Ga–Na system

14 accepted literature values from 1 paper(s) (experimental 8, model 6); 1 calculated phase diagram(s).

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (7) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	8
model	6

Accepted values by property group
Property group	Values
invariant reaction	8
formation	6

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
GaNa-07Wan.tdb	J. Wang, W. Yuan, M. Li, J. Crystal Growth, 307, 59-65(2007). doi:10.1016/j.jcrysgro.2007.05.044	`be24553ddd1d9c9aea912ad9bdc7ed2aa4206d08f95b9dd78e9ef60c1e28aaf0`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
GaNa-07Wan.tdb	798.35	GA39NA22 (x(Na) 0.36066) + LIQUID#2 (x(Na) 0.61119) + LIQUID (x(Na) 0.91791)
GaNa-07Wan.tdb	776.41	LIQUID (x(Na) 0.17653) + GA4NA_D13 (x(Na) 0.2) + GA39NA22 (x(Na) 0.36066)
GaNa-07Wan.tdb	776.41	LIQUID (x(Na) 0.17598) + GA4NA_D13 (x(Na) 0.2) + GA39NA22 (x(Na) 0.36066)
GaNa-07Wan.tdb	370.89	GA39NA22 (x(Na) 0.36066) + BCC_A2 (x(Na) 0.99995) + LIQUID (x(Na) 0.99999)
GaNa-07Wan.tdb	370.89	GA39NA22 (x(Na) 0.36066) + BCC_A2 (x(Na) 0.99995) + LIQUID (x(Na) 0.99999)
GaNa-07Wan.tdb	302.91	ORTHORHOMBIC_A11 (x(Na) 0) + LIQUID (x(Na) 0) + GA4NA_D13 (x(Na) 0.2)

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ga–Na system (8)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
797.15	monotectic: Liquid1 -> Liquid2 + Ga39Na22	Liquid1: Na 0.611; Liquid2: Na 0.918; Ga39Na22: Na 0.361	model	[1] Wang 2007	Table 2, p. 4, row 5 report
792.15	monotectic: Liquid1 -> Liquid2 + Ga39Na22	Liquid1: Na 0.6; Liquid2: Na 0.893; Ga39Na22: Na 0.361	experimental	[1] Wang 2007 cites Sh 1980	Table 2, p. 4, row 6 report
777.15	peritectic: NaGa4 -> Liquid + Ga39Na22	NaGa4: Na 0.2; Liquid: Na 0.176; Ga39Na22: Na 0.361	model	[1] Wang 2007	Table 2, p. 4, row 3 report
772.15	eutectic: Liquid -> Ga4Na + Ga39Na22	Liquid: Na 0.205; Ga4Na: Na 0.2; Ga39Na22: Na 0.361	experimental	[1] Wang 2007 cites Feschotte 1956	Table 2, p. 4, row 4 report
370.95	eutectic: Liquid -> Na + Ga39Na22	Liquid: Na 1; Na: Na 1; Ga39Na22: Na 0.361	experimental	[1] Wang 2007 cites Rinck 1960	Table 2, p. 4, row 8 report
370.95	eutectic: Liquid -> Na + Ga39Na22	Liquid: Na 1; Na: Na 1; Ga39Na22: Na 0.361	model	[1] Wang 2007	Table 2, p. 4, row 7 report
302.95	eutectic: Liquid -> Ga + Ga4Na	Liquid: Na 0; Ga: Na 0; Ga4Na: Na 0.2	model	[1] Wang 2007	Table 2, p. 4, row 1 report
302.95	eutectic: Liquid -> Ga + Ga4Na	Liquid: Na 3.000e-5; Ga: Na 0; Ga4Na: Na 0.2	experimental	[1] Wang 2007 cites Gilfillian 1934	Table 2, p. 4, row 2 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Ga–Na system (6)
Phase	Compound	Value	T (K)	Class	MP DFT (kJ/mol-atom)	OQMD DFT (kJ/mol-atom)	Source	Location
Ga39Na22		-25.5 kJ/mol-atom	723.15	model			[1] Wang 2007	Table 3, p. 4, row 4 report
Ga39Na22		-23.5 kJ/mol-atom	723.15	experimental			[1] Wang 2007 cites Zabdyr 1988 doi	Table 3, p. 4, row 6 report
Ga39Na22		-21.5 kJ/mol-atom	723.15	experimental			[1] Wang 2007 cites Gambino 1973 doi	Table 3, p. 4, row 5 report
Ga4Na	Ga4Na	-20.9 kJ/mol-atom	723.15	experimental	-13.759 (mp-aaaaaarm)	-15.938 (oqmd-17259)	[1] Wang 2007 cites Zabdyr 1983	Table 3, p. 4, row 3 report
Ga4Na	Ga4Na	-20.1 kJ/mol-atom	723.15	model	-13.759 (mp-aaaaaarm)	-15.938 (oqmd-17259)	[1] Wang 2007	Table 3, p. 4, row 1 report
Ga4Na	Ga4Na	-17.5 kJ/mol-atom	723.15	experimental	-13.759 (mp-aaaaaarm)	-15.938 (oqmd-17259)	[1] Wang 2007 cites Gambino 1973 doi	Table 3, p. 4, row 2 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Jingfang Wang, Wenxia Yuan, Min Li, Thermodynamic modeling of the Ga–N–Na system, Journal of Crystal Growth 307, 59-65 (2007). doi:10.1016/j.jcrysgro.2007.05.044

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}