B–Ni–Si system

22 accepted literature values from 1 paper(s) (model 22); 0 calculated phase diagram(s).

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Accepted values by evidence class
Evidence class	Values
model	22

Accepted values by property group
Property group	Values
invariant reaction	22

Invariant reactions (literature)

Invariant reactions reported in the literature for the B–Ni–Si system (22)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1543.15	L + (Si) + SiB6 -> SiB3	L: B 0.145, Si 0.697	model	[1] Tokunaga 2001	Table 3, p. 8, row 22 report
1367.15	L + Ni5Si2 (γ) -> Ni2Si (δ) + Ni6Si2B	L: B 0.143, Si 0.229	model	[1] Tokunaga 2001	Table 3, p. 8, row 21 report
1352.15	L + Ni2Si (δ) -> Ni6Si2B + Ni4.29Si2B1.43	L: B 0.16, Si 0.232	model	[1] Tokunaga 2001	Table 3, p. 8, row 20 report
1330.15	L + Ni5Si2 (γ) -> Ni3Si (β2) + Ni6Si2B	L: B 0.112, Si 0.166	model	[1] Tokunaga 2001	Table 3, p. 8, row 19 report
1320.15	L + Ni2Si (δ) -> Ni2Si (θ) + Ni4.29Si2B1.43	L: B 0.107, Si 0.345	model	[1] Tokunaga 2001	Table 3, p. 8, row 18 report
1308.15	L + fcc + Ni3Si (β2) -> Ni3Si (β1)	L: B 0.111, Si 0.152	model	[1] Tokunaga 2001	Table 3, p. 8, row 17 report
1304.15	L + Ni3Si (β2) -> Ni3Si (β1) + Ni6Si2B	L: B 0.116, Si 0.15	model	[1] Tokunaga 2001	Table 3, p. 8, row 16 report
1303.15	L + (B) -> NiB + SiBn	L: B 0.494, Si 0.006	model	[1] Tokunaga 2001	Table 3, p. 8, row 15 report
1301.15	L + Ni3Si (β1) -> fcc + Ni6Si2B	L: B 0.118, Si 0.148	model	[1] Tokunaga 2001	Table 3, p. 8, row 14 report
1294.15	L + SiB6 -> SiBn + Ni4.29Si2B1.43	L: B 0.323, Si 0.178	model	[1] Tokunaga 2001	Table 3, p. 8, row 13 report
1277.15	L -> fcc + Ni3B + Ni6Si2B	L: B 0.15, Si 0.122	model	[1] Tokunaga 2001	Table 3, p. 8, row 12 report
1268.15	L -> Ni3B + Ni2B + Ni6Si2B	L: B 0.236, Si 0.089	model	[1] Tokunaga 2001	Table 3, p. 8, row 11 report
1213.15	L + Ni2B -> o-Ni4B3 + Ni6Si2B	L: B 0.327, Si 0.0768	model	[1] Tokunaga 2001	Table 3, p. 8, row 10 report
1212.15	L + o-Ni4B3 -> m-Ni4B3 + Ni6Si2B	L: B 0.3274, Si 0.077	model	[1] Tokunaga 2001	Table 3, p. 8, row 9 report
1211.15	L + (Si) -> NiSi2 + SiB3	L: B 0.115, Si 0.526	model	[1] Tokunaga 2001	Table 3, p. 8, row 8 report
1209.15	L + SiB3 -> NiSi2 + SiB6	L: B 0.116, Si 0.523	model	[1] Tokunaga 2001	Table 3, p. 8, row 7 report
1178.15	L + m-Ni4B3 -> NiB + Ni6Si2B	L: B 0.352, Si 0.101	model	[1] Tokunaga 2001	Table 3, p. 8, row 6 report
1169.15	L + SiBn -> NiB + Ni4.29Si2B1.43	L: B 0.36, Si 0.115	model	[1] Tokunaga 2001	Table 3, p. 8, row 5 report
1168.15	L -> NiB + Ni6Si2B + Ni4.29Si2B1.43	L: B 0.353, Si 0.113	model	[1] Tokunaga 2001	Table 3, p. 8, row 4 report
1167.15	L + Ni2Si (θ) -> NiSi + Ni4.29Si2B1.43	L: B 0.092, Si 0.403	model	[1] Tokunaga 2001	Table 3, p. 8, row 3 report
1154.15	L -> NiSi + NiSi2 + SiB6	L: B 0.117, Si 0.471	model	[1] Tokunaga 2001	Table 3, p. 8, row 2 report
1136.15	L -> NiSi + SiB6 + Ni4.29Si2B1.43	L: B 0.139, Si 0.397	model	[1] Tokunaga 2001	Table 3, p. 8, row 1 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

T. Tokunaga, K. Nishio, M. Hasebe, Thermodynamic study of phase equilibria in the Ni-Si-B system, JPE 22, 291-299 (2001). doi:10.1361/105497101770338798

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}