# B–Ba–Ca–Sr system

> B–Ba–Ca–Sr system: 8 accepted literature values (invariant reaction 8) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/B-BA-CA-SR.html · Markdown: https://data.orchid-project.org/systems/B-BA-CA-SR.md

8 accepted literature values from 1 paper(s) (model 8); 0 calculated phase diagram(s).

Data: [JSON](https://data.orchid-project.org/literature/systems/B-BA-CA-SR.json) · [CSV](https://data.orchid-project.org/systems/B-BA-CA-SR.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#B-BA-CA-SR) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/B-BA-CA-SR.html) · [Markdown](https://data.orchid-project.org/systems/B-BA-CA-SR.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| model | 8 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 8 |

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the B–Ba–Ca–Sr system (8)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 3435 | gas + liq2 = CaB6 | gas: Ca 0.954; liq2: Ca 0.0095; CaB6: Ca 0.143 | model | [1] Shang 2007 | Table 4, p. 5, row 2; `ORC-JSHODT4JDT` |  |
| 3245 | gas + liq2 = BaB6 | gas: Ba 0.984; liq2: Ba 0.072; BaB6: Ba 0.143 | model | [1] Shang 2007 | Table 4, p. 5, row 16; `ORC-EYRA56WAV5` |  |
| 3228 | gas + liq2 = SrB6 | gas: Sr 0.985; liq2: Sr 0.012; SrB6: Sr 0.143 | model | [1] Shang 2007 | Table 4, p. 5, row 9; `ORC-BJE63KQACH` |  |
| 2348 | liq2 = SrB6 + β(B) | liq2: Sr 0; SrB6: Sr 0.143; β(B): Sr 0 | model | [1] Shang 2007 | Table 4, p. 5, row 10; `ORC-EZKFOO5XBF` |  |
| 2348 | liq2 = CaB6 + β(B) | liq2: Ca 0; CaB6: Ca 0.143; β(B): Ca 0 | model | [1] Shang 2007 | Table 4, p. 5, row 3; `ORC-NLBP7KR4VE` |  |
| 2348 | liq2 = BaB6 + β(B) | liq2: Ba 0; BaB6: Ba 0.143; β(B): Ba 0 | model | [1] Shang 2007 | Table 4, p. 5, row 17; `ORC-OWDSWV67RQ` |  |
| 2238 | BaB6 + gas = liq1 | BaB6: Ba 0.143; gas: Ba 1; liq1: Ba 0.893 | model | [1] Shang 2007 | Table 4, p. 5, row 18; `ORC-U7U2NNFN3J` |  |
| 1776 | CaB6 + gas = liq1 | CaB6: Ca 0.143; gas: Ca 1; liq1: Ca 0.984 | model | [1] Shang 2007 | Table 4, p. 5, row 4; `ORC-2SXAWEXUOH` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Shunli Shang, Tao Wang, Zi-Kui Liu, Thermodynamic modelling of the B–Ca, B–Sr and B–Ba systems, Calphad 31, 286-291 (2007). [doi:10.1016/j.calphad.2006.11.005](https://doi.org/10.1016/j.calphad.2006.11.005)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).
