Mo–Ni system

56 accepted literature values from 3 paper(s) (experimental 7, model 10, DFT 39); 5 calculated phase diagram(s). 10 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (10) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	7
model	10
DFT	39

Accepted values by property group
Property group	Values
invariant reaction	16
phase transition	1
formation	39

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
MoNi-01Mor.tdb	M. Morishita, K. Koyama, S. Yagi, G. Zhang, J. Alloys Compd., 314, 212-18(2001). doi:10.1016/S0925-8388(00)01258-5	`de623892aa4864fb3dff962e9c72ea7b4fbe6b51f2ec8bfeb02e38c1c869e48b`	viewer · TDB · JSON
MoNi-05Zho.tdb	S.H. Zhou, Y. Wang, C. Jiang, J.Z. Zhu, L.-Q. Chen, Z.-K. Liu, Mater. Sci. Eng. A, 397, 288-96(2005). doi:10.1016/j.msea.2005.02.037	`03fecfc9d1c2d36882310c5fd45abd995f1326922c853c1a619d776c2b67e59e`	viewer · TDB · JSON
MoNi-18Yaq.tdb	K. Yaqoob, J.-C. Crivello, J.-M. Joubert, Calphad, 62, 215-22(2018). doi:10.1016/j.calphad.2018.07.002	`3924118c417341268908ec0252e6f92fc8ed037b40cc0b02b79cb284df78edf0`	viewer · TDB · JSON
MoNi-90Fri.tdb	K. Frisk, Calphad, 14, 371-380(1990). doi:10.1016/0364-5916(90)90031-T	`466888685f3de89e12f0197db8319880a8e533eaa798bdfdd9023910c12b975d`	viewer · TDB · JSON
MoNi-99Cui-LB.tdb	Y. Cui, X. Lu, Z. Jin, Metall. Mater. Trans. A, 30A, 2735-44(1999). doi:10.1007/s11661-999-0110-0	`5e95ab16e2564ecb46a91c8647e272282afcc6ecc3189b68c28a5a29fbec178c`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
MoNi-01Mor.tdb	1641.99	BCC_A2 (x(Ni) 2.500e-4) + MONI (x(Ni) 0.5) + LIQUID (x(Ni) 0.61054)
MoNi-01Mor.tdb	1641.99	BCC_A2 (x(Ni) 2.500e-4) + MONI (x(Ni) 0.5) + LIQUID (x(Ni) 0.61053)
MoNi-01Mor.tdb	1597.88	MONI (x(Ni) 0.5) + LIQUID (x(Ni) 0.67095) + FCC_A1 (x(Ni) 0.73337)
MoNi-01Mor.tdb	1597.88	MONI (x(Ni) 0.5) + LIQUID (x(Ni) 0.67104) + FCC_A1 (x(Ni) 0.73347)
MoNi-05Zho.tdb	1618.28	BCC_A2 (x(Ni) 0.01837) + MONI (x(Ni) 0.4729) + LIQUID (x(Ni) 0.62366)
MoNi-05Zho.tdb	1577.29	MONI (x(Ni) 0.52051) + LIQUID (x(Ni) 0.66218) + FCC_A1 (x(Ni) 0.72937)
MoNi-05Zho.tdb	1200.81	MONI (x(Ni) 0.51763) + NI3X_D0A (x(Ni) 0.75177) + FCC_A1 (x(Ni) 0.78549)
MoNi-05Zho.tdb	1192.88	NI3X_D0A (x(Ni) 0.7526) + NI3X_II_D0A (x(Ni) 0.76105) + FCC_A1 (x(Ni) 0.78994)
MoNi-05Zho.tdb	1153.73	NI3X_II_D0A (x(Ni) 0.76382) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.80995)
MoNi-05Zho.tdb	1034.77	MONI (x(Ni) 0.51331) + MONI2 (x(Ni) 0.66667) + NI3X_D0A (x(Ni) 0.75186)
MoNi-05Zho.tdb	1034.77	MONI (x(Ni) 0.5133) + MONI2 (x(Ni) 0.66667) + NI3X_D0A (x(Ni) 0.75186)
MoNi-05Zho.tdb	909.68	MONI2 (x(Ni) 0.66667) + NI3X_D0A (x(Ni) 0.75258) + NI3X_II_D0A (x(Ni) 0.75683)
MoNi-05Zho.tdb	909.68	MONI2 (x(Ni) 0.66667) + NI3X_D0A (x(Ni) 0.75258) + NI3X_II_D0A (x(Ni) 0.75683)
MoNi-05Zho.tdb	632.03	BCC_A2 (x(Ni) 2.000e-5) + MONI (x(Ni) 0.4982) + MONI2 (x(Ni) 0.66667)
MoNi-05Zho.tdb	632.03	BCC_A2 (x(Ni) 2.000e-5) + MONI (x(Ni) 0.4982) + MONI2 (x(Ni) 0.66667)
MoNi-05Zho.tdb	557.03	NI4X_D1A (x(Ni) 0.8) + NI8X (x(Ni) 0.88889) + FCC_A1 (x(Ni) 0.97995)
MoNi-05Zho.tdb	557.03	NI4X_D1A (x(Ni) 0.8) + NI8X (x(Ni) 0.88889) + FCC_A1 (x(Ni) 0.97989)
MoNi-05Zho.tdb	557.03	NI4X_D1A (x(Ni) 0.8) + NI8X (x(Ni) 0.88889) + FCC_A1 (x(Ni) 0.97999)
MoNi-18Yaq.tdb	1622.56	BCC_A2 (x(Ni) 0.02024) + MONI (x(Ni) 0.48805) + LIQUID (x(Ni) 0.60977)
MoNi-18Yaq.tdb	1593.83	MONI (x(Ni) 0.52395) + LIQUID (x(Ni) 0.647) + FCC_A1 (x(Ni) 0.72562)
MoNi-18Yaq.tdb	1170.73	MONI (x(Ni) 0.50968) + NI3X_D0A (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.78347)
MoNi-18Yaq.tdb	1170.73	MONI (x(Ni) 0.50967) + NI3X_D0A (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.78348)
MoNi-18Yaq.tdb	1141.26	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.81953)
MoNi-18Yaq.tdb	1141.26	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.81942)
MoNi-18Yaq.tdb	1141.26	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.81969)
MoNi-18Yaq.tdb	919.5	BCC_A2 (x(Ni) 8.000e-4) + MONI (x(Ni) 0.46019) + NI3X_D0A (x(Ni) 0.75)
MoNi-18Yaq.tdb	919.5	BCC_A2 (x(Ni) 8.000e-4) + MONI (x(Ni) 0.46019) + NI3X_D0A (x(Ni) 0.75)
MoNi-90Fri.tdb	1638	BCC_A2 (x(Ni) 0.01602) + MONI (x(Ni) 0.49905) + LIQUID (x(Ni) 0.61635)
MoNi-90Fri.tdb	1585.5	MONI (x(Ni) 0.51407) + LIQUID (x(Ni) 0.65884) + FCC_A1 (x(Ni) 0.71485)
MoNi-90Fri.tdb	1180.2	MONI (x(Ni) 0.5204) + NI3X_D0A (x(Ni) 0.75) + FCC_A1 (x(Ni) 0.8035)
MoNi-90Fri.tdb	1141.97	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.82541)
MoNi-90Fri.tdb	1141.97	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.8253)
MoNi-90Fri.tdb	1141.97	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.82528)
MoNi-90Fri.tdb	317.51	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.99369)
MoNi-90Fri.tdb	317.51	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.99371)
MoNi-90Fri.tdb	317.51	NI3X_D0A (x(Ni) 0.75) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.99371)
MoNi-99Cui-LB.tdb	1668.27	BCC_A2 (x(Ni) 0.01568) + MONI (x(Ni) 0.49919) + LIQUID (x(Ni) 0.60969)
MoNi-99Cui-LB.tdb	1595.58	MONI (x(Ni) 0.5251) + LIQUID (x(Ni) 0.67398) + FCC_A1 (x(Ni) 0.73289)
MoNi-99Cui-LB.tdb	1179.7	MONI (x(Ni) 0.53848) + NI3X_D0A (x(Ni) 0.75934) + FCC_A1 (x(Ni) 0.79191)
MoNi-99Cui-LB.tdb	1136.96	NI3X_D0A (x(Ni) 0.76222) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.82329)
MoNi-99Cui-LB.tdb	1136.96	NI3X_D0A (x(Ni) 0.76223) + NI4X_D1A (x(Ni) 0.8) + FCC_A1 (x(Ni) 0.82333)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull MoNi-01Mor · CALPHAD hull MoNi-90Fri · CALPHAD hull MoNi-99Cui-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Mo–Ni system (16)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1619	Liquid + bcc -> δ-NiMo	δ-NiMo: Ni 0.5	experimental	[1] Zhou 2005 cites Grube 1938	Table 4, p. 8, row 3 report
1618	Liquid + bcc -> δ-NiMo	L: Ni 0.624; bcc: Ni 0.018; δ-NiMo: Ni 0.473	model	[1] Zhou 2005	Table 4, p. 8, row 1 report
1577	eutectic: Liquid -> δ-NiMo + fcc	L: Ni 0.662; δ-NiMo: Ni 0.521; fcc: Ni 0.729	model	[1] Zhou 2005	Table 4, p. 8, row 4 report
1574	eutectic: Liquid -> δ-NiMo + fcc	δ-NiMo: Ni 0.5	experimental	[1] Zhou 2005 cites Grube 1938	Table 4, p. 8, row 6 report
1201	fcc + δ-NiMo -> Ni3Mo	fcc: Ni 0.785; δ-NiMo: Ni 0.518; Ni3Mo: Ni 0.752	model	[1] Zhou 2005	Table 4, p. 8, row 7 report
1200	fcc + δ-NiMo -> Ni3Mo	δ-NiMo: Ni 0.5; Ni3Mo: Ni 0.75	experimental	[1] Zhou 2005 cites Grube 1938	Table 4, p. 8, row 9 report
1198	fcc + δ-NiMo -> Ni3Mo	fcc: Ni 0.786; δ-NiMo: Ni 0.518; Ni3Mo: Ni 0.76	model	[1] Zhou 2005	Table 4, p. 8, row 8 report
1151	fcc + Ni3Mo -> Ni4Mo	fcc: Ni 0.808; Ni3Mo: Ni 0.756; Ni4Mo: Ni 0.8	model	[1] Zhou 2005	Table 4, p. 8, row 10 report
1150	fcc + Ni3Mo -> Ni4Mo	fcc: Ni 0.81; Ni3Mo: Ni 0.764; Ni4Mo: Ni 0.8	model	[1] Zhou 2005	Table 4, p. 8, row 11 report
1148	fcc + Ni3Mo -> Ni4Mo	Ni3Mo: Ni 0.75; Ni4Mo: Ni 0.8	experimental	[1] Zhou 2005 cites Grube 1938	Table 4, p. 8, row 12 report
1040	δ-NiMo + Ni3Mo -> Ni2Mo	δ-NiMo: Ni 0.514; Ni3Mo: Ni 0.758; Ni2Mo: Ni 0.667	model	[1] Zhou 2005	Table 4, p. 8, row 14 report
1035	δ-NiMo + Ni3Mo -> Ni2Mo	δ-NiMo: Ni 0.513; Ni3Mo: Ni 0.752; Ni2Mo: Ni 0.667	model	[1] Zhou 2005	Table 4, p. 8, row 13 report
1033	δ-NiMo + Ni3Mo -> Ni2Mo	δ-NiMo: Ni 0.5; Ni3Mo: Ni 0.75; Ni2Mo: Ni 0.666667	experimental	[1] Zhou 2005 cites Pearson 1981	Table 4, p. 8, row 15 report
631	δ-NiMo -> bcc + Ni2Mo	δ-NiMo: Ni 0.498; bcc: Ni 0; Ni2Mo: Ni 0.667	model	[1] Zhou 2005	Table 4, p. 8, row 19 report
557	fcc + Ni4Mo -> Ni8Mo	fcc: Ni 0.98; Ni4Mo: Ni 0.8; Ni8Mo: Ni 0.889	model	[1] Zhou 2005	Table 4, p. 8, row 16 report
555	fcc + Ni4Mo -> Ni8Mo	Ni4Mo: Ni 0.8; Ni8Mo: Ni 0.888889	experimental	[1] Zhou 2005 cites Mayer 1985 doi	Table 4, p. 8, row 18 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Mo–Ni system (39)
Phase	Value	T (K)	Class	Source	Location
Mo3Ni	18.85 kJ/mol-atom		DFT	[2] Zhou 2009	Table 6, p. 7, row 39 report
Ni0.25Mo0.75	-4.063 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 31 report
Ni0.25Mo0.75	9.145 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 28 report
Ni0.50Mo0.50	-6.405 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 32 report
Ni0.75Mo0.25	-4.663 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 33 report
Ni0.75Mo0.25	5.083 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 30 report
Ni2Mo	-8.34 kJ/mol (basis unstated)		DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 40 report
Ni3Mo	-8.54 kJ/mol (basis unstated)		DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 42 report
Ni3Mo	-1.86 kJ/mol-atom		DFT	[2] Zhou 2009	Table 6, p. 7, row 38 report
Ni3Mo	2.84 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 44 report
Ni3Mo	17.06 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 43 report
Ni3Mo	42.65 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 41 report
Ni4Mo	-7.55 kJ/mol (basis unstated)		DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 45 report
Ni8Mo	-4.44 kJ/mol (basis unstated)		DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 46 report
Ni₀.₂₅Mo₀.₇₅	-4.063 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 31 report
Ni₀.₂₅Mo₀.₇₅	9.145 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 28 report
Ni₀.₅₀Mo₀.₅₀	-6.405 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 32 report
Ni₀.₅₀Mo₀.₅₀	10.45 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 29 report
Ni₀.₇₅Mo₀.₂₅	-4.663 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 33 report
Ni₀.₇₅Mo₀.₂₅	5.083 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 30 report
Ni₂Mo	-8.34 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 40 report
Ni₃Mo	-8.54 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 42 report
Ni₃Mo	2.84 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 44 report
Ni₃Mo	17.06 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 43 report
Ni₃Mo	42.65 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 41 report
Ni₄Mo	-7.55 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 45 report
Ni₈Mo	-4.44 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 46 report
δ-NiMo	-4.49 kJ/mol (basis unstated)		DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 35 report
δ-NiMo	-4.49 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005 cites Wang 2005 doi	Table 2, p. 4, row 35 report
δ-NiMo	-2.8 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 36 report
δ-NiMo	-2.8 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 36 report
δ-NiMo	-2.24 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 34 report
δ-NiMo	-2.24 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 34 report
δ-NiMo	-0.89 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 37 report
δ-NiMo	-0.89 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 37 report
δ-NiMo	-0.1 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 38 report
δ-NiMo	-0.1 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 38 report
δ-NiMo	1.98 kJ/mol (basis unstated)	0	DFT	[1] Zhou 2005	Table 2, p. 4, row 39 report
δ-NiMo	1.98 kJ/mol (basis unstated)		DFT	[1] Zhou 2005	Table 2, p. 4, row 39 report

Other properties

Phase transition (1)

Phase transition, Mo–Ni system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	1900 K	1900	other	experimental	[3] Morishita 2001 cites Takagi 1987	p. 1 report	The ternary intermetallic compound, NiMo 2 B 2 has a high incongruent melting point about 1900 K, high hardness and corrosion resistance against hydrochloric and hydrosulfuric acid aqueous solution.

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

S.H. Zhou, Y. Wang, C. Jiang, J.Z. Zhu, L.-Q. Chen, Z.-K. Liu, First-principles calculations and thermodynamic modeling of the Ni–Mo system, Materials Science and Engineering: A 397, 288-296 (2005). doi:10.1016/j.msea.2005.02.037
S.H. Zhou, Y. Wang, L.-Q. Chen, Z.-K. Liu, R.E. Napolitano, Solution-based thermodynamic modeling of the Ni–Ta and Ni–Mo–Ta systems using first-principle calculations, Calphad 33, 631-641 (2009). doi:10.1016/j.calphad.2009.06.006
M. Morishita, K. Koyama, S. Yagi, G. Zhang, Calculated phase diagram of the Ni–Mo–B ternary system, Journal of Alloys and Compounds 314, 212-218 (2001). doi:10.1016/s0925-8388(00)01258-5

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}