# Bi–In–Sn system

> Bi–In–Sn system: 13 accepted literature values (invariant reaction 13) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/BI-IN-SN.html · Markdown: https://data.orchid-project.org/systems/BI-IN-SN.md

13 accepted literature values from 1 paper(s) (experimental 7, model 4, unspecified 2); 0 calculated phase diagram(s).

Data: [JSON](https://data.orchid-project.org/literature/systems/BI-IN-SN.json) · [CSV](https://data.orchid-project.org/systems/BI-IN-SN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#BI-IN-SN) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/BI-IN-SN.html) · [Markdown](https://data.orchid-project.org/systems/BI-IN-SN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 7 |
| model | 4 |
| unspecified | 2 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 13 |

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Bi–In–Sn system (13)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 497.15 | liquid + bct(Sn) -> γ | liquid: Sn 0.957; bct(Sn): Sn 0.995; γ: Sn 0.99 | experimental | [1] Lee 1996; _cites Heumann 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990115-8) | Table I, p. 8, row 10; `ORC-NYSH25YJLC` |  |
| 496.55 | liquid + bct(Sn) -> γ | liquid: Sn 0.958; bct(Sn): Sn 0.986; γ: Sn 0.975 | model | [1] Lee 1996 | Table I, p. 8, row 9; `ORC-H5XJZ53SEN` |  |
| 495.75 | liquid + bct(Sn) -> γ | liquid: Sn 0.952; bct(Sn): Sn 0.99; γ: Sn 0.985 | experimental | [1] Lee 1996; _cites Evans 1983_ | Table I, p. 8, row 11; `ORC-A6DH34K4RA` |  |
| 416.15 | tet(In) + liquid -> β | tet(In): Sn 0.1; liquid: Sn 0.14; β: Sn 0.12 | experimental | [1] Lee 1996; _cites Heumann 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990115-8) | Table I, p. 8, row 2; `ORC-5GK3WPVE2K` |  |
| 415.15 | tet(In) + liquid -> β | tet(In): Sn 0.114; liquid: Sn 0.142; β: Sn 0.122 | model | [1] Lee 1996 | Table I, p. 8, row 1; `ORC-RI64MWUGJV` |  |
| 414.15 | tet(In) + liquid -> β | tet(In): Sn 0.115; liquid: Sn 0.14; β: Sn 0.12 | experimental | [1] Lee 1996; _cites Evans 1983_ | Table I, p. 8, row 3; `ORC-CP2QU43UDC` |  |
| 413.15 | tet(In) + liquid -> β | tet(In): Sn 0.087; liquid: Sn 0.147; β: Sn 0.111 | unspecified | [1] Lee 1996; _cites Kaplun 1983_ | Table I, p. 8, row 4; `ORC-L5EDGMJM7X` |  |
| 411.95 | liquid -> rho(Bi) + bct(Sn) | liquid: Sn 0.571; rho(Bi): Sn 0.002; bct(Sn): Sn 0.869 | model | [1] Lee 1996 | Table I, p. 8, row 12; `ORC-KDWDUBBU35` |  |
| 411.15 | liquid -> rho(Bi) + bct(Sn) | liquid: Sn 0.565; bct(Sn): Sn 0.87 | experimental | [1] Lee 1996; _cites Nagasaki 1952_ [doi](https://doi.org/10.2320/jinstmet1952.16.6_317) | Table I, p. 8, row 13; `ORC-CEQZHZJQHU` |  |
| 393.15 | liquid -> β + γ | liquid: Sn 0.483; β: Sn 0.44; γ: Sn 0.77 | experimental | [1] Lee 1996; _cites Heumann 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990115-8) | Table I, p. 8, row 6; `ORC-NXPDNCZ6YO` |  |
| 392.15 | liquid -> β + γ | liquid: Sn 0.474; β: Sn 0.442; γ: Sn 0.765 | experimental | [1] Lee 1996; _cites Evans 1983_ | Table I, p. 8, row 7; `ORC-7B3QMUC35U` |  |
| 391.55 | liquid -> β + γ | liquid: Sn 0.466; β: Sn 0.432 | unspecified | [1] Lee 1996; _cites Kaplun 1983_ | Table I, p. 8, row 8; `ORC-652VFMTBCQ` |  |
| 391.15 | liquid -> β + γ | liquid: Sn 0.475; β: Sn 0.446; γ: Sn 0.768 | model | [1] Lee 1996 | Table I, p. 8, row 5; `ORC-LRGHNWRTRY` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Byeong-Joo Lee, Chang-Seok Oh, Jae-Hyeok Shim, Thermodynamic assessments of the Sn-In and Sn-Bi binary systems, J. Electron. Mater. 25, 983-991 (1996). [doi:10.1007/bf02666734](https://doi.org/10.1007/bf02666734)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).
