# Hf–Ni–Sn system > Hf–Ni–Sn system: 48 accepted literature values (invariant reaction 27, formation 21) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/HF-NI-SN.html · Markdown: https://data.orchid-project.org/systems/HF-NI-SN.md 48 accepted literature values from 1 paper(s) (model 27, DFT 21); 0 calculated phase diagram(s). 3 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV. Data: [JSON](https://data.orchid-project.org/literature/systems/HF-NI-SN.json) · [CSV](https://data.orchid-project.org/systems/HF-NI-SN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#HF-NI-SN) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/HF-NI-SN.html) · [Markdown](https://data.orchid-project.org/systems/HF-NI-SN.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | model | 27 | | DFT | 21 | Table: Accepted values by property group | Property group | Values | |---|---:| | invariant reaction | 27 | | formation | 21 | ## Invariant reactions (literature) Table: Invariant reactions reported in the literature for the Hf–Ni–Sn system (27) | T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote | |---:|---|---|---|---|---|---| | 1426.2 | quasi-peritectic: Half + D88 -> liquid + D88 | | model | [1] Berche 2016 | Table 5, p. 6, row 1; `ORC-2YCYJJK67Z` | | | 1410.2 | eutectic: Liquid -> D88 + C40 + Half | | model | [1] Berche 2016 | Table 5, p. 6, row 2; `ORC-U2UDZOZ7SY` | | | 1405.3 | quasi-peritectic: D88 + BCC_A2 -> Liquid + HCP_A3 | | model | [1] Berche 2016 | Table 5, p. 6, row 3; `ORC-P5LY4DFAJA` | | | 1276.8 | quasi-peritectic: Liquid + Half -> D88 + Hf2Ni2Sn | | model | [1] Berche 2016 | Table 5, p. 6, row 4; `ORC-6LBN5BV23U` | | | 1262.3 | quasi-peritectic: Liquid + B_HfNi -> Hf2Ni2Sn + Ni11Hf9 | | model | [1] Berche 2016 | Table 5, p. 6, row 5; `ORC-UMVW56Z6LM` | | | 1237.2 | quasi-peritectic: Liquid + Half -> Heusler + Hf2Ni2Sn | | model | [1] Berche 2016 | Table 5, p. 6, row 6; `ORC-SPSSQ23MZ2` | | | 1212.1 | quasi-peritectic: Liquid + Hf2Ni2Sn -> B_HfNi + D88 | | model | [1] Berche 2016 | Table 5, p. 6, row 7; `ORC-6PWXYF7L6C` | | | 1201.7 | quasi-peritectic: Liquid + Ni11Hf9 -> Hf2Ni2Sn + Ni10Hf7 | | model | [1] Berche 2016 | Table 5, p. 6, row 8; `ORC-MJJYJ2UDJQ` | | | 1199.6 | quasi-peritectic: Liquid + β-HfNi3 -> α-HfNi3 + Ni7Hf2 | | model | [1] Berche 2016 | Table 5, p. 6, row 9; `ORC-N4MASVACNU` | | | 1199.6 | quasi-peritectic: Liquid + β-HfNi3 -> α-HfNi3 + Ni21Hf8 | | model | [1] Berche 2016 | Table 5, p. 6, row 10; `ORC-SDI6S6UB5C` | | | 1192.9 | quasi-peritectic: Liquid + Hf2Ni2Sn -> Heusler + Ni10Hf7 | | model | [1] Berche 2016 | Table 5, p. 6, row 11; `ORC-Z74TDBHKSK` | | | 1152.5 | eutectic: Liquid -> Heusler + α-HfNi3 + Ni7Hf2 | | model | [1] Berche 2016 | Table 5, p. 6, row 12; `ORC-CDFIV7WHP4` | | | 1150 | peritectic: Liquid + C16 + β-HfNi -> B33 | | model | [1] Berche 2016 | Table 5, p. 6, row 14; `ORC-4T6OWGCFJW` | | | 1150 | other: β-HfNi -> Liquid + D88 + B33 | | model | [1] Berche 2016 | Table 5, p. 6, row 13; `ORC-UIFVHSGPSA` | | | 1143.1 | other: Ni21Hf8 -> Liquid + Hf3Ni7 + α-HfNi3 | | model | [1] Berche 2016 | Table 5, p. 6, row 15; `ORC-PHOOP2ZLOQ` | | | 1139.2 | peritectic: Liquid + D88 + C16 -> Hf6Ni1.5Sn1.5 | | model | [1] Berche 2016 | Table 5, p. 6, row 16; `ORC-MI7ZLRC5IX` | | | 1138.7 | quasi-peritectic: Liquid + D88 -> Hf6Ni1.5Sn1.5 + HCP_A3 | | model | [1] Berche 2016 | Table 5, p. 6, row 17; `ORC-54O7Z747FS` | | | 1138.4 | eutectic: Liquid -> C16 + Hf6Ni1.5Sn1.5 + HCP_A3 | | model | [1] Berche 2016 | Table 5, p. 6, row 18; `ORC-4YDD5ARRCS` | | | 1135.3 | eutectic: Liquid -> D88 + B33 + C16 | | model | [1] Berche 2016 | Table 5, p. 6, row 19; `ORC-PQAHBHV4P5` | | | 1134.6 | quasi-peritectic: Liquid + α-HfNi3 -> Heusler + Hf3Ni7 | | model | [1] Berche 2016 | Table 5, p. 6, row 20; `ORC-EMLNW2G6KR` | | | 1120.6 | eutectic: Liquid -> Heusler + Ni10Hf7 + Hf3Ni7 | | model | [1] Berche 2016 | Table 5, p. 6, row 21; `ORC-QRCY4O37I2` | | | 1095.4 | eutectic: Liquid -> Ni7Hf2 + Ni3Sn2_HT + D03 | | model | [1] Berche 2016 | Table 5, p. 6, row 22; `ORC-CBVHX7OLBK` | | | 1091.9 | quasi-peritectic: Liquid + Ni7Hf2 -> D03 + C15B | | model | [1] Berche 2016 | Table 5, p. 6, row 23; `ORC-ASAVDM3ZYP` | | | 1078.2 | eutectic: Liquid -> D03 + C15B + FCC_A1 | | model | [1] Berche 2016 | Table 5, p. 6, row 24; `ORC-MMOI3IW5OD` | | | 1069.8 | eutectic: Liquid -> Heusler + Ni7Hf2 + Ni3Sn2_HT | | model | [1] Berche 2016 | Table 5, p. 6, row 25; `ORC-XJ5DHMWUUM` | | | 950.2 | quasi-peritectic: Liquid + Heusler -> Ni3Sn2_HT + Half | | model | [1] Berche 2016 | Table 5, p. 6, row 26; `ORC-STLO2JJK6Q` | | | 794.5 | quasi-peritectic: Liquid + Ni3Sn2_HT -> Ni3Sn4 + Half | | model | [1] Berche 2016 | Table 5, p. 6, row 27; `ORC-WJBP26CDAF` | | ## Other properties ### Formation (21) Table: Formation, Hf–Ni–Sn system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | defect formation energy; _printed: Enthalpy of formation of the defects_ | 211.7 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 1; `ORC-3J4HV2RD6E.b3dd86` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 18.1 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 2; `ORC-AVP4BLDVG5.65b247` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 270 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 9; `ORC-D7CNPHBOMT.56e35a` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 201.3 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 8; `ORC-EYH2TUTHTZ.51e9bb` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | -3.4 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 7; `ORC-J6FFOCJ36C.a56264` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 152.2 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 4; `ORC-KKAFA5BPXA.e7e82a` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 226.4 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 5; `ORC-LDAYZNGOPU.890082` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 77.4 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 3; `ORC-OQGVR2JUYV.565251` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 183.5 kJ/mol-defect | 0 | HfNi2Sn | DFT | [1] Berche 2016 | Table 3, p. 5, row 6; `ORC-TH5BPDLPA2.867eee` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 416.7 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 1; `ORC-3J4HV2RD6E.3e358d` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 260.4 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 2; `ORC-AVP4BLDVG5.015b7a` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 438.4 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 9; `ORC-D7CNPHBOMT.20e621` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 606.9 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 8; `ORC-EYH2TUTHTZ.8b6550` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 435.4 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 12; `ORC-IEUVTOLMNL.1a6c9d` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 159.4 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 7; `ORC-J6FFOCJ36C.74d161` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 352 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 4; `ORC-KKAFA5BPXA.d41ae7` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 362.1 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 10; `ORC-LBCEJBDSO4.8cd541` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 219.6 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 5; `ORC-LDAYZNGOPU.4c169b` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 110.2 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 11; `ORC-LLPCIIVZFK.6337c7` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 292.1 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 3; `ORC-OQGVR2JUYV.ab8d0d` | | | defect formation energy; _printed: Enthalpy of formation of the defects_ | 361.3 kJ/mol-defect | 0 | HfNiSn | DFT | [1] Berche 2016 | Table 3, p. 5, row 6; `ORC-TH5BPDLPA2.4631a4` | | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. A. Berche, J.C. Tédenac, P. Jund, Phase diagram and enthalpy of formation of Hf-Ni-Sn, Computational Materials Science 125, 271-277 (2016). [doi:10.1016/j.commatsci.2016.08.042](https://doi.org/10.1016/j.commatsci.2016.08.042) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).