Ho–Ni system

149 accepted literature values from 3 paper(s) (experimental 41, model 94, unspecified 14); 2 calculated phase diagram(s). 4 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (13) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	41
model	94
unspecified	14

Accepted values by property group
Property group	Values
invariant reaction	71
phase transition	18
formation	38
heat capacity / entropy / enthalpy	22

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
HoNi-15Kar.tdb	S. Kardellass, C. Servant, N. Selhaoui, J. Thermal Anal. Calorim., 119, 1225-34(2015). doi:10.1007/s10973-014-4189-1	`177f346c93bb88945400851e6f44de49db5f152086d2da69dc4ed49ef84fdb43`	viewer · TDB · JSON
HoNi-23Ye.tdb	H. Ye, M. Rong, Q. Yao, Q. Chen, J. Wang, G. Rao, H. Zhou, J. Mater. Sci., 58, 1260-92(2023). doi:10.1007/s10853-022-08039-1	`56caf76fef5f3fb037b7307e01e3b22123d7dfe940d6b4e814088c93527497f0`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
HoNi-15Kar.tdb	1592.57	LIQUID (x(Ni) 0.75724) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-15Kar.tdb	1592.56	LIQUID (x(Ni) 0.7569) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-15Kar.tdb	1592.56	LIQUID (x(Ni) 0.75672) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-15Kar.tdb	1560.42	LIQUID (x(Ni) 0.71286) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-15Kar.tdb	1560.42	LIQUID (x(Ni) 0.71311) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-15Kar.tdb	1560.42	LIQUID (x(Ni) 0.71279) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-15Kar.tdb	1560.42	LIQUID (x(Ni) 0.71278) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-15Kar.tdb	1559.09	HONI5_D2D (x(Ni) 0.83333) + HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.92292)
HoNi-15Kar.tdb	1559.09	HONI5_D2D (x(Ni) 0.83333) + HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.92271)
HoNi-15Kar.tdb	1551.96	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.93105) + FCC_A1 (x(Ni) 1)
HoNi-15Kar.tdb	1551.96	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.93096) + FCC_A1 (x(Ni) 1)
HoNi-15Kar.tdb	1551.96	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.93097) + FCC_A1 (x(Ni) 1)
HoNi-15Kar.tdb	1551.96	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.93107) + FCC_A1 (x(Ni) 1)
HoNi-15Kar.tdb	1469.69	LIQUID (x(Ni) 0.63998) + HONI2_C15 (x(Ni) 0.66584) + HONI3 (x(Ni) 0.75)
HoNi-15Kar.tdb	1469.69	LIQUID (x(Ni) 0.64001) + HONI2_C15 (x(Ni) 0.66584) + HONI3 (x(Ni) 0.75)
HoNi-15Kar.tdb	1325.05	HONI_B27 (x(Ni) 0.5) + LIQUID (x(Ni) 0.53581) + HONI2_C15 (x(Ni) 0.65686)
HoNi-15Kar.tdb	1325.05	HONI_B27 (x(Ni) 0.5) + LIQUID (x(Ni) 0.5358) + HONI2_C15 (x(Ni) 0.65686)
HoNi-15Kar.tdb	1240.64	LIQUID (x(Ni) 0.39227) + HO3NI2_HT (x(Ni) 0.4) + HONI_B27 (x(Ni) 0.5)
HoNi-15Kar.tdb	1240.64	LIQUID (x(Ni) 0.39232) + HO3NI2_HT (x(Ni) 0.4) + HONI_B27 (x(Ni) 0.5)
HoNi-15Kar.tdb	1031	HO3NI2_HT (x(Ni) 0.4) + HO3NI2_LT (x(Ni) 0.4) + HONI_B27 (x(Ni) 0.5)
HoNi-15Kar.tdb	1031	LIQUID (x(Ni) 0.29286) + HO3NI2_LT (x(Ni) 0.4) + HO3NI2_HT (x(Ni) 0.4)
HoNi-15Kar.tdb	1031	LIQUID (x(Ni) 0.29272) + HO3NI2_HT (x(Ni) 0.4) + HO3NI2_LT (x(Ni) 0.4)
HoNi-15Kar.tdb	1018.92	HCP_A3 (x(Ni) 2.000e-5) + HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.25684)
HoNi-15Kar.tdb	1018.92	HCP_A3 (x(Ni) 2.000e-5) + HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.25676)
HoNi-15Kar.tdb	1018.92	HCP_A3 (x(Ni) 2.000e-5) + HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.25682)
HoNi-15Kar.tdb	1010.67	HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.28186) + HO3NI2_LT (x(Ni) 0.4)
HoNi-15Kar.tdb	1010.67	HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.28202) + HO3NI2_LT (x(Ni) 0.4)
HoNi-15Kar.tdb	1010.67	HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.28178) + HO3NI2_LT (x(Ni) 0.4)
HoNi-23Ye.tdb	1592.49	LIQUID (x(Ni) 0.76803) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-23Ye.tdb	1592.49	LIQUID (x(Ni) 0.76818) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-23Ye.tdb	1592.49	LIQUID (x(Ni) 0.768) + HO2NI7 (x(Ni) 0.77778) + HONI5_D2D (x(Ni) 0.83333)
HoNi-23Ye.tdb	1561.5	HONI5_D2D (x(Ni) 0.83333) + HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.91482)
HoNi-23Ye.tdb	1561.5	HONI5_D2D (x(Ni) 0.83333) + HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.91465)
HoNi-23Ye.tdb	1558.25	LIQUID (x(Ni) 0.72089) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-23Ye.tdb	1558.25	LIQUID (x(Ni) 0.72117) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-23Ye.tdb	1558.25	LIQUID (x(Ni) 0.72084) + HONI3 (x(Ni) 0.75) + HO2NI7 (x(Ni) 0.77778)
HoNi-23Ye.tdb	1557.05	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.92132) + FCC_A1 (x(Ni) 0.99998)
HoNi-23Ye.tdb	1557.05	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.92142) + FCC_A1 (x(Ni) 0.99998)
HoNi-23Ye.tdb	1557.05	HO2NI17 (x(Ni) 0.89474) + LIQUID (x(Ni) 0.92142) + FCC_A1 (x(Ni) 0.99998)
HoNi-23Ye.tdb	1468.09	LIQUID (x(Ni) 0.65761) + HONI2_C15 (x(Ni) 0.66605) + HONI3 (x(Ni) 0.75)
HoNi-23Ye.tdb	1468.09	LIQUID (x(Ni) 0.6577) + HONI2_C15 (x(Ni) 0.66605) + HONI3 (x(Ni) 0.75)
HoNi-23Ye.tdb	1312.3	HONI_B27 (x(Ni) 0.5) + LIQUID (x(Ni) 0.55349) + HONI2_C15 (x(Ni) 0.65825)
HoNi-23Ye.tdb	1312.3	HONI_B27 (x(Ni) 0.5) + LIQUID (x(Ni) 0.55347) + HONI2_C15 (x(Ni) 0.65825)
HoNi-23Ye.tdb	1254.17	HO3NI2_HT (x(Ni) 0.4) + LIQUID (x(Ni) 0.40513) + HONI_B27 (x(Ni) 0.5)
HoNi-23Ye.tdb	1254.16	HO3NI2_HT (x(Ni) 0.4) + LIQUID (x(Ni) 0.40497) + HONI_B27 (x(Ni) 0.5)
HoNi-23Ye.tdb	1030.24	HO3NI2_HT (x(Ni) 0.4) + HO3NI2_LT (x(Ni) 0.4) + HONI_B27 (x(Ni) 0.5)
HoNi-23Ye.tdb	1030.24	LIQUID (x(Ni) 0.31353) + HO3NI2_LT (x(Ni) 0.4) + HO3NI2_HT (x(Ni) 0.4)
HoNi-23Ye.tdb	1027.44	HCP_A3 (x(Ni) 3.000e-5) + HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.25145)
HoNi-23Ye.tdb	1027.44	HCP_A3 (x(Ni) 3.000e-5) + HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.25141)
HoNi-23Ye.tdb	1002.77	HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.29794) + HO3NI2_LT (x(Ni) 0.4)
HoNi-23Ye.tdb	1002.77	HO3NI_D011 (x(Ni) 0.25) + LIQUID (x(Ni) 0.29805) + HO3NI2_LT (x(Ni) 0.4)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull HoNi-15Kar

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ho–Ni system (71)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location	Quote
1747.15	congruent melting: L -> (Ho)	(Ho): Ho 1	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 1 report
1728.15	congruent melting: L -> (Ni)	(Ni): Ho 0	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 14 report
1703	peritectic: L + bcc(Ho) -> hcp(Ho)	L: Ni 0.02	model	[2] Ye 2023	Table 10, p. 22, row 1 report
1643.15	congruent melting: L -> HoNi5	HoNi5: Ho 0.167	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 11 report
1593.15	peritectic: L + HoNi5 -> Ho7Ni2	L: Ho 0.26; HoNi5: Ho 0.167; Ho7Ni2: Ho 0.222	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 10 report
1593.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1593.15	L + HoNi5 -> Ho7Ni2	L: Ni 0.7587; HoNi5: Ni 0.833; Ho7Ni2: Ni 0.778	model	[1] Kardellass 2015	Table 6, p. 7, row 22 report
1593.15	L + HoNi5 -> Ho7Ni2	L: Ni 0.74; HoNi5: Ni 0.833; Ho7Ni2: Ni 0.778	experimental	[1] Kardellass 2015	Table 6, p. 7, row 21 report
1593	peritectic: L + HoNi5 -> Ho2Ni7	L: Ni 0.759; HoNi5: Ni 0.833333; Ho2Ni7: Ni 0.777778	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 26 report
1593	peritectic: L + HoNi5 -> Ho2Ni7	HoNi5: Ni 0.833333; Ho2Ni7: Ni 0.777778	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 27 report
1590.9	peritectic: L + HoNi5 -> Ho2Ni7	L: Ni 0.768; HoNi5: Ni 0.833333; Ho2Ni7: Ni 0.777778	model	[2] Ye 2023	Table 10, p. 22, row 28 report
1563.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1563.15	L + HoNi5 -> Ho17Ni2	L: Ni 0.92; HoNi5: Ni 0.833; Ho17Ni2: Ni 0.895	experimental	[1] Kardellass 2015	Table 6, p. 7, row 25 report
1563.15	L + HoNi5 -> Ho17Ni2	L: Ni 0.9193; HoNi5: Ni 0.833; Ho17Ni2: Ni 0.895	model	[1] Kardellass 2015	Table 6, p. 7, row 26 report
1563.15	peritectic: L + HoNi5 -> Ho17Ni2	L: Ho 0.08; HoNi5: Ho 0.167; Ho17Ni2: Ho 0.105	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 12 report
1563	peritectic: L + HoNi5 -> Ho2Ni17	HoNi5: Ni 0.833333; Ho2Ni17: Ni 0.894737	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 33 report
1563	peritectic: L + HoNi5 -> Ho2Ni17	L: Ni 0.919; HoNi5: Ni 0.833333; Ho2Ni17: Ni 0.894737	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 32 report
1560.3	peritectic: L + HoNi5 -> Ho2Ni17	L: Ni 0.915; HoNi5: Ni 0.833333; Ho2Ni17: Ni 0.894737	model	[2] Ye 2023	Table 10, p. 22, row 34 report
1558.15	L + Ho7Ni2 -> HoNi3	L: Ni 0.7; Ho7Ni2: Ni 0.778; HoNi3: Ni 0.75	experimental	[1] Kardellass 2015	Table 6, p. 7, row 19 report
1558.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1558.15	L + Ho7Ni2 -> HoNi3	L: Ni 0.7019; Ho7Ni2: Ni 0.778; HoNi3: Ni 0.75	model	[1] Kardellass 2015	Table 6, p. 7, row 20 report
1558.15	peritectic: L + Ho7Ni2 -> HoNi3	L: Ho 0.3; Ho7Ni2: Ho 0.222; HoNi3: Ho 0.25	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 9 report
1558	peritectic: L + Ho2Ni7 -> HoNi3	Ho2Ni7: Ni 0.777778; HoNi3: Ni 0.75	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 24 report
1558	peritectic: L + Ho2Ni7 -> HoNi3	L: Ni 0.712; Ho2Ni7: Ni 0.777778; HoNi3: Ni 0.75	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 23 report
1556	eutectic: L -> fcc(Ni) + Ho2Ni17	L: Ni 0.921; Ho2Ni17: Ni 0.894737	model	[2] Ye 2023	Table 10, p. 22, row 37 report
1555.8	peritectic: L + Ho2Ni7 -> HoNi3	L: Ni 0.72; Ho2Ni7: Ni 0.777778; HoNi3: Ni 0.75	model	[2] Ye 2023	Table 10, p. 22, row 25 report
1553.15	eutectic		experimental	[1] Kardellass 2015	p. 2 report	Three eutectic reactions formed between Ho3Ni and Ho2Ni3_LT at 720 C (30.0 at% Ni), between HoNi and HoNi2 at 975 C (54.0 at% Ni), and between Ho2Ni17 and Nickel at 1,280 C (93.0 at% Ni).
1553.15	eutectic: L -> Ho17Ni2 + fcc_A1	L: Ni 0.93; Ho17Ni2: Ni 0.895; fcc_A1: Ni 1	experimental	[1] Kardellass 2015	Table 6, p. 7, row 27 report
1553.15	eutectic: L -> Ho17Ni2 + fcc_A1	L: Ni 0.9314; Ho17Ni2: Ni 0.895; fcc_A1: Ni 1	model	[1] Kardellass 2015	Table 6, p. 7, row 28 report
1553.15	eutectic: L -> Ho17Ni2 + fcc_A1	L: Ho 0.07; Ho17Ni2: Ho 0.105; fcc_A1: Ho 0	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 13 report
1553	eutectic: L -> fcc(Ni) + Ho2Ni17	L: Ni 0.931; Ho2Ni17: Ni 0.894737	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 35 report
1553	eutectic: L -> fcc(Ni) + Ho2Ni17	L: Ni 0.93; Ho2Ni17: Ni 0.894737	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 36 report
1468.15	L + HoNi3 -> HoNi2	L: Ni 0.63; HoNi3: Ni 0.75; HoNi2: Ni 0.667	experimental	[1] Kardellass 2015	Table 6, p. 7, row 17 report
1468.15	peritectic: L + HoNi3 -> HoNi2	L: Ho 0.37; HoNi3: Ho 0.25; HoNi2: Ho 0.333	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 8 report
1468.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1468.15	L + HoNi3 -> HoNi2	L: Ni 0.64; HoNi3: Ni 0.75; HoNi2: Ni 0.667	model	[1] Kardellass 2015	Table 6, p. 7, row 18 report
1468	peritectic: L + HoNi3 -> HoNi2	L: Ni 0.64; HoNi3: Ni 0.75; HoNi2: Ni 0.666667	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 20 report
1468	peritectic: L + HoNi3 -> HoNi2	HoNi3: Ni 0.75; HoNi2: Ni 0.666667	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 21 report
1465.2	peritectic: L + HoNi3 -> HoNi2	L: Ni 0.657; HoNi3: Ni 0.75; HoNi2: Ni 0.666667	model	[2] Ye 2023	Table 10, p. 22, row 22 report
1333.15	congruent melting: L -> HoNi	HoNi: Ho 0.5	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 6 report
1322.15	eutectic: L -> HoNi + HoNi2	L: Ni 0.5355; HoNi: Ni 0.5; HoNi2: Ni 0.659	model	[1] Kardellass 2015	Table 6, p. 7, row 16 report
1322	eutectic: L -> HoNi + HoNi2	L: Ni 0.536; HoNi: Ni 0.5; HoNi2: Ni 0.666667	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 17 report
1308.9	eutectic: L -> HoNi + HoNi2	L: Ni 0.553; HoNi: Ni 0.5; HoNi2: Ni 0.666667	model	[2] Ye 2023	Table 10, p. 22, row 19 report
1248.15	eutectic		experimental	[1] Kardellass 2015	p. 2 report	Three eutectic reactions formed between Ho3Ni and Ho2Ni3_LT at 720 C (30.0 at% Ni), between HoNi and HoNi2 at 975 C (54.0 at% Ni), and between Ho2Ni17 and Nickel at 1,280 C (93.0 at% Ni).
1248.15	eutectic: L -> HoNi + HoNi2	L: Ni 0.54; HoNi: Ni 0.5; HoNi2: Ni 0.656	experimental	[1] Kardellass 2015	Table 6, p. 7, row 15 report
1248.15	eutectic: L -> HoNi + HoNi2	L: Ho 0.46; HoNi: Ho 0.5; HoNi2: Ho 0.344	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 7 report
1248	eutectic: L -> HoNi + HoNi2	L: Ni 0.54; HoNi: Ni 0.5; HoNi2: Ni 0.666667	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 18 report
1243.15	L + HoNi -> Ho3Ni2_HT	L: Ni 0.38; HoNi: Ni 0.5; Ho3Ni2_HT: Ni 0.4	experimental	[1] Kardellass 2015	Table 6, p. 7, row 11 report
1243.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1243.15	peritectic: L + HoNi -> Ho3Ni2_HT	L: Ho 0.62; HoNi: Ho 0.5; Ho3Ni2_HT: Ho 0.6	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 4 report
1243	peritectic: L + HoNi -> Ho3Ni2_HT	HoNi: Ni 0.5; Ho3Ni2_HT: Ni 0.4	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 12 report
1241.15	L + HoNi -> Ho3Ni2_HT	L: Ni 0.3944; HoNi: Ni 0.5; Ho3Ni2_HT: Ni 0.4	model	[1] Kardellass 2015	Table 6, p. 7, row 12 report
1241	peritectic: L + HoNi -> Ho3Ni2_HT	L: Ni 0.394; HoNi: Ni 0.5; Ho3Ni2_HT: Ni 0.4	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 11 report
1240.4	peritectic: L + HoNi -> Ho3Ni2_HT	L: Ni 0.399; HoNi: Ni 0.5; Ho3Ni2_HT: Ni 0.4	model	[2] Ye 2023	Table 10, p. 22, row 13 report
1033.15	L + HoNi -> Ho3Ni2_LT	L: Ni 0.31; HoNi: Ni 0.5; Ho3Ni2_LT: Ni 0.4	experimental	[1] Kardellass 2015	Table 6, p. 7, row 9 report
1033.15	polymorphic: Ho3Ni2_HT -> Ho3Ni2_LT	Ho3Ni2_HT: Ho 0.6; Ho3Ni2_LT: Ho 0.6, Ni 0.4	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 5 report
1031.15	L + HoNi -> Ho3Ni2_LT	L: Ni 0.2951; HoNi: Ni 0.5; Ho3Ni2_LT: Ni 0.4	model	[1] Kardellass 2015	Table 6, p. 7, row 10 report
1023.15	L + Ho -> Ho3Ni	L: Ni 0.29; Ho: Ni 0; Ho3Ni: Ni 0.25	experimental	[1] Kardellass 2015	Table 6, p. 7, row 3 report
1023.15	peritectic		experimental	[1] Kardellass 2015	p. 2 report	Six peritectic reactions included Ho3Ni, Ho2Ni3_HT, HoNi2, HoNi3, Ho2Ni7, and Ho2Ni17 at 750, 970, 1195, 1285, 1320, and 1290 C, respectively.
1023.15	peritectic: L + Ho -> Ho3Ni	L: Ho 0.71; Ho: Ho 1; Ho3Ni: Ho 0.75	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 2 report
1023	peritectic: L + hcp(Ho) -> Ho3Ni	L: Ni 0.3; Ho3Ni: Ni 0.25	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 3 report
1020.2	peritectic: L + hcp(Ho) -> Ho3Ni	L: Ni 0.251; Ho3Ni: Ni 0.25	model	[2] Ye 2023	Table 10, p. 22, row 4 report
1014.15	L + Ho -> Ho3Ni	L: Ni 0.2563; Ho: Ni 0; Ho3Ni: Ni 0.25	model	[1] Kardellass 2015	Table 6, p. 7, row 4 report
1014	peritectic: L + hcp(Ho) -> Ho3Ni	L: Ni 0.256; Ho3Ni: Ni 0.25	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 2 report
1006.15	eutectic: L -> Ho3Ni + Ho3Ni2_LT	L: Ni 0.2813; Ho3Ni: Ni 0.25; Ho3Ni2_LT: Ni 0.4	model	[1] Kardellass 2015	Table 6, p. 7, row 6 report
1006	eutectic: L -> Ho3Ni + Ho3Ni2_LT	L: Ni 0.281; Ho3Ni: Ni 0.25; Ho3Ni2_LT: Ni 0.4	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 5 report
996.3	eutectic: L -> Ho3Ni + Ho3Ni2_LT	L: Ni 0.297; Ho3Ni: Ni 0.25; Ho3Ni2_LT: Ni 0.4	model	[2] Ye 2023	Table 10, p. 22, row 7 report
993.15	eutectic: L -> Ho3Ni + Ho3Ni2_LT	L: Ho 0.7; Ho3Ni: Ho 0.75; Ho3Ni2_LT: Ho 0.6	unspecified	[1] Kardellass 2015	Table 2, p. 3, row 3 report
993.15	eutectic		experimental	[1] Kardellass 2015	p. 2 report	Three eutectic reactions formed between Ho3Ni and Ho2Ni3_LT at 720 C (30.0 at% Ni), between HoNi and HoNi2 at 975 C (54.0 at% Ni), and between Ho2Ni17 and Nickel at 1,280 C (93.0 at% Ni).
993.15	eutectic: L -> Ho3Ni + Ho3Ni2_LT	L: Ni 0.3; Ho3Ni: Ni 0.25; Ho3Ni2_LT: Ni 0.4	experimental	[1] Kardellass 2015	Table 6, p. 7, row 5 report
993	eutectic: L -> Ho3Ni + Ho3Ni2_LT	Ho3Ni: Ni 0.25; Ho3Ni2_LT: Ni 0.4	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 6 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Ho–Ni system (38)
Phase	Compound	Value	T (K)	Class	MP DFT (kJ/mol-atom)	OQMD DFT (kJ/mol-atom)	Source	Location
Ho2Ni17	Ho2Ni17	-23.1 kJ/mol-atom ± 0.3	650	experimental	-19.799 (mp-aaacqkjz)	-20.143 (oqmd-30551)	[1] Kardellass 2015 cites Gozzi 2005 doi	Table 3, p. 4, row 32 report
Ho2Ni17	Ho2Ni17	-21.33 kJ/mol-atom	298.15	model	-19.799 (mp-aaacqkjz)	-20.143 (oqmd-30551)	[1] Kardellass 2015	Table 3, p. 4, row 33 report
Ho2Ni17	Ho2Ni17	-16 kJ/mol-atom	298.15	model	-19.799 (mp-aaacqkjz)	-20.143 (oqmd-30551)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 34 report
Ho2Ni17	Ho2Ni17	-16 kJ/mol-atom	298.15	model	-19.799 (mp-aaacqkjz)	-20.143 (oqmd-30551)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 31 report
Ho2Ni7	Ho2Ni7	-40 kJ/mol-atom	298.15	model	-38.648 (mp-aaacpsuu)	-39.098 (oqmd-1483994)	[1] Kardellass 2015	Table 3, p. 4, row 24 report
Ho2Ni7	Ho2Ni7	-39.92 kJ/mol-atom	298.15	model	-38.648 (mp-aaacpsuu)	-39.098 (oqmd-1483994)	[1] Kardellass 2015	Table 3, p. 4, row 25 report
Ho2Ni7	Ho2Ni7	-35 kJ/mol-atom	298.15	model	-38.648 (mp-aaacpsuu)	-39.098 (oqmd-1483994)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 23 report
Ho2Ni7	Ho2Ni7	-34 kJ/mol-atom	298.15	model	-38.648 (mp-aaacpsuu)	-39.098 (oqmd-1483994)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 26 report
Ho3Ni	Ho3Ni	-38 kJ/mol-atom	298.15	model	-24.74 (mp-aaacprea)	-25.183 (oqmd-30550)	[1] Kardellass 2015	Table 3, p. 4, row 2 report
Ho3Ni	Ho3Ni	-25 kJ/mol-atom	298.15	model	-24.74 (mp-aaacprea)	-25.183 (oqmd-30550)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 1 report
Ho3Ni	Ho3Ni	-24 kJ/mol-atom	298.15	model	-24.74 (mp-aaacprea)	-25.183 (oqmd-30550)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 4 report
Ho3Ni	Ho3Ni	-23.95 kJ/mol-atom	298.15	model	-24.74 (mp-aaacprea)	-25.183 (oqmd-30550)	[1] Kardellass 2015	Table 3, p. 4, row 3 report
Ho3Ni2_HT	Ho3Ni2	-28.34 kJ/mol-atom	298.15	model	-36.512 (mp-aaacjmkp)	-37.585 (oqmd-30549)	[1] Kardellass 2015	Table 3, p. 4, row 9 report
Ho3Ni2_LT	Ho3Ni2	-47 kJ/mol-atom	298.15	model	-36.512 (mp-aaacjmkp)	-37.585 (oqmd-30549)	[1] Kardellass 2015	Table 3, p. 4, row 6 report
Ho3Ni2_LT	Ho3Ni2	-40 kJ/mol-atom	298.15	model	-36.512 (mp-aaacjmkp)	-37.585 (oqmd-30549)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 5 report
Ho3Ni2_LT	Ho3Ni2	-38.45 kJ/mol-atom	298.15	model	-36.512 (mp-aaacjmkp)	-37.585 (oqmd-30549)	[1] Kardellass 2015	Table 3, p. 4, row 7 report
Ho3Ni2_LT	Ho3Ni2	-38 kJ/mol-atom	298.15	model	-36.512 (mp-aaacjmkp)	-37.585 (oqmd-30549)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 8 report
HoNi	HoNi	-48.8 kJ/mol-atom	298.15	model	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[1] Kardellass 2015	Table 3, p. 4, row 13 report
HoNi	HoNi	-48.6 kJ/mol-atom ± 0.77	1476	experimental	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[1] Kardellass 2015 cites Gozzi 2005 doi	Table 3, p. 4, row 12 report
HoNi	HoNi	-48.23 kJ/mol-atom	298.15	model	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[1] Kardellass 2015	Table 3, p. 4, row 14 report
HoNi	HoNi	-45 kJ/mol-atom	298.15	model	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 10 report
HoNi	HoNi	-41.7 kJ/mol-atom ± 1.4	1476	experimental	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[1] Kardellass 2015 cites Guo 1998 doi	Table 3, p. 4, row 11 report
HoNi2	HoNi2	-47.5 kJ/mol-atom	298.15	model	-44.81 (mp-aaaaaazx)	-44.977 (oqmd-17463)	[1] Kardellass 2015	Table 3, p. 4, row 16 report
HoNi2	HoNi2	-45 kJ/mol-atom	298.15	model	-44.81 (mp-aaaaaazx)	-44.977 (oqmd-17463)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 15 report
HoNi2	HoNi2	-45 kJ/mol-atom	298.15	model	-44.81 (mp-aaaaaazx)	-44.977 (oqmd-17463)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 18 report
HoNi2	HoNi2	-42.67 kJ/mol-atom	298.15	model	-44.81 (mp-aaaaaazx)	-44.977 (oqmd-17463)	[1] Kardellass 2015	Table 3, p. 4, row 17 report
HoNi3	HoNi3	-42.5 kJ/mol-atom	298.15	model	-41.055 (mp-aaaaadao)	-41.425 (oqmd-19842)	[1] Kardellass 2015	Table 3, p. 4, row 20 report
HoNi3	HoNi3	-40.01 kJ/mol-atom	298.15	model	-41.055 (mp-aaaaadao)	-41.425 (oqmd-19842)	[1] Kardellass 2015	Table 3, p. 4, row 21 report
HoNi3	HoNi3	-37 kJ/mol-atom	298.15	model	-41.055 (mp-aaaaadao)	-41.425 (oqmd-19842)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 19 report
HoNi3	HoNi3	-37 kJ/mol-atom	298.15	model	-41.055 (mp-aaaaadao)	-41.425 (oqmd-19842)	[1] Kardellass 2015 cites Kayzel 1995	Table 3, p. 4, row 22 report
HoNi5	HoNi5	-35.49 kJ/mol-atom ± 0.04	1476	experimental	-32.138 (mp-aaaaacht)	-32.728 (oqmd-17464)	[1] Kardellass 2015 cites Guo 1998 doi	Table 3, p. 4, row 29 report
HoNi5	HoNi5	-34.04 kJ/mol-atom	298.15	model	-32.138 (mp-aaaaacht)	-32.728 (oqmd-17464)	[1] Kardellass 2015	Table 3, p. 4, row 30 report
HoNi5	HoNi5	-29.9 kJ/mol-atom ± 0.8	1474	experimental	-32.138 (mp-aaaaacht)	-32.728 (oqmd-17464)	[1] Kardellass 2015 cites Pot 1993	Table 3, p. 4, row 28 report
HoNi5	HoNi5	-26 kJ/mol-atom	298.15	model	-32.138 (mp-aaaaacht)	-32.728 (oqmd-17464)	[1] Kardellass 2015 cites de Boer FR 1989	Table 3, p. 4, row 27 report
Ni17Ho2	Ho2Ni17	-21.33 kJ/mol-atom	298.15	model	-19.799 (mp-aaacqkjz)	-20.143 (oqmd-30551)	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 2 report
Ni2Ho	HoNi2	-42.67 kJ/mol-atom	298.15	model	-44.81 (mp-aaaaaazx)	-44.977 (oqmd-17463)	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 9 report
Ni5Ho	HoNi5	-34.04 kJ/mol-atom	298.15	model	-32.138 (mp-aaaaacht)	-32.728 (oqmd-17464)	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 5 report
NiHo	HoNi	-48.23 kJ/mol-atom	298.15	model	-45.179 (mp-aaaaarop)	-45.907 (oqmd-18379)	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 13 report

Other properties

Phase transition (18)

Phase transition, Ho–Ni system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	1030.2 K	1030.2	polymorphic: Ho3Ni2_HT -> Ho3Ni2_LT Ho3Ni2_HT: Ni 0.4; Ho3Ni2_LT: Ni 0.4	model	[2] Ye 2023	Table 10, p. 22, row 10 report
Phase transition	1031 K	1031	polymorphic: Ho3Ni2_HT -> Ho3Ni2_LT Ho3Ni2_HT: Ni 0.4; Ho3Ni2_LT: Ni 0.4	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 8 report
Phase transition	1031.15 K	1031.15	Ho3Ni2_HT -> Ho3Ni2_LT Ho3Ni2_HT: Ni 0.4; Ho3Ni2_LT: Ni 0.4	model	[1] Kardellass 2015	Table 6, p. 7, row 8 report
Phase transition	1033 K	1033	polymorphic: Ho3Ni2_HT -> Ho3Ni2_LT Ho3Ni2_HT: Ni 0.4; Ho3Ni2_LT: Ni 0.4	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 9 report
Phase transition	1033.15 K	1033.15	Ho3Ni2_HT -> Ho3Ni2_LT Ho3Ni2_HT: Ni 0.4; Ho3Ni2_LT: Ni 0.4	experimental	[1] Kardellass 2015	Table 6, p. 7, row 7 report
Phase transition	1333 K	1333	congruent melting: L -> HoNi L: Ni 0.5; HoNi: Ni 0.5	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 14 report
Phase transition	1333 K	1333	congruent melting: L -> HoNi L: Ni 0.5; HoNi: Ni 0.5	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 15 report
Phase transition	1333.15 K	1333.15	L -> HoNi L: Ni 0.5; HoNi: Ni 0.5	model	[1] Kardellass 2015	Table 6, p. 7, row 14 report
Phase transition	1333.15 K	1333.15	L -> HoNi L: Ni 0.5; HoNi: Ni 0.5	experimental	[1] Kardellass 2015	Table 6, p. 7, row 13 report
Phase transition	1338 K	1338	congruent melting: L -> HoNi L: Ni 0.5; HoNi: Ni 0.5	model	[2] Ye 2023	Table 10, p. 22, row 16 report
Phase transition	1638.2 K	1638.2	congruent melting: L -> HoNi5 L: Ni 0.833; HoNi5: Ni 0.833333	model	[2] Ye 2023	Table 10, p. 22, row 31 report
Phase transition	1643 K	1643	congruent melting: L -> HoNi5 L: Ni 0.833; HoNi5: Ni 0.833333	experimental	[2] Ye 2023 cites ref. 45	Table 10, p. 22, row 30 report
Phase transition	1643 K	1643	congruent melting: L -> HoNi5 L: Ni 0.833; HoNi5: Ni 0.833333	model	[2] Ye 2023 cites ref. 40	Table 10, p. 22, row 29 report
Phase transition	1643.15 K	1643.15	L -> HoNi5 L: Ni 0.833; HoNi5: Ni 0.833	experimental	[1] Kardellass 2015	Table 6, p. 7, row 23 report
Phase transition	1643.15 K	1643.15	L -> HoNi5 L: Ni 0.833; HoNi5: Ni 0.833	model	[1] Kardellass 2015	Table 6, p. 7, row 24 report
Phase transition	1643.15 K	1643.15	congruent transformation	experimental	[1] Kardellass 2015	p. 2 report	Two congruent meltings for HoNi and HoNi5 at 1,060 and 1,370 C.
Phase transition	1747.15 K	1747.15	L -> (Ho) L: Ni 0; (Ho): Ni 0	model	[1] Kardellass 2015	Table 6, p. 7, row 2 report
Phase transition	1747.15 K	1747.15	L -> (Ho) L: Ni 0; (Ho): Ni 0	experimental	[1] Kardellass 2015	Table 6, p. 7, row 1 report

Heat capacity / entropy / enthalpy (22)

Heat capacity / entropy / enthalpy, Ho–Ni system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Entropy printed: Entropy of formation	33.56 J/mol-atom/K	298.15	Ho2Ni17 alloy: Ni 0.894737	model	[1] Kardellass 2015	Table 3, p. 4, row 33 report
Entropy printed: Entropy of formation	36.3 J/mol-atom/K	298.15	Ho2Ni7 alloy: Ni 0.777778	model	[1] Kardellass 2015	Table 3, p. 4, row 25 report
Entropy printed: Entropy of formation	59.24 J/mol-atom/K	298.15	Ho3Ni alloy: Ni 0.25	model	[1] Kardellass 2015	Table 3, p. 4, row 3 report
Entropy printed: Entropy of formation	63.25 J/mol-atom/K	298.15	Ho3Ni2_HT alloy: Ni 0.4	model	[1] Kardellass 2015	Table 3, p. 4, row 9 report
Entropy printed: Entropy of formation	53.31 J/mol-atom/K	298.15	Ho3Ni2_LT alloy: Ni 0.4	model	[1] Kardellass 2015	Table 3, p. 4, row 7 report
Entropy printed: Entropy of formation	46.21 J/mol-atom/K	298.15	HoNi alloy: Ni 0.5	model	[1] Kardellass 2015	Table 3, p. 4, row 14 report
Entropy printed: Entropy of formation	42.32 J/mol-atom/K	298.15	HoNi2 alloy: Ni 0.666667	model	[1] Kardellass 2015	Table 3, p. 4, row 17 report
Entropy printed: Entropy of formation	38.16 J/mol-atom/K	298.15	HoNi3 alloy: Ni 0.75	model	[1] Kardellass 2015	Table 3, p. 4, row 21 report
Entropy printed: Entropy of formation	34.27 J/mol-atom/K	298.15	HoNi5 alloy: Ni 0.833333	model	[1] Kardellass 2015	Table 3, p. 4, row 30 report
Entropy printed: Entropies of formation	33.56 J/mol-atom/K	298.15	Ni17Ho2 alloy: Ho 0.105263, Ni 0.894737	model	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 2 report
Entropy printed: Entropies of formation	42.32 J/mol-atom/K	298.15	Ni2Ho alloy: Ho 0.333333, Ni 0.666667	model	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 9 report
Entropy printed: Entropies of formation	34.27 J/mol-atom/K	298.15	Ni5Ho alloy: Ho 0.166667, Ni 0.833333	model	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 5 report
Entropy printed: Entropies of formation	46.21 J/mol-atom/K	298.15	NiHo alloy: Ho 0.5, Ni 0.5	model	[3] Kardellass 2016 cites Kardellass 2015 doi	Table 4, p. 7, row 13 report
Heat capacity	25.21 J/mol-atom/K	298.15	Ho2Ni17 alloy: Ni 0.894737	model	[1] Kardellass 2015	Table 3, p. 4, row 33 report
Heat capacity	25.46 J/mol-atom/K	298.15	Ho2Ni7 alloy: Ni 0.777778	model	[1] Kardellass 2015	Table 3, p. 4, row 25 report
Heat capacity	26.61 J/mol-atom/K	298.15	Ho3Ni alloy: Ni 0.25	model	[1] Kardellass 2015	Table 3, p. 4, row 3 report
Heat capacity	25.85 J/mol-atom/K	298.15	Ho3Ni2_HT alloy: Ni 0.4	model	[1] Kardellass 2015	Table 3, p. 4, row 9 report
Heat capacity	26.28 J/mol-atom/K	298.15	Ho3Ni2_LT alloy: Ni 0.4	model	[1] Kardellass 2015	Table 3, p. 4, row 7 report
Heat capacity	26.07 J/mol-atom/K	298.15	HoNi alloy: Ni 0.5	model	[1] Kardellass 2015	Table 3, p. 4, row 14 report
Heat capacity	25.71 J/mol-atom/K	298.15	HoNi2 alloy: Ni 0.666667	model	[1] Kardellass 2015	Table 3, p. 4, row 17 report
Heat capacity	25.52 J/mol-atom/K	298.15	HoNi3 alloy: Ni 0.75	model	[1] Kardellass 2015	Table 3, p. 4, row 21 report
Heat capacity	25.34 J/mol-atom/K	298.15	HoNi5 alloy: Ni 0.833333	model	[1] Kardellass 2015	Table 3, p. 4, row 30 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

S. Kardellass, C. Servant, N. Selhaoui, Thermodynamic description of the holmium–nickel system, J Therm Anal Calorim 119, 1225-1234 (2015). doi:10.1007/s10973-014-4189-1
Hongjian Ye, Maohua Rong, Qingrong Yao, Qing Chen, Jiang Wang, Guanghui Rao et al., Phase equilibria and thermodynamic properties in the RE-Ni (RE = rare earth metals) binary systems, J Mater Sci 58, 1260-1292 (2023). doi:10.1007/s10853-022-08039-1
Saïd Kardellass, Colette Servant, Najim Selhaoui, Thermodynamic description of the Ni–Yb and Ni–Eu binary systems, J Therm Anal Calorim 125, 255-269 (2016). doi:10.1007/s10973-016-5380-3

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}