# Ce–Mn system > Ce–Mn system: 15 accepted literature values (invariant reaction 13, phase transition 2) and 2 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/CE-MN.html · Markdown: https://data.orchid-project.org/systems/CE-MN.md 15 accepted literature values from 1 paper(s) (experimental 10, unspecified 5); 2 calculated phase diagram(s). 2 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV. Data: [JSON](https://data.orchid-project.org/literature/systems/CE-MN.json) · [CSV](https://data.orchid-project.org/systems/CE-MN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#CE-MN) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#CE-MN/CeMn-07Tan.json) · [phases (6)](https://data.orchid-project.org/phases/pages/CE-MN.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/CE-MN.html) · [Markdown](https://data.orchid-project.org/systems/CE-MN.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | experimental | 10 | | unspecified | 5 | Table: Accepted values by property group | Property group | Values | |---|---:| | invariant reaction | 13 | | phase transition | 2 | ## Calculated phase diagrams Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model. Table: Assessments with a calculated phase diagram | TDB file | Assessment | SHA-256 | Links | |---|---|---|---| | CeMn-07Tan.tdb | C. Tang, Y. Du, L. Zhang, H. Xu, Z. Zhu, J. Alloys Compd., 437, 102-6(2007). [doi:10.1016/j.jallcom.2006.07.071](https://doi.org/10.1016/j.jallcom.2006.07.071) | `1d3e4632db5ba67e959d32ef7e4b729d8c2c01603aed6d4d3e68e8a435de54e4` | [viewer](https://orchid-project.org/phase-diagrams/#CE-MN/CeMn-07Tan.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/CeMn-07Tan.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/CeMn-07Tan.json) | | CeMn-24Ye.tdb | H. Ye, J. Wang, Q. Chen, G. Rao, H. Zhou, Mater. Genome Eng. Adv., 2, 39(2024). [doi:10.1002/mgea.39](https://doi.org/10.1002/mgea.39) | `cd632a2aefd2788070df8cd6e858135fe4074ac77adaa69f54e67ea75f76a5b7` | [viewer](https://orchid-project.org/phase-diagrams/#CE-MN/CeMn-24Ye.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/CeMn-24Ye.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/CeMn-24Ye.json) | Table: Calculated three-phase invariants (model, mole fraction of the second component) | TDB file | T (K) | Phases at the invariant | |---|---:|---| | CeMn-07Tan.tdb | 1360.74 | LIQUID (x(Mn) 0.84615) + BCC_A2 (x(Mn) 0.97115) + FCC_A1 (x(Mn) 0.97794) | | CeMn-07Tan.tdb | 1271.27 | LIQUID (x(Mn) 0.71736) + FCC_A1 (x(Mn) 0.9676) + CUB_A13 (x(Mn) 0.98195) | | CeMn-07Tan.tdb | 911.37 | FCC_A1 (x(Mn) 0.01355) + BCC_A2 (x(Mn) 0.05247) + LIQUID (x(Mn) 0.14298) | | CeMn-07Tan.tdb | 898.44 | LIQUID (x(Mn) 0.16629) + CUB_A13 (x(Mn) 0.97193) + CBCC_A12 (x(Mn) 1) | | CeMn-07Tan.tdb | 894.78 | FCC_A1 (x(Mn) 0.01535) + LIQUID (x(Mn) 0.16347) + CBCC_A12 (x(Mn) 1) | | CeMn-07Tan.tdb | 894.78 | FCC_A1 (x(Mn) 0.01538) + LIQUID (x(Mn) 0.16381) + CBCC_A12 (x(Mn) 1) | | CeMn-24Ye.tdb | 1360.17 | LIQUID (x(Mn) 0.8383) + BCC_A2 (x(Mn) 0.96978) + FCC_A1 (x(Mn) 0.97673) | | CeMn-24Ye.tdb | 1270.96 | LIQUID (x(Mn) 0.7092) + FCC_A1 (x(Mn) 0.96707) + CUB_A13 (x(Mn) 0.98151) | | CeMn-24Ye.tdb | 913.48 | FCC_A1 (x(Mn) 0.01353) + BCC_A2 (x(Mn) 0.0514) + LIQUID (x(Mn) 0.15527) | | CeMn-24Ye.tdb | 898.39 | LIQUID (x(Mn) 0.1853) + CUB_A13 (x(Mn) 0.97191) + CBCC_A12 (x(Mn) 1) | | CeMn-24Ye.tdb | 898.39 | LIQUID (x(Mn) 0.18524) + CUB_A13 (x(Mn) 0.97191) + CBCC_A12 (x(Mn) 1) | | CeMn-24Ye.tdb | 894 | FCC_A1 (x(Mn) 0.01509) + LIQUID (x(Mn) 0.18157) + CBCC_A12 (x(Mn) 1) | | CeMn-24Ye.tdb | 894 | FCC_A1 (x(Mn) 0.0151) + LIQUID (x(Mn) 0.18181) + CBCC_A12 (x(Mn) 1) | Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/CE/CE-MN.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/CE/CE-MN.json) · [CALPHAD hull CeMn-07Tan](https://data.orchid-project.org/hulls/calphad-sgte/CE/CE-MN--CeMn-07Tan.json) ## Invariant reactions (literature) Table: Invariant reactions reported in the literature for the Ce–Mn system (13) | T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote | |---:|---|---|---|---|---|---| | 1360.95 | (δMn) -> (γMn) + Liquid | (δMn): Mn 0.9712; (γMn): Mn 0.9779; Liquid: Mn 0.8461 | unspecified | [1] Tang 2007 | Table 1, p. 3, row 12; `ORC-3CMTTRVIXX` | | | 1360.15 | (δMn) -> (γMn) + Liquid | (δMn): Mn 0.98; (γMn): Mn 0.983; Liquid: Mn 0.86 | experimental | [1] Tang 2007; _cites Mirgalovskaya 1957_ | Table 1, p. 3, row 11; `ORC-Q23B4I5XPQ` | | | 1271.15 | (γMn) -> (βMn) + Liquid | (γMn): Mn 0.98; (βMn): Mn 0.99; Liquid: Mn 0.71 | experimental | [1] Tang 2007; _cites Iandelli 1952_ | Table 1, p. 3, row 9; `ORC-KM6HBOFRQQ` | | | 1270.95 | (γMn) -> (βMn) + Liquid | (γMn): Mn 0.9676; (βMn): Mn 0.9819; Liquid: Mn 0.7174 | unspecified | [1] Tang 2007 | Table 1, p. 3, row 10; `ORC-QHEMPAAJPJ` | | | 913.15 | (δCe) -> (γCe) + Liquid | | experimental | [1] Tang 2007 | Table 1, p. 3, row 6; `ORC-2XYG5UZFAY` | | | 911.35 | (δCe) -> (γCe) + Liquid | (δCe): Mn 0.143; (γCe): Mn 0.0525; Liquid: Mn 0.0136 | unspecified | [1] Tang 2007 | Table 1, p. 3, row 5; `ORC-CKQ7LTQ7AK` | | | 911.15 | (δCe) -> (γCe) + Liquid | (δCe): Mn 0.14; (γCe): Mn 0.05; Liquid: Mn 0.02 | experimental | [1] Tang 2007; _cites Thamer 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990078-5) | Table 1, p. 3, row 4; `ORC-FRSZXDEDO7` | | | 898.35 | (βMn) -> (αMn) + Liquid | (βMn): Mn 0.9719; (αMn): Mn 1; Liquid: Mn 0.1663 | unspecified | [1] Tang 2007 | Table 1, p. 3, row 8; `ORC-QWRMHFG377` | | | 898.15 | (βMn) -> (αMn) + Liquid | (βMn): Mn 0.98; (αMn): Mn 0.995; Liquid: Mn 0.163 | experimental | [1] Tang 2007; _cites Tang_ | Table 1, p. 3, row 7; `ORC-MACLYA4AHK` | | | 895.15 | eutectic: Liquid -> (γCe) + (αMn) | Liquid: Mn 0.161; (γCe): Mn 0.02; (αMn): Mn 0.995 | experimental | [1] Tang 2007; _cites Thamer 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990078-5) | Table 1, p. 3, row 1; `ORC-ILMTW7LL56` | | | 895.15 | eutectic: Liquid → (␥Ce) + (␣Mn) | | experimental | [1] Tang 2007; _cites Thamer 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990078-5) | p. 2; `ORC-VJJJQE7P4I` | “The eutectic reaction: Liquid → (␥Ce) + (␣Mn) was determined to be at 16.1 ± 0.5 at.% Mn and 622 ◦ C \[8\].” | | 894.75 | eutectic: Liquid -> (γCe) + (αMn) | Liquid: Mn 0.1635; (γCe): Mn 0.0153; (αMn): Mn 1 | unspecified | [1] Tang 2007 | Table 1, p. 3, row 2; `ORC-QICHO5UF7I` | | | 894.15 | eutectic: Liquid -> (γCe) + (αMn) | | experimental | [1] Tang 2007 | Table 1, p. 3, row 3; `ORC-DBIF54X5BN` | | ## Other properties ### Phase transition (2) Table: Phase transition, Ce–Mn system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Phase transition | 898.15 K | 898.15 | other: (␤Mn) → (␣Mn) + Liquid | experimental | [1] Tang 2007 | p. 2; `ORC-JTIRKULRRM` | “Another invariant reaction, catatectic reaction: (␤Mn) → (␣Mn) + Liquid, was reported to exist at 625 ◦ C.” | | Phase transition | 911.15 K | 911.15 | other: (␦Ce) → (␥Ce) + Liquid | experimental | [1] Tang 2007; _cites Thamer 1964_ [doi](https://doi.org/10.1016/0022-5088%2864%2990078-5) | p. 2; `ORC-PQASK5KK6J` | “The catatectic reaction: (␦Ce) → (␥Ce) + Liquid, in the Cerich side was determined to occur at 5 ± 1 at.% Mn and 638 ◦ C \[8\].” | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. Chengying Tang, Yong Du, Lijun Zhang, Honghui Xu, Zhijun Zhu, Thermodynamic assessment of the Ce–Mn system, Journal of Alloys and Compounds 437, 102-106 (2007). [doi:10.1016/j.jallcom.2006.07.071](https://doi.org/10.1016/j.jallcom.2006.07.071) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859 - R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_phase_diagrams_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Diagrams: calculated binary phase diagrams}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735859}, url = {https://doi.org/10.5281/zenodo.23735859} } @misc{orchid_hulls_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735891}, url = {https://doi.org/10.5281/zenodo.23735891} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).