# Bi–Te system

> Bi–Te system: 92 accepted literature values (invariant reaction 54, phase equilibrium 14, crystal structure 12, formation 12) and 4 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/BI-TE.html · Markdown: https://data.orchid-project.org/systems/BI-TE.md

92 accepted literature values from 2 paper(s) (experimental 68, model 16, unspecified 8); 4 calculated phase diagram(s). 120 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/BI-TE.json) · [CSV](https://data.orchid-project.org/systems/BI-TE.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#BI-TE) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#BI-TE/BiTe-18Gie.json) · [phases (13)](https://data.orchid-project.org/phases/pages/BI-TE.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/BI-TE.html) · [Markdown](https://data.orchid-project.org/systems/BI-TE.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 68 |
| model | 16 |
| unspecified | 8 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 54 |
| phase equilibrium | 14 |
| formation | 12 |
| crystal structure | 12 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| BiTe-18Gie.tdb | W. Gierlotka, Calphad, 63, 6-11(2018). [doi:10.1016/j.calphad.2018.08.005](https://doi.org/10.1016/j.calphad.2018.08.005) | `e62921a019778da4d5e5384b559b125ef88e784e1b4d832bef5e7ba72c0f6564` | [viewer](https://orchid-project.org/phase-diagrams/#BI-TE/BiTe-18Gie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/BiTe-18Gie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/BiTe-18Gie.json) |
| BiTe-18Mao.tdb | C. Mao, M. Tan, L. Zhang, D. Wu, W. Bai, L. Liu, Calphad, 60, 81-89(2018). [doi:10.1016/j.calphad.2017.11.007](https://doi.org/10.1016/j.calphad.2017.11.007) | `48a482c6fa140bbaab54eaa9163d8aa9c983933077d401178a723eb044c1ba9b` | [viewer](https://orchid-project.org/phase-diagrams/#BI-TE/BiTe-18Mao.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/BiTe-18Mao.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/BiTe-18Mao.json) |
| BiTe-23Drz.tdb | S. Drzewowska, B. Onderka, J. Phase Equilib. Diffus., 44, 429-44(2023). [doi:10.1007/s11669-023-01049-9](https://doi.org/10.1007/s11669-023-01049-9) | `f0f0bd5a3c792778e02548758ebe877d643465cddc6b2da100735545be936ac3` | [viewer](https://orchid-project.org/phase-diagrams/#BI-TE/BiTe-23Drz.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/BiTe-23Drz.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/BiTe-23Drz.json) |
| BiTe-24Zho.tdb | J. Zhou, J. Wang, B. Hu, D. Cui, J. Phase Equilib. Diffus., 45, 89-113(2024). [doi:10.1007/s11669-024-01093-z](https://doi.org/10.1007/s11669-024-01093-z) | `2cbb5fbf130932bdae9ba54b68cbfba26166f66166312479595f0a1b4f6dc308` | [viewer](https://orchid-project.org/phase-diagrams/#BI-TE/BiTe-24Zho.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/BiTe-24Zho.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/BiTe-24Zho.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| BiTe-18Gie.tdb | 832.68 | LIQUID (x(Te) 0.45567) + BITE (x(Te) 0.56603) + BI2TE3_C33 (x(Te) 0.59697) |
| BiTe-18Gie.tdb | 713.01 | LIQUID (x(Te) 0.23695) + BI4TE3 (x(Te) 0.42857) + BITE (x(Te) 0.44321) |
| BiTe-18Gie.tdb | 695.99 | LIQUID (x(Te) 0.21371) + BITE (x(Te) 0.42665) + BI4TE3 (x(Te) 0.42857) |
| BiTe-18Gie.tdb | 688.72 | BI2TE3_C33 (x(Te) 0.60173) + LIQUID (x(Te) 0.88624) + HEXAGONAL_A8 (x(Te) 1) |
| BiTe-18Gie.tdb | 615.79 | LIQUID (x(Te) 0.10579) + BI2TE (x(Te) 0.33333) + BITE (x(Te) 0.35816) |
| BiTe-18Gie.tdb | 585.02 | LIQUID (x(Te) 0.06637) + BI2TE (x(Te) 0.33333) + BITE (x(Te) 0.33557) |
| BiTe-18Gie.tdb | 542.45 | RHOMBOHEDRAL_A7 (x(Te) 0) + LIQUID (x(Te) 0.02202) + BITE (x(Te) 0.30603) |
| BiTe-18Mao.tdb | 824.35 | LIQUID (x(Te) 0.43672) + BITE (x(Te) 0.53435) + BI2TE3_C33 (x(Te) 0.6) |
| BiTe-18Mao.tdb | 824.35 | LIQUID (x(Te) 0.43689) + BITE (x(Te) 0.5344) + BI2TE3_C33 (x(Te) 0.6) |
| BiTe-18Mao.tdb | 725.96 | LIQUID (x(Te) 0.22519) + BI4TE3 (x(Te) 0.42857) + BITE (x(Te) 0.44613) |
| BiTe-18Mao.tdb | 725.96 | LIQUID (x(Te) 0.22529) + BI4TE3 (x(Te) 0.42857) + BITE (x(Te) 0.44618) |
| BiTe-18Mao.tdb | 695.82 | LIQUID (x(Te) 0.18258) + BITE (x(Te) 0.42322) + BI4TE3 (x(Te) 0.42857) |
| BiTe-18Mao.tdb | 695.82 | LIQUID (x(Te) 0.18259) + BITE (x(Te) 0.42323) + BI4TE3 (x(Te) 0.42857) |
| BiTe-18Mao.tdb | 686.85 | BI2TE3_C33 (x(Te) 0.6) + LIQUID (x(Te) 0.91245) + HEXAGONAL_A8 (x(Te) 1) |
| BiTe-18Mao.tdb | 686.85 | BI2TE3_C33 (x(Te) 0.6) + LIQUID (x(Te) 0.91253) + HEXAGONAL_A8 (x(Te) 1) |
| BiTe-18Mao.tdb | 620.87 | LIQUID (x(Te) 0.09702) + BI2TE (x(Te) 0.33333) + BITE (x(Te) 0.36497) |
| BiTe-18Mao.tdb | 620.87 | LIQUID (x(Te) 0.09702) + BI2TE (x(Te) 0.33333) + BITE (x(Te) 0.36497) |
| BiTe-18Mao.tdb | 583.01 | LIQUID (x(Te) 0.06367) + BITE (x(Te) 0.33178) + BI2TE (x(Te) 0.33333) |
| BiTe-18Mao.tdb | 583.01 | LIQUID (x(Te) 0.0636) + BITE (x(Te) 0.3317) + BI2TE (x(Te) 0.33333) |
| BiTe-18Mao.tdb | 536.46 | RHOMBOHEDRAL_A7 (x(Te) 0) + LIQUID (x(Te) 0.03146) + BITE (x(Te) 0.27957) |
| BiTe-18Mao.tdb | 536.46 | RHOMBOHEDRAL_A7 (x(Te) 0) + LIQUID (x(Te) 0.0313) + BITE (x(Te) 0.2792) |
| BiTe-23Drz.tdb | 832.68 | LIQUID (x(Te) 0.45567) + BITE (x(Te) 0.56603) + BI2TE3_C33 (x(Te) 0.59697) |
| BiTe-23Drz.tdb | 694.45 | LIQUID (x(Te) 0.21161) + BI2TE (x(Te) 0.33333) + BITE (x(Te) 0.42519) |
| BiTe-23Drz.tdb | 688.72 | BI2TE3_C33 (x(Te) 0.60173) + LIQUID (x(Te) 0.88624) + HEXAGONAL_A8 (x(Te) 1) |
| BiTe-23Drz.tdb | 590.13 | LIQUID (x(Te) 0.04948) + BI7TE3 (x(Te) 0.3) + BI2TE (x(Te) 0.33333) |
| BiTe-23Drz.tdb | 590.13 | LIQUID (x(Te) 0.04947) + BI7TE3 (x(Te) 0.3) + BI2TE (x(Te) 0.33333) |
| BiTe-23Drz.tdb | 543.74 | RHOMBOHEDRAL_A7 (x(Te) 0) + LIQUID (x(Te) 0.00973) + BI7TE3 (x(Te) 0.3) |
| BiTe-24Zho.tdb | 833.61 | LIQUID (x(Te) 0.48844) + BI4TE5 (x(Te) 0.55556) + BI2TE3_C33 (x(Te) 0.59625) |
| BiTe-24Zho.tdb | 822.75 | LIQUID (x(Te) 0.45251) + BI8TE9 (x(Te) 0.52941) + BI4TE5 (x(Te) 0.55556) |
| BiTe-24Zho.tdb | 814.95 | LIQUID (x(Te) 0.42583) + BITE (x(Te) 0.5) + BI8TE9 (x(Te) 0.52941) |
| BiTe-24Zho.tdb | 707.94 | LIQUID (x(Te) 0.19546) + BI4TE3 (x(Te) 0.42857) + BITE (x(Te) 0.5) |
| BiTe-24Zho.tdb | 679.46 | BI2TE3_C33 (x(Te) 0.60707) + LIQUID (x(Te) 0.8822) + HEXAGONAL_A8 (x(Te) 1) |
| BiTe-24Zho.tdb | 664.8 | LIQUID (x(Te) 0.13643) + BI2TE (x(Te) 0.33333) + BI4TE3 (x(Te) 0.42857) |
| BiTe-24Zho.tdb | 604.83 | LIQUID (x(Te) 0.06467) + BI7TE3 (x(Te) 0.3) + BI2TE (x(Te) 0.33333) |
| BiTe-24Zho.tdb | 543.57 | RHOMBOHEDRAL_A7 (x(Te) 0) + LIQUID (x(Te) 0.01072) + BI7TE3 (x(Te) 0.3) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/BI/BI-TE.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/BI/BI-TE.json) · [CALPHAD hull BiTe-18Gie](https://data.orchid-project.org/hulls/calphad-sgte/BI/BI-TE--BiTe-18Gie.json) · [CALPHAD hull BiTe-18Mao](https://data.orchid-project.org/hulls/calphad-sgte/BI/BI-TE--BiTe-18Mao.json) · [CALPHAD hull BiTe-23Drz](https://data.orchid-project.org/hulls/calphad-sgte/BI/BI-TE--BiTe-23Drz.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Bi–Te system (54)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 862.15 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.6; Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Howlett 1964_ | Table 6, p. 13, row 3; `ORC-BOI6VEXEXH` |  |
| 859.15 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.5995; Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Brebrick 1968_ [doi](https://doi.org/10.1021/j100849a043) | Table 6, p. 13, row 4; `ORC-J3VVE3X3QU` |  |
| 859.15 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.6; Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Yamana 1979_ [doi](https://doi.org/10.1107/s0567740879002788) | Table 6, p. 13, row 6; `ORC-KXRMUYNPV6` |  |
| 858.05 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.6; Bi2Te3: Bi 0.4, Te 0.6 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 2; `ORC-C7PHHNGNTL` |  |
| 857.55 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.5997; Bi2Te3: Bi 0.4, Te 0.6 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 1; `ORC-NQFUUXUGK6` |  |
| 838.15 | congruent melting: Liquid -> Bi2Te3 | L: Te 0.6; Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Shimazaki 1978_ | Table 6, p. 13, row 5; `ORC-KUIYAM4CDW` |  |
| 836.15 | peritectic: Liquid + Bi2Te3 -> BiTe | Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | experimental | [1] Drzewowska 2023; _cites Brebrick 1968_ [doi](https://doi.org/10.1021/j100849a043) | Table 6, p. 13, row 11; `ORC-WRI7XO45AZ` |  |
| 835.15 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.5; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | experimental | [1] Drzewowska 2023; _cites Glatz 1965_ [doi](https://doi.org/10.1149/1.2423400) | Table 6, p. 13, row 12; `ORC-RIMW5VG6R2` |  |
| 835 | peritectic: Liquid + Bi2Te3 -> Bi4Te5 | Liquid: Te 0.52; Bi2Te3: Te 0.6; Bi4Te5: Te 0.556 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 15; `ORC-IC2ORRGPPX` |  |
| 834.75 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.477; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 8; `ORC-SF2TMFLEFA` |  |
| 834.15 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.5; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | experimental | [1] Drzewowska 2023; _cites Shimazaki 1978_ | Table 6, p. 13, row 13; `ORC-NBGMTDGCAS` |  |
| 834 | peritectic: Liquid + Bi2Te3 -> Bi4Te5 | Liquid: Te 0.49; Bi2Te3: Te 0.6; Bi4Te5: Te 0.556 | model | [2] Zhou 2024 | Table 6, p. 16, row 16; `ORC-2PRMXISEIP` |  |
| 833.15 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.436; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | unspecified | [1] Drzewowska 2023; _cites Mao 2018_ [doi](https://doi.org/10.1016/j.calphad.2017.11.007) | Table 6, p. 13, row 9; `ORC-GMDQBQXV2F` |  |
| 832.65 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.456; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 7; `ORC-OMS6EV2W5K` |  |
| 823 | peritectic: Liquid + Bi4Te5 -> Bi8Te9 | Liquid: Te 0.5; Bi4Te5: Te 0.556; Bi8Te9: Te 0.529 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 17; `ORC-7ZIC4T27SM` |  |
| 823 | peritectic: Liquid + Bi4Te5 -> Bi8Te9 | Liquid: Te 0.453; Bi4Te5: Te 0.556; Bi8Te9: Te 0.529 | model | [2] Zhou 2024 | Table 6, p. 16, row 18; `ORC-BAYMWHBHKS` |  |
| 815 | peritectic: Liquid + Bi8Te9 -> BiTe | Liquid: Te 0.45; Bi8Te9: Te 0.529; BiTe: Te 0.5 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 19; `ORC-CSB7XCCD7T` |  |
| 815 | peritectic: Liquid + Bi8Te9 -> BiTe | Liquid: Te 0.426; Bi8Te9: Te 0.529; BiTe: Te 0.5 | model | [2] Zhou 2024 | Table 6, p. 16, row 20; `ORC-FH3XQ3WF7K` |  |
| 813.15 | peritectic: Liquid + Bi2Te3 -> BiTe | L: Te 0.44; Bi2Te3: Bi 0.4, Te 0.6; BiTe: Bi 0.5, Te 0.5 | experimental | [1] Drzewowska 2023; _cites Abrikosov 1969_ [doi](https://doi.org/10.1007/978-1-4899-6373-4) | Table 6, p. 13, row 10; `ORC-TLORLBKHFP` |  |
| 708 | peritectic: Liquid + BiTe -> Bi4Te3 | Liquid: Te 0.23; BiTe: Te 0.5; Bi4Te3: Te 0.429 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 21; `ORC-33VBYNYU6Q` |  |
| 708 | peritectic: Liquid + BiTe -> Bi4Te3 | Liquid: Te 0.195; BiTe: Te 0.5; Bi4Te3: Te 0.429 | model | [2] Zhou 2024 | Table 6, p. 16, row 22; `ORC-VQB6T22JQ5` |  |
| 694.55 | peritectic: Liquid + BiTe -> Bi2Te | L: Te 0.212; BiTe: Bi 0.5, Te 0.5; Bi2Te: Bi 0.666667, Te 0.333333 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 14; `ORC-ND3K6C5NBG` |  |
| 693.85 | peritectic: Liquid + BiTe -> Bi2Te | L: Te 0.202; BiTe: Bi 0.5, Te 0.5; Bi2Te: Bi 0.666667, Te 0.333333 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 15; `ORC-O7APNEKFVB` |  |
| 693.15 | peritectic: Liquid + BiTe -> Bi2Te | L: Te 0.205; BiTe: Bi 0.5, Te 0.5; Bi2Te: Bi 0.666667, Te 0.333333 | experimental | [1] Drzewowska 2023; _cites Abrikosov 1969_ [doi](https://doi.org/10.1007/978-1-4899-6373-4) | Table 6, p. 13, row 16; `ORC-QZRKRBC5PA` |  |
| 689 | peritectic: Liquid -> Bi2Te3 + (Te) | Liquid: Te 0.886; Bi2Te3: Te 0.6; (Te): Te 1 | experimental | [2] Zhou 2024; _cites Drzewowska 2023_ [doi](https://doi.org/10.1007/s11669-023-01049-9) | Table 6, p. 16, row 13; `ORC-P367W2UHWG` |  |
| 688.75 | eutectic: Liquid -> Bi2Te3 + (Te) | L: Te 0.886; Bi2Te3: Bi 0.4, Te 0.6 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 17; `ORC-ASBPLZSWD5` |  |
| 687.15 | eutectic: Liquid -> Bi2Te3 + (Te) | L: Te 0.907; Bi2Te3: Bi 0.4, Te 0.6 | unspecified | [1] Drzewowska 2023; _cites Mao 2018_ [doi](https://doi.org/10.1016/j.calphad.2017.11.007) | Table 6, p. 13, row 19; `ORC-LQ4L2AIOLM` |  |
| 687.15 | eutectic: Liquid -> Bi2Te3 + (Te) | Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Glatz 1965_ [doi](https://doi.org/10.1149/1.2423400) | Table 6, p. 13, row 21; `ORC-MNXERCBX7X` |  |
| 687 | peritectic: Liquid -> Bi2Te3 + (Te) | Liquid: Te 0.907; Bi2Te3: Te 0.6; (Te): Te 1 | experimental | [2] Zhou 2024; _cites Mao 2018_ [doi](https://doi.org/10.1016/j.calphad.2017.11.007) | Table 6, p. 16, row 12; `ORC-FQJMPABJTM` |  |
| 686.25 | eutectic: Liquid -> Bi2Te3 + (Te) | L: Te 0.908; Bi2Te3: Bi 0.4, Te 0.6 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 18; `ORC-H47HSWT4TR` |  |
| 686.15 | eutectic: Liquid -> Bi2Te3 + (Te) | L: Te 0.9; Bi2Te3: Bi 0.4, Te 0.6 | experimental | [1] Drzewowska 2023; _cites Abrikosov 1969_ [doi](https://doi.org/10.1007/978-1-4899-6373-4) | Table 6, p. 13, row 20; `ORC-HEJSVJ7KVG` |  |
| 686 | peritectic: Liquid -> Bi2Te3 + (Te) | Liquid: Te 0.9; Bi2Te3: Te 0.6; (Te): Te 1 | experimental | [2] Zhou 2024; _cites Abrikosov 1958_ | Table 6, p. 16, row 10; `ORC-HEGD3AM5BM` |  |
| 686 | peritectic: Liquid -> Bi2Te3 + (Te) | Bi2Te3: Te 0.6; (Te): Te 1 | experimental | [2] Zhou 2024; _cites Glatz 1965_ [doi](https://doi.org/10.1149/1.2423400) | Table 6, p. 16, row 11; `ORC-MLNHPHY5LK` |  |
| 679 | peritectic: Liquid -> Bi2Te3 + (Te) | Liquid: Te 0.882; Bi2Te3: Te 0.607; (Te): Te 1 | model | [2] Zhou 2024 | Table 6, p. 16, row 14; `ORC-HJUCIKUX3N` |  |
| 665 | monotectic: Liquid + Bi4Te3 -> Bi2Te | Liquid: Te 0.16; Bi4Te3: Te 0.429; Bi2Te: Te 0.333 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 23; `ORC-J6MXXD66TY` |  |
| 665 | monotectic: Liquid + Bi4Te3 -> Bi2Te | Liquid: Te 0.136; Bi4Te3: Te 0.429; Bi2Te: Te 0.333 | model | [2] Zhou 2024 | Table 6, p. 16, row 24; `ORC-NUMB6U2CY7` |  |
| 605.15 | peritectic: Liquid + Bi2Te -> Bi7Te3 | L: Te 0.1; Bi2Te: Bi 0.666667, Te 0.333333; Bi7Te3: Bi 0.7, Te 0.3 | experimental | [1] Drzewowska 2023; _cites Yamana 1979_ [doi](https://doi.org/10.1107/s0567740879002788) | Table 6, p. 13, row 25; `ORC-VLQNTEZ2SG` |  |
| 605 | eutectic: Liquid + Bi2Te -> Bi7Te3 | Liquid: Te 0.1; Bi2Te: Te 0.333; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 2; `ORC-LFBHE3QDDA` |  |
| 605 | eutectic: Liquid + Bi2Te -> Bi7Te3 | Liquid: Te 0.065; Bi2Te: Te 0.333; Bi7Te3: Te 0.3 | model | [2] Zhou 2024 | Table 6, p. 16, row 4; `ORC-UGJPGXFIN7` |  |
| 590.05 | peritectic: Liquid + Bi2Te -> Bi7Te3 | L: Te 0.05; Bi2Te: Bi 0.666667, Te 0.333333; Bi7Te3: Bi 0.7, Te 0.3 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 22; `ORC-KC2O666DQX` |  |
| 590 | eutectic: Liquid + Bi2Te -> Bi7Te3 | Liquid: Te 0.05; Bi2Te: Te 0.333; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Drzewowska 2023_ [doi](https://doi.org/10.1007/s11669-023-01049-9) | Table 6, p. 16, row 3; `ORC-2SXSFFTKRQ` |  |
| 586.45 | peritectic: Liquid + Bi2Te -> Bi7Te3 | L: Te 0.063; Bi2Te: Bi 0.666667, Te 0.333333; Bi7Te3: Bi 0.7, Te 0.3 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 23; `ORC-5SLJGG4A75` |  |
| 585.15 | peritectic: Liquid + Bi2Te -> Bi7Te3 | L: Te 0.055; Bi2Te: Bi 0.666667, Te 0.333333; Bi7Te3: Bi 0.7, Te 0.3 | experimental | [1] Drzewowska 2023; _cites Abrikosov 1969_ [doi](https://doi.org/10.1007/978-1-4899-6373-4) | Table 6, p. 13, row 24; `ORC-QZOBLO2GEZ` |  |
| 585 | eutectic: Liquid + Bi2Te -> Bi7Te3 | Liquid: Te 0.055; Bi2Te: Te 0.333; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Abrikosov 1958_ | Table 6, p. 16, row 1; `ORC-2CKUMLD24F` |  |
| 544 | peritectic: Liquid -> (Bi) + Bi7Te3 | Liquid: Te 0.011; (Bi): Te 0; Bi7Te3: Te 0.3 | model | [2] Zhou 2024 | Table 6, p. 16, row 9; `ORC-P6AGMGWO2O` |  |
| 544 | peritectic: Liquid -> (Bi) + Bi7Te3 | Liquid: Te 0.01; (Bi): Te 0; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Drzewowska 2023_ [doi](https://doi.org/10.1007/s11669-023-01049-9) | Table 6, p. 16, row 8; `ORC-Q6YE5UGSLJ` |  |
| 543.75 | eutectic: Liquid -> (Bi) + Bi7Te3 | L: Te 0.01; Bi7Te3: Bi 0.7, Te 0.3 | model | [1] Drzewowska 2023 | Table 6, p. 13, row 26; `ORC-GMCQHZC7IL` |  |
| 539.15 | eutectic: Liquid -> (Bi) + Bi7Te3 | Bi7Te3: Bi 0.7, Te 0.3 | experimental | [1] Drzewowska 2023; _cites Glatz 1965_ [doi](https://doi.org/10.1149/1.2423400) | Table 6, p. 13, row 29; `ORC-HKQ3357ON6` |  |
| 539.15 | eutectic: Liquid -> (Bi) + Bi7Te3 | L: Te 0.024; Bi7Te3: Bi 0.7, Te 0.3 | experimental | [1] Drzewowska 2023; _cites Abrikosov 1969_ [doi](https://doi.org/10.1007/978-1-4899-6373-4) | Table 6, p. 13, row 28; `ORC-J2IESG66G6` |  |
| 539 | peritectic: Liquid -> (Bi) + Bi7Te3 | Liquid: Te 0.024; (Bi): Te 0; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Abrikosov 1958_ | Table 6, p. 16, row 5; `ORC-CZ73N2MJEQ` |  |
| 537.15 | eutectic: Liquid -> (Bi) + Bi7Te3 | L: Te 0.025; Bi7Te3: Bi 0.7, Te 0.3 | experimental | [1] Drzewowska 2023; _cites Yamana 1979_ [doi](https://doi.org/10.1107/s0567740879002788) | Table 6, p. 13, row 30; `ORC-WDZ2Z2JIHQ` |  |
| 537 | peritectic: Liquid -> (Bi) + Bi7Te3 | Liquid: Te 0.025; (Bi): Te 0; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 6, p. 16, row 7; `ORC-6RWL2CH6HY` |  |
| 537 | peritectic: Liquid -> (Bi) + Bi7Te3 | (Bi): Te 0; Bi7Te3: Te 0.3 | experimental | [2] Zhou 2024; _cites Glatz 1965_ [doi](https://doi.org/10.1149/1.2423400) | Table 6, p. 16, row 6; `ORC-KVTXYZBIX4` |  |
| 536.45 | eutectic: Liquid -> (Bi) + Bi7Te3 | L: Te 0.011; Bi7Te3: Bi 0.7, Te 0.3 | unspecified | [1] Drzewowska 2023; _cites Chizhevskaya 1994_ | Table 6, p. 13, row 27; `ORC-IZOALZZGS7` |  |

## Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json).

Table: Enthalpies of formation, Bi–Te system (12)

| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---:|---:|---|---:|---:|---|---|---|
| Bi2Te | [Bi2Te](https://data.orchid-project.org/compounds/Bi2Te.html) | -14.7 kJ/mol-atom | 298.15 | experimental | -14.943 (mp-aaacrvsf) | -13.097 (oqmd-2168844) | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 104; `ORC-J23QWW25N2` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -39.8 kJ/mol-atom | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Sidorko 2008_ [doi](https://doi.org/10.1007/s11106-008-9009-3) | Table 3, p. 5, row 110; `ORC-YHSAQCMMJG` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -16.903 kJ/mol-atom | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Semenkovich 1972_ [doi](https://doi.org/10.1007/978-1-4684-1686-2_27) | Table 3, p. 5, row 108; `ORC-UXJFB6ZCBM` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -16.82 kJ/mol-atom ± 0.67 | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Vecher 1968_ | Table 3, p. 5, row 109; `ORC-6JWJFOCD7U` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -16.1 kJ/mol-atom ± 1 | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Boncheva-Mladenova 1972_ [doi](https://doi.org/10.1007/978-1-4684-1686-2_26) | Table 3, p. 5, row 107; `ORC-WXJ6TLFSHD` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -15.84 kJ/mol-atom | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 112; `ORC-2RRZ5KKKRM` |  |
| Bi2Te3 | [Bi2Te3](https://data.orchid-project.org/compounds/Bi2Te3.html) | -15.7 kJ/mol-atom | 298.15 | experimental | -47.208 (mp-aaaabypm) | -22.887 (oqmd-3206) | [2] Zhou 2024; _cites Howlett 1964_ | Table 3, p. 5, row 106; `ORC-WIILY7GV7G` |  |
| Bi4Te3 | [Bi4Te3](https://data.orchid-project.org/compounds/Bi4Te3.html) | -11.717 kJ/mol-atom | 298.15 | experimental | -34.084 (mp-aaaabptt) | -16.486 (oqmd-5865) | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 103; `ORC-UDK76LZB4Z.009948` |  |
| Bi4Te5 |  | -16.578 kJ/mol-atom | 298.15 | experimental |  |  | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 100; `ORC-Y5NKJINWLB` |  |
| Bi7Te3 |  | -13.54 kJ/mol-atom | 298.15 | experimental |  |  | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 105; `ORC-3LB66OJ4CG` |  |
| Bi8Te9 | [Bi8Te9](https://data.orchid-project.org/compounds/Bi8Te9.html) | -16.871 kJ/mol-atom | 298.15 | experimental | -41.1 (mp-aaabhacc) | -20.289 (oqmd-90970) | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 101; `ORC-2FHRK2RG6F` |  |
| BiTe | [BiTe](https://data.orchid-project.org/compounds/BiTe.html) | -17 kJ/mol-atom | 298.15 | experimental | -39.379 (mp-aaaabijg) | -19.207 (oqmd-5864) | [2] Zhou 2024; _cites Hasanova 2021_ [doi](https://doi.org/10.1007/s11837-021-04621-1) | Table 3, p. 5, row 102; `ORC-FCIKWEFKSY` |  |

## Other properties

### Phase equilibrium (14)

Table: Phase equilibrium, Bi–Te system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase composition |  |  | Bi2Te + BiTe + (Bi); _Bi2Te: Bi 0.6593, Te 0.3407; BiTe: Bi 0.5906, Te 0.4094; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 8; `ORC-HP6IH7C6ZT` |  |
| Phase composition |  |  | Bi2Te + BiTe + (Bi); _Bi2Te: Bi 0.6548, Te 0.3453; BiTe: Bi 0.542, Te 0.458; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 5; `ORC-JUARI2K34K` |  |
| Phase composition |  |  | Bi2Te + BiTe + (Bi); _Bi2Te: Bi 0.6593, Te 0.3407; BiTe: Bi 0.5906, Te 0.4094; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 7; `ORC-MI2S67YOZQ` |  |
| Phase composition |  |  | Bi2Te3 + (Te) + eutectic; _Bi2Te3: Bi 0.3371, Te 0.6629; (Te): Bi 0.0124, Te 0.9876; eutectic: Bi 0.1717, Te 0.8283_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 1; `ORC-PYNSOBXFJR` |  |
| Phase composition |  |  | Bi2Te3 + BiTe + (Bi); _Bi2Te3: Bi 0.4068, Te 0.5932; BiTe: Bi 0.5574, Te 0.4426; (Bi): Bi 0.9633, Te 0.0368_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 3; `ORC-FMOPZ54D5N` |  |
| Phase composition |  |  | Bi2Te3 + eutectic; _Bi2Te3: Bi 0.3722, Te 0.6278; eutectic: Bi 0.2472, Te 0.7528_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 2; `ORC-SPJ7JRZ45R` |  |
| Phase composition |  |  | Bi7Te3 + BiTe + (Bi); _Bi7Te3: Bi 0.6977, Te 0.3023; BiTe: Bi 0.5607, Te 0.4393; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 6; `ORC-SCAPX4SUGR` |  |
| Phase composition |  |  | BiTe + (Bi) + Bi2Te; _BiTe: Bi 0.5099, Te 0.4902; (Bi): Bi 0.9922, Te 0.0078; Bi2Te: Bi 0.6186, Te 0.3814_ | experimental | [1] Drzewowska 2023 | Table 2, p. 5, row 4; `ORC-QIUPRRKZES` |  |
| Phase composition |  | 513.15 | Bi2Te; _Bi2Te: Bi 0.6589, Te 0.3411_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 5; `ORC-5B6HRQWDGZ` |  |
| Phase composition |  | 513.15 | Bi7Te3 + (Bi); _Bi7Te3: Bi 0.6995, Te 0.3005; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 6; `ORC-NGPX3H7IEZ` |  |
| Phase composition |  | 663.15 | Bi2Te3 + (Te); _Bi2Te3: Bi 0.3827, Te 0.6173; (Te): Bi 0, Te 1_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 1; `ORC-S7ILKEEVQZ` |  |
| Phase composition |  | 663.15 | BiTe + Bi2Te + (Bi); _BiTe: Bi 0.559, Te 0.441; Bi2Te: Bi 0.6645, Te 0.3355; (Bi): Bi 1, Te 0_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 4; `ORC-RVLUYUGQHQ` |  |
| Phase composition |  | 753.15 | Bi2Te3; _Bi2Te3: Bi 0.3858, Te 0.6142_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 2; `ORC-7QON6QDPGB` |  |
| Phase composition |  | 753.15 | BiTe; _BiTe: Bi 0.4257, Te 0.5743_ | experimental | [1] Drzewowska 2023 | Table 3, p. 5, row 3; `ORC-JXWAMWI3RR` |  |

### Crystal structure (12)

Table: Crystal structure, Bi–Te system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Lattice a | 0.449 Å | 298.15 | Bi2Te; _alloy: Te 0.333333_ | model | [2] Zhou 2024; _cites Mao 2018_ [doi](https://doi.org/10.1016/j.calphad.2017.11.007) | Table 1, p. 2, row 11; `ORC-C6RLPSKSF3.0dff29` |  |
| Lattice a | 0.438 Å | 298.15 | Bi2Te3; _alloy: Te 0.6_ | experimental | [2] Zhou 2024; _cites Soonpaa 1963_ [doi](https://doi.org/10.1063/1.1729264) | Table 1, p. 2, row 14; `ORC-SNY57UU57P.a63f6d` |  |
| Lattice a | 0.443 Å | 298.15 | Bi4Te3; _alloy: Te 0.428571_ | experimental | [2] Zhou 2024; _cites Yamana 1979_ [doi](https://doi.org/10.1107/s0567740879002788) | Table 1, p. 2, row 13; `ORC-WSJ7I3TSLP.7cceb1` |  |
| Lattice a | 4.4214 Å | 298.15 | Bi4Te5; _alloy: Te 0.555556_ | experimental | [2] Zhou 2024; _cites Brebrick 1968_ [doi](https://doi.org/10.1107/s0021889868005406) | Table 1, p. 2, row 17; `ORC-YFJAROQUR4.612323` |  |
| Lattice a | 4.41 Å | 298.15 | Bi8Te9; _alloy: Te 0.529412_ | experimental | [2] Zhou 2024; _cites Feutelais 1993_ [doi](https://doi.org/10.1016/0025-5408%2893%2990055-i) | Table 1, p. 2, row 15; `ORC-4ATMFSYF7U.512ed2` |  |
| Lattice a | 0.44 Å | 298.15 | BiTe; _alloy: Te 0.5_ | experimental | [2] Zhou 2024; _cites Semiletov 1954_ | Table 1, p. 2, row 12; `ORC-HJFSPBMEGD.7c61c6` |  |
| Lattice c | 11.9 Å | 298.15 | Bi2Te; _alloy: Te 0.333333_ | model | [2] Zhou 2024; _cites Mao 2018_ [doi](https://doi.org/10.1016/j.calphad.2017.11.007) | Table 1, p. 2, row 11; `ORC-C6RLPSKSF3.cbe93b` |  |
| Lattice c | 3.057 Å | 298.15 | Bi2Te3; _alloy: Te 0.6_ | experimental | [2] Zhou 2024; _cites Soonpaa 1963_ [doi](https://doi.org/10.1063/1.1729264) | Table 1, p. 2, row 14; `ORC-SNY57UU57P.ebaf2a` |  |
| Lattice c | 4.187 Å | 298.15 | Bi4Te3; _alloy: Te 0.428571_ | experimental | [2] Zhou 2024; _cites Yamana 1979_ [doi](https://doi.org/10.1107/s0567740879002788) | Table 1, p. 2, row 13; `ORC-WSJ7I3TSLP.db30d0` |  |
| Lattice c | 78.195 Å | 298.15 | Bi4Te5; _alloy: Te 0.555556_ | experimental | [2] Zhou 2024; _cites Brebrick 1968_ [doi](https://doi.org/10.1107/s0021889868005406) | Table 1, p. 2, row 17; `ORC-YFJAROQUR4.116727` |  |
| Lattice c | 103 Å | 298.15 | Bi8Te9; _alloy: Te 0.529412_ | experimental | [2] Zhou 2024; _cites Feutelais 1993_ [doi](https://doi.org/10.1016/0025-5408%2893%2990055-i) | Table 1, p. 2, row 15; `ORC-4ATMFSYF7U.b0b3fa` |  |
| Lattice c | 2.397 Å | 298.15 | BiTe; _alloy: Te 0.5_ | experimental | [2] Zhou 2024; _cites Semiletov 1954_ | Table 1, p. 2, row 12; `ORC-HJFSPBMEGD.5fc6c9` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. S. Drzewowska, B. Onderka, Different Approach to Thermodynamic Description of Bi-Te Binary System, J. Phase Equilib. Diffus. 44, 429-444 (2023). [doi:10.1007/s11669-023-01049-9](https://doi.org/10.1007/s11669-023-01049-9)
2. Jiaqiang Zhou, Jiong Wang, Biao Hu, Dongyu Cui, Thermodynamic Modeling of the Bi-Se and Bi-Te Binary Systems, J. Phase Equilib. Diffus. 45, 89-113 (2024). [doi:10.1007/s11669-024-01093-z](https://doi.org/10.1007/s11669-024-01093-z)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).