In–Ni system

6 accepted literature values from 1 paper(s) (experimental 3, model 3); 2 calculated phase diagram(s).

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (13) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	3
model	3

Accepted values by property group
Property group	Values
formation	6

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
InNi-13Cao.tdb	Z. Cao, W. Xie, K. Wang, G. Du, Z. Qiao, J. Electron. Mater., 42, 2615-29(2013). doi:10.1007/s11664-013-2599-7	`34c0438a40de80b3abb6e1468b276a996d24db9d293b89f983d5e2301d3c1d8c`	viewer · TDB · JSON
InNi-18Dor.tdb	T.T. Dorini, L.T.F. Eleno, Calphad, 62, 42-48(2018). doi:10.1016/j.calphad.2018.05.004	`36968af0e9cc88ce80e3a5152deecfee885c9c8d16f4b20314736f0048135f98`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
InNi-13Cao.tdb	1197.88	INNI_B2 (x(Ni) 0.48612) + LIQUID (x(Ni) 0.50919) + INNI2_B81 (x(Ni) 0.57673)
InNi-13Cao.tdb	1183.17	INNI2_B81 (x(Ni) 0.68584) + LIQUID (x(Ni) 0.75042) + FCC_A1 (x(Ni) 0.92134)
InNi-13Cao.tdb	1141.77	LIQUID (x(Ni) 0.23908) + IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.40441)
InNi-13Cao.tdb	1138.01	INNI_B2 (x(Ni) 0.48366) + IN9NI13 (x(Ni) 0.57617) + INNI2_B81 (x(Ni) 0.58716)
InNi-13Cao.tdb	1134.99	INNI_B2 (x(Ni) 0.48284) + INNI_B35 (x(Ni) 0.5) + IN9NI13 (x(Ni) 0.57586)
InNi-13Cao.tdb	1116.52	INNI2_B81 (x(Ni) 0.68369) + INNI3_D019 (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.93117)
InNi-13Cao.tdb	1116.52	INNI2_B81 (x(Ni) 0.68368) + INNI3_D019 (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.93121)
InNi-13Cao.tdb	1049.21	IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.44233) + INNI_B35 (x(Ni) 0.5)
InNi-13Cao.tdb	1049.21	IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.44229) + INNI_B35 (x(Ni) 0.5)
InNi-13Cao.tdb	1049.21	IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.44234) + INNI_B35 (x(Ni) 0.5)
InNi-13Cao.tdb	932.22	INNI2_B81 (x(Ni) 0.66546) + INNI2_B82 (x(Ni) 0.66667) + INNI3_D019 (x(Ni) 0.75)
InNi-13Cao.tdb	743.36	IN9NI13 (x(Ni) 0.59069) + INNI2_B81 (x(Ni) 0.64677) + INNI2_B82 (x(Ni) 0.66667)
InNi-13Cao.tdb	677.3	LIQUID (x(Ni) 0.03735) + IN7NI3_D8F (x(Ni) 0.3) + IN3NI2_D513 (x(Ni) 0.4)
InNi-13Cao.tdb	677.3	LIQUID (x(Ni) 0.03742) + IN7NI3_D8F (x(Ni) 0.3) + IN3NI2_D513 (x(Ni) 0.4)
InNi-13Cao.tdb	429.48	TETRAGONAL_A6 (x(Ni) 0) + LIQUID (x(Ni) 5.700e-4) + IN7NI3_D8F (x(Ni) 0.3)
InNi-13Cao.tdb	429.48	TETRAGONAL_A6 (x(Ni) 0) + LIQUID (x(Ni) 5.600e-4) + IN7NI3_D8F (x(Ni) 0.3)
InNi-18Dor.tdb	1201.16	INNI_B2 (x(Ni) 0.47467) + LIQUID (x(Ni) 0.5208) + INNI2_B81 (x(Ni) 0.58046)
InNi-18Dor.tdb	1182.87	INNI2_B81 (x(Ni) 0.68706) + LIQUID (x(Ni) 0.74582) + FCC_A1 (x(Ni) 0.92797)
InNi-18Dor.tdb	1142.79	INNI_B2 (x(Ni) 0.46385) + INNI2_B81 (x(Ni) 0.59088) + IN9NI13 (x(Ni) 0.59091)
InNi-18Dor.tdb	1141.93	LIQUID (x(Ni) 0.26829) + IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.40389)
InNi-18Dor.tdb	1139.24	INNI_B2 (x(Ni) 0.46301) + INNI_B35 (x(Ni) 0.5) + IN9NI13 (x(Ni) 0.59091)
InNi-18Dor.tdb	1120.05	INNI2_B81 (x(Ni) 0.68472) + INNI3_D019 (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.93632)
InNi-18Dor.tdb	1120.05	INNI2_B81 (x(Ni) 0.68472) + INNI3_D019 (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.93633)
InNi-18Dor.tdb	1044.47	IN3NI2_D513 (x(Ni) 0.4) + INNI_B2 (x(Ni) 0.43551) + INNI_B35 (x(Ni) 0.5)
InNi-18Dor.tdb	931.08	INNI2_B81 (x(Ni) 0.66183) + INNI2_B82 (x(Ni) 0.66667) + INNI3_D019 (x(Ni) 0.75)
InNi-18Dor.tdb	747.44	IN9NI13 (x(Ni) 0.59091) + INNI2_B81 (x(Ni) 0.65011) + INNI2_B82 (x(Ni) 0.66667)
InNi-18Dor.tdb	667.88	LIQUID (x(Ni) 0.04432) + IN7NI3_D8F (x(Ni) 0.3) + IN3NI2_D513 (x(Ni) 0.4)
InNi-18Dor.tdb	667.88	LIQUID (x(Ni) 0.04438) + IN7NI3_D8F (x(Ni) 0.3) + IN3NI2_D513 (x(Ni) 0.4)
InNi-18Dor.tdb	428.87	TETRAGONAL_A6 (x(Ni) 0) + LIQUID (x(Ni) 0.00179) + IN7NI3_D8F (x(Ni) 0.3)
InNi-18Dor.tdb	428.87	TETRAGONAL_A6 (x(Ni) 0) + LIQUID (x(Ni) 0.00178) + IN7NI3_D8F (x(Ni) 0.3)
InNi-18Dor.tdb	348.23	IN7NI3_D8F (x(Ni) 0.3) + IN3NI2_D513 (x(Ni) 0.4) + INNI_B35 (x(Ni) 0.5)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull InNi-13Cao

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, In–Ni system (6)
Phase	Value	T (K)	Class	Source	Location
ζ(Ni2In)	-18.771 kJ/mol (basis unstated) ± 0.478	1060	experimental	[1] Cao 2013 cites Predel 1979 doi	Table III, p. 7, row 5 report
ζ(Ni2In)	-18.523 kJ/mol (basis unstated)	850	model	[1] Cao 2013	Table III, p. 7, row 4 report
ζ(Ni2In)	-18.209 kJ/mol (basis unstated)	1060	model	[1] Cao 2013	Table III, p. 7, row 6 report
ζ(Ni2In)	-17.86 kJ/mol (basis unstated)	850	experimental	[1] Cao 2013 cites Vinokurova 1973	Table III, p. 7, row 3 report
ζ(Ni2In)	-17.3 kJ/mol (basis unstated)	298.15	experimental	[1] Cao 2013 cites Schmid 1995	Table III, p. 7, row 1 report
ζ(Ni2In)	-16.953 kJ/mol (basis unstated)	298.15	model	[1] Cao 2013	Table III, p. 7, row 2 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Zhanmin Cao, Wei Xie, Kunpeng Wang, Guangwei Du, Zhiyu Qiao, Thermodynamic Assessment of the In-Ni-Sb System and Predictions for Thermally Stable Contacts to InSb, Journal of Elec Materi 42, 2615-2629 (2013). doi:10.1007/s11664-013-2599-7

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}