Co–Cu system

75 accepted literature values from 2 paper(s) (experimental 63, model 12); 4 calculated phase diagram(s). 1 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (4) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	63
model	12

Accepted values by property group
Property group	Values
invariant reaction	12
phase equilibrium	10
mixing / partial	29
heat capacity / entropy / enthalpy	1
activity / EMF / Gibbs energy	23

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
CoCu-00Kub-LB.tdb	J. Kubista, J. Vrestal, J. Phase Equilib., 21, 125-29(2000). doi:10.1361/105497100770340165	`e190588a17897dcba6dee61dc2e7c674ce36a207c0491726a8d9c2ca5913041f`	viewer · TDB · JSON
CoCu-06Pal.tdb	M. Palumbo, S. Curiotto, L. Battezzati, Calphad, 30, 171-78(2006). doi:10.1016/j.calphad.2005.10.007	`e6f9f7cd2524034b8162b1891c3380d13aeb1840c86a06d8af76ef1067602cdb`	viewer · TDB · JSON
CoCu-80Has.tdb	M. Haseba, T. Nishizawa, Calphad, 4, 83-100(1980). doi:10.1016/0364-5916(80)90026-7	`aab8a56c0d106053f31f3346e4d994f30859ea4ec8d0585fc2ed300addb40897`	viewer · TDB · JSON
CoCu-97Oht.tdb	H. Ohtani, H. Suda, K. Ishida, ISIJ Int., 37, 207-16(1997). doi:10.2355/isijinternational.37.207	`dadbec645d9a2e07431ab1aa232a27aa4c28926f0a630e2a5ca264ea88d1ccc8`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
CoCu-00Kub-LB.tdb	1380.75	FCC_A1#2 (x(Cu) 0.09852) + FCC_A1 (x(Cu) 0.91183) + LIQUID (x(Cu) 0.92261)
CoCu-00Kub-LB.tdb	709.66	FCC_A1 (x(Cu) 0.00244) + HCP_A3 (x(Cu) 0.00404) + FCC_A1#2 (x(Cu) 0.99747)
CoCu-06Pal.tdb	1378.27	FCC_A1#2 (x(Cu) 0.12484) + FCC_A1 (x(Cu) 0.90809) + LIQUID (x(Cu) 0.94667)
CoCu-06Pal.tdb	685.61	HCP_A3 (x(Cu) 0.00136) + FCC_A1#2 (x(Cu) 0.00239) + FCC_A1 (x(Cu) 0.99954)
CoCu-80Has.tdb	1383.32	FCC_A1 (x(Cu) 0.10876) + FCC_A1#2 (x(Cu) 0.91943) + LIQUID (x(Cu) 0.94877)
CoCu-80Has.tdb	692.73	HCP_A3 (x(Cu) 2.100e-4) + FCC_A1#2 (x(Cu) 4.500e-4) + FCC_A1 (x(Cu) 0.99971)
CoCu-97Oht.tdb	1383.35	FCC_A1 (x(Cu) 0.10917) + FCC_A1#2 (x(Cu) 0.91939) + LIQUID (x(Cu) 0.94878)
CoCu-97Oht.tdb	692.65	HCP_A3 (x(Cu) 2.100e-4) + FCC_A1#2 (x(Cu) 4.600e-4) + FCC_A1 (x(Cu) 0.99971)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull CoCu-00Kub-LB · CALPHAD hull CoCu-80Has · CALPHAD hull CoCu-97Oht

Invariant reactions (literature)

Invariant reactions reported in the literature for the Co–Cu system (12)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1386	L + (αCo) <=> (αCu)	L: Co 0.057; (αCo): Co 0.883	model	[1] Turchanin 2007	Table 1, p. 6, row 12 report
1385	L + (αCo) <=> (αCu)	L: Co 0.051; (αCo): Co 0.874	model	[1] Turchanin 2007 cites ref. 13	Table 1, p. 6, row 10 report
1385	L + (αCo) <=> (αCu)	L: Co 0.048; (αCo): Co 0.88	experimental	[1] Turchanin 2007 cites ref. 27	Table 1, p. 6, row 3 report
1385	L + (αCo) <=> (αCu)		experimental	[1] Turchanin 2007 cites ref. 28	Table 1, p. 6, row 4 report
1381	L + (αCo) <=> (αCu)	L: Co 0.077; (αCo): Co 0.902	model	[1] Turchanin 2007 cites ref. 15	Table 1, p. 6, row 11 report
1379	L + (αCo) <=> (αCu)	L: Co 0.04; (αCo): Co 0.876	model	[1] Turchanin 2007 cites ref. 6	Table 1, p. 6, row 8 report
1370	L + (αCo) <=> (αCu)	L: Co 0.073; (αCo): Co 0.876	model	[1] Turchanin 2007 cites ref. 12	Table 1, p. 6, row 9 report
717	(αCo) <=> (Cu) + (εCo)	(αCo): Co 0.992; (Cu): Co 0.005; (εCo): Co 0.994	model	[1] Turchanin 2007 cites ref. 12	Table 1, p. 6, row 18 report
698	(Cu) + (αCo) <=> (εCo)	(Cu): Co 4.000e-4; (αCo): Co 0.9981; (εCo): Co 0.9977	model	[1] Turchanin 2007	Table 1, p. 6, row 20 report
695	(αCo) <=> (Cu) + (εCo)	(αCo): Co 0.999; (Cu): Co 4.000e-4; (εCo): Co 0.9996	model	[1] Turchanin 2007 cites ref. 13	Table 1, p. 6, row 19 report
693	(αCo) <=> (Cu) + (εCo)	(αCo): Co 0.9992; (Cu): Co 8.000e-4; (εCo): Co 0.9995	model	[1] Turchanin 2007 cites ref. 6	Table 1, p. 6, row 17 report
615	(αCo) <=> (Cu) + (εCo)	(αCo): Co 0.905	experimental	[1] Turchanin 2007 cites ref. 27	Table 1, p. 6, row 13 report

Other properties

Phase equilibrium (10)

Phase equilibrium, Co–Cu system
Property	Phases / composition	Class	Source	Location
Phase composition	Co-rich phase Co-rich phase: Co 0.9492, Cu 0.0508	experimental	[2] Kubišta 2000	Table 1, p. 3, row 10 report
Phase composition	Co-rich phase Co-rich phase: Co 0.9848, Cu 0.0152	experimental	[2] Kubišta 2000	Table 1, p. 3, row 9 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9274, Cu 0.0726; Cu-rich phase: Co 0.1065, Cu 0.8935	experimental	[2] Kubišta 2000	Table 1, p. 3, row 6 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.8992, Cu 0.1008; Cu-rich phase: Co 0.0715, Cu 0.9285	experimental	[2] Kubišta 2000	Table 1, p. 3, row 4 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9198, Cu 0.0802; Cu-rich phase: Co 0.04, Cu 0.96	experimental	[2] Kubišta 2000	Table 1, p. 3, row 1 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9088, Cu 0.0912; Cu-rich phase: Co 0.1131, Cu 0.8869	experimental	[2] Kubišta 2000	Table 1, p. 3, row 7 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9111, Cu 0.0889; Cu-rich phase: Co 0.0784, Cu 0.9216	experimental	[2] Kubišta 2000	Table 1, p. 3, row 5 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9004, Cu 0.0996; Cu-rich phase: Co 0.0751, Cu 0.9249	experimental	[2] Kubišta 2000	Table 1, p. 3, row 2 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9325, Cu 0.0675; Cu-rich phase: Co 0.1225, Cu 0.8775	experimental	[2] Kubišta 2000	Table 1, p. 3, row 8 report
Phase composition	Co-rich phase + Cu-rich phase Co-rich phase: Co 0.9131, Cu 0.0869; Cu-rich phase: Co 0.0715, Cu 0.9285	experimental	[2] Kubišta 2000	Table 1, p. 3, row 3 report

Mixing / partial (29)

Mixing / partial, Co–Cu system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Enthalpy of mixing printed: ΔH^E	5.575 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.8, Cu 0.2	experimental	[2] Kubišta 2000	Table 4, p. 4, row 3 report
Enthalpy of mixing printed: ΔHE	7.828 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.4, Cu 0.6	experimental	[2] Kubišta 2000	Table 4, p. 4, row 7 report
Enthalpy of mixing printed: ΔHE	6.733 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.3, Cu 0.7	experimental	[2] Kubišta 2000	Table 4, p. 4, row 8 report
Enthalpy of mixing printed: ΔH^E	3.186 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.9, Cu 0.1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 2 report
Enthalpy of mixing printed: HE	8.294 kJ/mol (basis unstated)	1810.15	liquid	model	[2] Kubišta 2000	p. 3 report	Liquid Co-Cu alloys are characterized by positive values of the molar excess Gibbs energies GE at 1537 °C (Fig. 2, Table 4), positive values of the molar excess entropies SE (Table 4), and endothermic molar heat of mixing HE (Fig. 3, Table 4). At that temperature, the maximum HE value is 8294 J·mol-1 at 50at.%Cu, the maximum SE value is 1.00 J·mol-1·K-1 at 40at.%Cu, and the maximum GE value is 65…
Enthalpy of mixing printed: ΔHE	2.785 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.1, Cu 0.9	experimental	[2] Kubišta 2000	Table 4, p. 4, row 10 report
Enthalpy of mixing printed: ΔHE	8.294 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.5, Cu 0.5	experimental	[2] Kubišta 2000	Table 4, p. 4, row 6 report
Enthalpy of mixing printed: ΔHE	7.201 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.7, Cu 0.3	experimental	[2] Kubišta 2000	Table 4, p. 4, row 4 report
Enthalpy of mixing printed: ΔHE	5.04 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.2, Cu 0.8	experimental	[2] Kubišta 2000	Table 4, p. 4, row 9 report
Enthalpy of mixing printed: ΔH^E	8.096 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.6, Cu 0.4	experimental	[2] Kubišta 2000	Table 4, p. 4, row 5 report
Enthalpy of mixing printed: mixing enthalpy	9.7 kJ/mol (basis unstated)	1834		experimental	[1] Turchanin 2007 cites ref. 17	p. 2 report	The integral mixing enthalpies were determined in [17] for 10 alloys of xCo = 0.092-0.931 by mixing metals heated to an experimental temperature of 1834 K in an isothermal calorimeter. It is established that the mixing enthalpy of the system is endothermic and is maximum (9.7 kJ/mole) near the equiatomic composition (Fig. 2).
Entropy of mixing printed: ΔS^E	0.779 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.8, Cu 0.2	experimental	[2] Kubišta 2000	Table 4, p. 4, row 3 report
Entropy of mixing printed: ΔSE	0.847 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.4, Cu 0.6	experimental	[2] Kubišta 2000	Table 4, p. 4, row 7 report
Entropy of mixing printed: ΔSE	0.671 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.3, Cu 0.7	experimental	[2] Kubišta 2000	Table 4, p. 4, row 8 report
Entropy of mixing printed: ΔS^E	0.468 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.9, Cu 0.1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 2 report
Entropy of mixing printed: ΔSE	0.227 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.1, Cu 0.9	experimental	[2] Kubišta 2000	Table 4, p. 4, row 10 report
Entropy of mixing printed: ΔSE	0.966 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.5, Cu 0.5	experimental	[2] Kubišta 2000	Table 4, p. 4, row 6 report
Entropy of mixing printed: ΔSE	0.952 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.7, Cu 0.3	experimental	[2] Kubišta 2000	Table 4, p. 4, row 4 report
Entropy of mixing printed: ΔSE	0.457 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.2, Cu 0.8	experimental	[2] Kubišta 2000	Table 4, p. 4, row 9 report
Entropy of mixing printed: ΔS^E	1.008 J/mol (basis unstated)/K	1810.15	liquid alloy: Co 0.6, Cu 0.4	experimental	[2] Kubišta 2000	Table 4, p. 4, row 5 report
Gibbs energy of mixing printed: ΔG^E	4.165 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.8, Cu 0.2	experimental	[2] Kubišta 2000	Table 4, p. 4, row 3 report
Gibbs energy of mixing printed: ΔGE	6.295 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.4, Cu 0.6	experimental	[2] Kubišta 2000	Table 4, p. 4, row 7 report
Gibbs energy of mixing printed: ΔGE	5.519 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.3, Cu 0.7	experimental	[2] Kubišta 2000	Table 4, p. 4, row 8 report
Gibbs energy of mixing printed: ΔG^E	2.339 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.9, Cu 0.1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 2 report
Gibbs energy of mixing printed: ΔGE	2.374 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.1, Cu 0.9	experimental	[2] Kubišta 2000	Table 4, p. 4, row 10 report
Gibbs energy of mixing printed: ΔGE	6.545 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.5, Cu 0.5	experimental	[2] Kubišta 2000	Table 4, p. 4, row 6 report
Gibbs energy of mixing printed: ΔGE	5.477 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.7, Cu 0.3	experimental	[2] Kubišta 2000	Table 4, p. 4, row 4 report
Gibbs energy of mixing printed: ΔGE	4.213 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.2, Cu 0.8	experimental	[2] Kubišta 2000	Table 4, p. 4, row 9 report
Gibbs energy of mixing printed: ΔG^E	6.272 kJ/mol (basis unstated)	1810.15	liquid alloy: Co 0.6, Cu 0.4	experimental	[2] Kubišta 2000	Table 4, p. 4, row 5 report

Heat capacity / entropy / enthalpy (1)

Heat capacity / entropy / enthalpy, Co–Cu system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
sm excess printed: SE	1 J·mol-1·K-1	1810.15	liquid	model	[2] Kubišta 2000	p. 3 report	Liquid Co-Cu alloys are characterized by positive values of the molar excess Gibbs energies GE at 1537 °C (Fig. 2, Table 4), positive values of the molar excess entropies SE (Table 4), and endothermic molar heat of mixing HE (Fig. 3, Table 4). At that temperature, the maximum HE value is 8294 J·mol-1 at 50at.%Cu, the maximum SE value is 1.00 J·mol-1·K-1 at 40at.%Cu, and the maximum GE value is 65…

Activity / EMF / Gibbs energy (23)

Activity / EMF / Gibbs energy, Co–Cu system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Activity Co printed: a_Co	0.856 1	1810.15	liquid alloy: Co 0.8, Cu 0.2	experimental	[2] Kubišta 2000	Table 4, p. 4, row 3 report
Activity Co printed: aCo	0.746 1	1810.15	liquid alloy: Co 0.4, Cu 0.6	experimental	[2] Kubišta 2000	Table 4, p. 4, row 7 report
Activity Co printed: aCo	0.703 1	1810.15	liquid alloy: Co 0.3, Cu 0.7	experimental	[2] Kubišta 2000	Table 4, p. 4, row 8 report
Activity Co printed: a_Co	0.915 1	1810.15	liquid alloy: Co 0.9, Cu 0.1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 2 report
Activity Co printed: aCo	0.413 1	1810.15	liquid alloy: Co 0.1, Cu 0.9	experimental	[2] Kubišta 2000	Table 4, p. 4, row 10 report
Activity Co printed: aCo	0.769 1	1810.15	liquid alloy: Co 0.5, Cu 0.5	experimental	[2] Kubišta 2000	Table 4, p. 4, row 6 report
Activity Co printed: aCo	0.816 1	1810.15	liquid alloy: Co 0.7, Cu 0.3	experimental	[2] Kubišta 2000	Table 4, p. 4, row 4 report
Activity Co printed: aCo	0.61 1	1810.15	liquid alloy: Co 0.2, Cu 0.8	experimental	[2] Kubišta 2000	Table 4, p. 4, row 9 report
Activity Co printed: a_Co	1 1	1810.15	liquid alloy: Co 1, Cu 0	experimental	[2] Kubišta 2000	Table 4, p. 4, row 1 report
Activity Co printed: a_Co	0.79 1	1810.15	liquid alloy: Co 0.6, Cu 0.4	experimental	[2] Kubišta 2000	Table 4, p. 4, row 5 report
Activity Co printed: aCo	0 1	1810.15	liquid alloy: Co 0, Cu 1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 11 report
Activity Cu printed: a_Cu	0.608 1	1810.15	liquid alloy: Co 0.8, Cu 0.2	experimental	[2] Kubišta 2000	Table 4, p. 4, row 3 report
Activity Cu printed: aCu	0.796 1	1810.15	liquid alloy: Co 0.4, Cu 0.6	experimental	[2] Kubišta 2000	Table 4, p. 4, row 7 report
Activity Cu printed: aCu	0.821 1	1810.15	liquid alloy: Co 0.3, Cu 0.7	experimental	[2] Kubišta 2000	Table 4, p. 4, row 8 report
Activity Cu printed: a_Cu	0.406 1	1810.15	liquid alloy: Co 0.9, Cu 0.1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 2 report
Activity Cu printed: aCu	0.916 1	1810.15	liquid alloy: Co 0.1, Cu 0.9	experimental	[2] Kubišta 2000	Table 4, p. 4, row 10 report
Activity Cu printed: aCu	0.776 1	1810.15	liquid alloy: Co 0.5, Cu 0.5	experimental	[2] Kubišta 2000	Table 4, p. 4, row 6 report
Activity Cu printed: aCu	0.705 1	1810.15	liquid alloy: Co 0.7, Cu 0.3	experimental	[2] Kubišta 2000	Table 4, p. 4, row 4 report
Activity Cu printed: aCu	0.859 1	1810.15	liquid alloy: Co 0.2, Cu 0.8	experimental	[2] Kubišta 2000	Table 4, p. 4, row 9 report
Activity Cu printed: a_Cu	0 1	1810.15	liquid alloy: Co 1, Cu 0	experimental	[2] Kubišta 2000	Table 4, p. 4, row 1 report
Activity Cu printed: a_Cu	0.751 1	1810.15	liquid alloy: Co 0.6, Cu 0.4	experimental	[2] Kubišta 2000	Table 4, p. 4, row 5 report
Activity Cu printed: aCu	1 1	1810.15	liquid alloy: Co 0, Cu 1	experimental	[2] Kubišta 2000	Table 4, p. 4, row 11 report
Gibbs energy printed: GE	6545 J·mol-1	1810.15	liquid	model	[2] Kubišta 2000	p. 3 report	Liquid Co-Cu alloys are characterized by positive values of the molar excess Gibbs energies GE at 1537 °C (Fig. 2, Table 4), positive values of the molar excess entropies SE (Table 4), and endothermic molar heat of mixing HE (Fig. 3, Table 4). At that temperature, the maximum HE value is 8294 J·mol-1 at 50at.%Cu, the maximum SE value is 1.00 J·mol-1·K-1 at 40at.%Cu, and the maximum GE value is 65…

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

M. A. Turchanin, P. G. Agraval, Phase equilibria and thermodynamics of binary copper systems with 3d-metals. V. Copper-cobalt system, Powder Metall Met Ceram 46, 77-89 (2007). doi:10.1007/s11106-007-0013-9
Jaroslav Kubišta, Jan Vřešt’ál, Thermodynamics of the liquid Co-Cu system and calculation of phase diagram, JPE 21, 125-129 (2000). doi:10.1361/105497100770340165

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}