# Au–Zn system

> Au–Zn system: 40 accepted literature values (invariant reaction 24, formation 8, phase transition 8) and 1 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/AU-ZN.html · Markdown: https://data.orchid-project.org/systems/AU-ZN.md

40 accepted literature values from 1 paper(s) (experimental 21, model 19); 1 calculated phase diagram(s).

Data: [JSON](https://data.orchid-project.org/literature/systems/AU-ZN.json) · [CSV](https://data.orchid-project.org/systems/AU-ZN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#AU-ZN) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#AU-ZN/AuZn-03Liu.json) · [phases (15)](https://data.orchid-project.org/phases/pages/AU-ZN.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/AU-ZN.html) · [Markdown](https://data.orchid-project.org/systems/AU-ZN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 21 |
| model | 19 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 24 |
| phase transition | 8 |
| formation | 8 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| AuZn-03Liu.tdb | H.S. Liu, K. Ishida, Z.P. Jin, Y. Du, Intermetallics, 11, 987-94(2003). [doi:10.1016/S0966-9795(03)00115-8](https://doi.org/10.1016/S0966-9795%2803%2900115-8) | `3f49fe4af92b316f8926fd10020aff767d8b1d9bda94ac60c005ed29c49333a3` | [viewer](https://orchid-project.org/phase-diagrams/#AU-ZN/AuZn-03Liu.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/AuZn-03Liu.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/AuZn-03Liu.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| AuZn-03Liu.tdb | 954.8 | FCC_A1 (x(Zn) 0.34554) + LIQUID (x(Zn) 0.36111) + AUZN_B2 (x(Zn) 0.39724) |
| AuZn-03Liu.tdb | 954.8 | FCC_A1 (x(Zn) 0.34554) + LIQUID (x(Zn) 0.36111) + AUZN_B2 (x(Zn) 0.39724) |
| AuZn-03Liu.tdb | 946.36 | AUZN_B2 (x(Zn) 0.57227) + LIQUID (x(Zn) 0.62496) + AU4ZN9_D82 (x(Zn) 0.64654) |
| AuZn-03Liu.tdb | 946.36 | AUZN_B2 (x(Zn) 0.57227) + LIQUID (x(Zn) 0.62496) + AU4ZN9_D82 (x(Zn) 0.64654) |
| AuZn-03Liu.tdb | 857.88 | AU4ZN9_D82 (x(Zn) 0.74043) + AUZN4 (x(Zn) 0.80123) + LIQUID (x(Zn) 0.81897) |
| AuZn-03Liu.tdb | 794.76 | AU4ZN9_D82 (x(Zn) 0.74205) + AUZN3 (x(Zn) 0.75) + AUZN4 (x(Zn) 0.80019) |
| AuZn-03Liu.tdb | 762.99 | AUZN4 (x(Zn) 0.84616) + HCP_IM_A3 (x(Zn) 0.88) + LIQUID (x(Zn) 0.92663) |
| AuZn-03Liu.tdb | 715.8 | HCP_IM_A3 (x(Zn) 0.90246) + HCP_A3 (x(Zn) 0.95349) + LIQUID (x(Zn) 0.96482) |
| AuZn-03Liu.tdb | 674.34 | AU3ZN_HT (x(Zn) 0.27038) + FCC_A1 (x(Zn) 0.28335) + AUZN_B2 (x(Zn) 0.3688) |
| AuZn-03Liu.tdb | 674.34 | AU3ZN_HT (x(Zn) 0.27038) + FCC_A1 (x(Zn) 0.28335) + AUZN_B2 (x(Zn) 0.3688) |
| AuZn-03Liu.tdb | 578.49 | AU3ZN_HT (x(Zn) 0.28755) + AU5ZN3 (x(Zn) 0.375) + AUZN_B2 (x(Zn) 0.39919) |
| AuZn-03Liu.tdb | 572.77 | FCC_A1 (x(Zn) 0.16052) + AU4ZN (x(Zn) 0.18568) + AU3ZN_HT (x(Zn) 0.22039) |
| AuZn-03Liu.tdb | 452.88 | AUZN_B2 (x(Zn) 0.5467) + AU44ZN56 (x(Zn) 0.56) + AU4ZN9_D82 (x(Zn) 0.66127) |
| AuZn-03Liu.tdb | 452.88 | AUZN_B2 (x(Zn) 0.5467) + AU44ZN56 (x(Zn) 0.56) + AU4ZN9_D82 (x(Zn) 0.66127) |
| AuZn-03Liu.tdb | 443.02 | AUZN4 (x(Zn) 0.84096) + AU3ZN17 (x(Zn) 0.85) + HCP_IM_A3 (x(Zn) 0.86866) |
| AuZn-03Liu.tdb | 307.05 | AUZN3 (x(Zn) 0.75) + AUZN4 (x(Zn) 0.82698) + AU3ZN17 (x(Zn) 0.85) |
| AuZn-03Liu.tdb | 307.05 | AUZN3 (x(Zn) 0.75) + AUZN4 (x(Zn) 0.82699) + AU3ZN17 (x(Zn) 0.85) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/AU/AU-ZN.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/AU/AU-ZN.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Au–Zn system (24)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 957 | eutectic: L -> (Au) + β' | L: Zn 0.34; β': Zn 0.5 | experimental | [1] Liu 2003; _cites Pemsler 1971_ [doi](https://doi.org/10.1007/bf02662640) | Table 4, p. 7, row 10; `ORC-6DEELBIY34` |  |
| 956 | eutectic: L -> (Au) + β' | L: Zn 0.36; (Au): Zn 0.335; β': Zn 0.395 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 9; `ORC-JQO7P6L64E` |  |
| 955 | eutectic: L -> (Au) + β' | L: Zn 0.36; (Au): Zn 0.345; β': Zn 0.395 | model | [1] Liu 2003 | Table 4, p. 7, row 11; `ORC-J3V7CYEIRM` |  |
| 946 | eutectic: L + β' -> γ (L -> β' + γ) | L: Zn 0.625; β': Zn 0.572; γ: Zn 0.646 | model | [1] Liu 2003 | Table 4, p. 7, row 21; `ORC-TUA5L4HDKK` |  |
| 932 | eutectic: L + β' -> γ (L -> β' + γ) | L: Zn 0.615; β': Zn 0.5; γ: Zn 0.692308 | experimental | [1] Liu 2003; _cites Pemsler 1971_ [doi](https://doi.org/10.1007/bf02662640) | Table 4, p. 7, row 20; `ORC-G3MZBNURW5` |  |
| 927 | eutectic: L + β' -> γ (L -> β' + γ) | L: Zn 0.63; β': Zn 0.57; γ: Zn 0.625 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 19; `ORC-XH2STLZQEJ` |  |
| 858 | peritectic: L + γ -> γ3 | L: Zn 0.845; γ: Zn 0.76; γ3: Zn 0.795 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 22; `ORC-INQC2V7U2K` |  |
| 855 | peritectic: L + γ -> γ3 | L: Zn 0.821; γ: Zn 0.741; γ3: Zn 0.793 | model | [1] Liu 2003 | Table 4, p. 7, row 23; `ORC-TZ4JHTINP5` |  |
| 794 | peritectoid: γ + γ3 -> γ2 | γ: Zn 0.742; γ3: Zn 0.79; γ2: Zn 0.75 | model | [1] Liu 2003 | Table 4, p. 7, row 25; `ORC-K5CPRBXBXU` |  |
| 793 | peritectoid: γ + γ3 -> γ2 | γ: Zn 0.74; γ3: Zn 0.78; γ2: Zn 0.75 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 24; `ORC-WEHG3E7YUV` |  |
| 763 | peritectic: L + γ3 -> ϵ | L: Zn 0.917; γ3: Zn 0.833; ϵ: Zn 0.875 | model | [1] Liu 2003 | Table 4, p. 7, row 27; `ORC-FQMEGJ7VWZ` |  |
| 763 | peritectic: L + γ3 -> ϵ | L: Zn 0.92; γ3: Zn 0.835; ϵ: Zn 0.88 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 26; `ORC-OKTREBUWTJ` |  |
| 718 | peritectic: L + ϵ -> (Zn) | L: Zn 0.958; ϵ: Zn 0.898; (Zn): Zn 0.948 | model | [1] Liu 2003 | Table 4, p. 7, row 31; `ORC-LXZR5ZJABP` |  |
| 711 | peritectic: L + ϵ -> (Zn) | L: Zn 0.96; ϵ: Zn 0.89; (Zn): Zn 0.925 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 30; `ORC-KB2I5BKXA3` |  |
| 676 | eutectoid: (Au) -> α1 + β' | (Au): Zn 0.295; α1: Zn 0.27; β': Zn 0.38 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 7; `ORC-5XGED6RVW5` |  |
| 670 | eutectoid: (Au) -> α1 + β' | (Au): Zn 0.292; α1: Zn 0.275; β': Zn 0.383 | model | [1] Liu 2003 | Table 4, p. 7, row 8; `ORC-M6IUQT54VW` |  |
| 578 | peritectoid: α1 + β' -> Au5Zn3 | α1: Zn 0.291; β': Zn 0.415; Au5Zn3: Zn 0.375 | model | [1] Liu 2003 | Table 4, p. 7, row 13; `ORC-E2JSO2YIAC` |  |
| 573 | peritectoid: (Au) + α1 -> α3 | (Au): Zn 0.18; α1: Zn 0.215; α3: Zn 0.19 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 1; `ORC-JE473AAQD2` |  |
| 573 | peritectoid: α1 + β' -> Au5Zn3 | α1: Zn 0.29; β': Zn 0.405; Au5Zn3: Zn 0.375 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 12; `ORC-RK7VGI7YFF` |  |
| 572 | peritectoid: (Au) + α1 -> α3 | (Au): Zn 0.16; α1: Zn 0.22; α3: Zn 0.186 | model | [1] Liu 2003 | Table 4, p. 7, row 2; `ORC-AYODUS3NCC` |  |
| 458 | peritectoid: ε + γ3 ε' | γ3: Zn 0.8; ε': Zn 0.85 | model | [1] Liu 2003 | Table 4, p. 7, row 29; `ORC-VYDFNUJYRI` |  |
| 455 | peritectoid: β' + γ -> δ | β': Zn 0.545; γ: Zn 0.641; δ: Zn 0.56 | model | [1] Liu 2003 | Table 4, p. 7, row 18; `ORC-ZYZYW6QDIE` |  |
| 453 | peritectoid: β' + γ -> δ | β': Zn 0.525; γ: Zn 0.655; δ: Zn 0.56 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 17; `ORC-42PXVCWHGX` |  |
| 443 | peritectoid: ε + γ3 ε' | γ3: Zn 0.825; ε': Zn 0.85 | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 28; `ORC-NZE223DGRT` |  |

## Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json).

Table: Enthalpies of formation, Au–Zn system (8)

| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---:|---:|---|---:|---:|---|---|---|
| α2 |  | -19.009 kJ/mol (basis unstated) |  | model |  |  | [1] Liu 2003 | Table 3, p. 5, row 10; `ORC-FHWXTLJBTK.6e1421` |  |
| α2 |  | -17.061 kJ/mol (basis unstated) | 298.15 | experimental |  |  | [1] Liu 2003; _cites Carpenter 1967_ | Table 3, p. 5, row 9; `ORC-FNSBFXKYKJ.45f7d9` |  |
| α₁ |  | -16.944 kJ/mol (basis unstated) |  | model |  |  | [1] Liu 2003 | Table 3, p. 5, row 8; `ORC-USBSFDV7DO.aa204a` |  |
| α₁ |  | -16.73 kJ/mol (basis unstated) | 298.15 | experimental |  |  | [1] Liu 2003; _cites Carpenter 1967_ | Table 3, p. 5, row 7; `ORC-5P5SLQEDI3.209b46` |  |
| β' |  | -25.816 kJ/mol (basis unstated) | 298.15 | experimental |  |  | [1] Liu 2003; _cites Carpenter 1967_ | Table 3, p. 5, row 5; `ORC-LFQTU2SQLE.60339d` |  |
| β' |  | -25.81 kJ/mol (basis unstated) |  | model |  |  | [1] Liu 2003 | Table 3, p. 5, row 6; `ORC-VBWPJSR5CQ.b0e2c9` |  |
| β’ |  | -26.274 kJ/mol (basis unstated) |  | model |  |  | [1] Liu 2003 | Table 3, p. 5, row 4; `ORC-AJ5ITFWFUZ.33888e` |  |
| β’ |  | -25.711 kJ/mol (basis unstated) | 298.15 | experimental |  |  | [1] Liu 2003; _cites Carpenter 1967_ | Table 3, p. 5, row 3; `ORC-CVEJVGLXCL.36de6a` |  |

## Other properties

### Phase transition (8)

Table: Phase transition, Au–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 540 K | 540 | congruent transformation: α1 -> α2; _α1: Zn 0.25; α2: Zn 0.25_ | model | [1] Liu 2003 | Table 4, p. 7, row 6; `ORC-4DTZP2EQQU` |  |
| Phase transition | 543 K | 543 | congruent transformation: α1 -> α2; _α1: Zn 0.25; α2: Zn 0.25_ | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 5; `ORC-2VSDBRPHXB` |  |
| Phase transition | 681 K | 681 | congruent transformation: (Au) -> α1; _(Au): Zn 0.256; α1: Zn 0.25_ | model | [1] Liu 2003 | Table 4, p. 7, row 4; `ORC-GZXJVL5R6X` |  |
| Phase transition | 693 K | 693 | congruent transformation: (Au) -> α1; _(Au): Zn 0.25; α1: Zn 0.25_ | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 3; `ORC-37FY33Z4JJ` |  |
| Phase transition | 954 K | 954 | congruent melting: Lγ; _L: Zn 0.667; γ: Zn 0.692308_ | model | [1] Liu 2003 | Table 4, p. 7, row 32; `ORC-O36OAMEOR5` |  |
| Phase transition | 1008 K | 1008 | congruent melting: L -> β'; _L: Zn 0.491; β': Zn 0.5_ | model | [1] Liu 2003 | Table 4, p. 7, row 16; `ORC-HDUOLYGZP2` |  |
| Phase transition | 1024 K | 1024 | congruent melting: L -> β'; _L: Zn 0.5; β': Zn 0.5_ | experimental | [1] Liu 2003; _cites Okamoto 1989_ [doi](https://doi.org/10.1007/bf02882177) | Table 4, p. 7, row 14; `ORC-IMRHNO5KBJ` |  |
| Phase transition | 1031 K | 1031 | congruent melting: L -> β'; _L: Zn 0.485; β': Zn 0.5_ | experimental | [1] Liu 2003; _cites Pemsler 1971_ [doi](https://doi.org/10.1007/bf02662640) | Table 4, p. 7, row 15; `ORC-MSI4UM6S4S` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. H.S. Liu, K. Ishida, Z.P. Jin, Y. Du, Thermodynamic assessment of the Au–Zn binary system, Intermetallics 11, 987-994 (2003). [doi:10.1016/s0966-9795(03)00115-8](https://doi.org/10.1016/s0966-9795%2803%2900115-8)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).