# Ni–Sb–Sn system

> Ni–Sb–Sn system: 92 accepted literature values (phase equilibrium 50, phase transition 35, invariant reaction 7) and 0 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

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92 accepted literature values from 1 paper(s) (experimental 85, unspecified 7); 0 calculated phase diagram(s). 75 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/NI-SB-SN.json) · [CSV](https://data.orchid-project.org/systems/NI-SB-SN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#NI-SB-SN) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/NI-SB-SN.html) · [Markdown](https://data.orchid-project.org/systems/NI-SB-SN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 85 |
| unspecified | 7 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 7 |
| phase transition | 35 |
| phase equilibrium | 50 |

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Ni–Sb–Sn system (7)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 759.35 | peritectic: P1: L+NiSb2+ζ->T | L: Ni 0.028, Sb 0.504, Sn 0.468; NiSb2: Ni 0.333, Sb 0.624, Sn 0.043; ζ: Ni 0.475, Sb 0.497, Sn 0.028; T: Ni 0.245, Sb 0.542, Sn 0.213 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 7; `ORC-LAXF4Z5TYF` |  |
| 743.05 | quasi-peritectic: U6: L+NiSb2->(Sb)+T | L: Ni 0.017, Sb 0.572, Sn 0.411; NiSb2: Ni 0.333, Sb 0.637, Sn 0.03; (Sb): Sb 0.886, Sn 0.114; T: Ni 0.245, Sb 0.56, Sn 0.195 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 6; `ORC-32IFBTIIAM` |  |
| 697.65 | quasi-peritectic: U5: L+(Sb)->T+SbSn | L: Ni 0.01, Sb 0.5, Sn 0.49; (Sb): Sb 0.845, Sn 0.155; T: Ni 0.245, Sb 0.539, Sn 0.216; SbSn: Ni 0.007, Sb 0.606, Sn 0.387 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 5; `ORC-4HHZXMMLQY` |  |
| 629.25 | quasi-peritectic: U4: L+ζ->T+Ni3Sn4 | L: Ni 0.012, Sb 0.118, Sn 0.87; ζ: Ni 0.497, Sb 0.312, Sn 0.191; T: Ni 0.245, Sb 0.44, Sn 0.315; Ni3Sn4: Ni 0.402, Sb 0.11, Sn 0.488 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 4; `ORC-4XWKYRHQUK` |  |
| 520.45 | quasi-peritectic: U3: L+T->SbSn+Ni3Sn4 | L: Ni 0.001, Sb 0.03, Sn 0.969; T: Ni 0.245, Sb 0.423, Sn 0.332; SbSn: Ni 0.105, Sb 0.394, Sn 0.501; Ni3Sn4: Ni 0.401, Sb 0.099, Sn 0.5 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 3; `ORC-DXJ566PWVB` |  |
| 518.85 | quasi-peritectic: U2: L+Sb2Sn3->(Sn)+SbSn | L: Ni 0, Sb 0.089, Sn 0.911; Sb2Sn3: Ni 0.002, Sb 0.398, Sn 0.6; Sn: Ni 0, Sb 0.107, Sn 0.893; SbSn: Ni 0.006, Sb 0.461, Sn 0.533 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 2; `ORC-6GX46RZPOI` |  |
| 509.25 | quasi-peritectic: U1: L+SbSn->(Sn)+Ni3Sn4 | L: Ni 0.001, Sb 0.024, Sn 0.975; SbSn: Ni 0.106, Sb 0.393, Sn 0.501; (Sn): Ni 0, Sb 0.035, Sn 0.965; Ni3Sn4: Ni 0.401, Sb 0.098, Sn 0.501 | unspecified | [1] Kroupa 2014 | Table 4, p. 11, row 1; `ORC-WRPFV2BBQX` |  |

## Other properties

### Phase transition (35)

Table: Phase transition, Ni–Sb–Sn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 960.15 K | 960.15 | other: Section Ni3Sn4–Sb, 79.4 (Liquidus, Cooling); _alloy: Sb 0.794_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 110; `ORC-LPW72LE47S` |  |
| Phase transition | 984.15 K | 984.15 | other: Section Ni3Sn2–Sb, 85.0 (Liquidus, Cooling); _alloy: Sb 0.85_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 70; `ORC-5VXTYNKX5E` |  |
| Phase transition | 992.15 K | 992.15 | other: Section Ni3Sn4–Sb, 72.4 (Liquidus, Cooling); _alloy: Sb 0.724_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 105; `ORC-DOKN375OU7` |  |
| Phase transition | 992.15 K | 992.15 | other: Section Ni3Sn–Sb, 90.0 (Liquidus, Cooling); _alloy: Sb 0.9_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 38; `ORC-JD4Z5OV6ME` |  |
| Phase transition | 1020.15 K | 1020.15 | other: Section Ni3Sn2–Sb, 85.0 (Liquidus, Heating); _alloy: Sb 0.85_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 69; `ORC-KBHOLCB26Y` |  |
| Phase transition | 1023.15 K | 1023.15 | other: Section Ni3Sn–Sb, 82.0 (Liquidus, Cooling); _alloy: Sb 0.82_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 33; `ORC-DLZOJWWNB3` |  |
| Phase transition | 1046.15 K | 1046.15 | other: Section Ni3Sn4–Sb, 79.4 (Liquidus, Heating); _alloy: Sb 0.794_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 109; `ORC-QIPB3R74ZX` |  |
| Phase transition | 1073.15 K | 1073.15 | other: Section Ni3Sn4–Sb, 72.4 (Liquidus, Heating); _alloy: Sb 0.724_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 104; `ORC-4B5MVOZ2N7` |  |
| Phase transition | 1093.15 K | 1093.15 | other: Section Ni3Sn2–Sb, 73.0 (Liquidus, Cooling); _alloy: Sb 0.73_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 66; `ORC-ELU4KLTN6P` |  |
| Phase transition | 1094.15 K | 1094.15 | other: Section Ni3Sn–Sb, 77.8 (Liquidus, Cooling); _alloy: Sb 0.778_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 28; `ORC-2YGTSKLNQL` |  |
| Phase transition | 1106.15 K | 1106.15 | other: Section Ni3Sn4–Sb, 64.2 (Liquidus, Cooling); _alloy: Sb 0.642_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 99; `ORC-Y4MCLCCPQQ` |  |
| Phase transition | 1126.15 K | 1126.15 | other: Section Ni3Sn–Sb, 90.0 (Liquidus, Heating); _alloy: Sb 0.9_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 37; `ORC-JSCWBTBUEX` |  |
| Phase transition | 1127.15 K | 1127.15 | other: Section Ni3Sn4–Sb, 64.2 (Liquidus, Heating); _alloy: Sb 0.642_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 98; `ORC-HV435BB2DK` |  |
| Phase transition | 1132.15 K | 1132.15 | other: Section Ni3Sn–Sb, 82.0 (Liquidus, Heating); _alloy: Sb 0.82_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 32; `ORC-3LK7XOTWBW` |  |
| Phase transition | 1136.15 K | 1136.15 | other: Section Ni3Sn4–Sb, 56.0 (Liquidus, Cooling); _alloy: Sb 0.56_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 92; `ORC-JXFICCRJ7M` |  |
| Phase transition | 1167.15 K | 1167.15 | other: Section Ni3Sn2–Sb, 73.0 (Liquidus, Heating); _alloy: Sb 0.73_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 65; `ORC-FVE3C6I3DO` |  |
| Phase transition | 1170.15 K | 1170.15 | other: Section Ni3Sn4–Sb, 48.0 (Liquidus, Cooling); _alloy: Sb 0.48_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 85; `ORC-AMOGLH5RWQ` |  |
| Phase transition | 1170.15 K | 1170.15 | other: Section Ni3Sn–Sb, 72.8 (Liquidus, Cooling); _alloy: Sb 0.728_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 23; `ORC-QUAA67U46Y` |  |
| Phase transition | 1173.15 K | 1173.15 | other: Section Ni3Sn4–Sb, 56.0 (Liquidus, Heating); _alloy: Sb 0.56_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 91; `ORC-MPAEMRQ4PO` |  |
| Phase transition | 1173.15 K | 1173.15 | other: Section Ni3Sn–Sb, 77.8 (Liquidus, Heating); _alloy: Sb 0.778_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 27; `ORC-OSZ4HQ3CUV` |  |
| Phase transition | 1197.15 K | 1197.15 | other: Section Ni3Sn2–Sb, 62.0 (Liquidus, Cooling); _alloy: Sb 0.62_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 60; `ORC-LMFRECXWIR` |  |
| Phase transition | 1202.15 K | 1202.15 | other: Section Ni3Sn–Sb, 72.8 (Liquidus, Heating); _alloy: Sb 0.728_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 22; `ORC-WV66EIHRSE` |  |
| Phase transition | 1212.15 K | 1212.15 | other: Section Ni3Sn4–Sb, 48.0 (Liquidus, Heating); _alloy: Sb 0.48_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 84; `ORC-D4OBNUUHBK` |  |
| Phase transition | 1218.15 K | 1218.15 | other: Section Ni3Sn4–Sb, 40.0 (Liquidus, Cooling); _alloy: Sb 0.4_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 78; `ORC-BGMW2DYKWB` |  |
| Phase transition | 1219.15 K | 1219.15 | other: Section Ni3Sn–Sb, 69.0 (Liquidus, Cooling); _alloy: Sb 0.69_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 17; `ORC-GZLLW7NV6H` |  |
| Phase transition | 1242.15 K | 1242.15 | other: Section Ni3Sn4–Sb, 40.0 (Liquidus, Heating); _alloy: Sb 0.4_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 77; `ORC-5C6L2QBBS2` |  |
| Phase transition | 1243.15 K | 1243.15 | other: Section Ni3Sn–Sb, 69.0 (Liquidus, Heating); _alloy: Sb 0.69_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 16; `ORC-DFMV6B5JI7` |  |
| Phase transition | 1244.15 K | 1244.15 | other: Section Ni3Sn–Sb, 60.0 (Liquidus, Heating); _alloy: Sb 0.6_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 10; `ORC-3P32MNJ7L5` |  |
| Phase transition | 1251.15 K | 1251.15 | other: Section Ni3Sn2–Sb, 53.0 (Liquidus, Cooling); _alloy: Sb 0.53_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 50; `ORC-2O23NOYULY` |  |
| Phase transition | 1273.15 K | 1273.15 | other: Section Ni3Sn–Sb, 60.0 (Liquidus, Cooling); _alloy: Sb 0.6_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 11; `ORC-AGQPXUIYMV` |  |
| Phase transition | 1280.15 K | 1280.15 | other: Section Ni3Sn2–Sb, 53.0 (Liquidus, Heating); _alloy: Sb 0.53_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 49; `ORC-TRZI3JTCCZ` |  |
| Phase transition | 1288.15 K | 1288.15 | other: Section Ni3Sn–Sb, 43.0 (Liquidus, Cooling); _alloy: Sb 0.43_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 5; `ORC-RLVIZ2PCCJ` |  |
| Phase transition | 1299.15 K | 1299.15 | other: Section Ni3Sn–Sb, 43.0 (Liquidus, Heating); _alloy: Sb 0.43_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 4; `ORC-DBZTBCAMAI` |  |
| Phase transition | 1355.15 K | 1355.15 | other: Section Ni3Sn2–Sb, 35.0 (Liquidus, Cooling); _alloy: Sb 0.35_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 44; `ORC-6UEDOMYGPM` |  |
| Phase transition | 1361.15 K | 1361.15 | other: Section Ni3Sn2–Sb, 35.0 (Liquidus, Heating); _alloy: Sb 0.35_ | experimental | [1] Kroupa 2014 | Table 3, p. 9, row 43; `ORC-3S3XEFXN23` |  |

### Phase equilibrium (50)

Table: Phase equilibrium, Ni–Sb–Sn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase composition |  | 673.15 | (Sb) + NiSb2 + T; _(Sb): Ni 0, Sb 0.909, Sn 0.091; NiSb2: Ni 0.327, Sb 0.632, Sn 0.041; T: Ni 0.236, Sb 0.6, Sn 0.164_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 36; `ORC-GIN7ZU6NFE` |  |
| Phase composition |  | 673.15 | (Sb) + NiSb2 + T; _(Sb): Ni 0, Sb 0.909, Sn 0.091; NiSb2: Ni 0.327, Sb 0.632, Sn 0.041; T: Ni 0.236, Sb 0.6, Sn 0.164_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 1; `ORC-TSIXFCKAON` |  |
| Phase composition |  | 673.15 | (Sb) + T + SbSn; _(Sb): Ni 0, Sb 0.877, Sn 0.123; T: Ni 0.244, Sb 0.563, Sn 0.193; SbSn: Ni 0, Sb 0.619, Sn 0.381_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 33; `ORC-DO3QSEKDIP` |  |
| Phase composition |  | 673.15 | (Sb) + T + SbSn; _(Sb): Ni 0, Sb 0.874, Sn 0.126; T: Ni 0.244, Sb 0.563, Sn 0.193; SbSn: Ni 0, Sb 0.62, Sn 0.38_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 32; `ORC-USJL7QJAJM` |  |
| Phase composition |  | 673.15 | (Sn) + T + SbSn; _(Sn): Ni 0.012, Sb 0.862, Sn 0.126; T: Ni 0.244, Sb 0.512, Sn 0.244; SbSn: Ni 0, Sb 0.497, Sn 0.503_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 34; `ORC-76RPNCQ3GY` |  |
| Phase composition |  | 673.15 | (Sn) + T + ζ; _(Sn): Ni 0.012, Sb 0.126, Sn 0.862; T: Ni 0.24, Sb 0.469, Sn 0.291; ζ: Ni 0.486, Sb 0.368, Sn 0.146_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 39; `ORC-2ILSTEWJKF` |  |
| Phase composition |  | 673.15 | (Sn) + T + ζ; _(Sn): Ni 0.012, Sb 0.126, Sn 0.862; T: Ni 0.24, Sb 0.469, Sn 0.291; ζ: Ni 0.486, Sb 0.368, Sn 0.146_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 4; `ORC-QTOJ57NKYG` |  |
| Phase composition |  | 673.15 | Ni3Sn4 + ζ + (Sn); _Ni3Sn4: Ni 0.419, Sb 0.063, Sn 0.518; ζ: Ni 0.495, Sb 0.28, Sn 0.225; (Sn): Ni 0.012, Sb 0.126, Sn 0.862_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 43; `ORC-2DXLP3AFAZ` |  |
| Phase composition |  | 673.15 | Ni3Sn4 + ζ + (Sn); _Ni3Sn4: Ni 0.419, Sb 0.063, Sn 0.518; ζ: Ni 0.495, Sb 0.28, Sn 0.225; (Sn): Ni 0.012, Sb 0.126, Sn 0.862_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 8; `ORC-6JMC62ZY5B` |  |
| Phase composition |  | 673.15 | T; _T: Ni 0.245, Sb 0.559, Sn 0.196_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 2; `ORC-QAZRRAYJHK` |  |
| Phase composition |  | 673.15 | T; _T: Ni 0.245, Sb 0.559, Sn 0.196_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 37; `ORC-WWF5PZB4HA` |  |
| Phase composition |  | 673.15 | T + ζ; _T: Ni 0.242, Sb 0.492, Sn 0.266; ζ: Ni 0.488, Sb 0.41, Sn 0.102_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 9; `ORC-F3EWZP24LN` |  |
| Phase composition |  | 673.15 | T + ζ; _T: Ni 0.245, Sb 0.517, Sn 0.238; ζ: Ni 0.481, Sb 0.426, Sn 0.093_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 6; `ORC-FAFPQ24JMO` |  |
| Phase composition |  | 673.15 | T + ζ; _T: Ni 0.245, Sb 0.517, Sn 0.238; ζ: Ni 0.481, Sb 0.426, Sn 0.093_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 41; `ORC-FXWPKSOZFB` |  |
| Phase composition |  | 673.15 | T + ζ; _T: Ni 0.242, Sb 0.492, Sn 0.266; ζ: Ni 0.488, Sb 0.41, Sn 0.102_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 44; `ORC-MVXKA5QIHZ` |  |
| Phase composition |  | 673.15 | T + ζ + (Sn); _T: Ni 0.241, Sb 0.466, Sn 0.293; ζ: Ni 0.486, Sb 0.368, Sn 0.146; (Sn): Ni 0.012, Sb 0.126, Sn 0.862_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 7; `ORC-2SSA7QMPYI` |  |
| Phase composition |  | 673.15 | T + ζ + (Sn); _T: Ni 0.241, Sb 0.466, Sn 0.293; ζ: Ni 0.486, Sb 0.368, Sn 0.146; (Sn): Ni 0.012, Sb 0.126, Sn 0.862_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 42; `ORC-KEPRXPHTA3` |  |
| Phase composition |  | 673.15 | T + ζ + NiSb2; _T: Ni 0.245, Sb 0.591, Sn 0.164; ζ: Ni 0.464, Sb 0.49, Sn 0.046; NiSb2: Ni 0.327, Sb 0.63, Sn 0.043_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 40; `ORC-2XCBXPCBDF` |  |
| Phase composition |  | 673.15 | T + ζ + NiSb2; _T: Ni 0.245, Sb 0.591, Sn 0.164; ζ: Ni 0.464, Sb 0.49, Sn 0.046; NiSb2: Ni 0.327, Sb 0.63, Sn 0.043_ | experimental | [1] Kroupa 2014 | Table 2, p. 5, row 5; `ORC-5O2GQYX3D7` |  |
| Phase composition |  | 773.15 | (Ni) + δ-Ni3Sb; _(Ni): Ni 0.909, Sb 0.047, Sn 0.044; δ-Ni3Sb: Ni 0.755, Sb 0.121, Sn 0.124_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 26; `ORC-RZJEXDRQWC` |  |
| Phase composition |  | 773.15 | Ni3Sn LT + ζ; _Ni3Sn LT: Ni 0.75, Sb 0.004, Sn 0.246; ζ: Ni 0.615, Sb 0.007, Sn 0.378_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 30; `ORC-K5ZFFIWEU2` |  |
| Phase composition |  | 773.15 | δ-Ni3Sb + Unknown + ζ; _δ-Ni3Sb: Ni 0.746, Sb 0.179, Sn 0.075; Unknown: Ni 0.668, Sb 0.221, Sn 0.111; ζ: Ni 0.586, Sb 0.272, Sn 0.142_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 27; `ORC-Y6EBYQ3H2N` |  |
| Phase composition |  | 773.15 | δ-Ni3Sb + ζ; _δ-Ni3Sb: Ni 0.747, Sb 0.131, Sn 0.123; ζ: Ni 0.62, Sb 0.182, Sn 0.198_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 28; `ORC-GJWE4TE4AQ` |  |
| Phase composition |  | 773.15 | δ-Ni3Sb + ζ; _δ-Ni3Sb: Ni 0.748, Sb 0.08, Sn 0.172; ζ: Ni 0.616, Sb 0.115, Sn 0.268_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 29; `ORC-VAPJOHQREN` |  |
| Phase composition |  | 773.15 | δ-Ni3Sb + ζ + T; _δ-Ni3Sb: Ni 0.745, Sb 0.148, Sn 0.107; ζ: Ni 0.589, Sb 0.235, Sn 0.176; T: Ni 0.589, Sb 0.235, Sn 0.176_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 31; `ORC-73II3KZF7A` |  |
| Phase composition |  | 1173.15 | Ni + δ-Ni3Sb; _Ni: Ni 0.912, Sb 0.088, Sn 0; δ-Ni3Sb: Ni 0.738, Sb 0.262, Sn 0_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 25; `ORC-RJ3MO6MOL4` |  |
| Phase composition |  | 1173.15 | Ni3Sn LT; _Ni3Sn LT: Ni 0.745, Sb 0, Sn 0.255_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 21; `ORC-DJLXNG632F` |  |
| Phase composition |  | 1173.15 | Ni3Sn LT + ζ; _Ni3Sn LT: Ni 0.73, Sb 0.07, Sn 0.2; ζ: Ni 0.615, Sb 0.05, Sn 0.335_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 20; `ORC-4BPEMUYDKU` |  |
| Phase composition |  | 1173.15 | Ni3Sn LT + ζ; _Ni3Sn LT: Ni 0.74, Sb 0.02, Sn 0.24; ζ: Ni 0.61, Sb 0.02, Sn 0.37_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 18; `ORC-CHQGXDEE2Q` |  |
| Phase composition |  | 1173.15 | Ni3Sn LT + ζ; _Ni3Sn LT: Ni 0.732, Sb 0.054, Sn 0.214; ζ: Ni 0.616, Sb 0.036, Sn 0.348_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 19; `ORC-R7VNFOMRN5` |  |
| Phase composition |  | 1173.15 | δ-Ni3Sb; _δ-Ni3Sb: Ni 0.748, Sb 0.125, Sn 0.127_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 23; `ORC-MZQTX2XYNI` |  |
| Phase composition |  | 1173.15 | δ-Ni3Sb + (Ni); _δ-Ni3Sb: Ni 0.747, Sb 0.19, Sn 0.063; (Ni): Ni 0.905, Sb 0.07, Sn 0.025_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 24; `ORC-VEWKQH6DIW` |  |
| Phase composition |  | 1173.15 | δ-Ni3Sb + ζ; _δ-Ni3Sb: Ni 0.746, Sb 0.063, Sn 0.191; ζ: Ni 0.617, Sb 0.079, Sn 0.304_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 22; `ORC-DGRDX27NEW` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.6, Sb 0.078, Sn 0.322_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 11; `ORC-7OUFXASNUV` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.577, Sb 0.101, Sn 0.322_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 8; `ORC-BMRZCLY572` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.562, Sb 0.049, Sn 0.389_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 7; `ORC-EGSKF5ZT5I` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.576, Sb 0.118, Sn 0.306_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 12; `ORC-KAQ66CVRRT` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.556, Sb 0.064, Sn 0.38_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 16; `ORC-KKYVGTVGLW` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.547, Sb 0.271, Sn 0.182_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 13; `ORC-RAMGTKO744` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.536, Sb 0.107, Sn 0.357_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 17; `ORC-SKYXHSOLMH` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.593, Sb 0.034, Sn 0.373_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 6; `ORC-SOAE2QA3AW` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.554, Sb 0.182, Sn 0.264_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 9; `ORC-W3W5DO6L2T` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.575, Sb 0.028, Sn 0.397_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 15; `ORC-WU6FDGCKGM` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.54, Sb 0.32, Sn 0.14_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 10; `ORC-Y75KIZFD6U` |  |
| Phase composition |  | 1173.15 | ζ; _ζ: Ni 0.514, Sb 0.395, Sn 0.091_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 14; `ORC-ZDIKQEVNGG` |  |
| Phase composition |  | 1273.15 | Ni + δ-Ni3Sb; _Ni: Ni 0.905, Sb 0.052, Sn 0.043; δ-Ni3Sb: Ni 0.731, Sb 0.148, Sn 0.121_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 1; `ORC-XKRROZOFPA` |  |
| Phase composition |  | 1273.15 | δ-Ni3Sb; _δ-Ni3Sb: Ni 0.73, Sb 0.207, Sn 0.063_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 2; `ORC-DC7HITQ2PD` |  |
| Phase composition |  | 1273.15 | δ-Ni3Sb; _δ-Ni3Sb: Ni 0.748, Sb 0.081, Sn 0.171_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 4; `ORC-FE5ZOR3CTO` |  |
| Phase composition |  | 1273.15 | δ-Ni3Sb; _δ-Ni3Sb: Ni 0.75, Sb 0.137, Sn 0.113_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 3; `ORC-G6E2THYKD2` |  |
| Phase composition |  | 1273.15 | δ-Ni3Sb + ζ; _δ-Ni3Sb: Ni 0.725, Sb 0.169, Sn 0.106; ζ: Ni 0.612, Sb 0.16, Sn 0.228_ | experimental | [1] Kroupa 2014 | Table 2, p. 4, row 5; `ORC-SJPSICKGBM` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Ales Kroupa, Ratikanta Mishra, Divakar Rajamohan, Hans Flandorfer, Andrew Watson, Herbert Ipser, Phase equilibria in the ternary Ni–Sb–Sn system: Experiments and calculations, Calphad 45, 151-166 (2014). [doi:10.1016/j.calphad.2013.11.007](https://doi.org/10.1016/j.calphad.2013.11.007)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).