# Cr–Ge–Mn–Si system

> Cr–Ge–Mn–Si system: 21 accepted literature values (invariant reaction 21) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/CR-GE-MN-SI.html · Markdown: https://data.orchid-project.org/systems/CR-GE-MN-SI.md

21 accepted literature values from 1 paper(s) (model 21); 0 calculated phase diagram(s).

Data: [JSON](https://data.orchid-project.org/literature/systems/CR-GE-MN-SI.json) · [CSV](https://data.orchid-project.org/systems/CR-GE-MN-SI.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#CR-GE-MN-SI) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/CR-GE-MN-SI.html) · [Markdown](https://data.orchid-project.org/systems/CR-GE-MN-SI.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| model | 21 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 21 |

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Cr–Ge–Mn–Si system (21)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 1817 | Liquid + A15 + D8m + D88 |  | model | [1] Berche 2015 | Table 4, p. 6, row 21; `ORC-T2PHQQFPYK` |  |
| 1510 | Liquid + A15 + B20 + D8m |  | model | [1] Berche 2015 | Table 4, p. 6, row 15; `ORC-Q6SLQ3PCC4` |  |
| 1499 | Liquid + A15 + Bcc_A2 + σ |  | model | [1] Berche 2015 | Table 4, p. 6, row 14; `ORC-HLQ7FB4F7G` |  |
| 1453 | Liquid + Mn11Ge8 + B20 + D8m |  | model | [1] Berche 2015 | Table 4, p. 6, row 13; `ORC-N23U67JS74` |  |
| 1386 | Liquid + Cub_A13 + Bcc_A2 + σ |  | model | [1] Berche 2015 | Table 4, p. 6, row 12; `ORC-ODRJTTDMYE` |  |
| 1385 | Liquid + Cub_A13 + Bcc_A2 + Fcc_A1 |  | model | [1] Berche 2015 | Table 4, p. 6, row 11; `ORC-RY2IQJG6SZ` |  |
| 1378 | Liquid + Cub_A13 + σ + Fcc_A1 |  | model | [1] Berche 2015 | Table 4, p. 6, row 10; `ORC-CT4XT4KIFC` |  |
| 1347 | Liquid + A15 + B20 + σ |  | model | [1] Berche 2015 | Table 4, p. 6, row 9; `ORC-DTI6YF4WAI` |  |
| 1281 | Liquid + B20 + D8m + Mn11Ge8 |  | model | [1] Berche 2015 | Table 4, p. 6, row 20; `ORC-ESATGJIKBR` |  |
| 1228 | Liquid + Diamond + CrSi2 + B20 |  | model | [1] Berche 2015 | Table 4, p. 6, row 19; `ORC-SUHF6KNJJG` |  |
| 1216 | Liquid + B20 + D8m + Mn11Si19 |  | model | [1] Berche 2015 | Table 4, p. 6, row 18; `ORC-TXNI7WKF2P` |  |
| 1210 | Liquid + B20 + Mn2Ge + D88 |  | model | [1] Berche 2015 | Table 4, p. 6, row 8; `ORC-OKTDJ4IURU` |  |
| 1180 | Liquid + Diamond + D8m + B20 |  | model | [1] Berche 2015 | Table 4, p. 6, row 16; `ORC-3SA6K4RHPM` |  |
| 1179 | Liquid + Diamond + D8m + Mn11Si19 |  | model | [1] Berche 2015 | Table 4, p. 6, row 17; `ORC-QV4ZZY6KGJ` |  |
| 1166 | Liquid + diamond + B20 + Mn11Si19 |  | model | [1] Berche 2015 | Table 4, p. 6, row 7; `ORC-QHPDMIE3IN` |  |
| 1153.5 | Liquid + B20 + Mn2Ge + Mn5Ge2 |  | model | [1] Berche 2015 | Table 4, p. 6, row 6; `ORC-WFCQP2BQV7` |  |
| 1151 | Liquid + σ + B20 + Mn5Ge2 |  | model | [1] Berche 2015 | Table 4, p. 6, row 5; `ORC-X7AQPYC777` |  |
| 1146 | Liquid + Mn3Ge + σ + Fcc_A1 |  | model | [1] Berche 2015 | Table 4, p. 6, row 4; `ORC-RCUWKIQMW3` |  |
| 1143.5 | Liquid + Mn3Ge + σ + Mn5Ge2 |  | model | [1] Berche 2015 | Table 4, p. 6, row 3; `ORC-FYE6ASFWFJ` |  |
| 1072 | Liquid + B20 + Mn11Ge8 + D88 |  | model | [1] Berche 2015 | Table 4, p. 6, row 2; `ORC-QEZZVGBHPO` |  |
| 998 | Liquid + Diamond + B20 + Mn11Ge8 |  | model | [1] Berche 2015 | Table 4, p. 6, row 1; `ORC-5CXXGF3FTN` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. A. Berche, J.C. Tédenac, P. Jund, Ab-initio calculations and CALPHAD description of Cr–Ge–Mn and Cr–Ge–Si, Calphad 49, 50-57 (2015). [doi:10.1016/j.calphad.2015.02.004](https://doi.org/10.1016/j.calphad.2015.02.004)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).
