# Ge–Li system

> Ge–Li system: 311 accepted literature values (activity / EMF / Gibbs energy 209, invariant reaction 71, formation 29, phase transition 2) and 2 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/GE-LI.html · Markdown: https://data.orchid-project.org/systems/GE-LI.md

311 accepted literature values from 2 paper(s) (experimental 236, model 60, DFT 8, unspecified 7); 2 calculated phase diagram(s). 36 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/GE-LI.json) · [CSV](https://data.orchid-project.org/systems/GE-LI.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#GE-LI) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#GE-LI/GeLi-18Wan.json) · [phases (16)](https://data.orchid-project.org/phases/pages/GE-LI.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/GE-LI.html) · [Markdown](https://data.orchid-project.org/systems/GE-LI.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 236 |
| model | 60 |
| DFT | 8 |
| unspecified | 7 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 71 |
| phase transition | 2 |
| formation | 29 |
| activity / EMF / Gibbs energy | 209 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| GeLi-18Wan.tdb | S. Wang, Y. Du, Y. Peng, P. Zhou, X. Yuan, S. Liu, J. Phase Equilib. Diffus., 39, 315-23(2018). [doi:10.1007/s11669-018-0632-5](https://doi.org/10.1007/s11669-018-0632-5) | `5eb8811b38c848dac3d3c2d886984a789eb4d77974b4203feb3f86fda1ed8c19` | [viewer](https://orchid-project.org/phase-diagrams/#GE-LI/GeLi-18Wan.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/GeLi-18Wan.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/GeLi-18Wan.json) |
| GeLi-22Gie.tdb | W. Gierlotka, A. Debski, M. Zabrocki, A. Goral, W. Gasior, J. Chem. Thermodyn., 175, 106883(2022). [doi:10.1016/j.jct.2022.106883](https://doi.org/10.1016/j.jct.2022.106883) | `ce9879aaebef3c3cca842c50a6a2df1d996510f02c5880caf8dfcda8f67fb47d` | [viewer](https://orchid-project.org/phase-diagrams/#GE-LI/GeLi-22Gie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/GeLi-22Gie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/GeLi-22Gie.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| GeLi-18Wan.tdb | 1019.74 | GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.70549) + GE4LI13 (x(Li) 0.76471) |
| GeLi-18Wan.tdb | 1019.74 | GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.70538) + GE4LI13 (x(Li) 0.76471) |
| GeLi-18Wan.tdb | 1019.74 | GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.7057) + GE4LI13 (x(Li) 0.76471) |
| GeLi-18Wan.tdb | 1011.45 | LIQUID (x(Li) 0.67038) + GE4LI9 (x(Li) 0.69231) + GE6LI14 (x(Li) 0.7) |
| GeLi-18Wan.tdb | 990.13 | GE4LI13 (x(Li) 0.76471) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.84034) |
| GeLi-18Wan.tdb | 990.13 | GE4LI13 (x(Li) 0.76471) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.8402) |
| GeLi-18Wan.tdb | 890.12 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89429) |
| GeLi-18Wan.tdb | 890.12 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89423) |
| GeLi-18Wan.tdb | 890.12 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89413) |
| GeLi-18Wan.tdb | 798.26 | LIQUID (x(Li) 0.53507) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231) |
| GeLi-18Wan.tdb | 797.93 | GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53482) + GE7LI12 (x(Li) 0.63158) |
| GeLi-18Wan.tdb | 797.93 | GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53483) + GE7LI12 (x(Li) 0.63158) |
| GeLi-18Wan.tdb | 791.72 | GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93117) |
| GeLi-18Wan.tdb | 791.72 | GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.9311) |
| GeLi-18Wan.tdb | 791.72 | GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93124) |
| GeLi-18Wan.tdb | 791.2 | DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.44511) + GELI (x(Li) 0.5) |
| GeLi-18Wan.tdb | 784.69 | DIAMOND_A4 (x(Li) 0) + GE12LI7 (x(Li) 0.36842) + GELI (x(Li) 0.5) |
| GeLi-18Wan.tdb | 670.84 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) |
| GeLi-18Wan.tdb | 453.33 | GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99953) + BCC_A2 (x(Li) 1) |
| GeLi-18Wan.tdb | 453.33 | GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99954) + BCC_A2 (x(Li) 1) |
| GeLi-22Gie.tdb | 1033.56 | GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73852) + GE2LI7 (x(Li) 0.77778) |
| GeLi-22Gie.tdb | 1033.55 | GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73875) + GE2LI7 (x(Li) 0.77778) |
| GeLi-22Gie.tdb | 1033.55 | GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73884) + GE2LI7 (x(Li) 0.77778) |
| GeLi-22Gie.tdb | 1018.15 | LIQUID (x(Li) 0.64185) + GE4LI9 (x(Li) 0.69231) + GE3LI7 (x(Li) 0.7) |
| GeLi-22Gie.tdb | 977.48 | GE2LI7 (x(Li) 0.77778) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.85599) |
| GeLi-22Gie.tdb | 977.48 | GE2LI7 (x(Li) 0.77778) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.85582) |
| GeLi-22Gie.tdb | 900.21 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.89319) |
| GeLi-22Gie.tdb | 900.21 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.8931) |
| GeLi-22Gie.tdb | 900.21 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.89292) |
| GeLi-22Gie.tdb | 812.8 | DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.49446) + GELI (x(Li) 0.5) |
| GeLi-22Gie.tdb | 812.8 | DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.49408) + GELI (x(Li) 0.5) |
| GeLi-22Gie.tdb | 808.16 | LIQUID (x(Li) 0.53669) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231) |
| GeLi-22Gie.tdb | 808.16 | LIQUID (x(Li) 0.53669) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231) |
| GeLi-22Gie.tdb | 805.5 | GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53476) + GE7LI12 (x(Li) 0.63158) |
| GeLi-22Gie.tdb | 805.5 | GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53476) + GE7LI12 (x(Li) 0.63158) |
| GeLi-22Gie.tdb | 795.07 | GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93574) |
| GeLi-22Gie.tdb | 795.07 | GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.9357) |
| GeLi-22Gie.tdb | 795.07 | GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93584) |
| GeLi-22Gie.tdb | 784.34 | DIAMOND_A4 (x(Li) 0) + GE12LI7 (x(Li) 0.36842) + GELI (x(Li) 0.5) |
| GeLi-22Gie.tdb | 672.9 | GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) |
| GeLi-22Gie.tdb | 453.5 | GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99982) + BCC_A2 (x(Li) 1) |
| GeLi-22Gie.tdb | 453.5 | GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99982) + BCC_A2 (x(Li) 1) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/GE/GE-LI.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/GE/GE-LI.json) · [CALPHAD hull GeLi-18Wan](https://data.orchid-project.org/hulls/calphad-sgte/GE/GE-LI--GeLi-18Wan.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Ge–Li system (71)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 1034 | eutectic: Liquid -> Ge3Li7 + Ge2Li7 | L: Li 0.738; Ge3Li7: Ge 0.3, Li 0.7; Ge2Li7: Ge 0.222222, Li 0.777778 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 1; `ORC-MOEITBNVQV` |  |
| 1019.75 | L = Li14Ge6 + Li13Ge4 | Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706 | model | [2] Wang 2018 | Table 4, p. 7, row 40; `ORC-MVD6YLIXRJ` |  |
| 1019 | Liquid + Ge3Li7 -> Ge4Li9 | L: Li 0.64; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 2; `ORC-AHP4S6QNVG` |  |
| 1015.95 | L = Li14Ge6 + Li13Ge4 | Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706 | model | [2] Wang 2018 | Table 4, p. 7, row 39; `ORC-2COBD5Q2GM` |  |
| 1013.15 | L + Li14Ge6 = Li9Ge4 | Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 6; `ORC-RJUBMUPH5O` |  |
| 1013 | Liquid + Ge3Li7 -> Ge4Li9 | Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 5; `ORC-VWBYWSODF6` |  |
| 1012.35 | L + Li14Ge6 = Li9Ge4 | Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308 | model | [2] Wang 2018 | Table 4, p. 7, row 41; `ORC-2PTFQEKWLU` |  |
| 1012 | Liquid + Ge3Li7 -> Ge4Li9 | L: Li 0.682; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 3; `ORC-I44KAJ2J6E` |  |
| 1011.55 | L + Li14Ge6 = Li9Ge4 | Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308 | model | [2] Wang 2018 | Table 4, p. 7, row 42; `ORC-WRINUT2VKO` |  |
| 1011 | Liquid + Ge3Li7 -> Ge4Li9 | L: Li 0.67; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 4; `ORC-7A7K2OCR2U` |  |
| 1003.15 | L = Li14Ge6 + Li13Ge4 | Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 3; `ORC-MPPGHWFRA2` |  |
| 995.05 | L + Li13Ge4 = Li15Ge4 | Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474 | model | [2] Wang 2018 | Table 4, p. 7, row 43; `ORC-USBGYRUOCP` |  |
| 995 | Liquid + Ge2Li7 -> Ge4Li15 | L: Li 0.837; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 7; `ORC-EAWN5TRR4V` |  |
| 994 | Liquid + Ge2Li7 -> Ge4Li15 | L: Li 0.841; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 8; `ORC-CCYC23DGWT` |  |
| 989.75 | L + Li13Ge4 = Li15Ge4 | Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474 | model | [2] Wang 2018 | Table 4, p. 7, row 44; `ORC-R2QFK67NA3` |  |
| 977 | Liquid + Ge2Li7 -> Ge4Li15 | L: Li 0.858; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 6; `ORC-7EFXPBIWP6` |  |
| 963.15 | L = Li13Ge4 + Li15Ge4 | Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 10; `ORC-VGQH3SAKCU` |  |
| 913.15 | L + Li15Ge4 = Li4Ge | Li15Ge4: Li 0.789474; Li4Ge: Li 0.8 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 14; `ORC-HTHCVINBYV` |  |
| 901 | Liquid + Ge5Li14 -> GeLi4.096 | L: Li 0.894; GeLi4.096: Ge 0.196232, Li 0.803768 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 9; `ORC-R4PNCI2GBV` |  |
| 900.15 | L + Li15Ge4 = Li4.1Ge | Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922 | experimental | [2] Wang 2018; _cites Zeilinger 2014_ [doi](https://doi.org/10.1039/c4dt00743c) | Table 4, p. 7, row 13; `ORC-I7VZRZ3EQS` |  |
| 900 | Liquid + Ge5Li14 -> GeLi4.096 | GeLi4.096: Ge 0.196232, Li 0.803768 | experimental | [1] Gierlotka 2022; _cites Zeilinger 2014_ [doi](https://doi.org/10.1039/c4dt00743c) | Table 11, p. 9, row 12; `ORC-JXTYZ3YAI7` |  |
| 897.45 | L + Li15Ge4 = Li4.1Ge | Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922 | model | [2] Wang 2018 | Table 4, p. 7, row 45; `ORC-7VBOD2QAAA` |  |
| 897 | Liquid + Ge5Li14 -> GeLi4.096 | L: Li 0.891; GeLi4.096: Ge 0.196232, Li 0.803768 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 10; `ORC-6DANEHBXWR` |  |
| 888.15 | L + Li15Ge4 = Li4.1Ge | Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922 | model | [2] Wang 2018 | Table 4, p. 7, row 46; `ORC-HC4AYOOQ6U` |  |
| 888 | Liquid + Ge5Li14 -> GeLi4.096 | L: Li 0.895; GeLi4.096: Ge 0.196232, Li 0.803768 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 11; `ORC-36BMY44XZ2` |  |
| 811 | Liquid + Ge4Li9 -> Ge3Li7 | L: Li 0.527; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 13; `ORC-SURTTLP337` |  |
| 810 | eutectic: Liquid -> GeLi + Diamond_A4 | L: Li 0.483; GeLi: Ge 0.5, Li 0.5 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 18; `ORC-IHK4OB65SS` |  |
| 809 | eutectic: Liquid -> GeLi + Ge7Li12 | L: Li 0.522; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 22; `ORC-SLYIT3WQ6R` |  |
| 803.15 | L = (Ge) + LiGe | (Ge): Li 0; LiGe: Li 0.5 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 17; `ORC-VGZ6TWEVGQ` |  |
| 803 | eutectic: Liquid -> GeLi + Diamond_A4 | GeLi: Ge 0.5, Li 0.5 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 21; `ORC-4G7A556GXP` |  |
| 801.15 | L + Li9Ge4 = Li12Ge7 | Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579 | experimental | [2] Wang 2018; _cites Pell 1957_ [doi](https://doi.org/10.1016/0022-3697%2857%2990050-1) | Table 4, p. 7, row 28; `ORC-W5RJEZ6J2M` |  |
| 801 | Liquid + Ge4Li9 -> Ge3Li7 | Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7 | experimental | [1] Gierlotka 2022; _cites Pell 1957_ [doi](https://doi.org/10.1016/0022-3697%2857%2990050-1) | Table 11, p. 9, row 17; `ORC-IH4YUQ3AYT` |  |
| 798.15 | L + Li9Ge4 = Li12Ge7 | Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579 | model | [2] Wang 2018 | Table 4, p. 7, row 54; `ORC-EIJLLPIX5C` |  |
| 798 | Liquid + Ge4Li9 -> Ge3Li7 | L: Li 0.535; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 15; `ORC-3LEF3ABUJ3` |  |
| 798 | eutectic: Liquid -> GeLi + Ge7Li12 | L: Li 0.535; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 24; `ORC-N4YUWFJ72O` |  |
| 797.95 | L = Li12Ge7 + LiGe | Li12Ge7: Li 0.631579; LiGe: Li 0.5 | model | [2] Wang 2018 | Table 4, p. 7, row 56; `ORC-2WYWLNSNMW` |  |
| 795.45 | L = (Ge) + LiGe | (Ge): Li 0; LiGe: Li 0.5 | model | [2] Wang 2018 | Table 4, p. 7, row 47; `ORC-5YOMETHD2Z` |  |
| 795 | eutectic: Liquid -> GeLi + Diamond_A4 | L: Li 0.462; GeLi: Ge 0.5, Li 0.5 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 19; `ORC-U5ZRSP2IGW` |  |
| 794.15 | L + Li4.1Ge = Li17Ge4 | Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524 | experimental | [2] Wang 2018; _cites Zeilinger 2014_ [doi](https://doi.org/10.1039/c4dt00743c) | Table 4, p. 7, row 20; `ORC-JAETRHMZWF` |  |
| 794 | Liquid + GeLi4.096 -> Ge4Li17 | L: Li 0.936; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 26; `ORC-3MI4ROPIZ3` |  |
| 794 | Liquid + GeLi4.096 -> Ge4Li17 | GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 29; `ORC-7YKBOTEZLW` |  |
| 791.45 | L + Li4.1Ge = Li17Ge4 | Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524 | model | [2] Wang 2018 | Table 4, p. 7, row 50; `ORC-T3HVMXTVEP` |  |
| 791.25 | L + Li4.1Ge = Li17Ge4 | Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524 | model | [2] Wang 2018 | Table 4, p. 7, row 49; `ORC-ST63UVSIAK` |  |
| 791.15 | L = (Ge) + LiGe | (Ge): Li 0; LiGe: Li 0.5 | model | [2] Wang 2018 | Table 4, p. 7, row 48; `ORC-OKT4VT64IW` |  |
| 791 | eutectic: Liquid -> GeLi + Diamond_A4 | L: Li 0.455; GeLi: Ge 0.5, Li 0.5 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 20; `ORC-2ZK2LKS6QB` |  |
| 789 | Liquid + GeLi4.096 -> Ge4Li17 | L: Li 0.94; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 27; `ORC-7GJY2K7OPN` |  |
| 789 | Liquid + GeLi4.096 -> Ge4Li17 | L: Li 0.93; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 28; `ORC-XLMK2KWR5O` |  |
| 783.35 | (Ge) + LiGe = Li7Ge12 | (Ge): Li 0; LiGe: Li 0.5; Li7Ge12: Li 0.368421 | model | [2] Wang 2018 | Table 4, p. 7, row 52; `ORC-K766B4LFLS.66071d` |  |
| 783.15 | (Ge) + LiGe = Li7Ge12 | (Ge): Li 0; LiGe: Li 0.5; Li7Ge12: Li 0.368421 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 24; `ORC-2CPF46N5KW` |  |
| 783.15 | L + Li9Ge4 = Li12Ge7 | Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 27; `ORC-KK36KGLWPL` |  |
| 783 | Liquid + Ge4Li9 -> Ge3Li7 | Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 16; `ORC-QXI4TBPRAI` |  |
| 782.65 | L + Li9Ge4 = Li12Ge7 | Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579 | model | [2] Wang 2018 | Table 4, p. 7, row 53; `ORC-62Z6JFA7X6` |  |
| 782 | Liquid + Ge4Li9 -> Ge3Li7 | L: Li 0.57; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 14; `ORC-R6MMEIERWG` |  |
| 773.15 | L = Li12Ge7 + LiGe | Li12Ge7: Li 0.631579; LiGe: Li 0.5 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 31; `ORC-IQGS6G7KIX` |  |
| 773 | eutectic: Liquid -> GeLi + Ge7Li12 | GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 25; `ORC-5SNB6VY2L3` |  |
| 769.35 | L = Li12Ge7 + LiGe | Li12Ge7: Li 0.631579; LiGe: Li 0.5 | model | [2] Wang 2018 | Table 4, p. 7, row 55; `ORC-4RQBLQAXI7` |  |
| 769 | eutectic: Liquid -> GeLi + Ge7Li12 | L: Li 0.564; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 23; `ORC-LF2RP66FM7` |  |
| 673.15 | Li4.1Ge = Li15Ge4 + Li17Ge4 | Li4.1Ge: Li 0.803922; Li15Ge4: Li 0.789474; Li17Ge4: Li 0.809524 | model | [2] Wang 2018 | Table 4, p. 7, row 58; `ORC-HHHXRNYTFZ.7a60e3` |  |
| 673.15 | Li4.1Ge = Li15Ge4 + Li17Ge4 | Li4.1Ge: Li 0.803922; Li15Ge4: Li 0.789474; Li17Ge4: Li 0.809524 | experimental | [2] Wang 2018; _cites Zeilinger 2014_ [doi](https://doi.org/10.1039/c4dt00743c) | Table 4, p. 7, row 34; `ORC-PZKJIFU3FL` |  |
| 673 | GeLi4.096 -> Ge4Li17 + Ge4Li15 | GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 30; `ORC-5Q56PMJQJL` |  |
| 673 | GeLi4.096 -> Ge4Li17 + Ge4Li15 | GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 31; `ORC-PO5VUQZPXC` |  |
| 673 | GeLi4.096 -> Ge4Li17 + Ge4Li15 | GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 33; `ORC-STIZWU4R2M` |  |
| 454 | eutectic: Liquid -> Ge4Li17 + BCC_A2 | L: Li 0.999; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 35; `ORC-4AW7NFCZJN` |  |
| 453.75 | L = Li17Ge4 + (Li) | Li17Ge4: Li 0.809524 | model | [2] Wang 2018 | Table 4, p. 7, row 59; `ORC-BWWFJ4WGOT` |  |
| 453.65 | L = Li17Ge4 + (Li) | Li17Ge4: Li 0.809524 | experimental | [2] Wang 2018; _cites Dadd 1981_ | Table 4, p. 7, row 38; `ORC-FG7Z6IF56A` |  |
| 453.5 | eutectic: Liquid -> Ge4Li17 + BCC_A2 | Ge4Li17: Ge 0.190476, Li 0.809524 | experimental | [1] Gierlotka 2022; _cites Dadd 1981_ | Table 11, p. 9, row 38; `ORC-OMNXEQJE2E` |  |
| 453.45 | L = Li17Ge4 + (Li) | Li17Ge4: Li 0.809524 | model | [2] Wang 2018 | Table 4, p. 7, row 60; `ORC-Q4LKJV3R7Q` |  |
| 453.15 | L = Li17Ge4 + (Li) | Li17Ge4: Li 0.809524 | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 37; `ORC-4KH3RHWF5D` |  |
| 453 | eutectic: Liquid -> Ge4Li17 + BCC_A2 | Ge4Li17: Ge 0.190476, Li 0.809524 | unspecified | [1] Gierlotka 2022; _cites Gruttner 1982_ | Table 11, p. 9, row 37; `ORC-FPDWVX7BLX` |  |
| 453 | eutectic: Liquid -> Ge4Li17 + BCC_A2 | L: Li 0.999; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 11, p. 9, row 36; `ORC-QHRRQGANMY` |  |
| 450 | eutectic: Liquid -> Ge4Li17 + BCC_A2 | L: Li 0.997; Ge4Li17: Ge 0.190476, Li 0.809524 | model | [1] Gierlotka 2022 | Table 11, p. 9, row 34; `ORC-5OVHFAUOTN` |  |

## Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json).

Table: Enthalpies of formation, Ge–Li system (29)

| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---:|---:|---|---:|---:|---|---|---|
| Ge12Li7 |  | -26.664 kJ/mol-atom | 0 | model |  |  | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 10, p. 8, row 4; `ORC-3SSP3VXDJV` |  |
| Ge12Li7 |  | -22.4 kJ/mol-atom | 298.15 | experimental |  |  | [1] Gierlotka 2022 | Table 4, p. 4, row 2; `ORC-RDQIWWBLWT` |  |
| Ge12Li7 |  | -22.4 kJ/mol-atom ± 1.3 | 298.15 | experimental |  |  | [1] Gierlotka 2022 | Table 4, p. 4, row 16; `ORC-VNQ4N44K42` |  |
| Ge12Li7 |  | -21.9 kJ/mol-atom ± 1.3 | 298.15 | experimental |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 2; `ORC-PSEXKKFKOW.e13e42` |  |
| Ge12Li7 |  | -20.819 kJ/mol-atom | 0 | model |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 3; `ORC-K43C3FDXV5` |  |
| Ge12Li7 |  | -20.006 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 1; `ORC-EHQYV3NZOV` |  |
| Ge2Li7 | [Ge2Li7](https://data.orchid-project.org/compounds/Ge2Li7.html) | -37.531 kJ/mol-atom | 0 | model | -30.764 (mp-aaaabrvq) | -32.508 (oqmd-1908167) | [1] Gierlotka 2022 | Table 10, p. 8, row 19; `ORC-UK7XHLGT5V` |  |
| Ge2Li7 |  | -31.164 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 18; `ORC-2TIGOND4RG` |  |
| Ge3Li7 | [Ge3Li7](https://data.orchid-project.org/compounds/Ge3Li7.html) | -35.913 kJ/mol-atom | 0 | model |  | -34.859 (oqmd-1797094) | [1] Gierlotka 2022 | Table 10, p. 8, row 17; `ORC-PWHHIDLAMZ` |  |
| Ge3Li7 |  | -34.957 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 16; `ORC-H5GZE6LSUB` |  |
| Ge4Li15 | [Ge4Li15](https://data.orchid-project.org/compounds/Ge4Li15.html) | -37.954 kJ/mol-atom | 0 | model | -31.616 (mp-aaaaacqj) | -32.315 (oqmd-8013) | [1] Gierlotka 2022 | Table 10, p. 8, row 21; `ORC-D7UYWDOYBK` |  |
| Ge4Li15 |  | -32.024 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 20; `ORC-NCPHCG4PGG` |  |
| Ge4Li17 | [Ge4Li17](https://data.orchid-project.org/compounds/Ge4Li17.html) | -33.465 kJ/mol-atom | 0 | model |  | -30.291 (oqmd-686163) | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 10, p. 8, row 24; `ORC-OYGMB237BY` |  |
| Ge4Li17 | [Ge4Li17](https://data.orchid-project.org/compounds/Ge4Li17.html) | -29.878 kJ/mol-atom | 0 | model |  | -30.291 (oqmd-686163) | [1] Gierlotka 2022 | Table 10, p. 8, row 23; `ORC-4OZOZTE7IB` |  |
| Ge4Li17 |  | -29.858 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 22; `ORC-WN6AU66ISA` |  |
| Ge4Li9 | [Ge4Li9](https://data.orchid-project.org/compounds/Ge4Li9.html) | -37.789 kJ/mol-atom | 0 | model | -33.572 (mp-aaafekwf) | -34.257 (oqmd-4751) | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 10, p. 8, row 15; `ORC-K22H7EXC5M` |  |
| Ge4Li9 | [Ge4Li9](https://data.orchid-project.org/compounds/Ge4Li9.html) | -35.845 kJ/mol-atom | 0 | model | -33.572 (mp-aaafekwf) | -34.257 (oqmd-4751) | [1] Gierlotka 2022 | Table 10, p. 8, row 14; `ORC-YCELDI2N2J` |  |
| Ge4Li9 |  | -33.919 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 13; `ORC-SZPIDA4HZG` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -36.407 kJ/mol-atom | 0 | model | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 10, p. 8, row 12; `ORC-5QDKXML7TZ` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -33.782 kJ/mol-atom | 0 | model | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022 | Table 10, p. 8, row 11; `ORC-OP52P5KE4T` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -33.4 kJ/mol-atom | 298.15 | experimental | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022 | Table 4, p. 4, row 10; `ORC-2YJCXCGONJ` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -33.4 kJ/mol-atom ± 1.9 | 298.15 | experimental | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022 | Table 4, p. 4, row 20; `ORC-JPAL3RXMNJ` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -32.6 kJ/mol-atom | 298.15 | experimental | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022 | Table 4, p. 4, row 11; `ORC-WDHJHBOBOJ` |  |
| Ge7Li12 | [Ge7Li12](https://data.orchid-project.org/compounds/Ge7Li12.html) | -32.2 kJ/mol-atom ± 1.9 | 298.15 | experimental | -30.866 (mp-aaacqzll) |  | [1] Gierlotka 2022 | Table 10, p. 8, row 10; `ORC-WZQAODEBEC.5de7d8` |  |
| Ge7Li12 |  | -32.131 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 9; `ORC-FLYJ7UHGWF` |  |
| GeLi | [GeLi](https://data.orchid-project.org/compounds/GeLi.html) | -33.637 kJ/mol-atom | 0 | model | -27.093 (mp-aaaaaorm) | -27.619 (oqmd-7668) | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 10, p. 8, row 8; `ORC-J26CZAOXZU` |  |
| GeLi | [GeLi](https://data.orchid-project.org/compounds/GeLi.html) | -28.25 kJ/mol-atom | 0 | model | -27.093 (mp-aaaaaorm) | -27.619 (oqmd-7668) | [1] Gierlotka 2022 | Table 10, p. 8, row 7; `ORC-5CJNTA576J` |  |
| GeLi |  | -27.542 kJ/mol-atom | 0 | DFT |  |  | [1] Gierlotka 2022 | Table 10, p. 8, row 5; `ORC-OU5WZP5TF4` |  |
| GeLi | [GeLi](https://data.orchid-project.org/compounds/GeLi.html) | -25.5 kJ/mol-atom ± 1.6 | 298.15 | experimental | -27.093 (mp-aaaaaorm) | -27.619 (oqmd-7668) | [1] Gierlotka 2022 | Table 10, p. 8, row 6; `ORC-BITKOMNVUS.d4a7d1` |  |

## Other properties

### Phase transition (2)

Table: Phase transition, Ge–Li system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 803.15 K | 803.15 | Li4Ge(ht) = Li4Ge(rt); _Li4Ge(ht): Li 0.8; Li4Ge(rt): Li 0.8_ | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 21; `ORC-NDBF2NXQBK` |  |
| Phase transition | 993.15 K | 993.15 | L = Li15Ge4; _L: Li 0.789474; Li15Ge4: Li 0.789474_ | experimental | [2] Wang 2018; _cites Gruttner 1982_ | Table 4, p. 7, row 9; `ORC-BKDGFJBWZW` |  |

### Activity / EMF / Gibbs energy (209)

Table: Activity / EMF / Gibbs energy, Ge–Li system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| EMF | 565.3 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.972, Li 0.028_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 7; `ORC-CG6GBE3CJE` |  |
| EMF | 1398.2 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.997, Li 0.003_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 1; `ORC-HAES3BLJUT` |  |
| EMF | 1007.5 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.994, Li 0.006_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 2; `ORC-KGAR3AS7AK` |  |
| EMF | 688.9 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.985, Li 0.015_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 4; `ORC-PHKWVPT5AR` |  |
| EMF | 538.7 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.968, Li 0.032_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 8; `ORC-Q6G5G6SYVM` |  |
| EMF | 523.6 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.964, Li 0.036_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 9; `ORC-TXOEF5OBZD` |  |
| EMF | 606 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.976, Li 0.024_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 6; `ORC-VKA3BOII2A` |  |
| EMF | 646.2 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.981, Li 0.019_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 5; `ORC-WVVQ756EEF` |  |
| EMF | 739.4 mV ± 0.1 | 634 | (Ge); _alloy: Ge 0.989, Li 0.011_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 3; `ORC-Y5L35YO7D2` |  |
| EMF | 521 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.637, Li 0.363_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 38; `ORC-3AHR4Q6V4X` |  |
| EMF | 526.8 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.924, Li 0.076_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 16; `ORC-3HKIFQXSVV` |  |
| EMF | 525.8 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.956, Li 0.044_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 10; `ORC-556WCEV2MK` |  |
| EMF | 524.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.793, Li 0.207_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 29; `ORC-7LO3CAU7K2` |  |
| EMF | 524.7 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.687, Li 0.313_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 35; `ORC-7Z3GBM5KYC` |  |
| EMF | 524.5 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.739, Li 0.261_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 32; `ORC-A7BANI3SPJ` |  |
| EMF | 527.4 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.839, Li 0.161_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 26; `ORC-AMKV7XGBVG` |  |
| EMF | 526.5 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.826, Li 0.174_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 27; `ORC-COXDDGSC57` |  |
| EMF | 522.9 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.654, Li 0.346_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 37; `ORC-FADKDYHEYF` |  |
| EMF | 523.2 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.671, Li 0.329_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 36; `ORC-FTVD7JXTUW` |  |
| EMF | 525.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.81, Li 0.19_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 28; `ORC-I3ZVHNFC7O` |  |
| EMF | 525.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.946, Li 0.054_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 12; `ORC-IJZ37V5QIY` |  |
| EMF | 525.7 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.721, Li 0.279_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 33; `ORC-IW3TSFZTB2` |  |
| EMF | 526.8 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.913, Li 0.087_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 18; `ORC-IY53EUEPQ7` |  |
| EMF | 523.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.762, Li 0.238_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 31; `ORC-JCBZQW5XW7` |  |
| EMF | 525.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.952, Li 0.048_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 11; `ORC-JYDAWYMTAL` |  |
| EMF | 525.5 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.703, Li 0.297_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 34; `ORC-KVGZOOTQKC` |  |
| EMF | 527.1 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.88, Li 0.12_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 23; `ORC-LMHMNMG5KP` |  |
| EMF | 526.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.907, Li 0.093_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 19; `ORC-MVCJ3QPQZZ` |  |
| EMF | 526.3 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.897, Li 0.103_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 21; `ORC-N6ID5Q77XB` |  |
| EMF | 525.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.935, Li 0.065_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 14; `ORC-PE7CO3UG4Z` |  |
| EMF | 527 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.868, Li 0.132_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 24; `ORC-QGGBZELTGI` |  |
| EMF | 527.1 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.891, Li 0.109_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 22; `ORC-RCDJ5MV7S3` |  |
| EMF | 520.7 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.929, Li 0.071_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 15; `ORC-RHLC6IEJ2T` |  |
| EMF | 523.9 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.777, Li 0.223_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 30; `ORC-VWP4QYI3YX` |  |
| EMF | 525.8 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.941, Li 0.059_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 13; `ORC-XBJHQK6RU3` |  |
| EMF | 526.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.902, Li 0.098_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 20; `ORC-XUKWWKJAEN` |  |
| EMF | 526.6 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.918, Li 0.082_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 17; `ORC-XZ3HXHUPG2` |  |
| EMF | 527.4 mV ± 0.1 | 634 | (Ge) + Ge12Li7; _alloy: Ge 0.854, Li 0.146_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 25; `ORC-Y7DCYKA6WB` |  |
| EMF | 516.1 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.593, Li 0.407_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 43; `ORC-2N6Y3QHYRL` |  |
| EMF | 520.6 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.622, Li 0.378_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 41; `ORC-35OZYPYADR` |  |
| EMF | 521 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Li 0.368421_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 40; `ORC-76WJXVJJ5I` |  |
| EMF | 507.5 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.561, Li 0.439_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 45; `ORC-HEKPLWIY27` |  |
| EMF | 520.1 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.607, Li 0.393_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 42; `ORC-QNWSXLF424` |  |
| EMF | 504.5 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.546, Li 0.454_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 46; `ORC-SPBOPIKKEG` |  |
| EMF | 492.9 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.53, Li 0.47_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 47; `ORC-WH65SNKX7Z` |  |
| EMF | 511.4 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.576, Li 0.424_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 44; `ORC-XAB7CGDXZO` |  |
| EMF | 432.5 mV ± 0.1 | 634 | Ge12Li7 + GeLi; _alloy: Ge 0.516, Li 0.484_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 48; `ORC-ZRJ5H4KKW2` |  |
| EMF | 162.9 mV ± 0.1 | 634 | Ge2Li7; _alloy: Ge 0.213, Li 0.787_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 84; `ORC-PE7MNBFFHB` |  |
| EMF | 177.1 mV ± 0.1 | 634 | Ge2Li7; _alloy: Ge 0.222, Li 0.778_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 82; `ORC-R7M6JL7ZBY` |  |
| EMF | 174 mV ± 0.1 | 634 | Ge2Li7; _alloy: Ge 0.218, Li 0.782_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 83; `ORC-YIQNO5DTHS` |  |
| EMF | 208.8 mV ± 0.1 | 634 | Ge3Li7; _alloy: Ge 0.3, Li 0.7_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 69; `ORC-3VUN5CVCIG` |  |
| EMF | 183.2 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.26, Li 0.74_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 75; `ORC-2ZOS7W2ZPX` |  |
| EMF | 183.1 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.254, Li 0.746_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 76; `ORC-6JSM2WJOUD` |  |
| EMF | 183.2 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.237, Li 0.763_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 79; `ORC-BDODBKUTOJ` |  |
| EMF | 183.4 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.242, Li 0.758_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 78; `ORC-D4RXQIA6HA` |  |
| EMF | 186.4 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.248, Li 0.752_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 77; `ORC-E6NPZC7W4V` |  |
| EMF | 184.3 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.266, Li 0.734_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 74; `ORC-MSXIA75OSY` |  |
| EMF | 182.7 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.227, Li 0.773_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 81; `ORC-OPVDOFS6KB` |  |
| EMF | 183.1 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.232, Li 0.768_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 80; `ORC-UCZYUYMSIG` |  |
| EMF | 182.6 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.28, Li 0.72_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 72; `ORC-UV3CNYGIVP` |  |
| EMF | 185.8 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.273, Li 0.727_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 73; `ORC-X5UGAV6SVW` |  |
| EMF | 182.3 mV ± 0.1 | 634 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.287, Li 0.713_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 71; `ORC-X6YCAJ5RUH` |  |
| EMF | 133.2 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.198, Li 0.802_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 89; `ORC-7PCSFURGJ5` |  |
| EMF | 72.5 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.191, Li 0.809_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 91; `ORC-HYE6MSQC5L` |  |
| EMF | 156.4 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.201, Li 0.799_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 88; `ORC-K6KVIEWIY2` |  |
| EMF | 156 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.205, Li 0.795_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 87; `ORC-MHFERAQBFH` |  |
| EMF | 156.1 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.209, Li 0.791_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 86; `ORC-ZGNP7ISM6R` |  |
| EMF | 89.2 mV ± 0.1 | 634 | Ge4Li17; _alloy: Ge 0.194, Li 0.806_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 90; `ORC-ZYWULRRMLB` |  |
| EMF | 253.9 mV ± 0.1 | 634 | Ge4Li9; _alloy: Ge 0.308, Li 0.692_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 67; `ORC-VYQPNSWAKF` |  |
| EMF | 407.2 mV ± 0.1 | 634 | Ge7Li12; _alloy: Ge 0.368, Li 0.632_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 60; `ORC-KDL7N7PYNN` |  |
| EMF | 401.3 mV ± 0.1 | 634 | Ge7Li12; _alloy: Ge 0.363, Li 0.637_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 61; `ORC-WYHEHDABPP` |  |
| EMF | 377.9 mV ± 0.1 | 634 | Ge7Li12 + Ga4Li9; _alloy: Ge 0.335, Li 0.665_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 64; `ORC-3P73OL6ZFO` |  |
| EMF | 388.1 mV ± 0.1 | 634 | Ge7Li12 + Ga4Li9; _alloy: Ge 0.353, Li 0.647_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 62; `ORC-567DEO6SQW` |  |
| EMF | 341 mV ± 0.1 | 634 | Ge7Li12 + Ga4Li9; _alloy: Ge 0.326, Li 0.674_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 65; `ORC-MPTJ53JD2U` |  |
| EMF | 385.8 mV ± 0.1 | 634 | Ge7Li12 + Ga4Li9; _alloy: Ge 0.344, Li 0.656_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 63; `ORC-MTOTIC575M` |  |
| EMF | 426.6 mV ± 0.1 | 634 | GeLi; _alloy: Ge 0.5, Li 0.5_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 50; `ORC-MZKEKKQ6F3` |  |
| EMF | 424.7 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.472, Li 0.528_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 52; `ORC-7EERZBOXN5` |  |
| EMF | 422.1 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.396, Li 0.604_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 57; `ORC-7O4ELIEMSI` |  |
| EMF | 424.3 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.455, Li 0.545_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 53; `ORC-EZCLG46DCE` |  |
| EMF | 423.1 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.411, Li 0.589_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 56; `ORC-F5WCQJYPP5` |  |
| EMF | 424.3 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.44, Li 0.56_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 54; `ORC-GPOH2SNZWC` |  |
| EMF | 410.1 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.385, Li 0.615_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 58; `ORC-LUOG4G4DIK` |  |
| EMF | 424.9 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.489, Li 0.511_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 51; `ORC-MUAQEKQBQR` |  |
| EMF | 424 mV ± 0.1 | 634 | GeLi + Ge7Li12; _alloy: Ge 0.426, Li 0.574_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 55; `ORC-XIOWNDZSXB` |  |
| EMF | 55.9 mV ± 0.1 | 634 | L; _alloy: Ge 0.175, Li 0.825_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 97; `ORC-JXKEJUJBM5` |  |
| EMF | 51.6 mV ± 0.1 | 634 | L; _alloy: Ge 0.173, Li 0.827_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 98; `ORC-MDU75YIUJV` |  |
| EMF | 56.6 mV ± 0.1 | 634 | L; _alloy: Ge 0.181, Li 0.819_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 95; `ORC-WT3B5KIDL5` |  |
| EMF | 55.2 mV ± 0.1 | 634 | L; _alloy: Ge 0.188, Li 0.812_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 93; `ORC-XAPG3HMJKB` |  |
| EMF | 53.9 mV ± 0.1 | 634 | L; _alloy: Ge 0.185, Li 0.815_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 94; `ORC-Y3PBB6V5SL` |  |
| EMF | 57.2 mV ± 0.1 | 634 | L; _alloy: Ge 0.178, Li 0.822_ | experimental | [1] Gierlotka 2022 | Table 5, p. 5, row 96; `ORC-ZTUQTPFXAF` |  |
| EMF | 614 mV ± 0.1 | 807 | (Ge); _alloy: Ge 0.93, Li 0.07_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 2; `ORC-2VGVVE3TAB` |  |
| EMF | 526.8 mV ± 0.1 | 807 | (Ge); _alloy: Ge 0.909, Li 0.091_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 3; `ORC-AXGJIBGQFH` |  |
| EMF | 643.1 mV ± 0.1 | 807 | (Ge); _alloy: Ge 0.966, Li 0.034_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 1; `ORC-V6BDOL6T7B` |  |
| EMF | 524.2 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.7, Li 0.3_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 10; `ORC-2R7FGFAIXQ` |  |
| EMF | 523.2 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.8, Li 0.2_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 7; `ORC-4WDU5BSAS6` |  |
| EMF | 524.1 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.65, Li 0.35_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 12; `ORC-AEPPHNDQXJ` |  |
| EMF | 523.5 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.6, Li 0.4_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 14; `ORC-BCFU4Y3AYA` |  |
| EMF | 523.7 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.625, Li 0.375_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 13; `ORC-GLYEFZXONG` |  |
| EMF | 524 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.725, Li 0.275_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 9; `ORC-IPPYCXYSFR` |  |
| EMF | 523.9 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.875, Li 0.125_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 4; `ORC-ITG3KQDZKT` |  |
| EMF | 522.9 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.849, Li 0.151_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 5; `ORC-QBEQVRSKGW` |  |
| EMF | 522.2 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.75, Li 0.25_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 8; `ORC-VDWTOHIG6U` |  |
| EMF | 523.2 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.825, Li 0.175_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 6; `ORC-WPV367T42D` |  |
| EMF | 524.3 mV ± 0.1 | 807 | (Ge) + L; _alloy: Ge 0.675, Li 0.325_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 11; `ORC-XKRODHGMFX` |  |
| EMF | 129 mV ± 0.1 | 807 | Ge3Li7; _alloy: Ge 0.3, Li 0.7_ | experimental | [1] Gierlotka 2022; _cites modeled stoichiometry of the phases based on Gruttner \[23\] description whereas this work adopts ab initio findings_ | Table 6, p. 6, row 44; `ORC-MP3EUZNNR6` |  |
| EMF | 101.6 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.255, Li 0.745_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 51; `ORC-3QTLTSODTE` |  |
| EMF | 101.5 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.245, Li 0.755_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 52; `ORC-DQD3FJRENQ` |  |
| EMF | 101.7 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.288, Li 0.712_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 47; `ORC-HRKNCTNUYU` |  |
| EMF | 101.5 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.265, Li 0.735_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 50; `ORC-JDGTVIJ5LO` |  |
| EMF | 100.5 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.235, Li 0.765_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 53; `ORC-KC6355ZV54` |  |
| EMF | 101.1 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.285, Li 0.715_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 48; `ORC-KJCACZYQCB` |  |
| EMF | 101.4 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.275, Li 0.725_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 49; `ORC-NWGPXFBSTF` |  |
| EMF | 100.9 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.29, Li 0.71_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 46; `ORC-OI3BDISAED` |  |
| EMF | 100.1 mV ± 0.1 | 807 | Ge3Li7 + Ge2Li7; _alloy: Ge 0.295, Li 0.705_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 45; `ORC-UU2C3O47XG` |  |
| EMF | 34.4 mV ± 0.1 | 807 | Ge4Li15 + GeLi4.096; _alloy: Ge 0.2, Li 0.8_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 60; `ORC-EN36FWT5BC` |  |
| EMF | 40 mV ± 0.1 | 807 | Ge4Li15 + GeLi4.096; _alloy: Ge 0.204, Li 0.796_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 59; `ORC-KFNGRM3GBR` |  |
| EMF | 196.9 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.34, Li 0.66_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 38; `ORC-3JJDXLZTNE` |  |
| EMF | 196.7 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.32, Li 0.68_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 40; `ORC-LSMALP5QTO` |  |
| EMF | 197 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.33, Li 0.67_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 39; `ORC-OPJPPLIQW5` |  |
| EMF | 196.8 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.35, Li 0.65_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 37; `ORC-PPYAEQKAJQ` |  |
| EMF | 195.5 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.31, Li 0.69_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 41; `ORC-SUSCVWCVJA` |  |
| EMF | 196.6 mV ± 0.1 | 807 | Ge7Li12 + Ge4Li9; _alloy: Ge 0.36, Li 0.64_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 36; `ORC-UCHZ62FVOH` |  |
| EMF | 16.9 mV ± 0.1 | 807 | GeLi4.096 + L; _alloy: Ge 0.144, Li 0.856_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 70; `ORC-5KHEXXO4DS` |  |
| EMF | 17.8 mV ± 0.1 | 807 | GeLi4.096 + L; _alloy: Ge 0.159, Li 0.841_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 68; `ORC-EZYVQ6PMER` |  |
| EMF | 15.9 mV ± 0.1 | 807 | GeLi4.096 + L; _alloy: Ge 0.13, Li 0.87_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 72; `ORC-KDN73UGHMG` |  |
| EMF | 16.3 mV ± 0.1 | 807 | GeLi4.096 + L; _alloy: Ge 0.152, Li 0.848_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 69; `ORC-N5PF2JGPTA` |  |
| EMF | 16.1 mV ± 0.1 | 807 | GeLi4.096 + L; _alloy: Ge 0.137, Li 0.863_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 71; `ORC-STVTUNPDJ6` |  |
| EMF | 522.5 mV ± 0.1 | 807 | L; _alloy: Ge 0.575, Li 0.425_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 15; `ORC-6BLUB4M5ZD` |  |
| EMF | 410.3 mV ± 0.1 | 807 | L; _alloy: Ge 0.49, Li 0.51_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 22; `ORC-G6TXXZIIKF` |  |
| EMF | 485.8 mV ± 0.1 | 807 | L; _alloy: Ge 0.54, Li 0.46_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 17; `ORC-JL6GXDUDON` |  |
| EMF | 441.9 mV ± 0.1 | 807 | L; _alloy: Ge 0.51, Li 0.49_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 20; `ORC-JODVSPFDFP` |  |
| EMF | 499.1 mV ± 0.1 | 807 | L; _alloy: Ge 0.55, Li 0.45_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 16; `ORC-OEENSZLP6V` |  |
| EMF | 426.3 mV ± 0.1 | 807 | L; _alloy: Ge 0.5, Li 0.5_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 21; `ORC-PS3JGCTZNN` |  |
| EMF | 457.1 mV ± 0.1 | 807 | L; _alloy: Ge 0.52, Li 0.48_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 19; `ORC-UU6VEGZ7PE` |  |
| EMF | 471.6 mV ± 0.1 | 807 | L; _alloy: Ge 0.53, Li 0.47_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 18; `ORC-XV2CUXNTD6` |  |
| EMF | 392.4 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.41, Li 0.59_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 30; `ORC-5L2OT5ZSNT` |  |
| EMF | 393.9 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.46, Li 0.54_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 25; `ORC-5MQGISUX6Q` |  |
| EMF | 393.4 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.44, Li 0.56_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 27; `ORC-BVXTBMXJTJ` |  |
| EMF | 393.2 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.43, Li 0.57_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 28; `ORC-HKSZUOG7EI` |  |
| EMF | 394.2 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.48, Li 0.52_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 23; `ORC-JO5XYJ2CWR` |  |
| EMF | 391.6 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.4, Li 0.6_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 31; `ORC-QD5K52IOSS` |  |
| EMF | 394 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.47, Li 0.53_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 24; `ORC-RFXI3RGDUX` |  |
| EMF | 393.7 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.45, Li 0.55_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 26; `ORC-STBT5CVIIA` |  |
| EMF | 392.9 mV ± 0.1 | 807 | L + Ge7Li12; _alloy: Ge 0.42, Li 0.58_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 29; `ORC-W3LN45OBMC` |  |
| EMF | 73.7 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.225, Li 0.775_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 54; `ORC-3SKBANI3PL` |  |
| EMF | 177.2 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.305, Li 0.695_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 43; `ORC-6X2T57ABD5` |  |
| EMF | 21.4 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.173, Li 0.827_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 66; `ORC-AMOWFSKGPY` |  |
| EMF | 389.9 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.39, Li 0.61_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 32; `ORC-DEF3JK7FY5` |  |
| EMF | 347.7 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.38, Li 0.62_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 33; `ORC-I4R2LLVWCY` |  |
| EMF | 28.6 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.18, Li 0.82_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 65; `ORC-J4IWOUA6T7` |  |
| EMF | 32.7 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.195, Li 0.805_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 62; `ORC-KIA33GLBOF` |  |
| EMF | 32 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.186, Li 0.814_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 64; `ORC-MBTZKRVUVL` |  |
| EMF | 48.2 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.21, Li 0.79_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 58; `ORC-MOTGESBRGW` |  |
| EMF | 19.3 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.166, Li 0.834_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 67; `ORC-MTJWLHI4HE` |  |
| EMF | 243.6 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.37, Li 0.63_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 34; `ORC-MXLVURD2U5` |  |
| EMF | 33.2 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.192, Li 0.808_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 63; `ORC-RAFBGIO4VI` |  |
| EMF | 48.1 mV ± 0.1 | 807 | UNKNOWN; _alloy: Ge 0.215, Li 0.785_ | experimental | [1] Gierlotka 2022 | Table 6, p. 6, row 56; `ORC-TLCSICEDLP` |  |
| EMF | 781.7 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.989, Li 0.011_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 7; `ORC-3CEFHH5FL4` |  |
| EMF | 535.5 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.968, Li 0.032_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 19; `ORC-4NZF3CZ4VA` |  |
| EMF | 828.8 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.993, Li 0.007_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 5; `ORC-5EXQOW2APT` |  |
| EMF | 759 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.987, Li 0.013_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 8; `ORC-6AAUOJYPVV` |  |
| EMF | 586.6 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.979, Li 0.021_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 13; `ORC-AG5CDTWAKD` |  |
| EMF | 1810.3 mV ± 0.1 | 841 | (Ge); _alloy: Ge 1, Li 0_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 1; `ORC-E57GZ6IMA3` |  |
| EMF | 533.8 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.966, Li 0.034_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 20; `ORC-HISVQ2YHVR` |  |
| EMF | 541.7 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.969, Li 0.031_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 18; `ORC-JKVMHKJ2K6` |  |
| EMF | 625.5 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.982, Li 0.018_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 11; `ORC-KEAHZFWWKE` |  |
| EMF | 602.5 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.98, Li 0.02_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 12; `ORC-KVEY4K3WMB` |  |
| EMF | 578.6 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.977, Li 0.023_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 14; `ORC-L2PXAFSKVW` |  |
| EMF | 540.3 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.973, Li 0.027_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 16; `ORC-L3CBS4K2BM` |  |
| EMF | 860.5 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.994, Li 0.006_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 4; `ORC-LEZBHVVYSL` |  |
| EMF | 912 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.996, Li 0.004_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 3; `ORC-LWKAQAJRIB` |  |
| EMF | 1215.7 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.998, Li 0.002_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 2; `ORC-M5JZQG5NTH` |  |
| EMF | 722.4 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.986, Li 0.014_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 9; `ORC-MXL6KCH7XE` |  |
| EMF | 536.2 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.972, Li 0.028_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 17; `ORC-RQRJAOGKTU` |  |
| EMF | 533.1 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.965, Li 0.035_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 21; `ORC-SMGS6ANDQD` |  |
| EMF | 665.7 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.984, Li 0.016_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 10; `ORC-WLGRKDWF7U` |  |
| EMF | 554 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.975, Li 0.025_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 15; `ORC-XVV6YYWNTJ` |  |
| EMF | 800.7 mV ± 0.1 | 841 | (Ge); _alloy: Ge 0.991, Li 0.009_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 6; `ORC-Y5DU66W2OD` |  |
| EMF | 530.9 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.929, Li 0.071_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 35; `ORC-2RBUACXN7B` |  |
| EMF | 532.6 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.956, Li 0.044_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 26; `ORC-567V5XSGO7` |  |
| EMF | 531.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.941, Li 0.059_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 32; `ORC-5CQEWBNCQN` |  |
| EMF | 530.7 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.884, Li 0.116_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 43; `ORC-746ZM4JONG` |  |
| EMF | 532.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.961, Li 0.039_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 23; `ORC-7RNZUEWPP4` |  |
| EMF | 530.8 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.919, Li 0.081_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 37; `ORC-B3R7MJK2X7` |  |
| EMF | 530.6 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.906, Li 0.094_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 40; `ORC-B63ANZGUCC` |  |
| EMF | 531.1 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.938, Li 0.062_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 33; `ORC-BSJSNN4KLA` |  |
| EMF | 532.1 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.95, Li 0.05_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 30; `ORC-DUDEDJG4YA` |  |
| EMF | 529 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.813, Li 0.187_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 52; `ORC-EDMS4O2FZQ` |  |
| EMF | 530.7 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.915, Li 0.085_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 38; `ORC-G4QV6J735C` |  |
| EMF | 529.6 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.835, Li 0.165_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 49; `ORC-GF3XDMK56S` |  |
| EMF | 530.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.875, Li 0.125_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 44; `ORC-IXDTLAVD4A` |  |
| EMF | 532.3 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.951, Li 0.049_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 29; `ORC-JBSGNG6UCO` |  |
| EMF | 532.7 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.963, Li 0.037_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 22; `ORC-NNH6OOQZOO` |  |
| EMF | 530.6 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.901, Li 0.099_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 41; `ORC-NZT4WAR433` |  |
| EMF | 529.9 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.851, Li 0.149_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 47; `ORC-OH2USE7DIE` |  |
| EMF | 532.4 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.958, Li 0.042_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 25; `ORC-ONBGIHDYFU` |  |
| EMF | 529.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.828, Li 0.172_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 50; `ORC-OQ3PFJ2IAS` |  |
| EMF | 529.3 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.82, Li 0.18_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 51; `ORC-PMBW4SWD6W` |  |
| EMF | 531 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.892, Li 0.108_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 42; `ORC-PTZMBT6QMZ` |  |
| EMF | 530.8 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.924, Li 0.076_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 36; `ORC-QKQ2J5FXYA` |  |
| EMF | 532.1 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.948, Li 0.052_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 31; `ORC-RE7H4EKQ57` |  |
| EMF | 532.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.955, Li 0.045_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 27; `ORC-SSWBODZ5E7` |  |
| EMF | 529.7 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.843, Li 0.157_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 48; `ORC-UF3NRSRHAK` |  |
| EMF | 530.4 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.859, Li 0.141_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 46; `ORC-UGSRLIY73K` |  |
| EMF | 531 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.933, Li 0.067_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 34; `ORC-UIR5YFMDM7` |  |
| EMF | 532.4 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.96, Li 0.04_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 24; `ORC-UJPRQXLLH2` |  |
| EMF | 530.5 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.867, Li 0.133_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 45; `ORC-UQBSW57H5D` |  |
| EMF | 532.4 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.953, Li 0.047_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 28; `ORC-V2L5PMAWGM` |  |
| EMF | 530.7 mV ± 0.1 | 841 | (Ge) + L; _alloy: Ge 0.91, Li 0.09_ | experimental | [1] Gierlotka 2022 | Table 7, p. 6, row 39; `ORC-YLBD4QATI5` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. W. Gierlotka, A. Dębski, M. Zabrocki, A. Góral, W. Gąsior, Phase diagram, thermodynamic studies, and ab-initio calculations of the Ge-Li system, The Journal of Chemical Thermodynamics 175, 106883 (2022). [doi:10.1016/j.jct.2022.106883](https://doi.org/10.1016/j.jct.2022.106883)
2. Shimin Wang, Yong Du, Yingbiao Peng, Peng Zhou, Xiaoming Yuan, Shuhong Liu, A Thermodynamic Assessment of the Li-Ge System, J. Phase Equilib. Diffus. 39, 315-323 (2018). [doi:10.1007/s11669-018-0632-5](https://doi.org/10.1007/s11669-018-0632-5)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).