Fe–Pb system

11 accepted literature values from 1 paper(s) (model 11); 2 calculated phase diagram(s). 17 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (5) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
model	11

Accepted values by property group
Property group	Values
invariant reaction	11

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
FePb-11Vaa.tdb	I. Vaajamo, P. Taskinen, Thermochim. Acta, 524, 56-61(2011). doi:10.1016/j.tca.2011.06.014	`05c82ebb8d79a2c26d144a6dc127bdb45599d84fd916a9dbfafcbdadaa63cf29`	viewer · TDB · JSON
FePb-87Din-LB.tdb	A.T. Dinsdale, D.D. Gohil, NPL, unpublished work, 1987.	`b26c9577ad72412f662da7af2a8dd1b0fb60605e0fdd2913c035404ab4ab631e`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
FePb-11Vaa.tdb	1809.58	BCC_A2 (x(Pb) 1.000e-5) + LIQUID#2 (x(Pb) 7.100e-4) + LIQUID (x(Pb) 0.99424)
FePb-11Vaa.tdb	1809.58	BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 7.100e-4) + LIQUID#2 (x(Pb) 0.99424)
FePb-11Vaa.tdb	1667.46	BCC_A2 (x(Pb) 1.000e-5) + FCC_A1 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.99671)
FePb-11Vaa.tdb	1667.46	FCC_A1 (x(Pb) 1.000e-5) + BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9967)
FePb-11Vaa.tdb	1667.46	FCC_A1 (x(Pb) 1.000e-5) + BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9967)
FePb-11Vaa.tdb	1184.79	BCC_A2 (x(Pb) 1.000e-5) + FCC_A1 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.99981)
FePb-11Vaa.tdb	1184.79	FCC_A1 (x(Pb) 1.000e-5) + BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.99981)
FePb-11Vaa.tdb	600.62	BCC_A2 (x(Pb) 0) + FCC_A1 (x(Pb) 0.99999) + LIQUID (x(Pb) 1)
FePb-87Din-LB.tdb	2020.84	LIQUID (x(Pb) 0.00108) + LIQUID#2 (x(Pb) 0.98988) + GAS (x(Pb) 0.9995)
FePb-87Din-LB.tdb	1810.05	BCC_A2 (x(Pb) 2.000e-5) + LIQUID (x(Pb) 4.800e-4) + LIQUID#2 (x(Pb) 0.99421)
FePb-87Din-LB.tdb	1810.05	BCC_A2 (x(Pb) 2.000e-5) + LIQUID (x(Pb) 4.800e-4) + LIQUID#2 (x(Pb) 0.99421)
FePb-87Din-LB.tdb	1667.49	FCC_A1 (x(Pb) 1.000e-5) + BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9966)
FePb-87Din-LB.tdb	1667.49	BCC_A2 (x(Pb) 1.000e-5) + FCC_A1 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9966)
FePb-87Din-LB.tdb	1667.49	FCC_A1 (x(Pb) 1.000e-5) + BCC_A2 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9966)
FePb-87Din-LB.tdb	1667.49	BCC_A2 (x(Pb) 1.000e-5) + FCC_A1 (x(Pb) 1.000e-5) + LIQUID (x(Pb) 0.9966)
FePb-87Din-LB.tdb	1184.81	FCC_A1 (x(Pb) 0) + BCC_A2 (x(Pb) 0) + LIQUID (x(Pb) 0.99977)
FePb-87Din-LB.tdb	1184.81	BCC_A2 (x(Pb) 0) + FCC_A1 (x(Pb) 0) + LIQUID (x(Pb) 0.99977)
FePb-87Din-LB.tdb	1184.81	FCC_A1 (x(Pb) 0) + BCC_A2 (x(Pb) 0) + LIQUID (x(Pb) 0.99977)
FePb-87Din-LB.tdb	600.61	BCC_A2 (x(Pb) 0) + FCC_A1 (x(Pb) 1) + LIQUID (x(Pb) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull FePb-87Din-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Fe–Pb system (11)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
4277.13	critical point: L1 + L2 -> bcc + L2	L1: Pb 0.496	model	[1] Vaajamo 2011	Table 3, p. 5, row 2 report
4270	critical point: L1 + L2 -> bcc + L2		model	[1] Vaajamo 2011 cites Onderka 2004	Table 3, p. 5, row 1 report
1809.7	monotectic: bcc + L2 -> fcc + L2	L2: Pb 0.9938	model	[1] Vaajamo 2011 cites Onderka 2004	Table 3, p. 5, row 4 report
1809.59	monotectic: bcc + L2 -> fcc + L2	bcc: Pb 1.000e-5; L2: Pb 0.9943	model	[1] Vaajamo 2011	Table 3, p. 5, row 5 report
1808.98	monotectic: bcc + L2 -> fcc + L2	bcc: Pb 0; L2: Pb 0.9916	model	[1] Vaajamo 2011 cites Hamalainen 1990	Table 3, p. 5, row 3 report
1667.7	polymorphic: bcc + L2 -> fcc + L2	L2: Pb 0.9965	model	[1] Vaajamo 2011 cites Onderka 2004	Table 3, p. 5, row 7 report
1667.47	polymorphic: bcc + L2 -> fcc + L2	bcc: Pb 0; L2: Pb 0.9949	model	[1] Vaajamo 2011 cites Hamalainen 1990	Table 3, p. 5, row 6 report
1667.47	polymorphic: bcc + L2 -> fcc + L2	bcc: Pb 1.000e-5; L2: Pb 0.99671	model	[1] Vaajamo 2011	Table 3, p. 5, row 8 report
1184.81	polymorphic: fcc + L2 -> bcc + L2	fcc: Pb 0; L2: Pb 0.9996	model	[1] Vaajamo 2011 cites Hamalainen 1990	Table 3, p. 5, row 9 report
1184.8	polymorphic: fcc + L2 -> bcc + L2	fcc: Pb 1.000e-5; L2: Pb 0.99981	model	[1] Vaajamo 2011	Table 3, p. 5, row 11 report
1184.8	polymorphic: fcc + L2 -> bcc + L2	L2: Pb 0.9998	model	[1] Vaajamo 2011 cites Onderka 2004	Table 3, p. 5, row 10 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

I. Vaajamo, P. Taskinen, A thermodynamic assessment of the iron–lead binary system, Thermochimica Acta 524, 56-61 (2011). doi:10.1016/j.tca.2011.06.014

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}