# Ca–Li–Na system > Ca–Li–Na system: 8 accepted literature values (invariant reaction 8) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/CA-LI-NA.html · Markdown: https://data.orchid-project.org/systems/CA-LI-NA.md 8 accepted literature values from 1 paper(s) (unspecified 8); 0 calculated phase diagram(s). Data: [JSON](https://data.orchid-project.org/literature/systems/CA-LI-NA.json) · [CSV](https://data.orchid-project.org/systems/CA-LI-NA.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#CA-LI-NA) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/CA-LI-NA.html) · [Markdown](https://data.orchid-project.org/systems/CA-LI-NA.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | unspecified | 8 | Table: Accepted values by property group | Property group | Values | |---|---:| | invariant reaction | 8 | ## Invariant reactions (literature) Table: Invariant reactions reported in the literature for the Ca–Li–Na system (8) | T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote | |---:|---|---|---|---|---|---| | 648.4 | peritectic: Liquid1 + liquid2 + bcc(Ca) -> fcc(Ca) | Liquid1: Ca 0.55467, Li 0.40843; liquid2: Ca 0.02915, Li 0.03553; bcc(Ca): Ca 0.00919, Li 0.07767; fcc(Ca): Ca 0.00938, Li 0.0596 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 1; `ORC-BYYNXPUYDD` | | | 648.4 | quasi-peritectic: Liquid2 + bcc(Ca) -> fcc(Ca) + liquid1 | Liquid2: Ca 0.02915, Li 0.03553; bcc(Ca): Ca 0.00919, Li 0.07767; fcc(Ca): Ca 0.00938, Li 0.0596; liquid1: Ca 0.55467, Li 0.40843 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 2; `ORC-T744TWVIT6` | | | 503.3 | eutectic: Liquid1 -> fcc(Ca) + CaLi2 + liquid2 | Liquid1: Ca 0.4187, Li 0.56827; fcc(Ca): Ca 0.90507, Li 0.09418; CaLi2: Ca 0.33333, Li 0.66667; liquid2: Ca 3.460e-4, Li 0.03853 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 3; `ORC-552DXZM7WF` | | | 503.3 | quasi-peritectic: Liquid2 + liquid1 -> fcc(Ca) + CaLi2 | Liquid2: Ca 3.460e-4, Li 0.03853; liquid1: Ca 0.4187, Li 0.56827; fcc(Ca): Ca 0.90507, Li 0.09418; CaLi2: Ca 0.33333, Li 0.66667 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 4; `ORC-OOUZEWTWY5` | | | 415 | quasi-peritectic: Liquid2 + liquid1 -> bcc(Li) + CaLi2 | Liquid2: Li 0.0709; liquid1: Ca 0.06343, Li 0.92035; bcc(Li): Ca 0.01401, Li 0.98335; CaLi2: Ca 0.33333, Li 0.66667 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 6; `ORC-TWVR2RYV3Y` | | | 415 | eutectic: Liquid1 -> bcc(Li) + CaLi2 + liquid2 | Liquid1: Ca 0.06343, Li 0.92035; bcc(Li): Ca 0.01401, Li 0.98335; CaLi2: Ca 0.33333, Li 0.66667; liquid2: Li 0.0709 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 5; `ORC-UKSAZEALKL` | | | 368.5 | quasi-peritectic: Liquid2 + fcc(Ca) -> bcc(Na) + CaLi2 | Liquid2: Li 0.00689; fcc(Ca): Ca 0.97337, Li 0.02658; bcc(Na): Li 0.00121; CaLi2: Ca 0.33333, Li 0.66667 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 7; `ORC-77CSXEYOK7` | | | 359.7 | quasi-peritectic: Liquid2 + CaLi2 -> bcc(Na) + bcc(Li) | Liquid2: Li 0.03525; CaLi2: Ca 0.33333, Li 0.66667; bcc(Na): Li 0.00496; bcc(Li): Li 0.50054 | unspecified | [1] Zhang 2003 | Table 6, p. 6, row 8; `ORC-RYPB6JM7P6` | | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003). [doi:10.1016/j.calphad.2003.09.001](https://doi.org/10.1016/j.calphad.2003.09.001) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).