Al–Re system

35 accepted literature values from 2 paper(s) (experimental 17, model 18); 3 calculated phase diagram(s). 14 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (13) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence classValues
experimental17
model18
Accepted values by property group
Property groupValues
invariant reaction23
phase transition8
heat capacity / entropy / enthalpy4

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB fileAssessmentSHA-256Links
AlRe-18Guo.tdbC. Guo, T. Wu, C. Li, Z. Du, Calphad, 61, 33-40(2018). doi:10.1016/j.calphad.2018.01.0057421e0e255df9d13b0af85dd78a8cd7253cbf7e684de3b562a9b1becdef4da30viewer · TDB · JSON
AlRe-20Tam.tdbR. Tamim, K. Mahdouk, S. Otmani, K. Achgar, J. Therm. Anal. Calorim., 139, 953-61(2020). doi:10.1007/s10973-019-08538-5eba53cb9a65daf58d0996585360066087ca4b10473122b7adbe008bce6c9f627viewer · TDB · JSON
AlRe-98Hua.tdbW. Huang, Y.A. Chang, J. Phase Equilib., 19, 361-66(1998). doi:10.1361/105497198770342094679b5be3d8b1640493eda90d7c806e796dba0042903d2d93d02e23a7393b5162viewer · TDB · JSON
Calculated three-phase invariants (model, mole fraction of the second component)
TDB fileT (K)Phases at the invariant
AlRe-18Guo.tdb2272.85LIQUID (x(Re) 0.56093) + ALRE2_C11B (x(Re) 0.66666) + HCP_A3 (x(Re) 0.98245)
AlRe-18Guo.tdb2272.85LIQUID (x(Re) 0.56094) + ALRE2_C11B (x(Re) 0.66666) + HCP_A3 (x(Re) 0.98246)
AlRe-18Guo.tdb1928.14AL11RE4 (x(Re) 0.26667) + LIQUID (x(Re) 0.33669) + ALRE2_C11B (x(Re) 0.66666)
AlRe-18Guo.tdb1928.14AL11RE4 (x(Re) 0.26667) + LIQUID (x(Re) 0.3367) + ALRE2_C11B (x(Re) 0.66666)
AlRe-18Guo.tdb1928.14AL11RE4 (x(Re) 0.26667) + LIQUID (x(Re) 0.33672) + ALRE2_C11B (x(Re) 0.66666)
AlRe-18Guo.tdb1883.12LIQUID (x(Re) 0.15462) + AL3RE (x(Re) 0.25) + AL11RE4 (x(Re) 0.26667)
AlRe-18Guo.tdb1883.12LIQUID (x(Re) 0.15478) + AL3RE (x(Re) 0.25) + AL11RE4 (x(Re) 0.26667)
AlRe-18Guo.tdb1683.43LIQUID (x(Re) 0.05582) + AL4RE_HT (x(Re) 0.21093) + AL3RE (x(Re) 0.25)
AlRe-18Guo.tdb1683.43LIQUID (x(Re) 0.05588) + AL4RE_HT (x(Re) 0.21094) + AL3RE (x(Re) 0.25)
AlRe-18Guo.tdb1332.48AL11RE4 (x(Re) 0.26667) + ALRE_B11 (x(Re) 0.5) + ALRE2_C11B (x(Re) 0.66667)
AlRe-18Guo.tdb1273.16LIQUID (x(Re) 9.200e-4) + AL4RE_LT (x(Re) 0.19804) + AL4RE_HT (x(Re) 0.20018)
AlRe-18Guo.tdb1218.82AL4RE_HT (x(Re) 0.21023) + AL3RE (x(Re) 0.25) + AL11RE4 (x(Re) 0.26667)
AlRe-18Guo.tdb1218.82AL4RE_HT (x(Re) 0.21023) + AL3RE (x(Re) 0.25) + AL11RE4 (x(Re) 0.26667)
AlRe-18Guo.tdb1106.17AL4RE_LT (x(Re) 0.20071) + AL4RE_HT (x(Re) 0.20922) + AL11RE4 (x(Re) 0.26667)
AlRe-18Guo.tdb1086.48LIQUID (x(Re) 4.000e-5) + AL6RE_D2H (x(Re) 0.14286) + AL4RE_LT (x(Re) 0.1925)
AlRe-18Guo.tdb1019.26LIQUID (x(Re) 1.000e-5) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)
AlRe-18Guo.tdb1019.26LIQUID (x(Re) 1.000e-5) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)
AlRe-18Guo.tdb933.47FCC_A1 (x(Re) 0) + LIQUID (x(Re) 0) + AL12RE (x(Re) 0.07692)
AlRe-20Tam.tdb2092.6LIQUID (x(Re) 0.24266) + AL3RE (x(Re) 0.42385) + AL4RE_HT (x(Re) 0.77195)
AlRe-20Tam.tdb1520.14AL11RE4 (x(Re) 0.26667) + AL3RE (x(Re) 0.32257) + AL4RE_HT (x(Re) 0.77011)
AlRe-20Tam.tdb1520.14AL11RE4 (x(Re) 0.26667) + AL3RE (x(Re) 0.32256) + AL4RE_HT (x(Re) 0.77011)
AlRe-20Tam.tdb1323.61LIQUID (x(Re) 0.03223) + AL4RE_LT (x(Re) 0.19182) + AL3RE (x(Re) 0.21193)
AlRe-20Tam.tdb1114.59AL4RE_LT (x(Re) 0.19569) + AL3RE (x(Re) 0.22631) + AL11RE4 (x(Re) 0.26667)
AlRe-20Tam.tdb1093.08LIQUID (x(Re) 0.00809) + AL6RE_D2H (x(Re) 0.14286) + AL4RE_LT (x(Re) 0.18816)
AlRe-20Tam.tdb1019.58LIQUID (x(Re) 0.00354) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)
AlRe-20Tam.tdb1019.58LIQUID (x(Re) 0.00354) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)
AlRe-20Tam.tdb1019.58LIQUID (x(Re) 0.00356) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)
AlRe-20Tam.tdb933.14FCC_A1 (x(Re) 0) + LIQUID (x(Re) 4.900e-4) + AL12RE (x(Re) 0.07692)
AlRe-20Tam.tdb933.14FCC_A1 (x(Re) 0) + LIQUID (x(Re) 4.900e-4) + AL12RE (x(Re) 0.07692)
AlRe-98Hua.tdb2276.01LIQUID (x(Re) 0.28774) + ALRE2_C11B (x(Re) 0.66667) + HCP_A3 (x(Re) 0.97266)
AlRe-98Hua.tdb2276.01LIQUID (x(Re) 0.28776) + ALRE2_C11B (x(Re) 0.66667) + HCP_A3 (x(Re) 0.97266)
AlRe-98Hua.tdb1875.7LIQUID (x(Re) 0.09032) + AL11RE4 (x(Re) 0.26667) + ALRE2_C11B (x(Re) 0.66667)
AlRe-98Hua.tdb1875.7LIQUID (x(Re) 0.09005) + AL11RE4 (x(Re) 0.26667) + ALRE2_C11B (x(Re) 0.66667)
AlRe-98Hua.tdb1875.7LIQUID (x(Re) 0.09009) + AL11RE4 (x(Re) 0.26667) + ALRE2_C11B (x(Re) 0.66667)
AlRe-98Hua.tdb1738.53LIQUID (x(Re) 0.02595) + AL4RE (x(Re) 0.2) + AL11RE4 (x(Re) 0.26667)
AlRe-98Hua.tdb1738.53LIQUID (x(Re) 0.0259) + AL4RE (x(Re) 0.2) + AL11RE4 (x(Re) 0.26667)
AlRe-98Hua.tdb1738.53LIQUID (x(Re) 0.02584) + AL4RE (x(Re) 0.2) + AL11RE4 (x(Re) 0.26667)
AlRe-98Hua.tdb1323.01AL11RE4 (x(Re) 0.26667) + ALRE_B11 (x(Re) 0.5) + ALRE2_C11B (x(Re) 0.66667)
AlRe-98Hua.tdb963.92LIQUID (x(Re) 0) + AL6RE_D2H (x(Re) 0.14286) + AL4RE (x(Re) 0.2)
AlRe-98Hua.tdb933.47LIQUID (x(Re) 0) + FCC_A1 (x(Re) 0) + AL6RE_D2H (x(Re) 0.14286)
AlRe-98Hua.tdb874.87FCC_A1 (x(Re) 0) + AL12RE (x(Re) 0.07692) + AL6RE_D2H (x(Re) 0.14286)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull AlRe-18Guo · CALPHAD hull AlRe-98Hua

Invariant reactions (literature)

Invariant reactions reported in the literature for the Al–Re system (23)
T (K)Reaction / phasesCompositions (mole fraction)ClassSourceLocationQuote
1934.15eutectic: L -> Al11Re4 + (Re)L: Re 0.3; Al11Re4: Re 0.266667model[1] Tamim 2020Table 1, p. 3, row 19
report
1928.15eutectic: L -> Al11Re4 + (Re)L: Re 0.28; Al11Re4: Re 0.266667experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 20
report
1883.15peritectic: L + Al11Re4 -> Al3ReL: Re 0.22; Al11Re4: Re 0.266667; Al3Re: Re 0.25experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 12
report
1878.15peritectic: L + Al11Re4 -> Al3ReL: Re 0.18; Al11Re4: Re 0.266667; Al3Re: Re 0.25model[1] Tamim 2020Table 1, p. 3, row 11
report
1876.15peritecticmodel[1] Tamim 2020
cites Huang 1998 doi
p. 8
report
In the phase diagram published by this authors, the Al11Re4 melts by a peritectic reaction at 1603 C (instead of a congruent melting at 1665 C) whereas AlRe2 undergoes a transformation at 2002 C (instead of 1494 C).
1767.15peritectoid: AlRe2 -> Al11Re4 + (Re)AlRe2: Re 0.666667; Al11Re4: Re 0.266667experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 24
report
1763.15peritectoid: AlRe2 -> Al11Re4 + (Re)AlRe2: Re 0.666667; Al11Re4: Re 0.266667model[1] Tamim 2020Table 1, p. 3, row 23
report
1688.15peritectic: L + Al3Re -> h-Al4ReL: Re 0.1; Al3Re: Re 0.25; h-Al4Re: Re 0.2model[1] Tamim 2020Table 1, p. 3, row 9
report
1683.15peritectic: L + Al3Re -> h-Al4ReL: Re 0.01; Al3Re: Re 0.25; h-Al4Re: Re 0.2experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 10
report
1333.15peritectoid: AlRe -> Al11Re4 + AlRe2AlRe: Re 0.5; Al11Re4: Re 0.266667; AlRe2: Re 0.666667experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 22
report
1329.15peritectoid: AlRe -> Al11Re4 + AlRe2AlRe: Re 0.5; Al11Re4: Re 0.266667; AlRe2: Re 0.666667model[1] Tamim 2020Table 1, p. 3, row 21
report
1293.15peritectic: L + h-Al4Re -> l-Al4ReL: Re 0.03; h-Al4Re: Re 0.2; l-Al4Re: Re 0.2model[1] Tamim 2020Table 1, p. 3, row 7
report
1273.15peritectic: L + h-Al4Re -> l-Al4ReL: Re 0.02; h-Al4Re: Re 0.2; l-Al4Re: Re 0.2experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 8
report
1219.15eutectoid: h-Al4Re + Al11Re4 -> Al3Reh-Al4Re: Re 0.2; Al11Re4: Re 0.266667; Al3Re: Re 0.25experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 18
report
1219.15eutectoid: h-Al4Re + Al11Re4 -> Al3Reh-Al4Re: Re 0.2; Al11Re4: Re 0.266667; Al3Re: Re 0.25model[1] Tamim 2020Table 1, p. 3, row 17
report
1106.15eutectoid: l-Al4Re + Al11Re4 -> h-Al4Rel-Al4Re: Re 0.2; Al11Re4: Re 0.266667; h-Al4Re: Re 0.2experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 16
report
1105.15eutectoid: l-Al4Re + Al11Re4 -> h-Al4Rel-Al4Re: Re 0.2; Al11Re4: Re 0.266667; h-Al4Re: Re 0.2model[1] Tamim 2020Table 1, p. 3, row 15
report
1086.15peritectic: L + l-Al4Re -> Al6ReL: Re 0.01; l-Al4Re: Re 0.2; Al6Re: Re 0.142857experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 6
report
1086.15peritectic: L + l-Al4Re -> Al6ReL: Re 0.008; l-Al4Re: Re 0.2; Al6Re: Re 0.142857model[1] Tamim 2020Table 1, p. 3, row 5
report
1020.15peritectic: L + Al6Re -> Al12ReL: Re 0.0035; Al6Re: Re 0.142857; Al12Re: Re 0.0769231model[1] Tamim 2020Table 1, p. 3, row 3
report
1019.15peritectic: L + Al6Re -> Al12ReL: Re 0.004; Al6Re: Re 0.142857; Al12Re: Re 0.0769231experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 4
report
933.15eutectic: L -> Al12Re + (Al)L: Re 0.005; Al12Re: Re 0.0769231model[1] Tamim 2020Table 1, p. 3, row 1
report
931.15eutectic: L -> Al12Re + (Al)L: Re 0.005; Al12Re: Re 0.0769231experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 2
report

Other properties

Phase transition (8)

Phase transition, Al–Re system
PropertyValueT (K)Phases / compositionClassSourceLocationQuote
Phase transition1767.15 K1767.15otherexperimental[1] Tamim 2020
cites Schuster 2001 doi
p. 8
report
In the phase diagram published by this authors, the Al11Re4 melts by a peritectic reaction at 1603 C (instead of a congruent melting at 1665 C) whereas AlRe2 undergoes a transformation at 2002 C (instead of 1494 C).
Phase transition1923.15 K1923.15Al11Re4experimental[1] Tamim 2020
cites Balanetskyy 2008 doi
p. 3
report
Moreover, we have adopted the temperature of 1665 C as being the Al11Re4 melting temperature [16] instead of 1650 C [4] which is below the temperature of the L $ Al11Re4 ? (Re) eutectic reaction (Fig. 1).
Phase transition1938.15 K1938.15Al11Re4experimental[1] Tamim 2020
cites Schuster 2001 doi
p. 3
report
Moreover, we have adopted the temperature of 1665 C as being the Al11Re4 melting temperature [16] instead of 1650 C [4] which is below the temperature of the L $ Al11Re4 ? (Re) eutectic reaction (Fig. 1).
Phase transition1938.15 K1938.15congruent melting: L -> Al11Re4
L: Re 0.266667; Al11Re4: Re 0.266667
experimental[1] Tamim 2020
cites Balanetskyy 2008
Table 1, p. 3, row 14
report
Phase transition1938.15 K1938.15congruent transformationexperimental[1] Tamim 2020
cites Schuster 2001 doi
p. 8
report
In the phase diagram published by this authors, the Al11Re4 melts by a peritectic reaction at 1603 C (instead of a congruent melting at 1665 C) whereas AlRe2 undergoes a transformation at 2002 C (instead of 1494 C).
Phase transition1943.15 K1943.15congruent melting: L -> Al11Re4
L: Re 0.266667; Al11Re4: Re 0.266667
model[1] Tamim 2020Table 1, p. 3, row 13
report
Phase transition2273 K2273chiexperimental[2] Huang 1998p. 2
report
For alloys with 30 to 90 at.% Re, the melting points were measured using an optical pyrometer, and with the help of microstructural analysis and hardness measurements, the invariant melting reactions at 2273, 1863, and 1758 K were determined to be the incongruent melting points of the 3(, AI~Re, and A12Re phases, respectively. The uncertainties of the measurements were estimated to be at least +…
Phase transition2275.15 K2275.15othermodel[1] Tamim 2020
cites Huang 1998 doi
p. 8
report
In the phase diagram published by this authors, the Al11Re4 melts by a peritectic reaction at 1603 C (instead of a congruent melting at 1665 C) whereas AlRe2 undergoes a transformation at 2002 C (instead of 1494 C).

Heat capacity / entropy / enthalpy (4)

Heat capacity / entropy / enthalpy, Al–Re system
PropertyValueT (K)Phases / compositionClassSourceLocationQuote
Heat capacity
printed: Cp
25 unspecified ± 2298.15model[2] Huang 1998p. 5
report
Therefore, a heat capacity value estimated by the Neumann-Kopp rule for 1 mole of atoms ofA1Re 2 at 298 K, Cp = 25 + 2 J/K. mol, was used in the optimization.
Heat capacity
printed: Cp
24.5 unspecified ± 2298.15model[2] Huang 1998p. 5
report
The thermodynamic property of A111Re4 was obtained from similar experimental data, with an estimated Cp = 24.5 + 2 J/K. mol at 298 K.
Heat content
printed: heat content
34.16 kJ/mol atoms1473model[2] Huang 1998p. 4
report
However, the calculated heat content of AlllRe 4 (34.95 kJ/mol of atoms) at 1473 K, that is, enthalpy of change from Eq 2, would be larger than that for AIRe 2 (34.16 kJ/mol atoms), while the experimental data show the opposite as given in Table 3.
Heat content
printed: heat content
34.95 kJ/mol of atoms1473model[2] Huang 1998p. 4
report
However, the calculated heat content of AlllRe 4 (34.95 kJ/mol of atoms) at 1473 K, that is, enthalpy of change from Eq 2, would be larger than that for AIRe 2 (34.16 kJ/mol atoms), while the experimental data show the opposite as given in Table 3.

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

  1. Rkia Tamim, Kamal Mahdouk, Samira Otmani, Khadija Achgar, Thermodynamic description of the aluminum–rhenium system, J Therm Anal Calorim 139, 953-961 (2020). doi:10.1007/s10973-019-08538-5
  2. W. Huang, Y. A. Chang, A thermodynamic analysis of the Al-Re system, JPE 19, 361-366 (1998). doi:10.1361/105497198770342094