Ca–In–Sb system

21 accepted literature values from 1 paper(s) (experimental 11, model 10); 0 calculated phase diagram(s).

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Accepted values by evidence class
Evidence class	Values
experimental	11
model	10

Accepted values by property group
Property group	Values
invariant reaction	18
crystal structure	3

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ca–In–Sb system (18)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1152.95	Liquid + Ca11Sb10 ↔ Ca5Sb3	Liquid: Ca 0.72; Ca11Sb10: Ca 0.5238; Ca5Sb3: Ca 0.625	model	[1] Qin 2015	Table 5, p. 5, row 19 report
1150.15	Liquid + Ca11Sb10 ↔ Ca5Sb3	Liquid: Ca 0.74; Ca11Sb10: Ca 0.5238; Ca5Sb3: Ca 0.625	experimental	[1] Qin 2015 cites Bouhajib 1999 doi	Table 5, p. 5, row 20 report
1113.15	Liquid + Ca5Sb3 ↔ Ca2Sb	Liquid: Ca 0.78; Ca5Sb3: Ca 0.625; Ca2Sb: Ca 0.667	experimental	[1] Qin 2015 cites Bouhajib 1999 doi	Table 5, p. 5, row 18 report
1108.55	Liquid + Ca5Sb3 ↔ Ca2Sb	Liquid: Ca 0.75; Ca5Sb3: Ca 0.625; Ca2Sb: Ca 0.667	model	[1] Qin 2015	Table 5, p. 5, row 17 report
1056.15	Liquid ↔ CaIn + CaIn2	Liquid: Ca 0.41; CaIn: Ca 0.5; CaIn2: Ca 0.3333	experimental	[1] Qin 2015 cites Bruzzone 1964 doi	Table 5, p. 5, row 6 report
1051.25	Liquid ↔ CaIn + CaIn2	Liquid: Ca 0.4031; CaIn: Ca 0.5; CaIn2: Ca 0.3333	model	[1] Qin 2015	Table 5, p. 5, row 5 report
938.05	Liquid ↔ Ca8In3 + CaIn	Liquid: Ca 0.6374; Ca8In3: Ca 0.7273; CaIn: Ca 0.5	model	[1] Qin 2015	Table 5, p. 5, row 3 report
933.65	Liquid ↔ (βCa) + Ca2Sb	Liquid: Ca 0.874; (βCa): Ca 1; Ca2Sb: Ca 0.667	model	[1] Qin 2015	Table 5, p. 5, row 15 report
933.15	Liquid ↔ (βCa) + Ca2Sb	Liquid: Ca 0.875; (βCa): Ca 1; Ca2Sb: Ca 0.667	experimental	[1] Qin 2015 cites Bouhajib 1999 doi	Table 5, p. 5, row 16 report
933.15	Liquid ↔ Ca8In3 + CaIn	Liquid: Ca 0.645; Ca8In3: Ca 0.75; CaIn: Ca 0.5	experimental	[1] Qin 2015 cites Bruzzone 1964 doi	Table 5, p. 5, row 4 report
909.25	Liquid + Ca11Sb10 ↔ CaSb2	Liquid: Ca 0.234; Ca11Sb10: Ca 0.5238; CaSb2: Ca 0.3333	model	[1] Qin 2015	Table 5, p. 5, row 21 report
907.95	Liquid ↔ (βCa) + Ca8In3	Liquid: Ca 0.853; (βCa): Ca 1; Ca8In3: Ca 0.7273	model	[1] Qin 2015	Table 5, p. 5, row 1 report
906.15	Liquid + Ca11Sb10 ↔ CaSb2	Liquid: Ca 0.22; Ca11Sb10: Ca 0.5238; CaSb2: Ca 0.3333	experimental	[1] Qin 2015 cites Poizeau 2012 doi	Table 5, p. 5, row 22 report
905.15	Liquid ↔ (βCa) + Ca8In3	Liquid: Ca 0.875; (βCa): Ca 1; Ca8In3: Ca 0.75	experimental	[1] Qin 2015 cites Bruzzone 1964 doi	Table 5, p. 5, row 2 report
860.15	Liquid ↔ CaSb2 + (Sb)	Liquid: Ca 0.16; CaSb2: Ca 0.3333; (Sb): Ca 0	experimental	[1] Qin 2015 cites Bouhajib 1999 doi	Table 5, p. 5, row 24 report
855.15	Liquid ↔ CaSb2 + (Sb)	Liquid: Ca 0.159; CaSb2: Ca 0.3333; (Sb): Ca 0	model	[1] Qin 2015	Table 5, p. 5, row 23 report
429.15	Liquid ↔ CaIn2 + (In)	Liquid: Ca 0; CaIn2: Ca 0.3333; (In): Ca 0	experimental	[1] Qin 2015 cites Bruzzone 1964 doi	Table 5, p. 5, row 8 report
428.15	Liquid ↔ CaIn2 + (In)	Liquid: Ca 1.000e-4; CaIn2: Ca 0.3333; (In): Ca 0	model	[1] Qin 2015	Table 5, p. 5, row 7 report

Other properties

Crystal structure (3)

Crystal structure, Ca–In–Sb system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Lattice a	55.18 Å		(αCa) alloy: In 0, Sb 0	model	[1] Qin 2015	Table 1, p. 2, row 3 report
Lattice a	55.82 Å	298.15	(αCa) alloy: In 0, Sb 0	experimental	[1] Qin 2015 cites Bruzzone 1966	Table 1, p. 2, row 2 report
Lattice a	44.8 Å	298.15	(βCa) alloy: In 0, Sb 0	experimental	[1] Qin 2015 cites Bernstein 1959 doi	Table 1, p. 2, row 1 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Song Qin, Shuhong Liu, Cong Zhang, Jinghua Xin, Yao Wang, Yong Du, Thermodynamic modeling of the Ca–In and Ca–Sb systems supported with first-principles calculations, Calphad 48, 35-42 (2015). doi:10.1016/j.calphad.2014.10.008

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}