# Bi–Pb–U system

> Bi–Pb–U system: 72 accepted literature values (mixing / partial 72) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/BI-PB-U.html · Markdown: https://data.orchid-project.org/systems/BI-PB-U.md

72 accepted literature values from 1 paper(s) (experimental 72); 0 calculated phase diagram(s).

Data: [JSON](https://data.orchid-project.org/literature/systems/BI-PB-U.json) · [CSV](https://data.orchid-project.org/systems/BI-PB-U.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#BI-PB-U) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/BI-PB-U.html) · [Markdown](https://data.orchid-project.org/systems/BI-PB-U.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 72 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| mixing / partial | 72 |

## Other properties

### Mixing / partial (72)

Table: Mixing / partial, Bi–Pb–U system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.069 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.4437_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 14; `ORC-257DHT5FC2` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.093 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.5101_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 15; `ORC-46TRZ4AVDG` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.975 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.3439_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 26; `ORC-5NUVIYZ2QN` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.732 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.773_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 2; `ORC-7SZ2PK7AZU` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.087 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.5502_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 4; `ORC-ASI32TVI7E` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.075 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.5502_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 16; `ORC-E7EYR3253U` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.287 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.9157_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 1; `ORC-EOBMIMFLOP` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.326 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.0984_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 11; `ORC-FC6VU2OJDA` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.079 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.5502_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 29; `ORC-GD3MD76ONA` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.003 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.6307_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 3; `ORC-IUBDHRKNAW` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.682 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.204_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 25; `ORC-LK3LFXTWLL` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.005 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.3716_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 13; `ORC-LYE3FXCFYP` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.092 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.5179_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 28; `ORC-MT7XYBA2EF` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -0.815 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.2635_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 12; `ORC-ONXC2COTC3` |  |
| Enthalpy of mixing; _printed: ΔH^bmix_ | -1.076 kJ/mol (basis unstated) | 843 | (Bi,Pb)liq; _alloy: Bi 0.443_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 27; `ORC-ZCVDMCZXO3` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -3.805 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0275_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 6; `ORC-2KLHD5XTQF.45c648` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -4.145 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0275_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 6; `ORC-2KLHD5XTQF.703329` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -11.638 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0789_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 21; `ORC-2VIUQAXVRG.8870d7` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -12.614 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0789_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 21; `ORC-2VIUQAXVRG.bde24c` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -6.784 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0422_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 32; `ORC-47YSDMAPXR.4c34aa` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -6.262 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0422_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 32; `ORC-47YSDMAPXR.b1f489` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -2.192 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0155_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 17; `ORC-62J7W7RMMY.76abac` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -2.384 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0155_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 17; `ORC-62J7W7RMMY.bf5592` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -15.731 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0972_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 22; `ORC-AGJUGAIUGU.163392` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -14.529 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0972_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 22; `ORC-AGJUGAIUGU.fa0cbf` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -7.172 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0489_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 7; `ORC-C7GKIO4O6Q.008a24` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -7.775 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0489_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 7; `ORC-C7GKIO4O6Q.717744` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -9.849 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0617_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 20; `ORC-DQPZEV4K6T.75cb62` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -9.086 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0617_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 20; `ORC-DQPZEV4K6T.ee6c60` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -18.779 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1264_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 24; `ORC-FZWUQ4VHXE.229e07` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -20.341 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1264_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 24; `ORC-FZWUQ4VHXE.4a04fa` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -3.8 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.027_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 31; `ORC-I3GP566CXU.18050f` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -4.134 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.027_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 31; `ORC-I3GP566CXU.7b8e0c` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -12.498 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0785_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 8; `ORC-KLFQKMT7N5.3968e9` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -11.528 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0785_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 8; `ORC-KLFQKMT7N5.fe36b0` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -21.564 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1335_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 10; `ORC-LPDJOIFQJX.b000db` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -19.914 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1335_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 10; `ORC-LPDJOIFQJX.bd1642` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -5.607 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0345_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 18; `ORC-MBRN5EF6IM.6ec8d6` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -5.181 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0345_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 18; `ORC-MBRN5EF6IM.de9277` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -8.244 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0512_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 19; `ORC-QSVCPEXXDY.83e20d` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -7.612 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0512_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 19; `ORC-QSVCPEXXDY.b9c58e` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -1.711 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0128_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 30; `ORC-S2FJR2ITVL.314699` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -1.869 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0128_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 30; `ORC-S2FJR2ITVL.822252` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -13.065 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0886_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 34; `ORC-SXNR3XVTU2.08df2c` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -14.16 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0886_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 34; `ORC-SXNR3XVTU2.cf0fc4` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -15.939 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1075_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 9; `ORC-WWUY7QUSWH.476868` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -17.267 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1075_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 9; `ORC-WWUY7QUSWH.60784d` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -0.863 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0047_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 5; `ORC-X3SEE2B46F.53a0e9` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -0.805 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0047_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 5; `ORC-X3SEE2B46F.e30d6d` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -10.123 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0636_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 33; `ORC-XHNYTVSHE2.13d4fd` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -9.337 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.0636_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 33; `ORC-XHNYTVSHE2.e668a8` |  |
| Enthalpy of mixing; _printed: Δ2H^Pbmix_ | -17.955 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1114_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 23; `ORC-XUSHVA4NLJ.8ce065` |  |
| Enthalpy of mixing; _printed: Δ1H^Pbmix_ | -16.579 kJ/mol (basis unstated) | 843 | LBE(l); _alloy: U 0.1114_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 23; `ORC-XUSHVA4NLJ.e0bd4d` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -144.045 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0275_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 6; `ORC-2KLHD5XTQF.4b094f` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -160.13 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0789_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 21; `ORC-2VIUQAXVRG.3d6907` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -173.26 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0422_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 32; `ORC-47YSDMAPXR.ccfb25` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -153.359 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0155_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 17; `ORC-62J7W7RMMY.ae6787` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -169.787 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0972_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 22; `ORC-AGJUGAIUGU.1b860a` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -169.994 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0489_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 7; `ORC-C7GKIO4O6Q.ea68b0` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -153.092 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0617_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 20; `ORC-DQPZEV4K6T.a19145` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -159.148 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.1264_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 24; `ORC-FZWUQ4VHXE.5411c7` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -160.025 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.027_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 31; `ORC-I3GP566CXU.e74733` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -158.894 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0785_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 8; `ORC-KLFQKMT7N5.ed73b5` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -164.504 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.1335_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 10; `ORC-LPDJOIFQJX.e02b28` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -170.094 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0345_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 18; `ORC-MBRN5EF6IM.abd035` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -157.802 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0512_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 19; `ORC-QSVCPEXXDY.8c4f56` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -145.653 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0128_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 30; `ORC-S2FJR2ITVL.8bfe4d` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -161.247 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0886_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 34; `ORC-SXNR3XVTU2.a3afa0` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -164.144 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.1075_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 9; `ORC-WWUY7QUSWH.5d7c49` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -184.376 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0047_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 5; `ORC-X3SEE2B46F.a487ed` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -156.307 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.0636_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 33; `ORC-XHNYTVSHE2.20bc58` |  |
| Partial enthalpy; _printed: ΔiHU^mix_ | -157.653 kJ/mol-atom | 843 | LBE(l); _alloy: U 0.1114_ | experimental | [1] Agarwal 2021 | Table 6, p. 10, row 23; `ORC-XUSHVA4NLJ.4a505e` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Renu Agarwal, Understanding uranium interactions with bismuth and lead-bismuth eutectic: Using calorimetric measurements, Thermochimica Acta 699, 178913 (2021). [doi:10.1016/j.tca.2021.178913](https://doi.org/10.1016/j.tca.2021.178913)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).