Cd–Ga system

18 accepted literature values from 1 paper(s) (experimental 18); 1 calculated phase diagram(s).

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (5) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	18

Accepted values by property group
Property group	Values
mixing / partial	18

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
CdGa-93Zak-LB.tdb	W. Zakulski, Z. Moser, K. Rzyman, H.L. Lukas, S.G. Fries, M. Sukiennik, R. Kaczmarczyk, R. Castanet, J. Phase Equilib., 14, 184-96(1993). doi:10.1007/BF02667807	`cbc5d29057993dcaee0e93370ab4d69474f6da0a3315ae4d4a0a3aee6b2d94fd`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
CdGa-93Zak-LB.tdb	552.07	HCP_A3 (x(Ga) 3.000e-5) + LIQUID#2 (x(Ga) 0.2157) + LIQUID (x(Ga) 0.76814)
CdGa-93Zak-LB.tdb	302.04	HCP_A3 (x(Ga) 3.000e-5) + LIQUID (x(Ga) 0.99327) + ORTHORHOMBIC_A11 (x(Ga) 1)
CdGa-93Zak-LB.tdb	302.04	HCP_A3 (x(Ga) 3.000e-5) + LIQUID (x(Ga) 0.99327) + ORTHORHOMBIC_A11 (x(Ga) 1)
CdGa-93Zak-LB.tdb	302.04	HCP_A3 (x(Ga) 3.000e-5) + LIQUID (x(Ga) 0.99328) + ORTHORHOMBIC_A11 (x(Ga) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Other properties

Mixing / partial (18)

Mixing / partial, Cd–Ga system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Enthalpy of mixing printed: ΔH	2.072 kJ/mol (basis unstated)	593	UNKNOWN alloy: Cd 0.75, Ga 0.25	experimental	[1] Zakulski 1993	Table 2, p. 4, row 1 report
Enthalpy of mixing printed: ΔH	2.541 kJ/mol (basis unstated)	593	UNKNOWN alloy: Cd 0.5, Ga 0.5	experimental	[1] Zakulski 1993	Table 2, p. 4, row 10 report
Enthalpy of mixing printed: ΔH	2.065 kJ/mol (basis unstated)	593	UNKNOWN alloy: Cd 0.25, Ga 0.75	experimental	[1] Zakulski 1993	Table 2, p. 4, row 20 report
Enthalpy of mixing printed: ΔH	2.521 kJ/mol (basis unstated)	602	UNKNOWN alloy: Cd 0.4, Ga 0.6	experimental	[1] Zakulski 1993	Table I, p. 2, row 31 report
Enthalpy of mixing printed: ΔH	2.09 kJ/mol (basis unstated)	602	UNKNOWN alloy: Cd 0.24641, Ga 0.75359	experimental	[1] Zakulski 1993	Table I, p. 2, row 1 report
Enthalpy of mixing printed: ΔH	2.09 kJ/mol (basis unstated)	602	UNKNOWN alloy: Cd 0.24678, Ga 0.75322	experimental	[1] Zakulski 1993	Table I, p. 2, row 9 report
Enthalpy of mixing printed: ΔH	2.385 kJ/mol (basis unstated)	602	UNKNOWN alloy: Cd 0.33181, Ga 0.66819	experimental	[1] Zakulski 1993	Table I, p. 2, row 20 report
Enthalpy of mixing printed: ΔH	2.299 kJ/mol (basis unstated)	659	UNKNOWN alloy: Cd 0.2465, Ga 0.7535	experimental	[1] Zakulski 1993	Table I, p. 2, row 52 report
Enthalpy of mixing printed: ΔH	2.81 kJ/mol (basis unstated)	659	UNKNOWN alloy: Cd 0.41662, Ga 0.58338	experimental	[1] Zakulski 1993	Table I, p. 2, row 72 report
Enthalpy of mixing printed: ΔH	1.874 kJ/mol (basis unstated)	659	UNKNOWN alloy: Cd 0.1755, Ga 0.8245	experimental	[1] Zakulski 1993	Table I, p. 2, row 42 report
Enthalpy of mixing printed: ΔH	1.874 kJ/mol (basis unstated)	659	liquid alloy: Cd 0.1755, Ga 0.8245	experimental	[1] Zakulski 1993	Table 1, p. 3, row 6 report
Enthalpy of mixing printed: ΔH	2.81 kJ/mol (basis unstated)	659	liquid alloy: Cd 0.41662, Ga 0.58338	experimental	[1] Zakulski 1993	Table 1, p. 3, row 36 report
Enthalpy of mixing printed: ΔH	2.299 kJ/mol (basis unstated)	659	liquid alloy: Cd 0.2465, Ga 0.7535	experimental	[1] Zakulski 1993	Table 1, p. 3, row 16 report
Enthalpy of mixing printed: ΔH	2.644 kJ/mol (basis unstated)	662	UNKNOWN alloy: Cd 0.33273, Ga 0.66727	experimental	[1] Zakulski 1993	Table I, p. 2, row 62 report
Enthalpy of mixing printed: ΔH	2.644 kJ/mol (basis unstated)	662	liquid alloy: Cd 0.33273, Ga 0.66727	experimental	[1] Zakulski 1993	Table 1, p. 3, row 26 report
Enthalpy of mixing printed: ΔH	2.916 kJ/mol (basis unstated)	673	UNKNOWN alloy: Cd 0.5, Ga 0.5	experimental	[1] Zakulski 1993	Table 2, p. 4, row 35 report
Enthalpy of mixing printed: ΔH	2.343 kJ/mol (basis unstated)	673	UNKNOWN alloy: Cd 0.75, Ga 0.25	experimental	[1] Zakulski 1993	Table 2, p. 4, row 28 report
Enthalpy of mixing printed: ΔH	2.357 kJ/mol (basis unstated)	673	UNKNOWN alloy: Cd 0.25, Ga 0.75	experimental	[1] Zakulski 1993	Table 2, p. 4, row 44 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

W. Zakulski, Z. Moser, K. Rzyman, H. L. Lukas, S. G. Fries, M. Sukiennik et al., Thermodynamic studies and phase diagrams of the Cd-Ga-In system, JPE 14, 184-196 (1993). doi:10.1007/bf02667807

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}