# Au–Bi system

> Au–Bi system: 42 accepted literature values (invariant reaction 41, phase transition 1) and 3 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/AU-BI.html · Markdown: https://data.orchid-project.org/systems/AU-BI.md

42 accepted literature values from 3 paper(s) (experimental 27, model 15); 3 calculated phase diagram(s). 9 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/AU-BI.json) · [CSV](https://data.orchid-project.org/systems/AU-BI.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AU-BI) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AU-BI/AuBi-06Ser.json) · [phases (6)](https://data.orchid-project.org/phases/pages/AU-BI.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AU-BI.html) · [Markdown](https://data.orchid-project.org/systems/AU-BI.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 27 |
| model | 15 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 41 |
| phase transition | 1 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AuBi-06Ser.tdb | C. Servant, E. Zoro, B. Legendre, Calphad, 30, 443-48(2006). [doi:10.1016/j.calphad.2006.07.002](https://doi.org/10.1016/j.calphad.2006.07.002) | `211df8efcc0e760472d50337daae2fca1f13b26b574878c63509276ed3dcc76c` | [viewer](https://orchid-project.org/phase-diagrams/#AU-BI/AuBi-06Ser.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuBi-06Ser.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuBi-06Ser.json) |
| AuBi-07Wan.tdb | J. Wang, F.G. Meng, H.S. Liu, L.B. Liu, Z.P. Jin, J. Electron. Mater., 36, 568-77(2007). [doi:10.1007/s11664-007-0090-z](https://doi.org/10.1007/s11664-007-0090-z) | `2708fcbef3e06ed310bb44012c8dd75dd2cbf430191100a6d7c618eced307235` | [viewer](https://orchid-project.org/phase-diagrams/#AU-BI/AuBi-07Wan.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuBi-07Wan.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuBi-07Wan.json) |
| AuBi-88Che-LB.tdb | P.-Y. Chevalier, Thermochim. Acta, 130, 15-24(1988). [doi:10.1016/0040-6031(88)87046-1](https://doi.org/10.1016/0040-6031%2888%2987046-1) | `7247b351d3e4203e163fa11853f1b18683fa1275e7c792a1c90be8005e3f9384` | [viewer](https://orchid-project.org/phase-diagrams/#AU-BI/AuBi-88Che-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuBi-88Che-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuBi-88Che-LB.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| AuBi-06Ser.tdb | 650.71 | FCC_A1 (x(Bi) 1.300e-4) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.66744) |
| AuBi-06Ser.tdb | 650.71 | FCC_A1 (x(Bi) 1.300e-4) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.66713) |
| AuBi-06Ser.tdb | 514.03 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.85419) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AuBi-06Ser.tdb | 514.03 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.85465) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AuBi-06Ser.tdb | 383.12 | FCC_A1 (x(Bi) 0) + AU2BI_C15 (x(Bi) 0.33333) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AuBi-07Wan.tdb | 651.15 | FCC_A1 (x(Bi) 5.000e-5) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.68091) |
| AuBi-07Wan.tdb | 651.15 | FCC_A1 (x(Bi) 5.000e-5) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.68052) |
| AuBi-07Wan.tdb | 651.15 | FCC_A1 (x(Bi) 5.000e-5) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.68053) |
| AuBi-07Wan.tdb | 512.86 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.8667) + RHOMBOHEDRAL_A7 (x(Bi) 0.99641) |
| AuBi-07Wan.tdb | 512.86 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.86722) + RHOMBOHEDRAL_A7 (x(Bi) 0.99643) |
| AuBi-07Wan.tdb | 375.07 | FCC_A1 (x(Bi) 0) + AU2BI_C15 (x(Bi) 0.33333) + RHOMBOHEDRAL_A7 (x(Bi) 0.99937) |
| AuBi-07Wan.tdb | 375.07 | FCC_A1 (x(Bi) 0) + AU2BI_C15 (x(Bi) 0.33333) + RHOMBOHEDRAL_A7 (x(Bi) 0.99937) |
| AuBi-07Wan.tdb | 375.07 | FCC_A1 (x(Bi) 0) + AU2BI_C15 (x(Bi) 0.33333) + RHOMBOHEDRAL_A7 (x(Bi) 0.99937) |
| AuBi-88Che-LB.tdb | 647.32 | FCC_A1 (x(Bi) 4.000e-5) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.66678) |
| AuBi-88Che-LB.tdb | 647.32 | FCC_A1 (x(Bi) 4.000e-5) + AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.66656) |
| AuBi-88Che-LB.tdb | 514.32 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.86702) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AuBi-88Che-LB.tdb | 514.32 | AU2BI_C15 (x(Bi) 0.33333) + LIQUID (x(Bi) 0.86763) + RHOMBOHEDRAL_A7 (x(Bi) 1) |
| AuBi-88Che-LB.tdb | 349.81 | FCC_A1 (x(Bi) 0) + AU2BI_C15 (x(Bi) 0.33333) + RHOMBOHEDRAL_A7 (x(Bi) 1) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AU/AU-BI.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AU/AU-BI.json) · [CALPHAD hull AuBi-06Ser](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-BI--AuBi-06Ser.json) · [CALPHAD hull AuBi-88Che-LB](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-BI--AuBi-88Che-LB.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Au–Bi system (41)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 1337.58 | congruent melting: Au(fcc) ⇌ Au(liq) | Au(liq): Bi 0 | experimental | [1] Chevalier 1988; _cites Okamoto 1983_ [doi](https://doi.org/10.1007/bf02868093) | Table 2, p. 6, row 2; `ORC-J5F66PNGES` |  |
| 1337.58 | congruent melting: Au(fcc) ⇌ Au(liq) | Au(liq): Bi 0 | model | [1] Chevalier 1988 | Table 2, p. 6, row 1; `ORC-V43EGLQT3J` |  |
| 668 | Fcc + L \<-> Au2Bi | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Wallbrecht 1981_ [doi](https://doi.org/10.1016/0040-6031%2881%2980143-8) | Table 1, p. 2, row 10; `ORC-P5HOK3EW4U` |  |
| 651 | Fcc + L \<-> Au2Bi | L: Bi 0.666; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Evans 1983_ | Table 1, p. 2, row 8; `ORC-APG3XP2CAA` |  |
| 651 | peritectic: fcc + (L) ⇌ Au2Bi | L: Bi 0.666; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Evans 1983_ | Table 2, p. 6, row 9; `ORC-EGVA7CPPAA` |  |
| 650.7 | Fcc + L \<-> Au2Bi | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Zoro 2005_ | Table 1, p. 2, row 4; `ORC-HN2NZZYP3T` |  |
| 650.7 | Fcc + L \<-> Au2Bi | L: Bi 0.6671; Au2Bi: Au 0.666667, Bi 0.333333; fcc: Bi 1.320e-4 | model | [2] Servant 2006 | Table 1, p. 2, row 1; `ORC-S7ROIO6E2K` |  |
| 650.5 | Fcc + L \<-> Au2Bi | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Evans 1983_ | Table 1, p. 2, row 5; `ORC-HT7GSWF3SX` |  |
| 647.8 | peritectic: fcc + (L) ⇌ Au2Bi | fcc: Bi 4.400e-5; L: Bi 0.667; Au2Bi: Au 0.666667, Bi 0.333333 | model | [1] Chevalier 1988 | Table 2, p. 6, row 5; `ORC-DSLEQJLKMO` |  |
| 647.8 | peritectic: fcc + (L) ⇌ Au2Bi | fcc: Bi 4.900e-5; L: Bi 0.667; Au2Bi: Au 0.666667, Bi 0.333333 | model | [1] Chevalier 1988 | Table 2, p. 6, row 6; `ORC-KWAX5JXFNJ` |  |
| 647.8 | Fcc + L \<-> Au2Bi | L: Bi 0.667; Au2Bi: Au 0.666667, Bi 0.333333; fcc: Bi 4.400e-5 | model | [2] Servant 2006; _cites Chevalier 1988_ [doi](https://doi.org/10.1016/0040-6031%2888%2987046-1) | Table 1, p. 2, row 2; `ORC-PTHGIBWRVN` |  |
| 647.8 | Fcc + L \<-> Au2Bi | L: Bi 0.667; Au2Bi: Au 0.666667, Bi 0.333333; fcc: Bi 4.900e-5 | model | [2] Servant 2006; _cites Chevalier 1988_ [doi](https://doi.org/10.1016/0040-6031%2888%2987046-1) | Table 1, p. 2, row 3; `ORC-UDSYSM6KDM` |  |
| 646 | Fcc + L \<-> Au2Bi | L: Bi 0.68; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Gather 1975_ | Table 1, p. 2, row 7; `ORC-3D3HBHT3G5` |  |
| 646 | peritectic: fcc + (L) ⇌ Au2Bi | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Jurriaanse 1948_ | Table 2, p. 6, row 10; `ORC-HORK5AMTBP` |  |
| 646 | peritectic: fcc + (L) ⇌ Au2Bi | L: Bi 0.68; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Gather 1975_ | Table 2, p. 6, row 8; `ORC-MQVVMGWZCK` |  |
| 644 | Fcc + L \<-> Au2Bi | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Hultgren 1973_ | Table 1, p. 2, row 9; `ORC-5SUHAPRSU7` |  |
| 644 | Fcc + L \<-> Au2Bi | L: Bi 0.669; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Nathans 1962_ | Table 1, p. 2, row 6; `ORC-7RWHWJ6ZUE` |  |
| 644 | peritectic: fcc + (L) ⇌ Au2Bi | L: Bi 0.669; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Nathans 1962_ | Table 2, p. 6, row 7; `ORC-7XL63FNFR3` |  |
| 520 | L \<-> Au2Bi + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Wallbrecht 1981_ [doi](https://doi.org/10.1016/0040-6031%2881%2980143-8) | Table 1, p. 2, row 19; `ORC-KQDDVK4JUE` |  |
| 515.1 | L \<-> Au2Bi + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Zoro 2005_ | Table 1, p. 2, row 13; `ORC-OLYNBT4KO7` |  |
| 514.4 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.868; Au2Bi: Au 0.666667, Bi 0.333333 | model | [1] Chevalier 1988 | Table 2, p. 6, row 11; `ORC-4GIEUADZXF` |  |
| 514.4 | L \<-> Au2Bi + (Bi) | L: Bi 0.868; Au2Bi: Au 0.666667, Bi 0.333333 | model | [2] Servant 2006; _cites Chevalier 1988_ [doi](https://doi.org/10.1016/0040-6031%2888%2987046-1) | Table 1, p. 2, row 12; `ORC-RTWHMCBDC6` |  |
| 514.25 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.868; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Nathans 1962_ | Table 2, p. 6, row 14; `ORC-EMFPSQK5E7` |  |
| 514.15 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.86; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Vogel 1906_ [doi](https://doi.org/10.1002/zaac.19060500116) | Table 2, p. 6, row 12; `ORC-V4GRWGD4T2` |  |
| 514.1 | L \<-> Au2Bi + (Bi) | L: Bi 0.868; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Nathans 1962_ | Table 1, p. 2, row 16; `ORC-RGLJHU4ET4` |  |
| 514 | L \<-> Au2Bi + (Bi) | L: Bi 0.864; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Evans 1983_ | Table 1, p. 2, row 18; `ORC-44NWWNN6KN` |  |
| 514 | L \<-> Au2Bi + (Bi) | L: Bi 0.8544; Au2Bi: Au 0.666667, Bi 0.333333 | model | [2] Servant 2006 | Table 1, p. 2, row 11; `ORC-4FNPUFP2OM` |  |
| 514 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.864; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Evans 1983_ | Table 2, p. 6, row 16; `ORC-RUWX2QVRJ7` |  |
| 514 | L \<-> Au2Bi + (Bi) | L: Bi 0.85; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Gather 1975_ | Table 1, p. 2, row 17; `ORC-SAGK2ONNF5` |  |
| 514 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.85; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Gather 1975_ | Table 2, p. 6, row 15; `ORC-XOUUDLXXSR` |  |
| 513.44 | L \<-> Au2Bi + (Bi) | L: Bi 0.81; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Vogel 1906_ [doi](https://doi.org/10.1002/zaac.19060500116) | Table 1, p. 2, row 14; `ORC-T32WCPHPF5` |  |
| 513 | L \<-> Au2Bi + (Bi) | L: Bi 0.8236; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Hajicek 1948_ | Table 1, p. 2, row 15; `ORC-4OXOIQO5QJ` |  |
| 513 | eutectic: (L) ⇌ Au2Bi + Bi(rho) | L: Bi 0.8236; Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites ref. 11_ | Table 2, p. 6, row 13; `ORC-SUY65227YJ` |  |
| 389 | other: Au2Bi ⇌ fcc + Bi(rho) | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [1] Chevalier 1988; _cites Okamoto 1983_ [doi](https://doi.org/10.1007/bf02868093) | Table 2, p. 6, row 19; `ORC-DOXHKW222S` |  |
| 389 | Au2Bi \<-> fcc + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Okamoto 1983_ [doi](https://doi.org/10.1007/bf02868093) | Table 1, p. 2, row 23; `ORC-LTTL72L5US` |  |
| 383.1 | Au2Bi \<-> fcc + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | model | [2] Servant 2006 | Table 1, p. 2, row 20; `ORC-4EP2ONKWVK` |  |
| 382.7 | Au2Bi \<-> fcc + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | model | [2] Servant 2006; _cites Chevalier 1988_ [doi](https://doi.org/10.1016/0040-6031%2888%2987046-1) | Table 1, p. 2, row 21; `ORC-IYIBRJHJSI` |  |
| 382.7 | other: Au2Bi ⇌ fcc + Bi(rho) | Au2Bi: Au 0.666667, Bi 0.333333 | model | [1] Chevalier 1988 | Table 2, p. 6, row 17; `ORC-MYUTIAMIXS` |  |
| 349.8 | Au2Bi \<-> fcc + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | model | [2] Servant 2006; _cites Chevalier 1988_ [doi](https://doi.org/10.1016/0040-6031%2888%2987046-1) | Table 1, p. 2, row 22; `ORC-B7YTOE6DVE` |  |
| 349.8 | other: Au2Bi ⇌ fcc + Bi(rho) | Au2Bi: Au 0.666667, Bi 0.333333 | model | [1] Chevalier 1988 | Table 2, p. 6, row 18; `ORC-BZQRO3RDAV` |  |
|  | Au2Bi \<-> fcc + (Bi) | Au2Bi: Au 0.666667, Bi 0.333333 | experimental | [2] Servant 2006; _cites Evans 1983_ | Table 1, p. 2, row 24; `ORC-PAQDH6K73T` |  |

## Other properties

### Phase transition (1)

Table: Phase transition, Au–Bi system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 389 K | 389 | other | model | [3] Wang 2007; _cites Okamoto 1983_ [doi](https://doi.org/10.1007/bf02868093) | p. 2; `ORC-KOMM6MAZYP` | “By thermodynamic calculation, Okamoto et al.14 also predicted the decomposition of Au2Bi phase at 389 K.” |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. P.-Y. Chevalier, Thermodynamic evaluation of the Au-Bi system, Thermochimica Acta 130, 15-24 (1988). [doi:10.1016/0040-6031(88)87046-1](https://doi.org/10.1016/0040-6031%2888%2987046-1)
2. C. Servant, E. Zoro, B. Legendre, Thermodynamic reassessment of the Au–Bi system, Calphad 30, 443-448 (2006). [doi:10.1016/j.calphad.2006.07.002](https://doi.org/10.1016/j.calphad.2006.07.002)
3. J. Wang, F.G. Meng, H.S. Liu, L.B. Liu, Z.P. Jin, Thermodynamic Modeling of the Au-Bi-Sb Ternary System, Journal of Elec Materi 36, 568-577 (2007). [doi:10.1007/s11664-007-0090-z](https://doi.org/10.1007/s11664-007-0090-z)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).