# Bi–Sb–Sn system

> Bi–Sb–Sn system: 52 accepted literature values (phase transition 52) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/BI-SB-SN.html · Markdown: https://data.orchid-project.org/systems/BI-SB-SN.md

52 accepted literature values from 1 paper(s) (experimental 52); 0 calculated phase diagram(s). 17 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/BI-SB-SN.json) · [CSV](https://data.orchid-project.org/systems/BI-SB-SN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#BI-SB-SN) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/BI-SB-SN.html) · [Markdown](https://data.orchid-project.org/systems/BI-SB-SN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 52 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| phase transition | 52 |

## Other properties

### Phase transition (52)

Table: Phase transition, Bi–Sb–Sn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 419.15 K | 419.15 | other: Bi-Sn 50.0/50.0; _alloy: Bi 0.5, Sb 0, Sn 0.5_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 7; `ORC-5XJOI6QGCU` |  |
| Phase transition | 424.15 K | 424.15 | other: Bi-Sn 36.3/63.7; _alloy: Bi 0.363, Sb 0, Sn 0.637_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 9; `ORC-4OXYJKJKNU` |  |
| Phase transition | 437.15 K | 437.15 | other: Bi-Sn 56.8/43.2; _alloy: Bi 0.568, Sb 0, Sn 0.432_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 5; `ORC-BCKXIE5R4N` |  |
| Phase transition | 443.15 K | 443.15 | other: Bi-Sn 27.5/72.5; _alloy: Bi 0.275, Sb 0, Sn 0.725_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 11; `ORC-VZ7VJON2I7` |  |
| Phase transition | 469.15 K | 469.15 | other: Bi-Sn 69.8/30.2; _alloy: Bi 0.698, Sb 0, Sn 0.302_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 3; `ORC-EWIQKZUEZZ` |  |
| Phase transition | 472.15 K | 472.15 | other: Bi-Sn 12.4/87.6; _alloy: Bi 0.124, Sb 0, Sn 0.876_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 13; `ORC-DYUJZOFYFV` |  |
| Phase transition | 476.15 K | 476.15 | other: Bi15 Sn80 Sb5 liquidus; _alloy: Bi 0.15, Sb 0.05, Sn 0.8_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 44; `ORC-ZUFEBEIM7A` |  |
| Phase transition | 478.15 K | 478.15 | other: Bi-Sn 5.9/94.1; _alloy: Bi 0.059, Sb 0, Sn 0.941_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 15; `ORC-ZVOLCXBKEP` |  |
| Phase transition | 481.15 K | 481.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 66; `ORC-JM557XXLJB` |  |
| Phase transition | 484.15 K | 484.15 | other: Bi15 Sn80 Sb5 liquidus; _alloy: Bi 0.15, Sb 0.05, Sn 0.8_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 46; `ORC-HYHB6CSMUT` |  |
| Phase transition | 498.15 K | 498.15 | other: Bi-Sn 83.6/16.4; _alloy: Bi 0.836, Sb 0, Sn 0.164_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 1; `ORC-HX3WVG45KZ` |  |
| Phase transition | 519.15 K | 519.15 | other: Bi30 Sn60 Sb10 liquidus; _alloy: Bi 0.3, Sb 0.1, Sn 0.6_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 40; `ORC-YLGJE76RUI` |  |
| Phase transition | 524.15 K | 524.15 | other: Bi50 Sn40 Sb10 liquidus; _alloy: Bi 0.5, Sb 0.1, Sn 0.4_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 37; `ORC-VTO2YGE26G` |  |
| Phase transition | 530.15 K | 530.15 | other: Bi30 Sn60 Sb10 liquidus; _alloy: Bi 0.3, Sb 0.1, Sn 0.6_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 42; `ORC-UUNVVNAJ7P` |  |
| Phase transition | 533.15 K | 533.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 53; `ORC-ECLBVH7AK6` |  |
| Phase transition | 554.15 K | 554.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 67; `ORC-V3EDGIHAKX` |  |
| Phase transition | 561.15 K | 561.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 68; `ORC-PGADITX5VF` |  |
| Phase transition | 570.15 K | 570.15 | other: Bi20 Sn60 Sb20 liquidus; _alloy: Bi 0.2, Sb 0.2, Sn 0.6_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 39; `ORC-E3P7YKVP4S` |  |
| Phase transition | 576.15 K | 576.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 62; `ORC-5CMRKW4VRB` |  |
| Phase transition | 580.15 K | 580.15 | other: Bi40 Sn40 Sb20 liquidus; _alloy: Bi 0.4, Sb 0.2, Sn 0.4_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 36; `ORC-K7SVEYFT27` |  |
| Phase transition | 583.15 K | 583.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 65; `ORC-B36OM2BJX4` |  |
| Phase transition | 596.15 K | 596.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 52; `ORC-YHW5EQN6JQ` |  |
| Phase transition | 596.15 K | 596.15 | other: Bi-Sb 90.5/9.5; _alloy: Bi 0.905, Sb 0.095, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 16; `ORC-U4Y4CEXQCI` |  |
| Phase transition | 620.15 K | 620.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 61; `ORC-SB2GS25KAV` |  |
| Phase transition | 629.15 K | 629.15 | other: Bi-Sb 80.3/19.7; _alloy: Bi 0.803, Sb 0.197, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 18; `ORC-5PAZGFBXTQ` |  |
| Phase transition | 629.15 K | 629.15 | other: Bi10 Sn60 Sb30 liquidus; _alloy: Bi 0.1, Sb 0.3, Sn 0.6_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 38; `ORC-DSSN53QGNZ` |  |
| Phase transition | 630.15 K | 630.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 64; `ORC-E3AIMF2WA3` |  |
| Phase transition | 639.15 K | 639.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 57; `ORC-V74A5APXZQ` |  |
| Phase transition | 641.15 K | 641.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 63; `ORC-DA2EPFZCHB` |  |
| Phase transition | 646.15 K | 646.15 | other: Bi25 Sn40 Sb35 liquidus; _alloy: Bi 0.25, Sb 0.35, Sn 0.4_ | experimental | [1] Ohtani 1994 | Table V, p. 8, row 34; `ORC-OFP36ZAVAZ` |  |
| Phase transition | 657.15 K | 657.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 51; `ORC-VW2WNRCGYV` |  |
| Phase transition | 660.15 K | 660.15 | other: Bi-Sb 70.1/29.9; _alloy: Bi 0.701, Sb 0.299, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 22; `ORC-5HIBAKNCQE` |  |
| Phase transition | 665.15 K | 665.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 60; `ORC-FAQPSO4G6K` |  |
| Phase transition | 685.15 K | 685.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 56; `ORC-6ZA4RQMODQ` |  |
| Phase transition | 695.15 K | 695.15 | other: Bi-Sb 72.0/28.0; _alloy: Bi 0.72, Sb 0.28, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 20; `ORC-ZJQEBTPDVZ` |  |
| Phase transition | 699.15 K | 699.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 50; `ORC-5SFHXQFGX3` |  |
| Phase transition | 713.15 K | 713.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 59; `ORC-7GDZWNCVTA` |  |
| Phase transition | 715.15 K | 715.15 | other: Bi-Sb 60.0/40.0; _alloy: Bi 0.6, Sb 0.4, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 23; `ORC-DC3ZOI66P5` |  |
| Phase transition | 720.15 K | 720.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 58; `ORC-CKWMBP4RBU` |  |
| Phase transition | 725.15 K | 725.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 55; `ORC-RZBMHID3ND` |  |
| Phase transition | 735.15 K | 735.15 | other: Bi-Sb 58.3/41.7; _alloy: Bi 0.583, Sb 0.417, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 24; `ORC-PQNILHLY4Y` |  |
| Phase transition | 742.15 K | 742.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 49; `ORC-D5CYUBDHXO` |  |
| Phase transition | 747.15 K | 747.15 | other: Bi-Sb 50.2/49.8; _alloy: Bi 0.502, Sb 0.498, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 26; `ORC-AGOYUOOJ3K` |  |
| Phase transition | 762.15 K | 762.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 54; `ORC-DOEOMEXJ7O` |  |
| Phase transition | 774.15 K | 774.15 | other: Bi-Sb 40.1/59.9; _alloy: Bi 0.401, Sb 0.599, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 28; `ORC-EPXPPDISUD` |  |
| Phase transition | 774.15 K | 774.15 | other: Bi-Sb 44.1/55.9; _alloy: Bi 0.441, Sb 0.559, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 27; `ORC-GR3QVN5ITD` |  |
| Phase transition | 778.15 K | 778.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 48; `ORC-DRQB5JQFOF` |  |
| Phase transition | 796.15 K | 796.15 | other: Bi-Sb 38.1/61.9; _alloy: Bi 0.381, Sb 0.619, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 29; `ORC-PR3DYMQU37` |  |
| Phase transition | 810.15 K | 810.15 | other | experimental | [1] Ohtani 1994 | Table V, p. 8, row 47; `ORC-HIGAR6IL7W` |  |
| Phase transition | 822.15 K | 822.15 | other: Bi-Sb 30.1/69.9; _alloy: Bi 0.301, Sb 0.699, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 31; `ORC-OEUCRLPWYP` |  |
| Phase transition | 846.15 K | 846.15 | other: Bi-Sb 19.1/80.9; _alloy: Bi 0.191, Sb 0.809, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 33; `ORC-DGD67YLZFJ` |  |
| Phase transition | 878.15 K | 878.15 | other: Bi-Sb 10.0/90.0; _alloy: Bi 0.1, Sb 0.9, Sn 0_ | experimental | [1] Ohtani 1994 | Table I, p. 2, row 34; `ORC-XYOIKKRPMW` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. H. Ohtani, K. Ishida, A thermodynamic study of the phase equilibria in the Bi-Sn-Sb system, JEM 23, 747-755 (1994). [doi:10.1007/bf02651369](https://doi.org/10.1007/bf02651369)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).