 0.41, Mo 0.33, Ti 0.26 | model | [1] Cupid 2010 cites Hansen 1970 | p. 4 report | Hansen and Raman [48] found the ternary s phase in the single phase alloy of composition 26 at.%Tie41 at.%Ale33 at.%Mo at 1198 K. | |
| Phase assemblage | 1273 | b0 alloy: Al 0.25, Mo 0.25, Ti 0.5 | experimental | [1] Cupid 2010 cites Singh 2007 doi | p. 4 report | Singh et al. [59] performed Rietveld refinement of X-ray and neutron diffraction data from an alloy of composition 50 at.%Tie25 at.%Ale25 at.%Mo which was homogenized at 1273 K and furnace cooled. The alloy was found to contain the b0 phase, and Rietveld refinement of the data showed that Ti atoms occupy A sites and Al and Mo atoms occupy the B sites in the CsCl structure. | |
| Phase assemblage | 1673 | a alloy: Al 0.48, Mo 0.02, Ti 0.5 | experimental | [1] Cupid 2010 cites Singh 1997 doi | p. 3 report | Although the maximum solubility of Mo in the a phase has not been measured, Singh and Banerjee [52] showed that an alloy of composition 50 at.%Tie48 at.%Ale2 at.%Mo is in the single phase a field at 1673 K and suggested that the a phase field extends to an alloy of composition 44 at.%Tie50 at.%Ale6 at.%Mo at 1673 K. | |
| Phase assemblage | 1673 | b + Al8Mo3 + d-AlMo3 alloy: Al 0.52, Mo 0.45, Ti 0.03 | experimental | [1] Cupid 2010 cites Nino 2003 doi | p. 3 report | For example, the equilibrium b þ Al8Mo3 þ d-AlMo3 tie-triangle data for an alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo, which was heat treated at 1673 K and quenched, showed that the Al8Mo3 phase dissolved 1 at.%Ti and that the d-AlMo3 phase dissolved 2.7 at.%Ti [15]. | |
| Phase assemblage | 1773 | b alloy: Al 0.52, Mo 0.45, Ti 0.03 | experimental | [1] Cupid 2010 cites Nino 2003 doi | p. 4 report | For example, although the alloy of composition 3 at.%Tie52 at.% Ale45 at.%Mo should be single phase b at 1773 K [15], this alloy is calculated in the liquid þ b þ Al63Mo37 three phase field at the same temperature and is located in the primary crystallization field of the d phase on the calculated liquidus surface [16]. | |
| Phase assemblage | 1773 | b alloy: Al 0.52, Mo 0.45, Ti 0.03 | experimental | [1] Cupid 2010 cites Nino 2003 doi | p. 4 report | The results of Nino et al. [15] also confirmed that the b phase is continuous in the solid state solution from the TieMo binary to the AleMo binary since an alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo, with only 3 at.%Ti, showed a single phase b microstructure following heat treatment at 1773 K and quenching [15]. | |
| Phase assemblage | 1773 | b alloy: Al 0.52, Mo 0.45, Ti 0.03 | model | [1] Cupid 2010 | p. 8 report | Fig. 4 shows the calculated isothermal section at 1773 K. The alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo is calculated in the single phase b field, which is in very good agreement with the experimental work of Nino et al. [15]. | |
| Phase assemblage | 1773 | liquid + b + Al63Mo37 alloy: Al 0.52, Mo 0.45, Ti 0.03 | model | [1] Cupid 2010 cites Cupid 2009 doi | p. 4 report | For example, although the alloy of composition 3 at.%Tie52 at.% Ale45 at.%Mo should be single phase b at 1773 K [15], this alloy is calculated in the liquid þ b þ Al63Mo37 three phase field at the same temperature and is located in the primary crystallization field of the d phase on the calculated liquidus surface [16]. |
Sources
Reporting papers the values were read from (a value cited from another work names that work in its row).
- Damian M. Cupid, Olga Fabrichnaya, Fereshteh Ebrahimi, Hans J. Seifert, Thermodynamic assessment of the Al–Mo system and of the Ti–Al–Mo System from 0 to 20at.% Ti, Intermetallics 18, 1185-1196 (2010). doi:10.1016/j.intermet.2010.03.010