Al–Mo–Ti system

29 accepted literature values from 1 paper(s) (experimental 11, model 18); 0 calculated phase diagram(s).

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Accepted values by evidence class
Evidence classValues
experimental11
model18
Accepted values by property group
Property groupValues
invariant reaction16
phase equilibrium13

Invariant reactions (literature)

Invariant reactions reported in the literature for the Al–Mo–Ti system (16)
T (K)Reaction / phasesCompositions (mole fraction)ClassSourceLocationQuote
1800Liquid + Al63Mo37 -> β + Al8Mo3Liquid: Al 0.649, Mo 0.337, Ti 0.014; Al63Mo37: Al 0.63, Mo 0.37, Ti 0; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0model[1] Cupid 2010Table 3, p. 9, row 1
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1773Liquid + Al63Mo37 -> β + Al8Mo3Al63Mo37: Al 0.63, Mo 0.37, Ti 0; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0experimental[1] Cupid 2010
cites Tretyachenko 2005
Table 3, p. 9, row 2
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1743Liquid + Al8Mo3 -> β + ηAl8Mo3: Al 0.727273, Mo 0.272727, Ti 0experimental[1] Cupid 2010
cites Tretyachenko 2005
Table 3, p. 9, row 6
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1713Liquid + α -> β + γexperimental[1] Cupid 2010
cites Tretyachenko 2005
Table 3, p. 9, row 4
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1701Liquid + α -> β + γLiquid: Al 0.551, Mo 0.015, Ti 0.435model[1] Cupid 2010Table 3, p. 9, row 3
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1676Liquid + Al8Mo3 -> β + ηLiquid: Al 0.634, Mo 0.251, Ti 0.115; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0model[1] Cupid 2010Table 3, p. 9, row 5
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1673Liquid + ζ -> η + γexperimental[1] Cupid 2010
cites Tretyachenko 2005
Table 3, p. 9, row 8
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1643Liquid -> γ + η + βexperimental[1] Cupid 2010
cites Tretyachenko 2005
Table 3, p. 9, row 10
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1627Liquid + ζ -> η + γLiquid: Al 0.674, Mo 0.024, Ti 0.302model[1] Cupid 2010Table 3, p. 9, row 7
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1569Liquid -> γ + η + βLiquid: Al 0.554, Mo 0.082, Ti 0.334model[1] Cupid 2010Table 3, p. 9, row 9
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1494Liquid + Al8Mo3 -> η + Al3MoLiquid: Al 0.952, Mo 0.047, Ti 0.001; Al8Mo3: Al 0.727273, Mo 0.272727, Ti 0model[1] Cupid 2010Table 3, p. 9, row 11
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1425Liquid + Al3Mo -> η + Al4MoLiquid: Al 0.967, Mo 0.033, Ti 0; Al4Mo: Al 0.8, Mo 0.2, Ti 0model[1] Cupid 2010Table 3, p. 9, row 12
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1270Liquid + Al4Mo -> η + Al17Mo4Liquid: Al 0.994, Mo 0.006, Ti 0; Al4Mo: Al 0.8, Mo 0.2, Ti 0model[1] Cupid 2010Table 3, p. 9, row 13
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1213Liquid + Al17Mo4 -> η + Al22Mo5Liquid: Al 0.998, Mo 0.002, Ti 0model[1] Cupid 2010Table 3, p. 9, row 14
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1119Liquid + Al22Mo5 -> η + Al5MoLiquid: Al 0.998, Mo 0.002, Ti 0; Al5Mo: Al 0.833333, Mo 0.166667, Ti 0model[1] Cupid 2010Table 3, p. 9, row 15
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985Liquid + η + Al5Mo -> Al12MoLiquid: Al 0.9997, Mo 3.000e-4, Ti 0; Al5Mo: Al 0.833333, Mo 0.166667, Ti 0; Al12Mo: Al 0.923077, Mo 0.076923, Ti 0model[1] Cupid 2010Table 3, p. 9, row 16
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Other properties

Phase equilibrium (13)

Phase equilibrium, Al–Mo–Ti system
PropertyValueT (K)Phases / compositionClassSourceLocationQuote
Phase assemblage1073a
alloy: Al 0.025, Mo 0.025, Ti 0.95
experimental[1] Cupid 2010
cites Eremenko 1990
p. 3
report
The Ti-rich a single phase was also observed in an alloy 95 at.%Tie2.5 at. %Ale2.5 at.%Mo which was heat treated at 1073 K for 222 h and quenched [53].
Phase assemblage1198d-AlMo3
alloy: Al 0.24, Mo 0.58, Ti 0.18
model[1] Cupid 2010
cites Hansen 1970
p. 3
report
Additionally, an alloy of composition 18 at.%Tie24 at.%Ale58 at.% Mo, which was heat treated at 1198 K and quenched, contained only the d-AlMo3 phase [48], which indicates that the d-AlMo3 phase extends to at least 18 at.%Ti at 1198 K in the TieAleMo system.
Phase assemblage1198h-(Ti,Mo)Al3
alloy: Al 0.75, Mo 0.125, Ti 0.125
model[1] Cupid 2010
cites Hansen 1970
p. 3
report
Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48].
Phase assemblage1198h-(Ti,Mo)Al3
alloy: Al 0.68, Mo 0.16, Ti 0.16
model[1] Cupid 2010
cites Hansen 1970
p. 3
report
Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48].
Phase assemblage1198h-(Ti,Mo)Al3
alloy: Al 0.64, Mo 0.1, Ti 0.26
model[1] Cupid 2010
cites Hansen 1970
p. 3
report
Hansen and Raman [48] showed that alloys of composition 26 at.%Tie64 at.%Ale10 at.%Mo, 16 at.%Tie68 at.% Ale16 at.%Mo, and 12.5 at.%Tie75 at.%Ale12.5 at.%Mo were all single phase h-(Ti,Mo)Al3 at 1198 K, and the h-(Ti,Mo)Al3 phase was found to extend to Mo compositions as high as 20 at.%Mo and Al compositions as low as 62 at.%Al at 1198 K [48].
Phase assemblage1198s
alloy: Al 0.41, Mo 0.33, Ti 0.26
model[1] Cupid 2010
cites Hansen 1970
p. 4
report
Hansen and Raman [48] found the ternary s phase in the single phase alloy of composition 26 at.%Tie41 at.%Ale33 at.%Mo at 1198 K.
Phase assemblage1273b0
alloy: Al 0.25, Mo 0.25, Ti 0.5
experimental[1] Cupid 2010
cites Singh 2007 doi
p. 4
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Singh et al. [59] performed Rietveld refinement of X-ray and neutron diffraction data from an alloy of composition 50 at.%Tie25 at.%Ale25 at.%Mo which was homogenized at 1273 K and furnace cooled. The alloy was found to contain the b0 phase, and Rietveld refinement of the data showed that Ti atoms occupy A sites and Al and Mo atoms occupy the B sites in the CsCl structure.
Phase assemblage1673a
alloy: Al 0.48, Mo 0.02, Ti 0.5
experimental[1] Cupid 2010
cites Singh 1997 doi
p. 3
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Although the maximum solubility of Mo in the a phase has not been measured, Singh and Banerjee [52] showed that an alloy of composition 50 at.%Tie48 at.%Ale2 at.%Mo is in the single phase a field at 1673 K and suggested that the a phase field extends to an alloy of composition 44 at.%Tie50 at.%Ale6 at.%Mo at 1673 K.
Phase assemblage1673b + Al8Mo3 + d-AlMo3
alloy: Al 0.52, Mo 0.45, Ti 0.03
experimental[1] Cupid 2010
cites Nino 2003 doi
p. 3
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For example, the equilibrium b þ Al8Mo3 þ d-AlMo3 tie-triangle data for an alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo, which was heat treated at 1673 K and quenched, showed that the Al8Mo3 phase dissolved 1 at.%Ti and that the d-AlMo3 phase dissolved 2.7 at.%Ti [15].
Phase assemblage1773b
alloy: Al 0.52, Mo 0.45, Ti 0.03
experimental[1] Cupid 2010
cites Nino 2003 doi
p. 4
report
For example, although the alloy of composition 3 at.%Tie52 at.% Ale45 at.%Mo should be single phase b at 1773 K [15], this alloy is calculated in the liquid þ b þ Al63Mo37 three phase field at the same temperature and is located in the primary crystallization field of the d phase on the calculated liquidus surface [16].
Phase assemblage1773b
alloy: Al 0.52, Mo 0.45, Ti 0.03
experimental[1] Cupid 2010
cites Nino 2003 doi
p. 4
report
The results of Nino et al. [15] also confirmed that the b phase is continuous in the solid state solution from the TieMo binary to the AleMo binary since an alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo, with only 3 at.%Ti, showed a single phase b microstructure following heat treatment at 1773 K and quenching [15].
Phase assemblage1773b
alloy: Al 0.52, Mo 0.45, Ti 0.03
model[1] Cupid 2010p. 8
report
Fig. 4 shows the calculated isothermal section at 1773 K. The alloy of composition 3 at.%Tie52 at.%Ale45 at.%Mo is calculated in the single phase b field, which is in very good agreement with the experimental work of Nino et al. [15].
Phase assemblage1773liquid + b + Al63Mo37
alloy: Al 0.52, Mo 0.45, Ti 0.03
model[1] Cupid 2010
cites Cupid 2009 doi
p. 4
report
For example, although the alloy of composition 3 at.%Tie52 at.% Ale45 at.%Mo should be single phase b at 1773 K [15], this alloy is calculated in the liquid þ b þ Al63Mo37 three phase field at the same temperature and is located in the primary crystallization field of the d phase on the calculated liquidus surface [16].

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

  1. Damian M. Cupid, Olga Fabrichnaya, Fereshteh Ebrahimi, Hans J. Seifert, Thermodynamic assessment of the Al–Mo system and of the Ti–Al–Mo System from 0 to 20at.% Ti, Intermetallics 18, 1185-1196 (2010). doi:10.1016/j.intermet.2010.03.010