# Ce system > Ce system: 27 accepted literature values (crystal structure 23, mixing / partial 2, phase transition 2) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/CE.html · Markdown: https://data.orchid-project.org/systems/CE.md 27 accepted literature values from 7 paper(s) (experimental 9, model 5, DFT 4, unspecified 9); 0 calculated phase diagram(s). Data: [JSON](https://data.orchid-project.org/literature/systems/CE.json) · [CSV](https://data.orchid-project.org/systems/CE.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#CE) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/CE.html) · [Markdown](https://data.orchid-project.org/systems/CE.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | experimental | 9 | | model | 5 | | DFT | 4 | | unspecified | 9 | Table: Accepted values by property group | Property group | Values | |---|---:| | phase transition | 2 | | mixing / partial | 2 | | crystal structure | 23 | ## Other properties ### Phase transition (2) Table: Phase transition, Ce system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Phase transition | 1001 K | 1001 | polymorphic: fcc↔bcc | model | [1] Mattern 2014; _cites Massalski 1990_ | Table 1, p. 3, row 2; `ORC-L5CFGFSLF6` | | | Phase transition | 1071 K | 1071 | other: bcc-Ce | unspecified | [1] Mattern 2014; _cites Gschneidner 1999_ [doi](https://doi.org/10.1361/105497199770340590) | Table 1, p. 3, row 1; `ORC-XFHHPLNTBG` | | ### Mixing / partial (2) Table: Mixing / partial, Ce system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Enthalpy of mixing; _printed: ΔH_ | 0 kJ/mol-atom | 1923.15 | liquid; _alloy: Ce 1_ | model | [2] Gröbner 2004 | Table VIII, p. 11, row 2; `ORC-2ONBIZ5QZD.9e6ce3` | | | Enthalpy of mixing; _printed: ΔH_ | 0 kJ/mol-atom | 1923.15 | liquid; _alloy: Ce 1_ | experimental | [2] Gröbner 2004; _cites Ryss 1977_ | Table VIII, p. 11, row 1; `ORC-EB4LAZM5M4.ca03f6` | | ### Crystal structure (23) Table: Crystal structure, Ce system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Lattice a | 5.15 Å | 298.15 | (γ Ce); _alloy: Ce 1_ | experimental | [3] Peng 2011; _cites Pavlov 1967_ | Table 1, p. 2, row 7; `ORC-H376DXN36M` | | | Lattice a | 4.12 Å | 298.15 | (δ Ce); _alloy: Ce 1_ | experimental | [3] Peng 2011; _cites Spedding 1961_ [doi](https://doi.org/10.1016/0022-5088%2861%2990003-0) | Table 1, p. 2, row 8; `ORC-A554B7FFNL` | | | Lattice a | 4.85 Å | 298.15 | αCe; _alloy: Ce 1_ | unspecified | [4] Dong 2013 | Table 1, p. 2, row 2; `ORC-235SZDVB3U` | | | Lattice a | 4.85 Å | 298.15 | αCe; _αCe: Ce 1_ | unspecified | [5] Moustaine 2016; _cites LomelloeTafin 2006_ | Table 1, p. 3, row 2; `ORC-WEOLFLOTZT` | | | Lattice a | 3.681 Å | 298.15 | βCe; _βCe: Ce 1_ | unspecified | [5] Moustaine 2016; _cites LomelloeTafin 2006_ | Table 1, p. 3, row 3; `ORC-DODROVBFP3.c22c47` | | | Lattice a | 3.681 Å | 298.15 | βCe; _alloy: Ce 1_ | unspecified | [4] Dong 2013 | Table 1, p. 2, row 3; `ORC-W5DFKBFDXF.04246d` | | | Lattice a | 5.161 not_printed | 298.15 | γ(Ce) | experimental | [6] Premović 2017; _cites Beaudry 1974_ [doi](https://doi.org/10.1016/0022-5088%2874%2990163-5) | Table 1, p. 2, row 3; `ORC-QMCW45QR34.2cdf34` | | | Lattice a | 5.161 Å | 298.15 | γCe; _alloy: Ce 1_ | unspecified | [4] Dong 2013 | Table 1, p. 2, row 4; `ORC-CHQYBOM66I` | | | Lattice a | 4.12 not_printed | 298.15 | δ(Ce); _alloy: Ce 1_ | model | [6] Premović 2017; _cites Massalski 1990_ | Table 1, p. 2, row 2; `ORC-QUTJ6UQCOU.ffce9d` | | | Lattice a | 4.12 Å | 298.15 | δCe; _alloy: Ce 1_ | unspecified | [4] Dong 2013 | Table 1, p. 2, row 5; `ORC-UH7VDHG3X7` | | | Lattice b | 5.161 not_printed | 298.15 | γ(Ce) | experimental | [6] Premović 2017; _cites Beaudry 1974_ [doi](https://doi.org/10.1016/0022-5088%2874%2990163-5) | Table 1, p. 2, row 3; `ORC-QMCW45QR34.8fea21` | | | Lattice b | 4.12 not_printed | 298.15 | δ(Ce); _alloy: Ce 1_ | model | [6] Premović 2017; _cites Massalski 1990_ | Table 1, p. 2, row 2; `ORC-QUTJ6UQCOU.8826de` | | | Lattice c | 11.857 Å | 298.15 | βCe; _βCe: Ce 1_ | unspecified | [5] Moustaine 2016; _cites LomelloeTafin 2006_ | Table 1, p. 3, row 3; `ORC-DODROVBFP3.525776` | | | Lattice c | 11.857 Å | 298.15 | βCe; _alloy: Ce 1_ | unspecified | [4] Dong 2013 | Table 1, p. 2, row 3; `ORC-W5DFKBFDXF.ad2050` | | | Lattice c | 5.161 not_printed | 298.15 | γ(Ce) | experimental | [6] Premović 2017; _cites Beaudry 1974_ [doi](https://doi.org/10.1016/0022-5088%2874%2990163-5) | Table 1, p. 2, row 3; `ORC-QMCW45QR34.f5f379` | | | Lattice c | 4.12 not_printed | 298.15 | δ(Ce); _alloy: Ce 1_ | model | [6] Premović 2017; _cites Massalski 1990_ | Table 1, p. 2, row 2; `ORC-QUTJ6UQCOU.d1e30f` | | | lattice unspecified axis; _printed: Calculated lattice parameter_ | 3.759 Å | | bcc; _alloy: Ce 1_ | DFT | [7] Zhang 2008 | Table 1, p. 2, row 5; `ORC-Q2VXLQC73N.64877b` | | | lattice unspecified axis; _printed: Lattice parameter_ | 3.756 Å | 1041 | Ce; _alloy: Ce 1_ | DFT | [7] Zhang 2008 | Table 1, p. 2, row 3; `ORC-35EQDN7AUN.cfaa06` | | | lattice unspecified axis; _printed: Lattice parameter_ | 4.11 Å | 1041 | Ce; _alloy: Ce 1_ | experimental | [7] Zhang 2008; _cites Koskenmaki 1981_ | Table 1, p. 2, row 4; `ORC-SXSOTOHSCL.1a860d` | | | lattice unspecified axis; _printed: Lattice parameter_ | 4.11 Å | 1041 | Ce (with magnetic); _alloy: Ce 1_ | experimental | [7] Zhang 2008; _cites Koskenmaki 1981_ | Table 1, p. 2, row 6; `ORC-BDXH2CZH7Q.8b1fdc` | | | lattice unspecified axis; _printed: Lattice parameter_ | 3.759 Å | 1041 | Ce (with magnetic); _alloy: Ce 1_ | DFT | [7] Zhang 2008 | Table 1, p. 2, row 5; `ORC-Q2VXLQC73N.bf484d` | | | lattice unspecified axis; _printed: Calculated lattice parameter_ | 3.756 Å | 1041 | bcc; _alloy: Ce 1_ | DFT | [7] Zhang 2008 | Table 1, p. 2, row 3; `ORC-35EQDN7AUN.5adfc9` | | | lattice unspecified axis; _printed: Lattice parameter_ | 4.11 Å | 1041 | bcc; _alloy: Ce 1_ | experimental | [7] Zhang 2008; _cites Koskenmaki 1981_ | Table 1, p. 2, row 6; `ORC-BDXH2CZH7Q.1225d9` | | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. N. Mattern, Y. Yokoyama, A. Mizuno, J.H. Han, O. Fabrichnaya, H. Wendrock et al., Experimental and thermodynamic assessment of the Ce–Zr system, Calphad 46, 213-219 (2014). [doi:10.1016/j.calphad.2014.05.002](https://doi.org/10.1016/j.calphad.2014.05.002) 2. Joachim Gröbner, Djordje Mirković, Rainer Schmid-Fetzer, Thermodynamic aspects of the constitution, grain refining, and solidification enthalpies of Al-Ce-Si alloys, Metall Mater Trans A 35, 3349-3362 (2004). [doi:10.1007/s11661-004-0172-y](https://doi.org/10.1007/s11661-004-0172-y) 3. Yingbiao Peng, Yong Du, Lijun Zhang, Chunsheng Sha, Shuhong Liu, Feng Zheng et al., Thermodynamic modeling of the C–RE (RE=La, Ce and Pr) systems, Calphad 35, 533-541 (2011). [doi:10.1016/j.calphad.2011.09.002](https://doi.org/10.1016/j.calphad.2011.09.002) 4. H.Q. Dong, X.M. Tao, T. Laurila, V. Vuorinen, M. Paulasto-Kröckel, Thermodynamic modeling of Au–Ce–Sn ternary system, Calphad 42, 38-50 (2013). [doi:10.1016/j.calphad.2013.07.013](https://doi.org/10.1016/j.calphad.2013.07.013) 5. D. Moustaine, K. Mahdouk, Thermodynamic reassessment of the cerium gold binary system, Journal of Alloys and Compounds 683, 599-609 (2016). [doi:10.1016/j.jallcom.2016.05.116](https://doi.org/10.1016/j.jallcom.2016.05.116) 6. Milena Premović, Yong Du, Fan Zhang, Bo Sundman, Duško Minić, Biao Hu, Phase equilibria in the ternary B-Ce-Cu system with a thermodynamic reassessment of the binary B-Ce system, Thermochimica Acta 657, 185-196 (2017). [doi:10.1016/j.tca.2017.10.006](https://doi.org/10.1016/j.tca.2017.10.006) 7. Hui Zhang, Yi Wang, Shunli Shang, Long-Qing Chen, Zi-Kui Liu, Thermodynamic modeling of Mg–Ca–Ce system by combining first-principles and CALPHAD method, Journal of Alloys and Compounds 463, 294-301 (2008). [doi:10.1016/j.jallcom.2007.09.020](https://doi.org/10.1016/j.jallcom.2007.09.020) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).