# In–Sb system > In–Sb system: 12 accepted literature values (formation 7, heat capacity / entropy / enthalpy 4, phase transition 1) and 5 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote. HTML: https://data.orchid-project.org/systems/IN-SB.html · Markdown: https://data.orchid-project.org/systems/IN-SB.md 12 accepted literature values from 3 paper(s) (experimental 3, model 8, unspecified 1); 5 calculated phase diagram(s). 3 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV. Data: [JSON](https://data.orchid-project.org/literature/systems/IN-SB.json) · [CSV](https://data.orchid-project.org/systems/IN-SB.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#IN-SB) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-03Liu.json) · [phases (7)](https://data.orchid-project.org/phases/pages/IN-SB.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/IN-SB.html) · [Markdown](https://data.orchid-project.org/systems/IN-SB.md) Table: Accepted values by evidence class | Evidence class | Values | |---|---:| | experimental | 3 | | model | 8 | | unspecified | 1 | Table: Accepted values by property group | Property group | Values | |---|---:| | phase transition | 1 | | formation | 7 | | heat capacity / entropy / enthalpy | 4 | ## Calculated phase diagrams Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model. Table: Assessments with a calculated phase diagram | TDB file | Assessment | SHA-256 | Links | |---|---|---|---| | InSb-03Liu.tdb | H.S. Liu, C.L. Liu, C. Wang, Z.P. Jin, K. Ishida, J. Electron. Mater., 32, 81-88(2003). [doi:10.1007/s11664-003-0240-x](https://doi.org/10.1007/s11664-003-0240-x) | `8e3372858668e0fe38e19320471c0f7944e2fd8101eb31b8e75aa1aefb738036` | [viewer](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-03Liu.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/InSb-03Liu.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/InSb-03Liu.json) | | InSb-13Cao.tdb | Z. Cao, W. Xie, K. Wang, G. Du, Z. Qiao, J. Electron. Mater., 42, 2615-29(2013). [doi:10.1007/s11664-013-2599-7](https://doi.org/10.1007/s11664-013-2599-7) | `462ef51afa935db94e1f1375b4d03a2af41fd6940a72561db42442ad001c4a14` | [viewer](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-13Cao.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/InSb-13Cao.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/InSb-13Cao.json) | | InSb-19Gie.tdb | W. Gierlotka, S.-W. Chen, S.-M. Tseng, P.-H. Lin, Metall. Mater. Trans. A, 50A, 3891-3902(2019). [doi:10.1007/s11661-019-05288-9](https://doi.org/10.1007/s11661-019-05288-9) | `ad0e725af0bc5e367c69dbc74b441543d2b21c57065925a852bb41c9209b2235` | [viewer](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-19Gie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/InSb-19Gie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/InSb-19Gie.json) | | InSb-94Ans-LB.tdb | I. Ansara, C. Chatillon, H.L. Lukas, T. Nishizawa, H. Ohtani, K. Ishida, M. Hillert, B. Sundman, B.B. Argent, A. Watson, T.G. Chart, T. Anderson, Calphad, 18, 177-222(1994). [doi:10.1016/0364-5916(94)90027-2](https://doi.org/10.1016/0364-5916%2894%2990027-2) | `00dc9a7748d9814817cca9786ec12ac02570a28dfa088ccacc579e150ea1fcb0` | [viewer](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-94Ans-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/InSb-94Ans-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/InSb-94Ans-LB.json) | | InSb-97Xie.tdb | Y. Xie, Z. Qiao, X. Xing, C. Wang, J. Shen, Rare Met., 16, 81-89(1997). | `7b7c5eb7b886d1e5f57441438104988ed048b37597d0e8add636540773e89381` | [viewer](https://orchid-project.org/phase-diagrams/#IN-SB/InSb-97Xie.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/InSb-97Xie.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/InSb-97Xie.json) | Table: Calculated three-phase invariants (model, mole fraction of the second component) | TDB file | T (K) | Phases at the invariant | |---|---:|---| | InSb-03Liu.tdb | 771.36 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.69125) + RHOMBOHEDRAL_A7 (x(Sb) 0.99239) | | InSb-03Liu.tdb | 771.36 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.69146) + RHOMBOHEDRAL_A7 (x(Sb) 0.9924) | | InSb-03Liu.tdb | 427.89 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.004) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-03Liu.tdb | 427.89 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00395) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-13Cao.tdb | 775.39 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.69811) + RHOMBOHEDRAL_A7 (x(Sb) 0.99509) | | InSb-13Cao.tdb | 775.39 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.69856) + RHOMBOHEDRAL_A7 (x(Sb) 0.9951) | | InSb-13Cao.tdb | 428.56 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00259) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-13Cao.tdb | 428.56 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00253) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-19Gie.tdb | 774.26 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.71644) + RHOMBOHEDRAL_A7 (x(Sb) 0.99455) | | InSb-19Gie.tdb | 774.26 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.71644) + RHOMBOHEDRAL_A7 (x(Sb) 0.99455) | | InSb-19Gie.tdb | 426.91 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00584) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-19Gie.tdb | 426.91 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00583) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-94Ans-LB.tdb | 767.76 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.687) + RHOMBOHEDRAL_A7 (x(Sb) 0.99482) | | InSb-94Ans-LB.tdb | 767.76 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.68707) + RHOMBOHEDRAL_A7 (x(Sb) 0.99482) | | InSb-94Ans-LB.tdb | 427.52 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00475) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-94Ans-LB.tdb | 427.52 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00472) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-97Xie.tdb | 765.47 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.67731) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | InSb-97Xie.tdb | 765.47 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.67754) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | InSb-97Xie.tdb | 765.47 | ZINCBLENDE_B3 (x(Sb) 0.5) + LIQUID (x(Sb) 0.67809) + RHOMBOHEDRAL_A7 (x(Sb) 1) | | InSb-97Xie.tdb | 426.32 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00735) + ZINCBLENDE_B3 (x(Sb) 0.5) | | InSb-97Xie.tdb | 426.32 | TETRAGONAL_A6 (x(Sb) 0) + LIQUID (x(Sb) 0.00729) + ZINCBLENDE_B3 (x(Sb) 0.5) | Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/IN/IN-SB.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/IN/IN-SB.json) · [CALPHAD hull InSb-03Liu](https://data.orchid-project.org/hulls/calphad-sgte/IN/IN-SB--InSb-03Liu.json) · [CALPHAD hull InSb-13Cao](https://data.orchid-project.org/hulls/calphad-sgte/IN/IN-SB--InSb-13Cao.json) · [CALPHAD hull InSb-94Ans-LB](https://data.orchid-project.org/hulls/calphad-sgte/IN/IN-SB--InSb-94Ans-LB.json) · [CALPHAD hull InSb-97Xie](https://data.orchid-project.org/hulls/calphad-sgte/IN/IN-SB--InSb-97Xie.json) ## Formation enthalpies Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json). Table: Enthalpies of formation, In–Sb system (7) | Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote | |---|---|---:|---:|---|---:|---:|---|---|---| | InSb | | -32.47 kJ/mol (basis unstated) | 298.15 | model | | | [1] Onderka 2002; _cites Ansara 1994_ | Table AI, p. 19, row 26; `ORC-B3BBKENM2D.ce5911` | | | InSb | | -30.5 kJ/mol (basis unstated) | 298.15 | unspecified | | | [1] Onderka 2002; _cites Wagman 1968_ | Table AI, p. 19, row 27; `ORC-LIMGRBQSRY` | | | InSb | | -30 kJ/mol (basis unstated) | 298.15 | model | | | [1] Onderka 2002; _cites Kaufman 1981_ | Table AI, p. 19, row 25; `ORC-5RT26BWS36.06bccb` | | | InSb | | -20.615 kJ/mol (basis unstated) | 723 | model | | | [2] Cao 2013 | Table V, p. 9, row 4; `ORC-J23XL3YR7P` | | | InSb | | -18.367 kJ/mol (basis unstated) | 273 | model | | | [2] Cao 2013 | Table V, p. 9, row 2; `ORC-5U6I7MN4LT` | | | InSb | | -18.003 kJ/mol (basis unstated) | 723 | experimental | | | [2] Cao 2013; _cites Kleppa 1955_ [doi](https://doi.org/10.1021/ja01609a025) | Table V, p. 9, row 3; `ORC-P2IP3IATME` | | | InSb | | -14.53 kJ/mol (basis unstated) | 273 | experimental | | | [2] Cao 2013; _cites Schottky 1958_ [doi](https://doi.org/10.1016/0001-6160%2858%2990069-5) | Table V, p. 9, row 1; `ORC-VKAVYWJVBM` | | ## Other properties ### Phase transition (1) Table: Phase transition, In–Sb system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Phase transition | 798.15 K | 798.15 | congruent transformation: InSb -> liquid | experimental | [3] Gierlotka 2019 | p. 3; `ORC-YIEATHEBMQ.d6b161` | “The InSb is involved in reactions: the first invariant reaction is the congruent melting reaction of InSb, at 525 °C.” | ### Heat capacity / entropy / enthalpy (4) Table: Heat capacity / entropy / enthalpy, In–Sb system | Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote | |---|---:|---:|---|---|---|---|---| | Entropy; _printed: S°298_ | 85.26 J/mol-formula K | 298.15 | InSb | model | [1] Onderka 2002; _cites Ansara 1994_ | Table AI, p. 19, row 26; `ORC-B3BBKENM2D.0c5b1e` | | | Heat capacity; _printed: Cp,298_ | 49.54 J/mol (basis unstated)/K | 298.15 | InSb | model | [1] Onderka 2002; _cites Ansara 1994_ | Table AI, p. 19, row 26; `ORC-B3BBKENM2D.17b573` | | | sm fusion; _printed: ΔmS_ | 58.53 J/mol-formula K | 798 | InSb; _alloy: In 0.5, Sb 0.5_ | model | [1] Onderka 2002; _cites Kaufman 1981_ | Table AI, p. 19, row 25; `ORC-5RT26BWS36.aa471e` | | | sm fusion; _printed: ΔmS_ | 61.83 J/mol-formula K | 800 | InSb; _alloy: In 0.5, Sb 0.5_ | model | [1] Onderka 2002; _cites Ansara 1994_ | Table AI, p. 19, row 26; `ORC-B3BBKENM2D.20a74c` | | ## Sources Reporting papers the values were read from (a value cited from another work names that work in its row). 1. B. Onderka, J. Unland, R. Schmid-Fetzer, Thermodynamics and phase stability in the In–N system, J. Mater. Res. 17, 3065-3083 (2002). [doi:10.1557/jmr.2002.0445](https://doi.org/10.1557/jmr.2002.0445) 2. Zhanmin Cao, Wei Xie, Kunpeng Wang, Guangwei Du, Zhiyu Qiao, Thermodynamic Assessment of the In-Ni-Sb System and Predictions for Thermally Stable Contacts to InSb, Journal of Elec Materi 42, 2615-2629 (2013). [doi:10.1007/s11664-013-2599-7](https://doi.org/10.1007/s11664-013-2599-7) 3. Wojciech Gierlotka, Sinn-wen Chen, Ssu-ming Tseng, Po-han Lin, Co-In-Sb Ternary System (II): Isoplethal Section and Thermodynamic Modeling, Metall Mater Trans A 50, 3891-3902 (2019). [doi:10.1007/s11661-019-05288-9](https://doi.org/10.1007/s11661-019-05288-9) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859 - R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_phase_diagrams_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Diagrams: calculated binary phase diagrams}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735859}, url = {https://doi.org/10.5281/zenodo.23735859} } @misc{orchid_hulls_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735891}, url = {https://doi.org/10.5281/zenodo.23735891} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).