# Au–Sb system > Au–Sb system: 37 accepted literature values (invariant reaction 19, formation 18) and 5 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/AU-SB.html · Markdown: https://data.orchid-project.org/systems/AU-SB.md 37 accepted literature values from 4 paper(s) (experimental 25, model 12); 5 calculated phase diagram(s). 22 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV. Data: [JSON](https://data.orchid-project.org/literature/systems/AU-SB.json) · [CSV](https://data.orchid-project.org/systems/AU-SB.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AU-SB) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-02Kim.json) · [phases (6)](https://data.orchid-project.org/phases/pages/AU-SB.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AU-SB.html) · [Markdown](https://data.orchid-project.org/systems/AU-SB.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | experimental | 25 | | model | 12 | Table: Accepted values by property group | Property group | Values | |---|---:| | invariant reaction | 19 | | formation | 18 | ## Calculated phase diagrams Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model. Table: Assessments with a calculated phase diagram | TDB file | Assessment | SHA-256 | Links | |---|---|---|---| | AuSb-02Kim.tdb | J.H. Kim, S.W. Jeong, H.M. Lee, J. Electron. Mater., 31, 557-63(2002). [doi:10.1007/s11664-002-0125-4](https://doi.org/10.1007/s11664-002-0125-4) | `db53175b1bacbeb54c082f94e32ca97f2b6ebd2a28301607b8d360d59b2f1b5b` | [viewer](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-02Kim.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuSb-02Kim.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuSb-02Kim.json) | | AuSb-03Liu.tdb | H.S. Liu, C.L. Liu, C. Wang, Z.P. Jin, K. Ishida, J. Electron. Mater., 32, 81-88(2003). [doi:10.1007/s11664-003-0240-x](https://doi.org/10.1007/s11664-003-0240-x) | `c4f2198262a6e367e11338497d75b5c84bcefe7e950f8a87f4897c54bd47bde9` | [viewer](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-03Liu.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuSb-03Liu.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuSb-03Liu.json) | | AuSb-11Wan.tdb | J. Wang, Y.J. Liu, L.B. Liu, H.Y. Zhou, Z.P. Jin, J. Alloys Compd., 509, 3057-64(2011). [doi:10.1016/j.jallcom.2010.11.199](https://doi.org/10.1016/j.jallcom.2010.11.199) | `0354d7420fa903d8915784b58a78b1d68a88f2e8050380bc6e5b31328553a0b5` | [viewer](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-11Wan.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuSb-11Wan.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuSb-11Wan.json) | | AuSb-13Gie.tdb | W. Gierlotka, J. Alloys Compd., 579, 533-39(2013). [doi:10.1016/j.jallcom.2013.04.186](https://doi.org/10.1016/j.jallcom.2013.04.186) | `420d77300456541e4cfb5840a604a34acfba0b49c40f29c0b30803e81dee7683` | [viewer](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-13Gie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuSb-13Gie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuSb-13Gie.json) | | AuSb-89Che-LB.tdb | P.-Y. Chevalier, Thermochim. Acta, 155, 211-25(1989). [doi:10.1016/0040-6031(89)87147-3](https://doi.org/10.1016/0040-6031%2889%2987147-3) | `080bb55f5b27634800b3566052b781e0cccf39ef4af46ad11ed4086cc5ca59de` | [viewer](https://orchid-project.org/phase-diagrams/#AU-SB/AuSb-89Che-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuSb-89Che-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuSb-89Che-LB.json) | Table: Calculated three-phase invariants (model, mole fraction of the second component) | TDB file | T (K) | Phases at the invariant | |---|---:|---| | AuSb-02Kim.tdb | 735.55 | LIQUID (x(Sb) 0.63909) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-02Kim.tdb | 735.55 | LIQUID (x(Sb) 0.63939) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-02Kim.tdb | 735.55 | LIQUID (x(Sb) 0.6396) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-02Kim.tdb | 634.7 | FCC_A1 (x(Sb) 0.00726) + LIQUID (x(Sb) 0.3722) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-02Kim.tdb | 634.7 | FCC_A1 (x(Sb) 0.00727) + LIQUID (x(Sb) 0.37215) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-03Liu.tdb | 739.98 | LIQUID (x(Sb) 0.65502) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-03Liu.tdb | 739.98 | LIQUID (x(Sb) 0.65532) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-03Liu.tdb | 739.98 | LIQUID (x(Sb) 0.65568) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-03Liu.tdb | 626.23 | FCC_A1 (x(Sb) 0.00842) + LIQUID (x(Sb) 0.36614) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-03Liu.tdb | 626.23 | FCC_A1 (x(Sb) 0.00843) + LIQUID (x(Sb) 0.36607) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-11Wan.tdb | 732.32 | LIQUID (x(Sb) 0.65267) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-11Wan.tdb | 732.32 | LIQUID (x(Sb) 0.65279) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-11Wan.tdb | 732.32 | LIQUID (x(Sb) 0.65311) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-11Wan.tdb | 629.67 | FCC_A1 (x(Sb) 0.00707) + LIQUID (x(Sb) 0.36945) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-11Wan.tdb | 629.67 | FCC_A1 (x(Sb) 0.00707) + LIQUID (x(Sb) 0.3693) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-13Gie.tdb | 726.24 | LIQUID (x(Sb) 0.64778) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-13Gie.tdb | 726.24 | LIQUID (x(Sb) 0.64786) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-13Gie.tdb | 726.24 | LIQUID (x(Sb) 0.64831) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-13Gie.tdb | 628.38 | FCC_A1 (x(Sb) 0.0102) + LIQUID (x(Sb) 0.36517) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-13Gie.tdb | 628.38 | FCC_A1 (x(Sb) 0.0102) + LIQUID (x(Sb) 0.36504) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-89Che-LB.tdb | 732.13 | LIQUID (x(Sb) 0.6597) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-89Che-LB.tdb | 732.13 | LIQUID (x(Sb) 0.6601) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-89Che-LB.tdb | 732.13 | LIQUID (x(Sb) 0.66075) + AUSB2_C2 (x(Sb) 0.66667) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | AuSb-89Che-LB.tdb | 630.25 | FCC_A1 (x(Sb) 0.01054) + LIQUID (x(Sb) 0.3488) + AUSB2_C2 (x(Sb) 0.66667) | | AuSb-89Che-LB.tdb | 630.25 | FCC_A1 (x(Sb) 0.01053) + LIQUID (x(Sb) 0.34869) + AUSB2_C2 (x(Sb) 0.66667) | Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AU/AU-SB.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AU/AU-SB.json) · [CALPHAD hull AuSb-02Kim](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-SB--AuSb-02Kim.json) · [CALPHAD hull AuSb-03Liu](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-SB--AuSb-03Liu.json) · [CALPHAD hull AuSb-11Wan](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-SB--AuSb-11Wan.json) · [CALPHAD hull AuSb-89Che-LB](https://data.orchid-project.org/hulls/calphad-sgte/AU/AU-SB--AuSb-89Che-LB.json) ## Invariant reactions (literature) Table: Invariant reactions reported in the literature for the Au–Sb system (19) | T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote | |---:|---|---|---|---|---|---| | 740 | peritectic: L + (Sb) -> AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Wallbrecht 1981_ [doi](https://doi.org/10.1016/0040-6031%2881%2980143-8) | Table II, p. 3, row 4; `ORC-WVMH6AGGMZ` | | | 734.3 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.663; AuSb2: Au 0.333333, Sb 0.666667 | model | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table II, p. 3, row 7; `ORC-6JKZNZHND5` | | | 733.17 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.655; (Sb): Sb 1; AuSb2: Sb 0.667 | experimental | [1] Kim 2002 | Table II, p. 3, row 8; `ORC-JAT47GF4CD` | | | 733 | peritectic: L + (Sb) -> AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Gaither 1976_ | Table II, p. 3, row 3; `ORC-ATYLKXDYHY` | | | 733 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.666; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Okamoto 1984_ [doi](https://doi.org/10.1007/bf02868954) | Table II, p. 3, row 5; `ORC-KAEJQIWG54` | | | 732.4 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.66; AuSb2: Au 0.333333, Sb 0.666667 | model | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table II, p. 3, row 6; `ORC-BTGYEC4WSZ` | | | 725 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.666; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Grigorjew 1932_ [doi](https://doi.org/10.1002/zaac.19322090312) | Table II, p. 3, row 2; `ORC-B64I7UWB4S` | | | 723 | peritectic: L + (Sb) -> AuSb2 | L: Sb 0.666; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Vogel 1906_ [doi](https://doi.org/10.1002/zaac.19060500116) | Table II, p. 3, row 1; `ORC-DRQGXZVMIN` | | | 634 | eutectic: L -> (Au) + AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Wallbrecht 1981_ [doi](https://doi.org/10.1016/0040-6031%2881%2980143-8) | Table II, p. 3, row 13; `ORC-5YQGMHLXVX` | | | 633 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.355; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Okamoto 1984_ [doi](https://doi.org/10.1007/bf02868954) | Table II, p. 3, row 14; `ORC-5JJC77YAEE` | | | 633 | eutectic: L -> (Au) + AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Gasgnier 1974_ [doi](https://doi.org/10.1002/pssa.2210240241) | Table II, p. 3, row 11; `ORC-HKASMWQEXH` | | | 633 | eutectic: L -> (Au) + AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Gaither 1976_ | Table II, p. 3, row 12; `ORC-KBLUTE6AOW` | | | 632.74 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.362; (Au): Sb 0.007; AuSb2: Sb 0.667 | experimental | [1] Kim 2002 | Table II, p. 3, row 18; `ORC-BWIUMIEEUF` | | | 632 | eutectic | | experimental | [2] Gierlotka 2013 | p. 1; `ORC-F5Y573F3Z7` | “There is also an eutectic reaction between liquid, IMC and FCC_A1(Au) phase at 632 K.” | | 630.9 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.349; (Au): Sb 0.01; AuSb2: Sb 0.667 | model | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table II, p. 3, row 15; `ORC-KHLSNND3QL` | | | 630.37 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.35; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Hayer 1995_ | Table II, p. 3, row 17; `ORC-HZTNC4ZM3C` | | | 630 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.33; AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Vogel 1906_ [doi](https://doi.org/10.1002/zaac.19060500116) | Table II, p. 3, row 9; `ORC-QGNY2JUX62` | | | 629.4 | eutectic: L -> (Au) + AuSb2 | L: Sb 0.353; (Au): Sb 0.0076; AuSb2: Sb 0.667 | model | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table II, p. 3, row 16; `ORC-SA4A3WRA74` | | | 624 | eutectic: L -> (Au) + AuSb2 | AuSb2: Au 0.333333, Sb 0.666667 | experimental | [1] Kim 2002; _cites Grigorjew 1932_ [doi](https://doi.org/10.1002/zaac.19322090312) | Table II, p. 3, row 10; `ORC-CAGKNBJG6N` | | ## Formation enthalpies Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json). Table: Enthalpies of formation, Au–Sb system (18) | Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote | |---|---|---:|---:|---|---:|---:|---|---|---| | AuSb | [AuSb](https://data.orchid-project.org/compounds/AuSb.html) | -4.895 kJ/mol-atom | 363 | experimental | | -5.168 (oqmd-1105404) | [3] Chevalier 1989; _cites Biltz 1934_ | p. 3; `ORC-2MQGSC5SZ6.e5993b` | “The heat of formation of the intermetallic compound AuSb, referred to the pure solid components was measured calorimetrically by: Jena and Bever \[16\], T = 273 K, AH = - 4351 J (g at.))'; by Kleppa \[17\], T = 723 K, AH = - 3138 J (g at.)-'; and by Biltz et al. \[18\], T = 363 K, AH = - 4895 J (g at.))'.” | | AuSb | [AuSb](https://data.orchid-project.org/compounds/AuSb.html) | -4.351 kJ/mol-atom | 273 | experimental | | -5.168 (oqmd-1105404) | [3] Chevalier 1989; _cites Jena 1968_ | p. 3; `ORC-2MQGSC5SZ6.666712` | “The heat of formation of the intermetallic compound AuSb, referred to the pure solid components was measured calorimetrically by: Jena and Bever \[16\], T = 273 K, AH = - 4351 J (g at.))'; by Kleppa \[17\], T = 723 K, AH = - 3138 J (g at.)-'; and by Biltz et al. \[18\], T = 363 K, AH = - 4895 J (g at.))'.” | | AuSb | [AuSb](https://data.orchid-project.org/compounds/AuSb.html) | -3.138 kJ/mol-atom | 723 | experimental | | -5.168 (oqmd-1105404) | [3] Chevalier 1989; _cites Kleppa 1956_ [doi](https://doi.org/10.1021/j150541a006) | p. 3; `ORC-2MQGSC5SZ6.e3f181` | “The heat of formation of the intermetallic compound AuSb, referred to the pure solid components was measured calorimetrically by: Jena and Bever \[16\], T = 273 K, AH = - 4351 J (g at.))'; by Kleppa \[17\], T = 723 K, AH = - 3138 J (g at.)-'; and by Biltz et al. \[18\], T = 363 K, AH = - 4895 J (g at.))'.” | | AuSb2 | | -6.364 kJ/mol (basis unstated) | 298.15 | model | | | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table III, p. 4, row 5; `ORC-E5NFJBJZ4V` | | | AuSb2 | | -6.364 kJ/mol (basis unstated) | 298.15 | model | | | [2] Gierlotka 2013; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table 2, p. 2, row 3; `ORC-QBIBDUA3LC` | | | AuSb2 | | -5.54 kJ/mol (basis unstated) | 298.15 | model | | | [2] Gierlotka 2013; _cites Liu 2003_ [doi](https://doi.org/10.1007/s11664-003-0240-x) | Table 2, p. 2, row 6; `ORC-BHOYVKYMGY` | | | AuSb2 | | -5.5 kJ/mol (basis unstated) | 298.15 | model | | | [2] Gierlotka 2013; _cites Kim 2002_ [doi](https://doi.org/10.1007/s11664-002-0125-4) | Table 2, p. 2, row 5; `ORC-K6LKSCUPDV` | | | AuSb2 | | -5.41 kJ/mol (basis unstated) | 298.15 | model | | | [2] Gierlotka 2013; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table 2, p. 2, row 2; `ORC-4T2EX3FKWH` | | | AuSb2 | | -5.41 kJ/mol (basis unstated) | 298.15 | model | | | [1] Kim 2002; _cites Chevalier 1989_ [doi](https://doi.org/10.1016/0040-6031%2889%2987147-3) | Table III, p. 4, row 4; `ORC-FPBFDILKWN` | | | AuSb2 | | -5.40955 kJ/mol (basis unstated) | 298.15 | model | | | [4] Wang 2011 | p. 5; `ORC-VD4C6PJR6U.2b5ea6` | “The enthalpy of formation of AuSb2 referred to fcc A1(Au) and rhombohedral A7(Sb) at 298 K is calculated to be -5409.55 J/mol, which agrees well with the experimental values measured by Hayer and Castanet \[41\] (-5400 ± 600 J/mol) as well as the assessed values by Liu et al. \[20\] (-4962 J/mol) and Kim et al. \[32\] (-5500 J/mol).” | | AuSb2 | | -5.4 kJ/mol (basis unstated) ± 0.6 | 298.15 | experimental | | | [2] Gierlotka 2013; _cites Hayer 1995_ | Table 2, p. 2, row 4; `ORC-O2HFB5F4VP` | | | AuSb2 | | -5.148 kJ/mol (basis unstated) | 298.15 | model | | | [2] Gierlotka 2013 | Table 2, p. 2, row 7; `ORC-3T7A4QOXU7` | | | AuSb2 | | -4.9 kJ/mol (basis unstated) | 363 | experimental | | | [1] Kim 2002; _cites Biltz 1934_ [doi](https://doi.org/10.1002/zaac.19342200202) | Table III, p. 4, row 1; `ORC-KOMUEHZIKL` | | | AuSb2 | | -4.9 kJ/mol (basis unstated) | 363 | experimental | | | [2] Gierlotka 2013; _cites Blitz 1934_ | Table 2, p. 2, row 8; `ORC-QOIYQMXN4S` | | | AuSb2 | | -4.35 kJ/mol (basis unstated) ± 0.13 | 298.15 | experimental | | | [1] Kim 2002; _cites Jena 1968_ | Table III, p. 4, row 2; `ORC-FLEY5QWPG6` | | | AuSb2 | | -4.35 kJ/mol (basis unstated) ± 0.13 | 298.15 | experimental | | | [2] Gierlotka 2013; _cites Jena 1968_ | Table 2, p. 2, row 1; `ORC-QSPJIEFNOJ` | | | AuSb2 | | -3.14 kJ/mol (basis unstated) | 723 | experimental | | | [1] Kim 2002; _cites Kleppa 1956_ [doi](https://doi.org/10.1021/j150541a006) | Table III, p. 4, row 3; `ORC-ALIZ7RB3FR` | | | AuSb2 | | -3.14 kJ/mol (basis unstated) | 723 | experimental | | | [2] Gierlotka 2013; _cites Kleppa 1956_ [doi](https://doi.org/10.1021/j150541a006) | Table 2, p. 2, row 9; `ORC-MBGFCGHQ42` | | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. Jong Hoon Kim, Sang Won Jeong, Hyuck Mo Lee, A thermodynamic study of phase equilibria in the Au-Sb-Sn solder system, Journal of Elec Materi 31, 557-563 (2002). [doi:10.1007/s11664-002-0125-4](https://doi.org/10.1007/s11664-002-0125-4) 2. Wojciech Gierlotka, Thermodynamic description of the binary Au–Sb and ternary Au–In–Sb systems, Journal of Alloys and Compounds 579, 533-539 (2013). [doi:10.1016/j.jallcom.2013.04.186](https://doi.org/10.1016/j.jallcom.2013.04.186) 3. Pierre-Yves Chevalier, A thermodynamic evaluation of the Au-Sb and Au-Tl systems, Thermochimica Acta 155, 211-225 (1989). [doi:10.1016/0040-6031(89)87147-3](https://doi.org/10.1016/0040-6031%2889%2987147-3) 4. J. Wang, Y.J. Liu, L.B. Liu, H.Y. Zhou, Z.P. Jin, Thermodynamic modeling of the Au–Sb–Si ternary system, Journal of Alloys and Compounds 509, 3057-3064 (2011). [doi:10.1016/j.jallcom.2010.11.199](https://doi.org/10.1016/j.jallcom.2010.11.199) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859 - R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_phase_diagrams_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Diagrams: calculated binary phase diagrams}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735859}, url = {https://doi.org/10.5281/zenodo.23735859} } @misc{orchid_hulls_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735891}, url = {https://doi.org/10.5281/zenodo.23735891} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).