Bi–Cr–Ti–V system

23 accepted literature values from 1 paper(s) (experimental 11, model 12); 0 calculated phase diagram(s).

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Accepted values by evidence class
Evidence class	Values
experimental	11
model	12

Accepted values by property group
Property group	Values
invariant reaction	21
crystal structure	2

Invariant reactions (literature)

Invariant reactions reported in the literature for the Bi–Cr–Ti–V system (21)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
2157.95	Liquid#1=Gas+(V)	Liquid#1: Bi 0.017; Gas: Bi 0.999; (V): Bi 0.22	model	[1] Cao 2013	Table 3, p. 5, row 25 report
2150.15	Liquid#1=Gas+(V)	Liquid#1: Bi 0.021; Gas: Bi 0.998; (V): Bi 0.13	experimental	[1] Cao 2013 cites Smith 1990	Table 3, p. 5, row 24 report
1849.15	Gas+(V)=Liquid#2	Gas: Bi 0.999; (V): Bi 0.0035; Liquid#2: Bi 0.989	experimental	[1] Cao 2013 cites Smith 1990	Table 3, p. 5, row 22 report
1840.95	Liquid#1+Gas=Liquid#2	Liquid#1: Bi 0.151; Gas: Bi 0.999; Liquid#2: Bi 0.937	model	[1] Cao 2013	Table 3, p. 5, row 15 report
1832.15	Liquid#1=Liquid#2+(Cr)	Liquid#1: Bi 0.15; Liquid#2: Bi 0.938; (Cr): Bi 0	model	[1] Cao 2013	Table 3, p. 5, row 17 report
1831.55	Gas+(V)=Liquid#2	Gas: Bi 0.999; (V): Bi 0.0045; Liquid#2: Bi 0.973	model	[1] Cao 2013	Table 3, p. 5, row 23 report
1826.15	Liquid#1=Liquid#2+(Cr)	Liquid#2: Bi 0.91; (Cr): Bi 0	experimental	[1] Cao 2013 cites Williams 1907	Table 3, p. 5, row 16 report
1613.15	Liquid+Bcc_A2=BiTi3	Liquid: Bi 0.26; Bcc_A2: Bi 0.1; BiTi3: Bi 0.25	experimental	[1] Cao 2013 cites Obinata 1960	Table 3, p. 5, row 11 report
1609.15	Liquid+Bcc_A2=BiTi3	Liquid: Bi 0.255; Bcc_A2: Bi 0.105; BiTi3: Bi 0.25	model	[1] Cao 2013	Table 3, p. 5, row 12 report
1562.65	Liquid+BiTi3=BiTi2	Liquid: Bi 0.397; BiTi3: Bi 0.25; BiTi2: Bi 0.333	model	[1] Cao 2013	Table 3, p. 5, row 10 report
1560.15	Liquid+BiTi3=BiTi2	BiTi3: Bi 0.25; BiTi2: Bi 0.333	experimental	[1] Cao 2013 cites Vasseilev 2006	Table 3, p. 5, row 9 report
1270.95	Liquid+BiTi2=Bi9Ti8	Liquid: Bi 0.749; BiTi2: Bi 0.333; Bi9Ti8: Bi 0.529	model	[1] Cao 2013	Table 3, p. 5, row 8 report
1270.15	Liquid+BiTi2=Bi9Ti8	BiTi2: Bi 0.333; Bi9Ti8: Bi 0.529	experimental	[1] Cao 2013 cites Vasseilev 2006	Table 3, p. 5, row 7 report
1090.35	Liquid+Bi9Ti8=Bi3Ti2	Liquid: Bi 0.934; Bi9Ti8: Bi 0.529; Bi3Ti2: Bi 0.6	model	[1] Cao 2013	Table 3, p. 5, row 6 report
1090.15	Liquid+Bi9Ti8=Bi3Ti2	Bi9Ti8: Bi 0.529; Bi3Ti2: Bi 0.6	experimental	[1] Cao 2013 cites Vasseilev 2006	Table 3, p. 5, row 5 report
998.15	Bcc_A2=BiTi3+Hcp_A3	Bcc_A2: Bi 0.086; BiTi3: Bi 0.25; Hcp_A3: Bi 0.003	experimental	[1] Cao 2013 cites Obinata 1960	Table 3, p. 5, row 13 report
992.65	Bcc_A2=BiTi3+Hcp_A3	Bcc_A2: Bi 0.06; BiTi3: Bi 0.25; Hcp_A3: Bi 0.004	model	[1] Cao 2013	Table 3, p. 5, row 14 report
960.65	Liquid+Bi3Ti2=Bi2Ti	Liquid: Bi 0.976; Bi3Ti2: Bi 0.6; Bi2Ti: Bi 0.6	model	[1] Cao 2013	Table 3, p. 5, row 4 report
960.15	Liquid+Bi3Ti2=Bi2Ti	Bi3Ti2: Bi 0.6; Bi2Ti: Bi 0.6	experimental	[1] Cao 2013 cites Vasseilev 2006	Table 3, p. 5, row 3 report
544.55	Liquid#2=(Bi)+(V)		experimental	[1] Cao 2013 cites Smith 1990	Table 3, p. 5, row 20 report
544.15	Liquid=Bi2Ti+(Bi)	Bi2Ti: Bi 0.667; (Bi): Bi 1	experimental	[1] Cao 2013 cites Vasseilev 2006	Table 3, p. 5, row 1 report

Other properties

Crystal structure (2)

Crystal structure, Bi–Cr–Ti–V system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Lattice a	4.746 Å	298.15	(Bi) alloy: Cr 0, Ti 0, V 0	model	[1] Cao 2013 cites King 1981	Table 1, p. 2, row 9 report
Lattice a	4.746 Å	544.55 (<)	(Bi) alloy: Cr 0, Ti 0, V 0	model	[1] Cao 2013 cites King 1981	Table 1, p. 2, row 1 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Z. Cao, J. Xin, C. Chen, S. Liu, B. Hu, C. Tang et al., Thermodynamic modeling of the Bi-M (M = Ti, Cr, V) systems, J min metall B Metall 49, 307-313 (2013). doi:10.2298/jmmb130127033c

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}