Ca–H–Li system

14 accepted literature values from 1 paper(s) (experimental 7, model 7); 0 calculated phase diagram(s).

Data: JSON · CSV · interactive explorer · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	7
model	7

Accepted values by property group
Property group	Values
invariant reaction	14

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ca–H–Li system (14)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1163.65	L + βCaH2 = (βCa)	L: H 0.292; βCaH2: H 0.667; (βCa): H 0.343	model	[1] Wang 2012	Table 3, p. 3, row 8 report
1163.15	L + βCaH2 = (βCa)	L: H 0.3; βCaH2: H 0.667	experimental	[1] Wang 2012 cites Peterson 1961 doi	Table 3, p. 3, row 7 report
1053.25	βCaH2 = αCaH2	βCaH2: H 0.667; αCaH2: H 0.667; L: H 0.257	model	[1] Wang 2012	Table 3, p. 3, row 10 report
1053.15	βCaH2 = αCaH2	βCaH2: H 0.667; αCaH2: H 0.667; L: H 0.294	experimental	[1] Wang 2012 cites Peterson 1961 doi	Table 3, p. 3, row 9 report
962.15	L2 -> L1 + LiH	L2: H 0.496; L1: H 0.19; LiH: H 0.5	experimental	[1] Wang 2012 cites Sangster 1993 doi	Table 3, p. 3, row 3 report
961.55	L2 -> L1 + LiH	L2: H 0.492; L1: H 0.18; LiH: H 0.5	model	[1] Wang 2012	Table 3, p. 3, row 4 report
873.15	(βCa) + αCaH2 = γ	αCaH2: H 0.667; γ: H 0.161	experimental	[1] Wang 2012 cites Peterson 1961 doi	Table 3, p. 3, row 11 report
872.05	(βCa) + αCaH2 = γ	(βCa): H 0.117; αCaH2: H 0.667; γ: H 0.146	model	[1] Wang 2012	Table 3, p. 3, row 12 report
720.45	(βCa) + γ = (αCa)	(βCa): H 0.0085; γ: H 0.013; (αCa): H 0.0095	model	[1] Wang 2012	Table 3, p. 3, row 14 report
716.15	(βCa) + γ = (αCa)		experimental	[1] Wang 2012 cites Peterson 1961 doi	Table 3, p. 3, row 13 report
633.15	γ = (αCa) + αCaH2	γ: H 0.033; αCaH2: H 0.667	experimental	[1] Wang 2012 cites Peterson 1961 doi	Table 3, p. 3, row 15 report
630.35	γ = (αCa) + αCaH2	γ: H 0.035; (αCa): H 0.018	model	[1] Wang 2012	Table 3, p. 3, row 16 report
453.65	L -> (Li) + LiH	L: H 3.000e-4; (Li): H 1.000e-4; LiH: H 0.5	experimental	[1] Wang 2012 cites Sangster 1993 doi	Table 3, p. 3, row 1 report
453.45	L -> (Li) + LiH	L: H 2.000e-4; (Li): H 0; LiH: H 0.5	model	[1] Wang 2012	Table 3, p. 3, row 2 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Man Wang, Weihua Sun, Chunsheng Sha, Biao Hu, Yong Du, Lixian Sun et al., Thermodynamic Modeling of the Li-H and Ca-H Systems, J. Phase Equilib. Diffus. 33, 89-96 (2012). doi:10.1007/s11669-012-9997-z

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}