Fe–Tb system

45 accepted literature values from 1 paper(s) (experimental 15, model 30); 3 calculated phase diagram(s). 1 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (8) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	15
model	30

Accepted values by property group
Property group	Values
invariant reaction	38
phase transition	7

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
FeTb-17Ron.tdb	M.H. Rong, X.L. Chen, J. Wang, G.H. Rao, H.Y. Zhou, Calphad, 59, 154-63(2017). doi:10.1016/j.calphad.2017.10.003	`46346f5bff319295d6485f426e1c534c7b986239e67fd24c2aa0128025114e9f`	viewer · TDB · JSON
FeTb-23Ye.tdb	H. Ye, M. Rong, Q. Chen, Q. Yao, J. Wang, G. Rao, H. Zhou, J. Mater. Inf., 3, 15(2023).	`0eb2e62ea5c9bc113ee57ca55d8fd8a9acb4dcae874a32118b4648934f51e744`	viewer · TDB · JSON
FeTb-94Lan.tdb	S. Landin, J. Agren, J. Alloys Compd., 207-208, 449-53(1994). doi:10.1016/0925-8388(94)90261-5	`4276274a275273a7487c0c4d613e47325771b9d1438c927c46120eebc7c69db3`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
FeTb-17Ron.tdb	1653.64	FCC_A1 (x(Tb) 1.300e-4) + BCC_A2 (x(Tb) 6.200e-4) + LIQUID (x(Tb) 0.07765)
FeTb-17Ron.tdb	1653.64	FCC_A1 (x(Tb) 1.300e-4) + BCC_A2 (x(Tb) 6.200e-4) + LIQUID (x(Tb) 0.07765)
FeTb-17Ron.tdb	1584.44	FCC_A1 (x(Tb) 1.500e-4) + FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.11199)
FeTb-17Ron.tdb	1584.44	FCC_A1 (x(Tb) 1.500e-4) + FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.1119)
FeTb-17Ron.tdb	1560.88	LIQUID (x(Tb) 0.96664) + BCC_A2 (x(Tb) 0.99976) + HCP_A3 (x(Tb) 1)
FeTb-17Ron.tdb	1560.88	LIQUID (x(Tb) 0.9667) + BCC_A2 (x(Tb) 0.99976) + HCP_A3 (x(Tb) 1)
FeTb-17Ron.tdb	1546.16	FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.1989) + FE23TB6_D8A (x(Tb) 0.2069)
FeTb-17Ron.tdb	1546.15	FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.19957) + FE23TB6_D8A (x(Tb) 0.2069)
FeTb-17Ron.tdb	1546.15	FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.19992) + FE23TB6_D8A (x(Tb) 0.2069)
FeTb-17Ron.tdb	1484.17	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.3524)
FeTb-17Ron.tdb	1484.17	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.3518)
FeTb-17Ron.tdb	1458.67	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.39087)
FeTb-17Ron.tdb	1458.67	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.39157)
FeTb-17Ron.tdb	1458.66	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.39118)
FeTb-17Ron.tdb	1184.93	FCC_A1 (x(Tb) 0) + BCC_A2 (x(Tb) 1.000e-5) + FE17TB2 (x(Tb) 0.10526)
FeTb-17Ron.tdb	1184.93	FCC_A1 (x(Tb) 0) + BCC_A2 (x(Tb) 1.000e-5) + FE17TB2 (x(Tb) 0.10526)
FeTb-17Ron.tdb	1119.25	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.69342) + HCP_A3 (x(Tb) 1)
FeTb-17Ron.tdb	1119.25	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.69336) + HCP_A3 (x(Tb) 1)
FeTb-17Ron.tdb	1119.25	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.6935) + HCP_A3 (x(Tb) 1)
FeTb-17Ron.tdb	1119.25	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.6935) + HCP_A3 (x(Tb) 1)
FeTb-23Ye.tdb	1666.88	FCC_A1 (x(Tb) 1.000e-5) + BCC_A2 (x(Tb) 3.000e-5) + LIQUID (x(Tb) 0.05049)
FeTb-23Ye.tdb	1666.88	FCC_A1 (x(Tb) 1.000e-5) + BCC_A2 (x(Tb) 3.000e-5) + LIQUID (x(Tb) 0.0505)
FeTb-23Ye.tdb	1666.88	FCC_A1 (x(Tb) 1.000e-5) + BCC_A2 (x(Tb) 3.000e-5) + LIQUID (x(Tb) 0.05049)
FeTb-23Ye.tdb	1575.15	FCC_A1 (x(Tb) 1.000e-5) + LIQUID (x(Tb) 0.07639) + FE17TB2 (x(Tb) 0.10526)
FeTb-23Ye.tdb	1575.15	FCC_A1 (x(Tb) 1.000e-5) + LIQUID (x(Tb) 0.07641) + FE17TB2 (x(Tb) 0.10526)
FeTb-23Ye.tdb	1575.15	FCC_A1 (x(Tb) 1.000e-5) + LIQUID (x(Tb) 0.07638) + FE17TB2 (x(Tb) 0.10526)
FeTb-23Ye.tdb	1561.4	LIQUID (x(Tb) 0.96804) + BCC_A2 (x(Tb) 0.99987) + HCP_A3 (x(Tb) 1)
FeTb-23Ye.tdb	1561.4	LIQUID (x(Tb) 0.96811) + BCC_A2 (x(Tb) 0.99987) + HCP_A3 (x(Tb) 1)
FeTb-23Ye.tdb	1546.59	FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.16657) + FE23TB6_D8A (x(Tb) 0.2069)
FeTb-23Ye.tdb	1546.59	FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.16624) + FE23TB6_D8A (x(Tb) 0.2069)
FeTb-23Ye.tdb	1485.39	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.31961)
FeTb-23Ye.tdb	1485.39	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.31956)
FeTb-23Ye.tdb	1461.48	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.34893)
FeTb-23Ye.tdb	1461.48	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.34863)
FeTb-23Ye.tdb	1461.48	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.34897)
FeTb-23Ye.tdb	1184.82	BCC_A2 (x(Tb) 0) + FCC_A1 (x(Tb) 0) + FE17TB2 (x(Tb) 0.10526)
FeTb-23Ye.tdb	1116.04	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.67484) + HCP_A3 (x(Tb) 1)
FeTb-23Ye.tdb	1116.04	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.67465) + HCP_A3 (x(Tb) 1)
FeTb-23Ye.tdb	1116.04	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.67502) + HCP_A3 (x(Tb) 1)
FeTb-94Lan.tdb	1637.02	FCC_A1 (x(Tb) 0.00254) + BCC_A2 (x(Tb) 0.00363) + LIQUID (x(Tb) 0.09819)
FeTb-94Lan.tdb	1578.32	FCC_A1 (x(Tb) 0.0028) + FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.13399)
FeTb-94Lan.tdb	1578.32	FCC_A1 (x(Tb) 0.0028) + FE17TB2 (x(Tb) 0.10526) + LIQUID (x(Tb) 0.13387)
FeTb-94Lan.tdb	1560.46	LIQUID (x(Tb) 0.96474) + BCC_A2 (x(Tb) 0.99882) + HCP_A3 (x(Tb) 0.99915)
FeTb-94Lan.tdb	1542.75	FE17TB2 (x(Tb) 0.10526) + FE23TB6_D8A (x(Tb) 0.2069) + LIQUID (x(Tb) 0.21167)
FeTb-94Lan.tdb	1542.75	FE17TB2 (x(Tb) 0.10526) + FE23TB6_D8A (x(Tb) 0.2069) + LIQUID (x(Tb) 0.21131)
FeTb-94Lan.tdb	1542.75	FE17TB2 (x(Tb) 0.10526) + FE23TB6_D8A (x(Tb) 0.2069) + LIQUID (x(Tb) 0.21193)
FeTb-94Lan.tdb	1482.35	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.36103)
FeTb-94Lan.tdb	1482.34	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.3616)
FeTb-94Lan.tdb	1482.34	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.36179)
FeTb-94Lan.tdb	1482.34	FE23TB6_D8A (x(Tb) 0.2069) + FE3TB (x(Tb) 0.25) + LIQUID (x(Tb) 0.3618)
FeTb-94Lan.tdb	1455.8	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.4043)
FeTb-94Lan.tdb	1455.8	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.40366)
FeTb-94Lan.tdb	1455.8	FE3TB (x(Tb) 0.25) + FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.40467)
FeTb-94Lan.tdb	1185.05	FCC_A1 (x(Tb) 9.000e-5) + BCC_A2 (x(Tb) 1.100e-4) + FE17TB2 (x(Tb) 0.10526)
FeTb-94Lan.tdb	1122.85	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.68684) + HCP_A3 (x(Tb) 0.99865)
FeTb-94Lan.tdb	1122.85	FE2TB_C15 (x(Tb) 0.33333) + LIQUID (x(Tb) 0.68674) + HCP_A3 (x(Tb) 0.99865)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull FeTb-17Ron · CALPHAD hull FeTb-94Lan

Invariant reactions (literature)

Invariant reactions reported in the literature for the Fe–Tb system (38)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location	Quote
1667	metatectic/catatectic: bcc(δ-Fe) ↔ fcc(γ-Fe) + L	L: Tb 0.12	experimental	[1] Ye 2023 cites ref. 94	Table 6, p. 12, row 1 report
1666.9	metatectic/catatectic: bcc(δ-Fe) ↔ fcc(γ-Fe) + L	L: Tb 0.05	model	[1] Ye 2023	Table 6, p. 12, row 4 report
1665.1	metatectic/catatectic: bcc(δ-Fe) ↔ fcc(γ-Fe) + L	L: Tb 0.08	model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 2 report
1664	metatectic/catatectic: bcc(δ-Fe) ↔ fcc(γ-Fe) + L	L: Tb 0.1	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 3 report
1585	peritectic		experimental	[1] Ye 2023 cites ref. 92	p. 4 report	Four Fe17Tb2, Fe23Tb6, Fe3Tb, and Fe2Tb intermetallic compounds are produced via the peritectic transformation at 1,585 K, 1,549 K, 1,485 K, and 1,460 K, respectively, and Fe17Tb2 is produced at 1,589 K by the congruent melting.
1579	eutectic: L ↔ Fe17Tb2 + fcc(γ-Fe)	L: Tb 0.082	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 10 report
1576	eutectic: L ↔ Fe17Tb2 + fcc(γ-Fe)	L: Tb 0.075	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 11 report
1575	eutectic: L ↔ Fe17Tb2 + fcc(γ-Fe)	L: Tb 0.076	model	[1] Ye 2023	Table 6, p. 12, row 12 report
1574	eutectic: L ↔ Fe17Tb2+bcc-Fe		experimental	[1] Ye 2023 cites ref. 95	p. 4 report	A eutectic reaction (L ↔ Fe17Tb2+bcc-Fe) takes place according to the DTA results[95] at 1,574 K.
1574	eutectic: L ↔ Fe17Tb2 + fcc(γ-Fe)	L: Tb 0.075	experimental	[1] Ye 2023 cites ref. 95	Table 6, p. 12, row 9 report
1549	eutectic: L ↔ Fe17Tb2 + Fe23Tb6	L: Tb 0.216	experimental	[1] Ye 2023 cites ref. 92	Table 6, p. 12, row 17 report
1549	peritectic		experimental	[1] Ye 2023 cites ref. 92	p. 4 report	Four Fe17Tb2, Fe23Tb6, Fe3Tb, and Fe2Tb intermetallic compounds are produced via the peritectic transformation at 1,585 K, 1,549 K, 1,485 K, and 1,460 K, respectively, and Fe17Tb2 is produced at 1,589 K by the congruent melting.
1547	eutectic: L ↔ Fe17Tb2 + Fe23Tb6		experimental	[1] Ye 2023 cites ref. 95	Table 6, p. 12, row 18 report
1546.5	eutectic: L ↔ Fe17Tb2 + Fe23Tb6	L: Tb 0.167	model	[1] Ye 2023	Table 6, p. 12, row 22 report
1546	eutectic: L ↔ Fe17Tb2 + Fe23Tb6	L: Tb 0.208	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 21 report
1546	eutectic: L ↔ Fe17Tb2 + Fe23Tb6	L: Tb 0.19	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 20 report
1542.7	eutectic: L ↔ Fe17Tb2 + Fe23Tb6	L: Tb 0.212	model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 19 report
1486	peritectic: L+ Fe23Tb6 ↔ Fe3Tb	L: Tb 0.319	model	[1] Ye 2023	Table 6, p. 12, row 29 report
1485	peritectic: L+ Fe23Tb6 ↔ Fe3Tb	L: Tb 0.34	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 28 report
1485	peritectic: L+ Fe23Tb6 ↔ Fe3Tb	L: Tb 0.349	experimental	[1] Ye 2023 cites ref. 92	Table 6, p. 12, row 25 report
1485	peritectic		experimental	[1] Ye 2023 cites ref. 92	p. 4 report	Four Fe17Tb2, Fe23Tb6, Fe3Tb, and Fe2Tb intermetallic compounds are produced via the peritectic transformation at 1,585 K, 1,549 K, 1,485 K, and 1,460 K, respectively, and Fe17Tb2 is produced at 1,589 K by the congruent melting.
1481	peritectic: L+ Fe23Tb6 ↔ Fe3Tb	L: Tb 0.388	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 27 report
1473.1	peritectic: L+ Fe23Tb6 ↔ Fe3Tb	L: Tb 0.361	model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 26 report
1462.7	peritectic: L + Fe3Tb ↔ Fe2Tb	L: Tb 0.348	model	[1] Ye 2023	Table 6, p. 12, row 34 report
1460	peritectic: L + Fe3Tb ↔ Fe2Tb	L: Tb 0.405	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 33 report
1460	peritectic: L + Fe3Tb ↔ Fe2Tb	L: Tb 0.412	experimental	[1] Ye 2023 cites ref. 92	Table 6, p. 12, row 30 report
1460	peritectic		experimental	[1] Ye 2023 cites ref. 92	p. 4 report	Four Fe17Tb2, Fe23Tb6, Fe3Tb, and Fe2Tb intermetallic compounds are produced via the peritectic transformation at 1,585 K, 1,549 K, 1,485 K, and 1,460 K, respectively, and Fe17Tb2 is produced at 1,589 K by the congruent melting.
1459	peritectic: L + Fe3Tb ↔ Fe2Tb	L: Tb 0.424	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 32 report
1456.6	peritectic: L + Fe3Tb ↔ Fe2Tb	L: Tb 0.403	model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 31 report
1185	peritectoid: Fe17Tb2 + fcc(γ-Fe) ↔ bcc(α-Fe)		model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 7 report
1185	peritectoid: Fe17Tb2 + fcc(γ-Fe) ↔ bcc(α-Fe)		experimental	[1] Ye 2023 cites ref. 94	Table 6, p. 12, row 5 report
1184.8	peritectoid: Fe17Tb2 + fcc(γ-Fe) ↔ bcc(α-Fe)		model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 6 report
1184.8	peritectoid: Fe17Tb2 + fcc(γ-Fe) ↔ bcc(α-Fe)		model	[1] Ye 2023	Table 6, p. 12, row 8 report
1123	eutectic: L ↔ Fe2Tb + hcp-Tb	L: Tb 0.687	model	[1] Ye 2023 cites ref. 104	Table 6, p. 12, row 36 report
1122	eutectic: L ↔ Fe2Tb + hcp-Tb	L: Tb 0.7	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 37 report
1120	eutectic: L ↔ Fe2Tb + hcp-Tb	L: Tb 0.69	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 38 report
1120	eutectic: L ↔ Fe2Tb + hcp-Tb	L: Tb 0.72	experimental	[1] Ye 2023 cites ref. 92	Table 6, p. 12, row 35 report
1117.1	eutectic: L ↔ Fe2Tb + hcp-Tb	L: Tb 0.675	model	[1] Ye 2023	Table 6, p. 12, row 39 report

Other properties

Phase transition (7)

Phase transition, Fe–Tb system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	1547 K	1547	congruent melting: L ↔ Fe23Tb6 L: Tb 0.207	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 23 report
Phase transition	1561.1 K	1561.1	congruent melting: L ↔ Fe23Tb6 L: Tb 0.207	model	[1] Ye 2023	Table 6, p. 12, row 24 report
Phase transition	1585 K	1585	congruent melting: L ↔ Fe17Tb2 L: Tb 0.105	model	[1] Ye 2023 cites (cal	Table 6, p. 12, row 14 report
Phase transition	1586 K	1586	congruent melting: L ↔ Fe17Tb2 L: Tb 0.105	model	[1] Ye 2023 cites ref. 27	Table 6, p. 12, row 15 report
Phase transition	1587.5 K	1587.5	congruent melting: L ↔ Fe17Tb2 L: Tb 0.105	model	[1] Ye 2023	Table 6, p. 12, row 16 report
Phase transition	1589 K	1589	congruent melting: L ↔ Fe17Tb2 L: Tb 0.105	experimental	[1] Ye 2023 cites ref. 95	Table 6, p. 12, row 13 report
Phase transition	1589 K	1589	congruent transformation	experimental	[1] Ye 2023 cites ref. 92	p. 4 report	Four Fe17Tb2, Fe23Tb6, Fe3Tb, and Fe2Tb intermetallic compounds are produced via the peritectic transformation at 1,585 K, 1,549 K, 1,485 K, and 1,460 K, respectively, and Fe17Tb2 is produced at 1,589 K by the congruent melting.

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Hongjian Ye, Maohua Rong, Qing Chen, Qingrong Yao, Jiang Wang, Guanghui Rao et al., Assessment of phase equilibria and thermodynamic properties in the Fe-RE (RE = rare earth metals) binary systems, J Mater Inf 3 (2023). doi:10.20517/jmi.2023.08

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}